Jee Main 2021 Mar 18 First Shift Paper

JEE-MAIN-2021 (18th March-First Shift)-PCM-8
PART – B (CHEMISTRY)
SECTION - A
(One Options Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
Q1. Reagent, 1-naphthylamine and sulphanilic acid in acetic acid is used for the detection of :
(A) NO (B) N2O

(C) NO2 (D) NO3
Q2. Match List – I with List – II:

List – I List – II
(Class of Drug) (Example)
(a) Antacid (i) Novestrol
(b) Artificial Sweetener (ii) Cimetidine
(c) Antifertility (iii) Valium
(d) Tranquilizers (iv) Alitame
Choose the most appropriate match.
(A) (a)-(iv), (b)-(i), (c)-(ii), (d)-(iii) (B) (a)-(iv), (b)-(iii), (c)-(i), (d)-(ii)
(C) (a)-(ii), (b)-(iv), (c)-(iii), (d)-(i) (D) (a)-(ii), (b)-(iv), (c)-(i), (d)-(iii)

(Process) ( Catalyst)
(a) Deacon’s process (i) ZSM-5
(b) Contact process (ii) CuCl2
(c) Cracking of hydrocarbons (iii) Particles ‘Ni’
(d) Hydrogenation of vegetable oils (iv) V2O5
Choose the most appropriate answer from the options given below:
(A) (a)-(i), (b)-(iii), (c)-(ii), (d)-(iv) (B) (a)-(iii), (b)-(i), (c)-(iv), (d)-(ii)
(C) (a)-(iv), (b)-(ii), (c)-(i), (d)-(iii) (D) (a)-(ii), (b)-(iv), (c)-(i), (d)-(iii)
Q4.
H 3C CH3
NH2 N
NaNO2,HCl
"X"
273 K - 278 K (Major Product) "Y"
(Major Product)
Considering the above reaction, X and Y respectively are:
Cl
N
N
(A) and
N
H3C CH3
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N2 Cl CH3
N N
N
(B) CH3
and
Cl CH3
N N
N
CH3
(C) and
N2 Cl
N
N
(D) and
N CH3
CH3

(a) Ca(OCl)2 (i) Antacid
1
(b) CaSO4. H2O (ii) Cement
2
(c) CaO (iii) Bleach
(d) CaCO3 (iv) Plaster of Paris
(A) (a)-(iii),(b)-(ii),(c)-(iv),(d)-(i) (B) (a)-(iii),(b)-(ii),(c)-(i),(d)-(iv)
(C) (a)-(iii),(b)-(iv),(c)-(ii),(d)-(i) (D) (a)-(i), (b)-(iv),(c)-(iii),(d)-(ii)
Q6. Given below are two statements : One is labelled as Assertion A and the other is labelled as
Reason R:
Assertion A : During the boiling of water having temporary hardness, Mg(HCO3)2 is converted to
MgCO3.
Reason R: The solubility product of Mg(OH)2 is greater than that of MgCO3. In the light of the
above statements, choose the most appropriate answer from the options given below:
(A) Both A and R are true and R is the correct explanation of A
(B) A is false but R is true
(C) A is true but R is false
(D) Both A and R are true but R is NOT the correct explanation of A
Q7. A certain orbital has no angular nodes and two radial nodes. The orbital is:
(A) 3s (B) 3p
(C) 2s (D) 2p
Q8. Compound with molecular formula C3H6O can show:

