Professional Documents
Culture Documents
SS JEE(M) &
ADVANCED
Chemistry
Chapterwise Practise Problems (CPP) for JEE (Main & Advanced)
Chapter - Alcohols, Phenols and Ethers
Level-1
SECTION - A
(A) Br
Straight Objective Type
This section contains multiple choice questions. Each
question has 4 choices (A), (B), (C) and (D) for its
OH
answer, out of which ONLY ONE is correct. (B) CH3O
1. The reactivity of compound Z with different halogens
under appropriate conditions is given below :
OH
OH Monohalo substituted
derivative when X2 = l2 Cl
X2
Dihalo substituted derivative (C)
C(CH3)3 when X2 = Br2
Z Trihalo substituted derivative
when X2 = Cl2
(D) All can be used
The observed pattern of electrophilic substitution
can not be explained by–
(A) the steric effect of the halogen
(B) the steric effect of the tert-butyl group 4.
(C) the electronic effect of the phenolic group
(D) the electronic effect of the tert-butyl group
Hl
2. Me2CHOCMe3
0C
X Y
(A) (B)
Predict the nature of products and the type of
reaction involved in their formation.
(A) Me 2 CH-I and Me 3 COH, f ormed by S N 1
reaction
(B) Me2CHOH and Me3C-I, formed by SN1 reaction (C) (D)
(C) Me 2 CH-I and Me 3 COH, f orm ed by S N 2
reaction
(D) Me2CHOH and Me2C-I, formed by SN2 reaction
5.
3. Find out the compound that could be used to get
the following epoxide in one step.
O (A) (B)
H3C
H3C
(C) (D)
(1)
Alcohols, Phenols and Ethers Aakash Institute
6. In the given reaction :
(A) (B)
(C) (D)
(C) Mixture of (A) and (B) (D)
7. Which of the following oxidation reactions is 10. In which of the following case, the given first
incorrect? reaction is faster than the second reaction?
Cr VI
(A) CH3 CH2 OH
H3O
CH3 CHO CH3I OH–
H2O
CH3OH I
(A) H2O
CH3I SH CH3SH I
(No CH3COOH will be produced)
C2H5OH
(B) CH3(CH2)2C C CH CH3 CrO3 , H2SO4
CH3(CH2)2C C C CH3 CH3CH2Br SH CH3CH2SH Br
Acetone, 0 C°
O (B) DMF
OH CH3CH2Br SH CH3CH2SH Br
MnO2 O
(D) CHCl3 , 250C HOCH2CH2CH2Cl + OH– +
HO O
(D)
O
HOCH2CH2I + OH– +
OH
+
H
8. P
Ph
RMgX
11. CH3 ?
O H3O+
(Most Stable product)
Ph Ph
(A) HO CH3 (B) CH3
HO
(A) (B) R OH
Ph
(C) CH3 (D) None of the above
R
OH
(C) (D) No reaction
12. Identify correct decreasing order of relative acid
strength of following compunds.
9.
H
+
OH OH OH
OH O
Ph OH Me Me
O O
Re-arranged alkene product after re-arrangement at (X) (Y) (Z)
low temperature will be mainly,
OH (A) (B)
COOH NO2
Br2 HNO3 NO2
14. Y water X
OH OH
X and Y are OCH3
(A) picric acid and 2,4,6-tribromophenol (C) (D)
The correct statements about the above conversion (C) Lewis base (D) Bronsted acid
are :
18. Which of the following compounds will give a
yellow precipitate with iodine and alkali ?
OH OH
NO2 (A) Propan-2-ol (B) Acetophenone
(A) The compound X is and Z is
(3)
Alcohols, Phenols and Ethers Aakash Institute
20. Compound which gives alcohol on reduction is/are detach from the migration origin and then form bond
with the migration terminus or may remain partly bonded
(A) Me – C – Cl (B) Me – C – NH2 to both migration origin and terminus to form a bridged
O O ion intermediate. Similar to the electron deficient
carbons such as carbocation and carbene
O O O intermediates, electron-deficient nitrogen species are
(C) (D) Me – C – OC – Me known in which the nitrogen bears a positive charge or
H3C the nitrogen has an open sextet of electrons, i.e. a
nitrene.
