ORGANIC CHEMISTRY

ENTHUSE
DPP # 19

1. Column-I (Reaction) Column-II (Intermediate)

(A) Wurtz reaction (P) Carbocation
(B) Dehydration of alcohol with conc. H3PO4 (Q) Electrophile (excluding free radicals)
(C) Kolbe's Electrolysis (R) Free radical
(D) Diazotisation (S) Carbanion
(T) N2 gas liberated in Intermediate step

2. Statement-1 : Propane on photochlorination gives 2-chloro propane as major product.

Statement-2 : 2° carbocation is more stable than 1° carbocation.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.
3. Major product of the following reaction is :

(A) (B)

I O
I
(C) (D) ONa

4. Total number of the monobrominated products formed in the following reaction is :

CH2 NBS

h

(A) 5 (B) 6 (C) 7 (D) 4

5. Major product of the following reaction is :
Ph Me

Cl2
18

CH3OH excess ,

H H
Ph Ph Ph Ph
18

H H H Cl H Cl H CH3O
(A) CH3 (B) H (C) CH3O (D) Cl
18
18
H OCH3 H H
H H CH3 CH3

H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, 0744-2423333 1
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 ORGANIC CHEMISTRY
ENTHUSE
6. The incorrect statement about the major product (P) of the reaction is/are :

H Me
Br2 /CCl4
P
Me H
(A) P is optically inactive due to internal compensation
(B) P is optically inactive due to the presence of plane of symmetry in the molecule
(C) The structure P posses 4 optical isomerism
(D) Compound P does not show optical isomerism

7. Potential energy diagram for the formation of major product in above reaction.

dil H 2SO 4


(A) (B) (C) (D)

8. Major product obtained in following sequence is :

Cl
(A) (B) (C) (D)
Cl Cl Cl

9. Total number of theoritically possible dichloro derivatives are :

Cl
Cl
2 
h

10. Give product(s) in each of the following reactions

(A) CH3 – CH – CH2 – CH2– CH3 Br / hv

2 
|
CH 3

( C H CO ) O
(B) + NBS 6 5  2

hv
(C) CH3 – CH2 – CH = CH2 + Me3COCl 
CH 3
|
CH3  C O  Cl / 
|
CH3
(D) C6H5 – CH2 – CH2 – CH3     

H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, 0744-2423333 2
www. nucleuseducation.in