DPP # 15 TIME : 30 MIN.

1. Match the column :

Column I Column II

(A) (P) Three fold axis of symmetry

Cl Cl
Cl
(B) (Q) Three fold alternative axis of symmetry

(In given form only)

Br

Cl
(C) I (R) Odd number of degree of unsaturation

F
(D) Gauche form of n-butane (S) Chiral compound

(T) Centre of symmetry

2. Major product in following reaction is :

CH2–OH
Conc.H 2SO 4
 

CH2
CH2 CH3 CH2– HSO4

(A) (B) (C) (D)

OH
3. Which of the following(s) can show optical isomerism :
Me Br

H Me Me O
(A) Cl (B) H Cl (C) H (D)
Me Me C=C O
H Cl Me Et
Me

C.O.: NAIVEDHYAM, Plot No. SP-11, Old INOX, Indira Vihar, Kota (Raj.) 324005 Ph. 0744-2799900 1
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4. Major product in following reaction is :
Ph Ph

H
14



OH OH

Ph Ph O
O

(A) C Ph (B) C Ph
14 14
14

Ph Ph O
O

(C) C (D) 14
C
14

Ph Ph
5. Correct relations between (I), (II), (III) & (IV) is :

(I) (II) (III) (D)

(A) I, III are Diastereomer (B)I & II are Enantiomer

(C) II, III are Identical (D) II & IV are Identical

6. Major product in following reaction is :

OH
OH 
H



O
OH
(A) (B) (C) (D)
O
O
7. Which of the following reaction will produce same major product ?

(A) (B)

(C) (D)

C.O.: NAIVEDHYAM, Plot No. SP-11, Old INOX, Indira Vihar, Kota (Raj.) 324005 Ph. 0744-2799900 2
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8. Major product in following reaction is :
Me
H Et
NaNO 2 / HCl
H Et 
Me Et
CH2NH2

Me Me
H Et H EtMe
Me H OH
H Et H Et H Et H Et
(B) H
CH2 Et CH2
(A) (C) (D) H Et
HO Et Me H
Me OH HO Me
Pr Pr
Et Et

9. How many alcohols shows faster dehydration reaction rate than 2-methyl propan-2-ol ?
OH
OH
(i) OH (ii) Ph (iii) (iv)
OH

OH
OH OH OH
(v) (vi) (vii) (viii)

OH
OH
(ix) (x)

10. Give major product of following reaction.

CH 3
| conc.H SO H 3PO 4
(a) CH 3CH 2CH 2CH 2CCH 2OH  24  (b) CH 3CHCH 2CH 2CH 2  
45C

| | |
CH 3 OH OH
18

C.O.: NAIVEDHYAM, Plot No. SP-11, Old INOX, Indira Vihar, Kota (Raj.) 324005 Ph. 0744-2799900 3
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