(A) Metamerism
(B) Both positional isomerism and metamerism
(C) Positional isomerism
(D) Functional group isomerism
Q9. The chemical that is added to reduce the melting point of the reaction mixture during the
extraction of aluminium is:
(A) Kaolite (B) Bauxite
(C) Calamine (D) Cryolite
(Chemicals) (Use / Preparation / Constituent)
(a) Alcoholic potassium hydroxide (i) electrodes in batteries
(b) Pd/ BaSO4 (ii) obtained by addition reaction
(c) BHC (Benzene hexachloride) (iii) used for -elimination reaction
(d) Polyacetylene (iv) Lindlar’s Catalyst
Choose the most appropriate match:
(A) (a)-(ii),(b)-(iv),(c)-(i),(d)-(iii) (B) (a)-(ii),(b)-(i),(c)-(iv),(d)-(iii)
(C) (a)-(iii),(b)-(i),(c)-(iv),(d)-(ii) (D) (a)-(iii), (b)-(iv), (c)-(ii), (d)-(i)
Q11. Match List – I with List – II
(a) Chlorophyll (i) Ruthenium
(b) Vitamin – B12 (ii) Platinum
(c) Anticancer drug (iii) Cobalt
(d) Grubbs catalyst (iv) Magnesium
(A) (a)-(iv), (b)-(iii), (c)-(ii), (d)-(i) (B) (a)-(iv), (b)-(iii),(c)-(i), (d)-(ii)
(C) (a)-(iii), (b)-(ii), (c)-(iv), (d)-(i) (D) (a)-(iv),(b)-(ii),(c)-(iii), (d)-(i)
Q12.
CH3
Alkaline KMnO4
"X"
H+
OCH3
Considering the above chemical reaction, identify the product “X”:
CHO COOH
(A) X - (B) X-
OCH3 OCH3
CH3 CH2OH
(C) X - (D) X -
OH OCH3
Q13. A non-reducing sugar “A” hydrolyses to give two reducing mono saccharides. Sugar A is:
(A) Galactose (B) Fructose
(C) Glucose (D) Sucrose
Q14. The correct structures of trans-[NiBr2(PPh3)2] and meridonial-[Co(NH3)3(NO2)3], respectively, are :

NO 2
Br NO 2
Ph3P H 3 N
Ni and Co
(A)
PPh3 NH3
Br O 2N
NH3
NO 2
Br NH3
Ph3P O 2N
Ni and Co
(B)
Br NH3
Ph3P O 2N
NH3
NO 2
Br NO 2
Ph3P H3N
Ni and Co
(C)
PPh3 NO 2
Br H3N
NH3
NH3
Br NH3
Ph3P O 2N
Ni and Co
(D)
Br NO 2
Ph3P O 2N
NH3
o o
Q15. The ionic radius of Na+ ion is 1.02 A . The ionic radii (in A ) of Mg2+ and Al3+, respectively are:
(A) 0.85 and 0.99 (B) 0.68 and 0.72
(C) 0.72 and 0.54 (D) 1.05 and 0.99
Q16. In a binary compound, atoms of element A form a hcp structure and those of element M occupy
2/3 of the tetrahedral voids of the hcp structure. The formula of the binary compound is:
(A) M2A3 (B) MA3
(C) M4A (D) M4A3
Q17. Reaction of Grignard reagent, C2H5MgBr with C8H8O followed by hydrolysis gives compound “A”
which reacts instantly with Lucas reagent to give compound B, C10H13Cl. The compound B is:
Cl
CH3
Cl
CH3 CH3
(A) (B)
Cl CH3 CH3
CH3
(C) (D)
Cl
Q18.
C N
COOH
H2O H2O
"A"
H+ ( Major Prdouct) H+ , 
Consider the above chemical reaction and identify product “A”:
CH2NO 2 CONH 2
(A) (B)
H
C N OH CH2NH2
(C) (D)
Q19. The number of ionisable hydrogens present in the product obtained from a reaction of
phosphorus trichloride and phosphonic acid is:
(A) 1 (B) 3
(C) 0 (D) 2
Q20. The statements that are TRUE:

(A) Methane leads to both global warming and photochemical smog.
(B) Methane is generated from paddy fields.
(C) Methane is a stronger global warming gas than CO2.
(D) Methane is a part of reducing smog.
(A) (A), (B), (C) only (B) (A) and (B) only
(C) (A), (B), (D) only (D) (B), (C), (D) only
SECTION - B
(Numerical Answer Type)
This section contains 10 questions. The answer to each question is a NUMERICAL VALUE. For each
question, enter the correct numerical value (in decimal notation, truncated/rounded-off to the second
decimal place).
Q1. A reaction of 0.1 mole of Benzylamine with bromomethane gave 23g of Benzyl trimethyl
ammonium bromide. The number of moles of bromomethane consumed in this reaction are
n101, when n=__________. (Round off to the nearest integer).
[Given: Atomic masses: C=12.0u, H:1.0u, N:14.0u, Br:80.0u]
Q2. For the reaction C2H6  C2H4  H2 the reaction enthalpy rH =_____________ kJ mol1.
(Round off to the nearest integer).
[ Given: Bond enthalpies in kJ mol1 : C-C: 347, C=C:611; C-H:414,H-H:436]
Q3. In order to prepare a buffer solution of pH 5.74, sodium acetate is added to acetic acid. If the
concentration of acetic acid in the buffer is 1.0 M, the concentration of sodium acetate in the
buffer is ___________M. (Round off to the nearest integer).
[ Given: pKa (acetic acid) = 4.74]
Q4. AX is a covalent diatomic molecule where A and X are second row elements of periodic table.
Based on molecular orbital theory, the bond order of AX is 2.5. The total number of electrons in
AX is _____________. (Round off to the nearest integer).
Q5. For the reaction

2Fe3   aq  2I (aq)  2Fe2  aq  I2 (s)
The magnitude of the standard molar free energy change,
r Gmo =  _________________kJ (Round off to the nearest integer).
E o 2    0.440V; EoFe3  / Fe(s)  0.036V 
 Fe / Fe(s) 
Eo   0.539V; F  96500C 
 I2 / 2I 
Q6. ___________ grams of 3-Hydroxy propanal (MW = 74) must be dehydrated to produce 7.8g of
acrolein (MW = 56) (C3H4O) if the percentage yield is 64.
(Round off to the nearest integer).
[ Given: Atomic masses : C: 12.0u, H:1.0u, O:16.0u]
Q7. 2NO(g)  Cl2 (g)  2NOCl(s)

This reaction was studied at -10oC and the following data was obtained
run [NO]0 [Cl2]0 r0
1 0.10 0.10 0.18
2 0.10 0.20 0.35
3 0.20 0.20 1.40
[NO]0 and [Cl2]0 are the initial concentrations and r0 is the initial reaction rate. The overall
order of the reaction is ___________. (Round off to the nearest integer).
Q8. 2 molal solution of a weak acid HA has a freezing point of 3.885oC. The degree of
dissociation of this acid is ___________ 103. (Round off to the nearest integer).
[ Given : Molal depression constant of water = 1.85 K kg mol1,
Freezing point of pure water = 0oC]
22
Q9. Complete combustion of 3 g of ethane gives x10 molecules of water. The value of x is
__________. (Round off to the nearest integer).
23
[ Use : NA = 6.023 10 ; Atomic masses in u: C:12.0,O:16.0; H:1.0]
Q10. The total number of unpaired electrons present in the complex K3[Cr(oxalate)3] is______.
FIITJEE
KEYS to JEE (Main)-2021
PART – A (PHYSICS)
SECTION - A
1. A 2. A 3. A 4. B
5. B 6. A 7. D 8. A
9. C 10. D 11. D 12. B
13. D 14. C 15. B 16. D
17. C 18. D 19. B 20. B
SECTION - B
1. 100 2. 161 3. 70 4. 10
5. 20 6. 5 7. 32 8. 2
9. 10 10. 6
SECTION - A
1. C 2. D 3. D 4. C
5. C 6. C 7. A 8. D
9. D 10. D 11. A 12. B
13. D 14. A 15. C 16 D
17. B 18. B 19. D 20. A
SECTION - B
1. 3 2. 128 3. 10 4. 15
5. 45 6. 16 7. 3 8. 50
9. 18 10. 3
SECTION - A
1. NO2  CH3 COOH  HNO2  CH3 COO
O
-
NH3CH3COO N N O C CH3
+HNO 2 +2H2O
SO 3H SO 3H
Sulphanilic acid
O
N N O C CH3 NH2
SO 3H
SO 3H N N NH2 +CH3COOH
(Red Azodye)
2. Antacid: Cimetidine
Artificial Sweetner: Alitame
Antifertility: Novestrol
Tranquilizers: Valium
3. (a) Deacon’s process: CuCl2 used as catalyst