21. HBO, oxymercuration-demercuration and acid
24. Which of the following is stable product for given
catalysed hydration will give same product in
reaction ?
(A) (B) CH 3
CH3
H
OH
(C) (D)
CH3
CH3 CH3
22. Cyclopentyl ether can be obtained by :
(A) (B) (C)
(A) ONa CH3CH2Br CH2
CH3
CH3
(D)
(B) Br + CH3 – C – O–Na+ CH3
CH3
23. Which of the following statement(s) is(are) true? (A) HO CH2 CH2 CH CH2 (B)
(A) All alcohols are weaker acids than water O
except methanol
CH2
(B) All alcohols are stronger acids than water (C) HO (D)
(C) All alcohols are much weaker acids than Ch3
terminal alkynes
(D) All alcohols are stronger acids than terminal OH
alkynes
COOH
OH O
C O
(C) O (D)
(5)
Alcohols, Phenols and Ethers Aakash Institute
33. Match Column–I with Column–II : 34. Two isomeric products X and Y are obtained in the
following reaction.
Column – I Column –II
OH
(A) 2-Pentanol or 3-Pentanol (p) SN2
(1) CCl4/KOH/ X + Y
on heating with conc. HCl + (Ortho Product) (Para Product)
(2) H
gives the same mixture of
2-Chloropentane and Match the Column–I with Column–II.
3-Chloropentane.
Column–I Column–II
(B) Friedel Crafts reaction of (q) Carbocation
benzene with isobutyl intermediate (A) Acidic Strength (p) X > Y
alcohol in presence of
(B) Solubility in H2O (q) Y = X
H2SO4 gives tertiary
butyl benzene. (C) Basicity (r) Y > X
(C) Reaction of tertiary-butyl (r) Dichloro (D) Melting Point (s) Can’t say
ethyl ether on heating carbene
with conc. HI at 373K intermediate SECTION-E
gives ethanol and
Integer Answer Type
tert-butyl iodide
This section contains Integer type questions. The answer
(D) Sodium tertiary butoxide (s) Electrophilic
on heating with ethyl substitution to each of the questions is a single digit integer, ranging
bromide gives tertiary reaction from 0 to 9. The appropriate bubbles below the respective
question numbers in the ORS have to be darkened. For
butyl ethyl ether
example, if the correct answers to question numbers X,
Y and Z(say) are 6, 0 and 9, respectively, then the correct
(E) Hydration of 3, 3-dimethyl (t) Rearrange- darkening of bubbles will look like the following :
but 1-ene in presence ment of
of dil. H2SO4 gives 2, carbocations
X Y Z
3 dimethyl butan-2-ol.
0 0 0
(F) Reaction of chloroform
1 1 1
with phenol in presence (u) SN1
of NaOH at 340 K 2 2 2
mainly gives 2-hydroxy- 3 3 3
benzaldehyde. 4 4 4
5 5 5
6 6 6
7 7 7
8 8 8
9 9 9
OH
final product in the given reaction?
Na 2CrO4
1. O3
[A] [B]
2. H2O2 CaO
+
H 39. How many compounds of molecular formula C5H10O
36. Product
is possible which gives positive Tollen’s test?
OH OH
40. How many isomers from the molecular formula
C4H10O can give blood red colourisation by Victor
Number of carbon atom in largest cycle is
Mayer’s test
37. Cosider the following reaction
OH
H PO (conc.) (i) O
3 4
[A] 3
(ii) Zn—H O
[B]
2
(7)
Alcohols, Phenols and Ethers Aakash Institute
Level-2
SECTION - A
Straight Objective Type (A)
This section contains multiple choice questions. Each
question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONLY ONE is correct.
(B)
Cl
1. OEt
–
* The product is
O
(C)
Cl
(A)
*
HO OEt
(D)
Cl
(B) 4. In the given reaction,
*
EtO OH
EtO
(C)
*
O
*
OEt [X] will be :
(D)
O
(A)
(B)
2.
