PINNAACLE CLASSES

with a current of 10 amperes for 109 minutes (1

46. At molar conductance of 0.1 molar aqueous
solution of ammonium hydroxide is 9.54 Faraday ; Atomic mass of Co )

and at infinite dilution its molar (a) 4.0 (b) 20.0

(c) 40.0 (d) 0.66(KarnatakaNEET2013)
conductance is 238 . The degree of
ionisation of ammonium hydroxide at the same 51. Limiting molar conductivity of NHOH
concentration and temperature is
(a) 4.008% (b) 40.800% is equal to
(c) 2.080% (d) 20.800% (NEET2013)
(a)
47. A button cell used in watches function as following:
b

C
If half-cell potentials are
d (2012)

52. Standard reduction potentials of the half reactions

are given below:
The cell potential will be
(a) 0.84 V (b) 1.34 V
(c) 1.10 V (d) 0.42 V (NEET2013)

48. A hydrogen gas electrode is made by dipping

platinum wire in a solution ofHCl of and

by-passing hydrogen gas around the platinum wire
at one atm pressure. The oxidation potential of
electrode would be
The strongest oxidising and reducing agents
(a) 0.118 V (b) 1.18 V respectively are
(c) 0.059 V (d) 0.59 V (NEET2013)
(a) and
49. Consider the half‐cell reduction reaction (b) and

(c) and

(d) and (Mains2012)

The for the reaction

and possibility of the

forward reaction are respectively 53. Molar conductivities at infinite dilution

(a) and yes ofNaCl, HC1 and are 126.4, 425.9

(b) and yes
(c) and no and 91.0 respectively. for
(d) and no (KarnatakaNEET2013)
will be
50. How many grams of cobalt metal will be deposited
(a) 425.5
when a solution ofcobalt (II) chloride is electrolyzed
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 PINNAACLE CLASSES

(b) 180.5 (c) (d) (2011)

(c) 290.8
(d) 390.5 (Mains2012) 58. A solution contains and ions. This

solution was treated with iodine at for

54. The Gibb’s energy for the decomposition of
and for
at is as follows V. The favourable redox reaction is

(a) will be reduced to

(b) there will be no redox reaction
The potential difference needed for the electrolytic
(c) will be oxidised to
reduction of aluminium oxide at is at
least (d) will be oxidised to (Mains2011)
(a) 4.5 V (b) 3.0 V
(c) 2.5 V (d) 5.0 V (Mains2012) 59. For the reduction of silver ions with copper metal,
the standard cell potential was found to

at . The value of standard Gibbs

55. Standard electrode potentials of three metals

and are and—3.0 V energy, will be

respectively. The reducing power of these metals
will be (a) (b)
(c) (d) (2010)
(a)
(b) 60. An increase in equivalent conductance of a strong
(c) electrolyte with dilution is mainly due to
(d) (2011) (a) increase in ionic mobility of ions
(b) 100% ionisation of electrolyte at normal dilution
(c) increase in both i.e., number of ions and ionic
56. The electrode potentials for mobility of ions
(d) increase in number of ions. (2010)
and are and
61. Consider the following relations for emf of an
respectively The value of will be electrochemical cell(i) EMF ofcell (Oxidation
potential ofanode) ‐(Reduction potential of
(a) 0.500 V (b) 0.325 V
(c) 0.650 V (d) 0.150 V (2011) cathode)(ii) EMF ofcell (Oxidation potential

ofanode) ( Reduction potential of cathode)(iii)

57. Standard electrode potential for couple EMF of cell (Reductional potential of anode)

is and that for the couple is— (Reduction potential of cathode) (iv) EMF ofcell
O.74 V These two couples in their standard state (Oxidation potential ofanode) ‐(Oxidation potential
are connected to make a cell. The cell potential will of cathode)Which of the above relations are
be correct?
(a) (iii) and (i)
(a) (b)
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 PINNAACLE CLASSES

(b) (i) and (ii) 66. Kohlrausch’s law states that at

(c) (iii) and (iv)
(a) Infinite dilution, each ion makes definite
(d) (ii) and (iv) (Mains2010)
contribution to conductance of an electrolyte whatever
be the nature of the other ion of the electrolyte
(b) Infinite dilution, each ion makes definite
62. Given:(i) (ii)
contribution to equivalent conductance of an
electrolyte, whatever be the nature of the other ion of
Electrode potential,
the electrolyte
for the reaction, , will be (c) Finite dilution, each ion makes definite contribution
to equivalent conductance of an electrolyte, whatever
(a) 0.90 V (b) 0.30 V be the nature of the other ion of the electrolyte
(c) 0.38 V (d) 0.52 V (2009) (d) Infinite dilution each ion makes definite contribution
to equivalent conductance of an electrolyte depending
on the nature of the other ion of the electrolyte. (2008)
63. is reduced by electrolysis at low potentials
67. Standard free energies of formation (in kJ/mol)
and high currents. amperes of current
at298 are and for
is passed through molten for 6 hours, what
mass of aluminium is produced? (Assume 100%
and pentane (g) respectively The value of

current efficiency, at. mass of Al .

