MOCK TEST- I, JEEM

Shift-II, 4-11-2023
Maximum marks: 100 Time: 60 mins

Instructions
Section – A (01 – 20) contains 20 multiple choice questions which have one correct answer. Each
question carries +4marks for correct answer and – 1 mark for wrong answer.

Section – C (01 – 05) contains 05 Numerical based questions with single digit integer as answer, ranging
from 0 to 9 and each question carries +4 marks for correct answer. and – 1 mark for wrong answer
_______________________________________________________________________________
1. Which of the following is strongest acid?
(A) CHCl3 (B) CHl3
(C) CHBr3 (D) CH(CN)3

2. Which of the following alkaline earth metal nitrate does not have water of crystallization?
(A) Ca(NO3)2 (B) Mg(NO3)2
(C) Sr(NO3)2 (D) Ba(NO3)2

3. Which of the following is not correct about Henry’s law?

(A) On increasing temperature value of KH increases
(B) Value of KH increases solubility of gas increases
(C) Value of KH for two different gases at same temperature is not same
(D) None of these

4. A solid having HCP arrangement with formula A2B3. Which atom form lattice and which atom
occupied void
(A) B atom occupy lattice and A atom occupy 2/3 octahedral voids
(B) B atom occupy lattice and A atom occupy 1/3 octahedral voids
(C) A atom occupy lattice and B atom occupy 2/3 octahedral voids
(D) A atom occupy lattice and B atom occupy 1/3 octahedral voids

5. When Na is treated with liquid NH3 blue colour solution is formed. What is the reason for
colour formation
(A) Due to [Na(NH3)x]+
(B) Due to Ammoniated (solvated) e– or [e(NH3)y]–
(C) Due to hydrated e–
(D) Due to formation of NaNH2

6. Which of the following carbonate decompose most easily on heating?

(A) Rb2CO3 (B) K 2CO3 (C) Na2CO3 (D) MgCO3

7. The alkali metals form salt-like hydrides by the direct synthesis at elevated temperature. The
thermal stability of these hydrides decreases in which of the following orders ?
(A) KH>NaH>LiH>CsH>RbH (B) NaH>LiH>KH>RbH>CsH
(C)LiH>NaH>KH>RbH>CsH (D)CsH>RbH>KH>NaH>LiH

8. If bond energy of C=C & CC at 298 K are 600 & 330 KJ mol1 respectively then the
magnitude of enthalpy change when 112 g of ethylene changes into polythene is
(A) 240 KJ (B) 270 KJ (C) 1080 KJ (D) 540 KJ

9. Which of the following is the correct order of the rate of reaction of C6H6 ,C6D6 , and
C6 T6 towards sulphonation?
(A) Same rates of reaction of C6H6 ,C6D6 and C6T6,
(B) C6 T6  C6D6  C6H6
(C) C6H6  C6D6  C6 T6
 (D) C6H6  C6D6  C6 T6

10. When phenyl magnesium bromide reacts with t-butanol, the product would be:
(A) Benzene (B) Phenol (C) t-Butyl benzene (D) t-Butyl phenyl ether

11. In the reaction

O (i) NaOH/Br2
H3C C (T)
O
NH2 (ii) C
Cl
The structure of the product (T) is:

(A) O (B)
H3C C O NH
O C C CH3
O

(C) (D) O
H3C NH H3C C O
C NH C
O

12. Which of the following pairs give positive Tollen’s test?

(A) Glucose, sucrose (B) Glucose, fructose
(C) Hexanal, acetophenone (D) Fructose, sucrose

13. If the standard half cell reduction potentials are 0.522 V for Cu  / Cu and 0.3402 V for
Cu 2 / Cu . The standard half cell reduction potential for Cu  / Cu 2+ is
(A) 0.20 V (B) 0.158 V (C) 0.40 V (D) 0.80 V

14. In the isoelectronic series of metal carbonyl, the stability of complex is expected to increase
in the order
   
(A)  Mn  CO 6    Cr  CO 6    V  CO 6  (B)  V  CO 6    Cr  CO 6    Mn  CO 6 
   
(C)  V  CO 6    Mn  CO 6    Cr  CO 6  (D)  Cr  CO 6    Mn  CO 6    V  CO 6 

15 The correct order of boiling point is

(A) HI < HB < HCl < HF (B) HBr < HCl < HF < HI
(C) HCl < HBr < HI < HF (D) HI < HBr < HF < HCl

16. Which does not react with NaOH

(A) NaH2PO2 (B) NaH2PO4
(C) Na2HPO4 (D) NaHCO3

17. What is the correct order of stability of following anions?

(A) (B)
< < < <

(C) (D)
< < < <
18. Mutaroration is most favourable in
(A) non-polar solvent (B) acidic solvent
(C) basic solvent (D) amphiprotic solvent

19. Liquid O2 is blue in colour due to electronic transition from

(A) triplet ground state to singlet excited state
(B) single ground state to triplet excited state
(C) charge transfer
(D) polarisability

20

(A) aromatic (B) non-aromatic

(C) anti-aromatic (D) quasi-aromatic

Numerical Type

1.
P

Conc

R
5
Time in min
For a given 1st order reaction R  3P
What is the time required for 20% completion of reaction in minute unit?

2. How many of the chromium compounds have odd oxidation number

CrO3, CrO5, K3CrO8, K2Cr2O7 (NH3)3CrO4, K3[Cr(C2O4)3], CrO2, CrO2Cl2, Cr2O3

3. Number of hydrogen bond formed by a molecule of HF = x, H2O = y & NH3 = z. Value of

xyz

4. If the solubility of solid zinc hydroxide at pH = 5 is x. What is the value of x/2?

Given:

Zn  OH  s   6
 Zn  OH  aq  ; K1  10 M
2 2



Zn  OH2  aq 
  Zn  OH   aq  OH  aq ; K 2  10 7 M

 Zn  OH  

 aq  2 
 Zn  aq  OH  aq  ; K 3  10 4 M

 
 K 4  103 M
 Zn  OH2   aq  OH  aq 
  Zn  OH3   aq ;
 
 2


 aq  OH  aq 
 Zn  OH3    Zn  OH4   aq  ;
  K 5  10 M

5. The molar solubility of Fe(OH)3 in a buffer solution is 1012 M at 25C. Find the pH of buffer
solution
Ksp of Fe(OH)3 = 1036