(C)
O O
(D)
(A) (B)
CH3
3. CH2 H2O
(B) Ag +
CH3 Cl
OH
O
CH3MgBr H3O+
(D) CH3
CH3 CH3
Ether
(A) H3C
+ H3C
O
6. Quinones are good electron acceptors, partly be-
cause reduction restores aromaticity
OH
O O H3C CH3
(B) 14
+ HCHO
+e
-e
O O O
HO O
O
O
(D) Can’t be predicted by structure HO OH
(pKa=4.71)
14
O CH2 Identify the form of ascorbic acid that is present in
the body (aqueous solution, pH = 7.4)
CH3
7. H3C
O3
Zn/HO
2
(9)
Alcohols, Phenols and Ethers Aakash Institute
H OH Me OH (i)CHCl/NaOH/
3 Br/Fe
2
+ (X) (Y)
(ii)HO
3
HO O
O
(A)
HO O (A)
H OH
HO O
O
(B)
(B)
O OH
H OH
(C)
(C) O
O O
(D)
HO OH
H O SECTION - B
Multiple Correct Answer Type
(D) HO O
O This section contains multiple choice questions. Each
question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE is/are correct.
HO OH
–
CH3 CH3
– –
– –
CHOH , COH
CH2OH CH2OH
O
SeO2
15. Ph — C — CH 3 A
(11)
Alcohols, Phenols and Ethers Aakash Institute
(D) a carboxylic acid (C) (r) X=(i) O3 (ii) Zn/H2O
CH3
(i) NaOH Y = NaOH
(ii) CO 2
17. Compound (D)
4 7 atm,125K
(X)
(iii) HCl
CH COCl
(Y)
3
CH(CH)3 2
32
The product (Y) is
x
(A) an antiseptic (B) an antiallergic
O
(C) an antipyretic (D) an antibiotic H3C—C—(CH2)2—CH—CH2–CHO
CH(CH3)2
SECTION-D
Matrix-Match Type
y
This Section D have “match the following” type question.
Question contains two columns, Col-I and Col-II. Match (CH3)2CH
the entries in Col-I with the entries in Col-II. One or more CHO
entries in Col-I may match with one or more entries in
Col-II.
18. Column-I contains reactions and Column-II
consists of reagents used in these reactions.
(D) (CH)C=CH—CH—CH = CH—CH3 (s) X=HIO4;
Match the following : 3
2
2
x
Column-I Column–II Y=NaOH
O O
(A) CHO (p) X=B2H6/H2O2, HC(HC)—C—CH—CH–C——CH
3 2 2 2 3
NaOH, H2CrO4 y
Y=NaOH/ O
x
Br
CHO (CH(CH))
32
y
SECTION-E
y
CHO
9 9 9
OH OH OH OH
CH2 CH CH CH CH2 OH
(13)
Alcohols, Phenols and Ethers Aakash Institute
CPP-11
SS JEE(M) &
ADVANCED
ANSWERS
LEVEL-1
13. (A) 14. (A) 15. (B) 16. (A) 17. (A,B,C) 18. (A,B)
19. (B) 20. (A,C,D) 21. (C) 22. (A,C,D) 23. (A,D) 24. (B)
25. (B) 26. (A,B) 27. (B) 28. (D) 29. (C) 30. (B)
35. (4) 36. (6) 37. (9) 38. (3) 39. (5) 40. (2)
LEVEL-2
13. (B) 14. (A,C,D) 15. (B,C) 16. (C) 17. (C)
Mathematics
Chapterwise Practise Problems (CPP) for JEE (Main & Advanced)
Chapter - Probability
Level-1
SECTION - A
1 1 1 1
(A) , (B) ,
Straight Objective Type 3 2 3 2
This section contains multiple choice questions. Each
1 1 1 1
question has 4 choices (A), (B), (C) and (D) for its answer, (C) , (D) ,
out of which ONLY ONE is correct. 3 2 3 2
(1)
(1)
Probability Aakash Institute
8. Let E and F be two independent events. The is/are ture? {P(m) represents probability of passing
1
probability that both E and F happens is and in mathematics similarly P(p) and P(c)}
12
1 19
the probability that neither E nor F happens is . (A) p + m + c =
2 20
Then
1 1 27
(A) P(E) = , P F (B) p + m + c =
3 4 20
1 1
(B) P(E) = , P(F ) 1
2 6 (C) P(m p c)
10
1 1
(C) P(E) = , P F
6 2 1
(D) P(m p c)
1 1 4
(D) P(E) = , P F
4 3
SECTION - C
9. There are n married couples at a party. Each
person shakes hand with every other person other Linked Comprehension Type
than her or his spouse. The total number of hand
This section contains paragraph. Based upon this
shakes must be
paragraph, 3 multiple choice questions have to be
(A) 2nC –n (B) 2nC – (n – 1)
2 2 answered. Each question has 4 choices (A), (B), (C) and
(C) 2n(n – 1) (D) 2nC
2 (D) for its answer, out of which ONLY ONE is correct.
