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CHEMISTRY
Instructions (Q 1 to 6) : Single Option Correct type MCQs
1. An oxime (A) has two geometrical isomers when a mixture of both geometrical isomers is heated with conc. H2SO4 then
following two amides C and D are obtained
O O
||  ||
Ph  NH  C  CH 3 CH 3  N H  C  Ph
(70%) (30%)
Now, in the mixture, amount of which of the following geometrical isomers were more :

(A) (B)

(C) Both isomers were in 1 : 1 ratio (D) None

2. 1 mole of AgNO3 is added to 10 litre of 1 M NH3. What is the concentration of Ag(NH3)+ in solution?
[Given : For Ag (NH3)2+, Kf = 2.0 × 103; Kf = 104]
1 2
(A) 8 × 10–5 (B) 1.25 × 10–5 (C) 4 × 10–6 (D) 1.25 × 10–4

3. The orbitals occupy more space will have more “s” character and accordingly which is incorrect statement.
(A) l.p. will go to the axial position of PBP (pentagonal bipyramidal) geometry
(B) l.p.will go to the equitorial position of TBP (trigonal bipyramidal) geometry
(C) Axial bond lengths of PBP geometry is longer than equatorial
(D) Equatorial bond lengths of TBP geometry are shorter than axial

4. Hydrazine, a component of rocket fuel, undergoes combustion to yield N2 and H2O.

N2H4 (l) + O2 (g)  N2 (g) + 2H2O (l)
What is the change in internal energy for above reaction of N2H4 (in kJ/mole)?
Given : Reaction H/kJ
2NH3 (g) + 3N2O (g)  4N2 (g) + 3H2O (l) – 1011 kJ
N2O (g) + 3H2 (g)  N2H4 (l) + H2O (l) – 317 kJ
4NH3 (g) + O2 (g)  2N2H4 (l) + 2H2O (l) – 286 kJ
1
H2 (g) + O2 (g)  H2O (l) – 285 kJ
2
(A) – 620.5 (B) – 622.75 (C) 1167.5 (D) None of these
5. The complex having highest  value :
(A) [Ni(en)3]2+ (B) [Ni(CN)4]2– (C) [NiCl4]2– (D) [Ni(NH3)6]2+

6. In which of following reaction CO2 gas will be evolved.

CO2H O O
|| ||
(A) Ph–CH2–CH 

 (B) Ph  C  CH 2  C  OH  

CO2H
SO3H
NaHCO
(C) 
3
 (D) All
Δ

Instructions (Q 7 to 10) : Multiple Option Correct type MCQs.

7. Nitration of phenol follows parallel first order kinetics and gives o and p isomers as simultaneous products, o-isomer
being the major product.

OH
K1
NO2
OH
HNO3

OH
K2

NO2

Which of the following is correct regarding the given information ?

(A) Activation energy for formation of p-isomer is greater than the activation energy for formation of o-isomer
(B) Half life for the formtaion of p-isomer is greater than the half life for formation of o-isomer
K1
(C) If = 3 and t1/2 for o-isomer is 3 minutes then the overall half life of the reaction is 0.75 minutes
K2
(D) Activation energy of both the reactions will be same

8. For the following compound, correct statements is / are :

CHO CHO CHO
H OH H OH HO H
H OH H OH H OH
(I) H OH (II) HO H (III) H OH
H OH H OH H OH
CH2OH CH2OH CH2OH
(A) I and II are C4 epimer (B) II and III are C2 epimer
(C) I is diastereomers of II and III (D) All are optically active

9. Which of them has correct order of Lewis acidic nature ?

(A) BF3 > BCl3 (B) SiF4 > SiCl4 (C) BeF2 > BeCl2 (D) BCl3 > AlCl3
10. Which are identical compounds :