(b) Contact process : V2O5 used as catalyst
(c) Cracking of hydrocarbon: ZSM-5 used as catalyst
(d) Hydrogenation of vegetable oil: Particles Ni used as catalyst
4.
H3C CH3
N
NH2 N2Cl
NaNO2 , HCl
273 - 278 K
H3C CH3
Diazonium Salt N
N
N
5. Ca(OCl)2 : Bleach
1
CaSO4. H2O: Plaster of paris
2
CaO: Component of cement
CaCO3: Antacid

6. Mg HCO3 2   Mg  OH2  2CO2
whiteppt
MgCO3 is more soluble than Mg(OH)2, so ppt of Mg(OH)2 is formed.
Ksp of Mg(OH)2 is higher than MgCO3.
7. Total Node = n1   Azimuthal Q.N

Radial Node = n-  -l
Angular Node : 
Angular node = 0
 = 0 i.e S orbital
Radial nodes = 2
n-  -1 = 2
n-0-1 = 2  n=3
so; orbital is 3s
8. Functional group isomers.

C3H6O
O O
H3C CH2 C H H3C C CH3

Aldehyde Ketone
9. When we add crylolite in extraction of aluminium the melting point of alumina decreases
Crylolite Na3AlF6
10. Alcoholic potassium hydroxide (Alc KOH):- used for  - elimination

Pd / BaSO4 : - Lindlar’s Catalyst
BHC (Benzene hexa chloride) : - Obtained by addition reaction

Polyacetylene : Electrodes in batteries.
11. Chlorophyll: Magnesium present in chlorophyll

Vitamin – B12 : Cobalt (cynocobalamin)
Anticancer drug: Platinum (Co-ordination compound of platinum)
Grubbs catalyst:- Ruthenium
12.
CH3 COOH
Alkaline KMnO4
H+
OCH3 OCH3
13.
H2O
Sucrose Glucose + Fructose
Non Reducing Reducing Reducing

Sugar Sugar Sugar
14. Trans- [ NiBr2 (PPh3)2]

Ph3P Br
Ni
Br PPh3
Meridonial- [ Co(NH3)3(NO3)3]
O 2N
H3N NO 2
Co
O 2N NH3
H3N
15.
electron
+
Na 10
2+
Mg 10 isoelectronic
3+
Al 10
But Zeff value Al3   Mg2  Na
+ 2+ 3+
Ionic Radius Na > Mg > Al
0.72 0.54
16. Let number of atoms be N;

Tetrahedral voids = 2N
Atoms of element A = N
2
Atoms of element M =  2N
3
M:A
4
:1
3
So, formula of the compound is M4 A 3
17.
O OH
Et MgBr
H2O
C8H8O A
3o Alcohol
Readily gives Lucas test (ZnCl 2-HCl)

Cl
18.
O
O
C N C NH2
C
H3O+ + OH
H2O , H

H+ complete hydrolysis
Partial hydrolysis
A
19. Phosphrous Trichloride + Phosphonic acid

PCl3 + H3PO3  H4P2O5 + HCl
O O
P P
O O O
H H H H
Polar bond Polar bond
O-H bond is polar bond, so number of ionisable hydrogens are 2.
20. CH4(methane) is produced / generated from paddy fields. And methane leads both global
warming and photochemical smog.
CO2  used in photosynthesis, acid rain etc. but methane is not consume
So methane is stronger global warming gas than CO2
SECTION - B
1.
CH3
-
H 2C NH2 N Br
CH 3
CH2
CH3
+3CH3Br
Benzyl amine
0.1 mole
23
Moles of Benzyl trimethyl ammonium bromide =  0.1 mol
230
nCH3Br  0.3  3  101
n3
2. C2H6  C2H4 + H2
Bond formation  Energy released
Bond breaking  Energy consumed
H H H H
H C C H H C C H + H H
H H
Hf   HC C  6HC H   HC C  4HC H  HHH
 HC C  2HCH  HC C  HHH
 347  2  414  611  436
 128kJ / mol
3. Acidic Buffer solution
pH  pK a  log
Base 
 Acid
5.74  4.74  log
Base
1
1  log Base 
Base  10M
4. AX Diatomic molecule
Bond order is 2.5
Compound is NO  Total number of electrons = 15 (7+8)
5.
o o
E1 E2
Fe3   Fe2  Fe
Eo3
E1o  2Eo2  3E3o
E1o  3E3o  2Eo2
 3  0.036   2  0.44 
 0.772 V
Eocell  EFe
o
3
/ Fe2 
 EI0 / 2I
2
 0.233 V
Go  nEocellF
 2  96.5  0.233
 45kJ
6. 3-Hydroxy propanal
O