ing in exactly two. Which of the following relation(s) (C) 20/26 (D) 21/26
D:/ Math equation.pm6/aloke/Determinant (2)
Aakash Institute Probability
question numbers in the ORS have to be darkened. For
SECTION-D
example, if the correct answers to question numbers X, Y
Single-Match Type and Z(say) are 6, 0 and 9, respectively, then the correct
darkening of bubbles will look like the following :
This section contains Single match questions. Each
X Y Z
question contains statements given in two columns which
have to be matched. The statements in Column I are 0 0 0
labelled A, B, C and D, while the statements in Column 1 1 1
II are labelled p,q,r,s. Four options A, B, C and D are
given below. Out of which, only one shows the right 2 2 2
matching 3 3 3
16. Let A and B be two independent events such that 4 4 4
probability of occurence of A is higher than that of 5 5 5
1
B. The probability that both A and B happen is 6 6 6
12
1 7 7 7
and the probability that neither happens is .
2 8 8 8
Denote by P(X), the probability of happening of
9 9 9
event X and by X the complement of event X.
Match the probabilities in column I with their
possible values in column II 17. Three numbers a, b, c are selected from the set
A = {1, 2, 3, 4, 5, 6, 7, 8, 9, 10}. p is probability
Column I Column II
of selecting them such that the equation ax3 +
(b – a)x2 + (c – b) x – c = 0 has all the three
1 equal roots. The value of 4p is ________ .
(A) P(A) (p)
4
18. Consider the system of equations
2 ax + by = 0
(B) P(B) (q)
3 cx + dy = 0, where a, b, c, d {0, 1}
The probability that the system of equations has
1 unique solution is “p” then 8p is __________ .
(C) P(A) (r)
3
19. A square is inscribed in a circle of Radius R. A
point is selected form the inside of a circle. The
3 probability that the point is inside the square is P.
(D) P(B) (s)
4 1
Then , where [X] is greatest integer of X is
P
A B C D ______ .
(A) q s r p 20. India and Australia play a series of 7 one-day
matches. Each team has equal probability of win-
(B) q p r s
ing a match. No match ends in draw. If the probabil-
(C) q r s p ity that India wins at least three consecutive matches
(D) r p q s p
can be expressed as where p & q are relatively
q
SECTION - E prime positive integers. Find the unit digit of p.
Integer Answer Type 21. A bag contains 2 red, 3 green and 4 black balls. 3
This section contains Integer type questions. The answer balls are drawn randomly and exactly 2 of them found
to each of the questions is a single digit integer, ranging to be red. If P denotes the chance that one of the
from 0 to 9. The appropriate bubbles below the respective three balls drawn is green. Find the value of 7P.
(3)
Probability Aakash Institute
Level-2
SECTION - A SECTION - B
Straight Objective Type Multiple Correct Answer Type
This section contains multiple choice questions. Each This section contains multiple choice questions. Each
question has 4 choices (A), (B), (C) and (D) for its answer, question has 4 choices (A), (B), (C) and (D) for its answer,
out of which ONLY ONE is correct. out of which ONE OR MORE is/are correct.