Cl
Cl
OH OH
(A) (B)
H Cl Cl
H

Cl Cl Me Me
Me Me
(C) (D)
Me Me Br NH2 H 2N Br
Cl Cl

MATHEMATICS
Instructions (Q 1 to 4) : Single Option Correct type MCQs

x2 y2
1. If the portion of the asymptotes between centre and the tangent at the vertex of hyperbola 2 – = 1 in the third
a b2
quadrant is cut by the line y + (x + a) = 0,  being parameter, then

1 1
(C)    0, 
1
(A)   R+ (B)  ,  (D) none of these
2 4  2

2. In a shooting competition a man can score 5, 4, 3, 2, 1 or 0 points for each shot. Then the number of different ways in
which he can score 30 in seven shots is :
(A) 6538 (B) 6539 (C) 6537 (D) none of these

3. One mapping is selected at random from all mappings of the set S = {1, 2, 3, …, n} into itself. If the probability that the
3
mapping is one-one is , then the value of n is
32
(A) 2 (B) 3 (C) 4 (D) none of these

4. Three equal circles, each of radius r touch one another. The radius of the circle touching all the three given circle,
internally is

(2  3) (2  3)
(A) (2  3)r (B) r (C) r (D) (2  3)r
3 3

Instructions (Q 5) : Multiple Option Correct type MCQs.

3  4i
5. If = x + iy, then the point (x, y) lies on same side of the line 2x + y – 6 = 0 as the point
1 i
(A) (3, 2) (B) (1, 3) (C) (1, 5) (D) (0, 0)

Instructions (Q 6 to 8) : Single Option Correct type MCQs based on below comprehension passage
2
4  e2 , then
Let f (x) is a differentiable function such that f ' (x) = f (x) +  f ( x)dx if f (0) =
0 3
6. f (x) is equal to

 e2  1   e2  1   e2  1 
(A) ex –   (B) ex +   (C) ex –  3  (D) none of these
 3   3   

7. The number of solution of x + f (x) = 0 is

(A) 0 (B) 1 (C) 2 (D) none of these

1
8.  f ( x)dx equal to
0

3e  e2  2 3e  e 2  4 3e  e2  4
(A) (B) (C) (D) none of these
3 3 3

Instructions (Q 9) : Assertion - Reason type MCQs.

   dx = 0
/2

9. Statement–1 : 
/ 2
sin log x  1  x 2

Statement–2 : 
a
f ( x) dx = 0 if f (x) is an odd function.

(A) Statement–1 is True, Statement–2 is True, Statement–2 is a correct explanation for Statement–1.
(B) Statement–1 is True, Statement–2 is True, Statement–2 is NOT a correct explanation for Statement–1.
(C) Statement–1 is True, Statement–2 is False.
(D) Statement–1 is False, Statement–2 is True.

PHYSICS
Instructions (Q 1 to 3) : Single Option Correct type MCQs
1. Block A of mass 2 m, B and C each of mass m are in equilibrium and at rest shown in the figure. The spring balance,
pulley and strings are massless. Now, a force mg is applied on block C in downward direction. Find the new reading of
spring balance. Assume all pulleys to be frictionless. (Given m = 2 kg)

2m
A

m m
B C

(A) 7 kg (B) 5 kg (C) 11 kg (D) 12 kg

2. A manufacturer is able to offer two models of heat-conserving windows, as described below. Window A is a simple pane
of glass, 4 mm thick. Window B, on the other hand, consists of two extremely thin panes of glass, separated by an air
gap of 2 mm, as shown in the figure below. If the thermal conductivity of glass is known to be 0.8 Wm–1K–1 and that of
air is 0.025 Wm–1K–1 , then the ratio of heat flow QA through Window A to the heat flow QB through Window B is given
QA
by =
QB

Outdoor Outdoor
Indoor Indoor
Glass Air

Glass Glass

4mm 2mm
Window A Window B

1 1
(A) 4 (B) 16 (C) (D)
4 16

3. An open pipe 0.400 m in length is placed vertically in a cylindrical bucket and nearly touches the bottom of the bucket
which has an area of 0.100 m2. Water is slowly poured into the bucket until a sounding tuning fork of frequency 440 Hz,
held over the pipe, produces resonance. Find the mass of water in the bucket at this moment. Take speed of sound in
air as 330 m/s :
(A) 18.75 kg (B) 21.25 kg (C) 40.00 kg (D) 26.75 kg

Instructions (Q 4 to 6) : Multiple Option Correct type MCQs.