H2C CH2 C H C3H4O + H2O
OH
mole x/74 - -
7.8/56 mole
x 7.8

74 56
7.8  74
x mole of 3- hydroxy propanal.
56
7.8  74 100
Weight =  g
56 64
 16.10 g
Ans = 16 (Rounded off)
7. 2NO(g)  Cl2 (g)  2NOCl(g)

m n
rate  K NO  Cl2 
m n
rate1  k  0.1  0.1 --------------------------(i)
(0.18)
m n
rate2  K  0.1  0.2  ------------------------(ii)
 0.35 
m n
rate3  K  0.2   0.2  -----------------------(iii)
1.40 
m n
0.35 k  0.1  0.2 

0.18 k  0.1m  0.1n
2  2n
n 1
m n
1.40 k  0.2   0.2 

0.35 k  0.1m  0.2 n
4  2m
22  2m
m2
Overall order  m  n  2  1  3
8. K f  1.85K kg mol1
Tf  iK f .m
3.885  i  1.85  2
i  1.05
i  1  n  1 
1.05  1   2  1 
1.05  1  
  0.05
  50  10 3
9.
C2H6 + 7/ 2O2 2CO2 + 3H2O
3
Mole of C2H6   0.1 mol
30
Moles of H2O produced = 0.3mol
Number of H2O molecules  0.3  6.023  1023
 18.06  1022
So; x = 18 (Rounded off)
10. K 3 Cr  oxalate 3 

3
3K   Cr  oxalate 3 
Cr 3  
Cr  24    Ar  4s13d5
Cr 3    Ar  4so 3d3
no. of unpaired electron = 3
PART – C (MATHEMATICS)
SECTION - A
1. a | z |2 z   z  d  0
az.z  z  z  d  0
  d
z.z  z  z   0
a a a

Centre 
a
2
 d
Radius  
a a
2
 d
  0
a a

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JEE-MAIN-2021 (18th March-First Shift)-PCM-8

Q2. Match List – I with List – II:

Q3. Match List – I with List – II:

Q5. Match List – I with List – II:

Q8. Compound with molecular formula C3H6O can show:

Q14. The correct structures of trans-[NiBr2(PPh3)2] and meridonial-[Co(NH3)3(NO2)3], respectively, are :

Q20. The statements that are TRUE:

Q5. For the reaction

Q7. 2NO(g)  Cl2 (g)  2NOCl(s)

3. (a) Deacon’s process: CuCl2 used as catalyst

7. Total Node = n1   Azimuthal Q.N

8. Functional group isomers.

H3C CH2 C H H3C C CH3

10. Alcoholic potassium hydroxide (Alc KOH):- used for  - elimination

BHC (Benzene hexa chloride) : - Obtained by addition reaction

11. Chlorophyll: Magnesium present in chlorophyll

Non Reducing Reducing Reducing

14. Trans- [ NiBr2 (PPh3)2]

16. Let number of atoms be N;

Readily gives Lucas test (ZnCl 2-HCl)

19. Phosphrous Trichloride + Phosphonic acid

3. Acidic Buffer solution

7. 2NO(g)  Cl2 (g)  2NOCl(g)

10. K 3 Cr  oxalate 3 

no. of unpaired electron = 3

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