1. 10 people sit around a circular table. Probability 6. A polygon is of n sides, if a triangle is formed from
(exactly 4 people sit between two specified this n sided polygon by joining its vertices, then
people)= the probability that the triangle has no side
common with that of the polygon is
(A) 5/9 (B) 1/9
(C) 2/9 (D) 4/9 (n – 4) (n – 5)
(A)
(n – 1) (n – 2)
2. A die is thrown again and again until an odd
number comes up. Probability that even number of
trials are needed is 1
(B) , if n = 6
10
1 1
(A) (B)
2 4 (n – 3) (n – 4)
(C)
(n – 1) (n – 2)
1 2
(C) (D)
3 3
3
(D) , if n = 6
3. Probability of getting 5 heads in 12 tosses of a fair 10
coin is
7. The probability that an anti-aircraft gun will hit the
99 99 1
(A) (B) target when it is first seen is , if it is not hit,
512 1024 2
then it fires again and probability of hitting the
33 33
(C) (D) 1
512 1024 target is . If this shot also fails, then probability
3
4. A quadratic equation is chosen from the set of all 1
quadratic equations which are unchanged by squar- of hitting the target in third shot is . Which of
4
ing their roots. The chance that the chosen equation
the following statement(s) is/are true?
has equal root is :
(A) 1/2 (B) 1/3 1
(A) Probability that target is hit in third trial is
(C) 1/4 (D) 2/3 4
5. Two numbers x and y are choosen at random (with- (B) Probability that third trial is not needed and
out replacement) from amongst the numbers 1, 2, 2
3,....., 2004. The probability that x3 + y3 is divisible target is hit is
3
by 3 is
(C) Probability that target is hit in second trial is
1 2 1
(A) (B) 6
3 3
(D) Probability that second trial is not needed is
1 1 1
(C) (D)
6 4 2
I. The first one is a rotten mango In a test an examinee either guesses or copies or
knows the answer to a multiple choice question (one
II. The second one is not a rotten mango choice correct) with four choices. The probability that he
1
III. The two mangoes are either both rotten or both makes a guess is . The probability that he copies
3
fresh
1
the answer is . The probability that the answer is
(A) I and II are independent event 6
(B) II & III are independent events 1
correct, given that he copied it, is .
8
(C) III & I are independent event
13. What is the probability of the examinee answering
(D) I, II, III are mutually independent events
the question correctly?
1 1 1
11. Consider the equation as given x y p where, 11 19
(A) (B)
24 48
x,y, p I+ and p is a prime number . If (x, y) repre-
sents the solution pair then
29 13
(C) (D)
1 48 24
(A) probability that x < y is
3
(5)
Probability Aakash Institute
14. What is the probability that the examinee knew the E the event that horse A wins
answer to the question, given that he correctly
answered it? E1 the event that jockey B rides horse A
13 11 E1
(C) (D) 18. The value of P is
24 24 E
Paragraph for Question Nos. 15 to 17 (A) 1/3 (B) 1/6
There are ‘n’ urns each containing (n+1) balls, each con- (C) 1/2 (D) 2/5
tain i white balls and (n+1–i) red balls. Let ui be the event
of selecting ith urn, i=1,2,3,.....n and w denotes the event 19. The value of P(A2) is
of getting a white ball
1 1
(A) (B)
3 6
15. If P(ui) =i where i = 1, 2, 3, ..... then nlim
P(w) is
equal to 1
(C) (D) none of these
2
1 2
(A) (B)
4 3 20. The odds against winning of A is
3 (A) 2:1 (B) 1:1
(C) (D) 1
4
(C) 13:5 (D) none of these
un
16. If P(ui) = c, where c is a constant then P is
w
equal to SECTION-D
2 1 Single-Match Type
(A) (B)
n 1 n 1 This section contains Single match questions. Each
question contains statements given in two columns which
n 1 have to be matched. The statements in Column I are
(C) (D)
n 1 2 labelled A, B, C and D, while the statements in Column
II are labelled p,q,r,s. Four options A,B,C and D are given
17. If n is even and E denotes the event of choosing even
below. Out of which, only one shows the right matching
1
numbered um p ui then the value of P(w/E) 21. A is a set containing n elements, A subset P is
n
selected at random from set A and the set A is
is
then reconstructed by replacing the element of P.
