DPP # 13 TIME : 30 MIN.

1. Column - I Column - II

Cl Cl Cl Cl

(A) and (P) Structural isomers

H Me Me H

CH3 CH3 CH3 H

(B) and (Q) Compounds are optical isomers and enantiomers
H H H CH3

Me Me H
H
C C
(C) and (R) Compounds which are geometrical isomer and
C C
Et O
H CH2–CH2–COOH C H

O
diastereo isomers

COOH COOH
H OH HO H
(D) and (S) Compounds are geometrical isomer and
H OH HO H
COOEt COOEt enantiomers

(T) Compounds can show geometrical isomersim

2. ¾H¾¾
2SO 4
®
OH

Which carbocation is involved in the above reaction ?

(A) (B) (C) Both (D) None of these

+ +

(i) conc. H2SO4

3. CH3—CH = CH2 Major product
18
(ii) H3O

(A) CH3—CH—CH3 (B) CH3—CH—CH3 (C) CH3—CH2—CH2 (D) CH3—CH—CH3

OH 18OH OH O

C.O.: NAIVEDHYAM, Plot No. SP-11, Old INOX, Indira Vihar, Kota (Raj.) 324005 Ph. 0744-2799900 1
Online Partner UNACADEMY
 +
4. ¾H¾® X, X is:
D

(A) (B) (C) (D)

5. What is the correct order of heterolytic bond energy of C–Br bond

Br Br
Br
Br

(I) (II) (III) (IV)

6. Which of the following pair represent enantiomers :

CH3 CH3
Cl Br
H OH HO H
(A) H OH HO H (B)
HO H H OH Br Cl
CH3 CH3
Me Me H Me
(C) C=C=C C=C=C (D)
H H Me H

7. How many 1,2-shifts are involved in the following rearrangement of carbocaiton ?

Å
Å

8. In which of the following solvent Cl will behave better nucleophile than I
(1) H2O (2) HCOOH (3) HCONMe2 (4) CCl4
(5) CH3COCH3 (6) (Me2N)3P = 0 (7) 1,4,7,10 tetraoxa cyclododecane

9. Number of alcohols which on H+/D gives following alkene as a major product.

C.O.: NAIVEDHYAM, Plot No. SP-11, Old INOX, Indira Vihar, Kota (Raj.) 324005 Ph. 0744-2799900 2
Online Partner UNACADEMY
 Q.10 Indicate whether each of the following structure has the R configuration or the S-configuration. [21]

(a) (b) (c) (d)

(e) (f) (g) (h)

(i) (j) (k) (l)

(m) (n) (o) (p)

CH2CH3
CH3 H
(q) (r) (s) (t) Br CH3
CH2CH3

(u)

C.O.: NAIVEDHYAM, Plot No. SP-11, Old INOX, Indira Vihar, Kota (Raj.) 324005 Ph. 0744-2799900 3
Online Partner UNACADEMY