4. A plank is moving along a smooth surface with a constant speed V. A block of mass M is gently placed on it. Initially the
block slips and then acquires the constant speed (V) same as the plank. Throughout the period, a horizontal force is
applied on the plank to keep its speed constant.

M
V

smooth

(A) the work performed by the external force is MV2

(B) the work performed by the external force is 1/2 MV2
(C) the heat developed due to friction between the block and the plank is 1/2 MV2
(D) the heat developed due to friction between the block and the plank is 1/4 MV2

5. A simple pendulum of length 1 m hangs at rest. It is suddenly projected with a horizontal velocity 10 m/s. Then (mass
of the bob = 0.5 kg.)
(A) velocity of the bob when string becomes horizontal is 8.97 m/s
(B) velocity of the bob when string becomes horizontal is 17.94 m/s
(C) tension in the string when string becomes horizontal is 20.1 N
(D) tension in the string when string becomes horizontal is 40.2 N
6. Plane rectangular loop is placed in a magnetic field. The emf induced in the loop due to this field is i whose maximum

value is im. The loop was pulled out of the magnetic field at a variable velocity. Assume the B is uniform and constant.
i is plotted against time t as shown in the graph. Which of the following are/is correct statement(s) :

0 =0
× × ×
× × ×
× × ×
× × ×

(A) im is independent of rate of removal of coil from the field.

(B) The total charge that passes through any point of the loop in the process of complete removal of the loop does not
depend on velocity of removal.
(C) The total area under the curve (i vs t) is independent of rate of removal of coil from the field.
(D) The area under the curve is dependent on the rate of removal of the coil.

Instructions (Q 7) : Numerical Value Answer type question. Answer to be calculated upto two decimal places

7. Intensity observed in an interference pattern is I = I0 sin2. At  = 30°, intensity I = 5 ± 0.0020 W/m2. If I0 = 20 W/m2 and
n
percentage error in angle  is 3 × 10–2 %, then the value of n is.


Instructions (Q 8 to 10) : Single Option Correct type MCQs based on below comprehension passage
In the circuit shown, switch K is initially open. Both the cells are ideal and C = 30µF, E1 = 1V, R1 = 2, E2 = 3V,
R2 = 4. At t = 0 second, the switch K is closed. A and B are two points on circuit as shown.

1 2

1 2

8. Just after the switch K is closed, the magnitude of current in amperes through resistance R1 is :
1 4
(A) (B) (C) 1 (D) 2
3 3

9. VA and VB are potentials of points A and B respectively. After the switch K is closed, the potential difference VB – VA.
(A) Remains constant
(B) Decreases
(C) Increases and then becomes constant after long time
(D) Decreases and then becomes constant after long time

10. Long after the switch K is closed, the magnitude of charge on the capacitor in steady state is :
(A) 10 C (B) 30 C (C) 50 C (D) 90 C

* * * * *
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CHEMISTRY
1. (B) 2. (B) 3. (C) 4. (A)
5. (B) 6. (D) 7. (A, B) 8. (A, C, D)
9. (B, D) 10. (A, B, C, D)

MATHEMATICS
1. (C) 2. (D) 3. (C) 4. (B)
5. (A, C) 6. (A) 7. (B) 8. (A)
9. (A)

PHYSICS
1. (B) 2. (B) 3. (B) 4. (A, C)
5. (A, D) 6. (B, C) 7. (4) 8. (A)
9. (A) 10. (C)

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