for the pentane‐oxygen fuel cell is
(a) 8. (b) (a) 1.0968 V (b) 0.0968 V
(c) 1.968 V (d) 2.0968 V (2008)
(c) 1. (d) (2009)
68. The equilibrium constant of the reaction:
64. The equivalent conductance of M/32 solution of a

weak monobasic acid is 8.0 mho and at ; at

298 is
infinite dilution is 400 mhos . The dissociation
constant of this acid is
(a) (b)
(a) (b) (c) (d) (2007)
(c) (d) (2009)

69. The efficiency of a fuel cell is given by

65. On the basis of the following values, the
(a) (b)
strongest oxidizing agent is
(c) (d) (2007)

70. A hypothetical electrochemical cell is shown below.

;

A
(a) (b)
The emfmeasured V. The cell reaction is
(c) (d) (2008)
(a)
(b)
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 PINNAACLE CLASSES

(c)
75. The e.m.f . of a Daniell cell at 298 is
(d) the cell reaction cannot be predicted. (2006)

71. and , the When the concentration of is 1.0 and that

standard EMF ofthe reaction of is 0.01 , the e.m. . changed to

will be
What is the relationship between and ?
(a) 0. (b) 0.
(a) (b)
(c) 1.653 V (d) 1.212 V (2006)
(c) (d) (2003)

72. 4.5 of aluminium (at. mass 27 ) is 76. On the basis of the information available from the
deposited at cathode from solution by a
reaction,
certain quantity of electric charge. The volume of

hydrogen produced at STP from ions in of the minimum e.m.f.

solution by the same quantity of electric charge will
be required to carry out an electrolysis is

(a) 44.8 (b) 22.4

(c) 11.2 (d) 5.6 (2005)
(a) 2.14 V (b) 4.28 V
(c) 6.42 V (d) 8.56 V (2003)
73. The mass of carbon anode consumed (giving only
carbon dioxide) in the production of 270 kg of
aluminium metal from bauxite by the Hall process
77. In electrolysis of when Pt electrode is taken
is
(a) 270 kg then is liberated at cathode while with Hg
(b) 540 kg cathode it forms sodium amalgam
(c) 90 kg
(a) Hg is more inert than Pt
(d) 180 kg (Atomic mass: Al ) (2005)
(b) More voltage is required to reduce at Hg than
at Pt
74. The standard e.m.f of a galvanic cell involving cell
(c) Na is dissolved in Hg while it does not dissolve in
reaction with is found to be 0.295 V at Pt
C. The equilibrium constant of the reaction would (d) Conc. ions is larger when Pt electrode is
be
taken. (2002)
(a)
(b) 78. Standard electrode potentials are ;
(c)
and
(d) Given and Fe blocks are kept together, then
(2004)
(a) increases
(b) decreases

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 PINNAACLE CLASSES

(c) remains unchanged

(d) decreases. (2001) 83. for the cell, Cu is 1. at

, the equilibrium constant for the reaction

79. Equivalent conductances of and ions
is the order of
are 127 and 76 respectively.
(a) (b)
Equivalent conductance of at infinite (c) (d) (1997)
dilution is
(a) 139.5 (b) 101.5
84. The molar conductances of , HC1 and
(c) 203 (d) 279 (2000)

at infinite dilution are 126.45, 426.16

80. For the disproportionation of copper
and 91 respectively The molar
is (Given: for
conductance of at infinite dilution
is 0.34 V and for is 0.15
V.)
is
(a) 0.49 V (b)
(a) 698.28
(c) 0.38 V (d) (2000)
(b) 540.48
(c) 201.28
81. The specific conductance of a 0.1 KC1 solution
(d) 390.71 (1997)
at is 0.012 . The resistance of cell
containing the solution at the same temperature 85. A 5-ampere current is passed through a solution of
was found to be 55 ohms. The cell constant will be zinc sulphate for 40 minutes. The amount of zinc
deposited at the cathode is
(a) 0.918 (b) 0.66
(a) 0.4065 (b) 65.04
(c) 1.142 (d) 1.12 (1999)
(c) 40.65 (d) 4.065 (1996)

82. For the cell reaction 86. Reduction potential for the following half‐cell

of an electrochemical cell, the reactions areZn ;Fe

change in free energy at a given temperature V.The EMF for the cell
is a function of
reaction will be
(a) (b)
(a) (b)
(c) (d) (1998) (c) (d) (1996)

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 PINNAACLE CLASSES

87. An electrochemical cell is set up as: Pt; (1 atm)

HCl (O. 1 M) CHCOOH ; Pt.

The e.m.f. of this cell will not be zero, because
(a) acids used in two compartments are different
(b)e.m.f depends on molarities of acids used
(c) the temperature is constant

(d) of 0.1 M and 0.1 M is not

same. (1995)

88. On heating one end of a piece of a metal, the other

end becomes hot because of
(a) energised electrons moving to the other end
(b) minor perturbation in the energy of atoms
(c) resistance of the metal
(d) mobility of atoms in the metal. (1995)

89. Standard reduction potentials at of

and

and—2.37 volt respectively Which

one of the following is the strongest oxidising
agent?

(a) (b)
(c) (d) (1994)

90. On electrolysis of dilute sulphuric acid using

platinum electrodes, the product obtained at the
anode will be
(a) hydrogen
(b) oxygen
(c) hydrogen sulphide
(d) sulphur dioxide. (1992)

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