n2 n2 A subset Q of A is again chosen at random. The
(A) (B) 2 n 1 probability that
2n 1
n Column I Column II
1
(C) (D)
n 1 n 1 (A) Number of elements in P is (p) n(3n–1)/4n
22n 2n Cn
symmetric is
(C) P Q = is (r)
22n1
27 1
(Q) A square matrix of order (2) x
n
64 46
3
(D) P Q is singleton (s) 4 3 is constructed whose
elements belongs to the set
A B C D A then probability that matrix
(A) q r s p is symmetric is
(B) p s q r 3
(R) A function f : A A is (3)
8
(C) p q r s
defined then probability
(D) p r s q
that function is onto is
22. Let A and B are two independent events such that
3
1 1 (S) A function f : A A is (4)
P(A) = and P(B) . 32
3 4
defined and ‘f’ is onto then
Column I probability that f (i) i i A
Column II
is
(A) P(A B) is equal to (p) 1 Codes :
P Q R S
1
(B) P(A/A B) is equal to (q) (A) 3 1 2 4
2
(B) 2 1 4 3
2
(C) P(B/A B) is equal to (r) (C) 3 2 1 4
3
(D) 4 1 2 3
(D) P A A B is equal to (s) 0
SECTION-E
Integer Answer Type
A B C D This section contains Integer type questions. The answer
(A) r p q s to each of the questions is a single digit integer, ranging
from 0 to 9. The appropriate bubbles below the respective
(B) s p r q question numbers in the ORS have to be darkened. For
(C) r p s q example, if the correct answers to question numbers X, Y
and Z(say) are 6, 0 and 9, respectively, then the correct
(D) q r s p darkening of bubbles will look like the following :
23. There is a set A = {1,0, - 1,2} then match the follow-
ing :
Column -I Column -II
1
(P) A square matrix of order (1)
64
3 is constructed
whose element belongs
to set A then probability
that matrix is skew-
(7)
Probability Aakash Institute
X Y Z Mr. B lives far from mall M2,so the probability that he
0 0 0 goes to mall M2is (1/7). The probability that Mr. B
1 1 1 goes to mall M1 is the same as the probability that
he goes to mall M3.
2 2 2
3 3 3 The probability that Mr. C goes to the three malls,
4 4 4 mall M1,M2 and M3 are all equal.
5 5 5
If the probability P that atmost 2 out of the 3 friends
6 6 6 will meet at the same mall, is expressed as lowest
7 7 7 rational (m/n), then find the sum of the digits in
8 8 8 (n - m)
9 9 9
26. In a knockout tournament 2n equally skilled players;
24. The number ‘a’ is randomly selected from the set {0, S1,S2,........, S2n are participating. In each round play-
1, 2, 3,.......,98,99}. The number ‘b’ is selected from ers are divided in pair at random and winner from
the same set. Probability that the number 3a + 7b each pair moves in the next round. If S2n reaches
has a digit equal to 8 at the units place, is , then the semifinal then the probability that S1 wins the
16
1
= tournament is . Find the value of ‘n’.
20
25. Three friends A, B and C decides to go to one of the 27. A positive integer n is randomly guessed. Let the
three malls M1, M2, and M3. Mr. A lives near the mall probability that xn+1xn + 1 is divisible by x2x +1
M1, so the probability that he goes to mall M1is (5/ be P. The value of 12P is ____________
9). The probability that Mr. A goes to the mall is M2 28. f is any function from A to A where A = {1, 2,.... 10}.
is the same as the probability that he goes to the The discrete points on the graph of f (x) are joined
with line segments the probability that f is onto and
mall M3.
the resulting graph has only one local minima and
2k 2
no local maxima is then k is ________ .
1010
CPP-11
SS JEE(M) &
ADVANCED
ANSWERS
LEVEL-1
LEVEL-2
13. (C) 14. (B) 15. (B ) 16. (A) 17. (B) 18. (D)
19. (B) 20. (C) 21. (A) 22. (D) 23. (B) 24. (3)
(9)