wich one of the following compounds agives a primary alcohol upon reaction witn

methyl magnesium bromide?

(AEthylene oxide " a s R - 0 1
(B) Propylene oxide
CO,+2 coH
(C) Ethyl formate
(D) Carbon dioxide
2 Which one of the following statements is correct for alkyl halide ?
(A) Alkyl halide will always show Sy1 mechanism
E1
(B) In a unimolecular reaction increasing the temperature does not favour
mechanism
(C) E1 mechanism is favored over S1 mechanism for primary alkyl halides
0) E1mechanism is favored over S1 mechanismfor tertiary alkyl halides
3. Aryl halides are less reactive towards nucleophilic substitution reactions as compared
to alkyl halides This is dueto
Ct,e
(A) Theformation ofa less stable carbanion
(B) The inductive effect
(C) Longer carbon halogen bond
(D) sp-hybridized carboh attached to the halogen (o
4 Identify the reactant X in the following reaction sequence:
Br
NaNO2 Z CHsOH
X Br/H,0 Y- HCI
A
Br u
Nh
(A) Benzoic acid
Na N,
(B) Salicylic acid H
(CAniline
(D) Phenol ,/9ko
(3) (Turn over)
XL-25/10
 5. Which
one of the following structures represent the major productsin the following
reaction ?

CH3
H-OH HBr
H,CH ?

C2Hs

ÇH3 CH3
HBr Br-H
(A) HCH HCH
CHs GpHs

CH3
CH3 HH
(B) HCBr BrCH
CHs
H . PH
(C) HCBr H,C-H
CHs CaHs

CH CH
(D) HCHH-CH
HBr BrH
CaHs CaHs

6. If 2-methyl butane will be

subjected to monobromination, then hoW many isomers will
it form ?

(A) 4

(B) 6
A
C) 5
(D) 2

XL-25/10
(4) (Continued)
 caiculate the max value for the following compound using Woodward and FisCne
ules:

(A) 254 nm
(B) 279 nm
(C) 290 nm
(D) 315 am
Which one of the following compounds with molecular formula C,H,NO, shows
H-NMR peaks at 8 5.30 (broad, 1H), 4.10(q, 2H), 2.80 (d, 3H) and 1.20 (t, 3H)
ppm ?

(A) CH,CH,NHCOOCH
(B) CH,oCH,cONHCH
(C) CH NHCOOCH,CH
(D) CH,CH,OCH,CONH
treatment
9. The sodium extract of an organic compound develops a blood-red color on
is
with FeCl, solution. The ion responsible for this colortest
(A) CN
(B) NCS
(C) CNO
(D) s
statements is correct regarding the following reaction?
10. Which one of the following
CH t-BuOK*
?
t-BuOH

alkene formed according to Saytzeff

Major product is endocyclic
(A)
alkene formed according to Saytzeff
Major product is exocyclic
(B) to Hoffmann
alkene formed according
(C) Major product is endocyclic Hoffmann
alkene formed according to
productis exocyclic
(D) Major
(Turnover)
(5)
XL-25/10
 11. Suggest the product of the following reaction
CA

H
oCHs NaOCH?
OH

(A) CHs
H,COOH
H
(B)
CH
oH

(C)
H
IcHs
OCHs

(D) CH

12 Which one of the following reactions is not an

example of E1CB reaction ?
(A) OH
OHO OH
(B) Ph Ph OH

OH
(C) MsCl
i) NMes

(D) t-BuO

XL-25/10 (6) (Continued)

 13. What is the correct
statement for the given reacions
OT OT
(A) CH,COOX CH,COO Y
(B)
OcoCH CH,COOH
CHCOOH
OcOCH
(A) Breacts faster than A
(B) Both give the same product

(C) A gives cis- and B gives trans-product

(D) Agives trans- and B gives cis-product

14. Which is the correct order of nucleophilicity in the following options ?

A) (CHco>CH5
(B) (CH,CH,),N> (CH,CH,),P
(C) CH,S> CH,SH
() CH,CH,CH,0< (CH),co
Which one ofthe following statements is true about the reaction given below?
15
A NaOCH H,co
CH,OH

(A) Itproceeds via a concerted Sy2 pathway

carbanion intermediate
(B) Itinvolves a
carbocation intermediate
(C) It involves a
(D) It proceeds via a
concerted S,1 pathway
substituents on the benzene ring is not a meta directing
16. Which one ofthe following
substitution reaction?
group in an electrophilic

(A) CF
(B) NO
(C) Br

(D) NH
(7) (Turnover)
XL-25/10
17. Which one ofthe following alkanes exhibits optical activity?

(A) Neopentane
(B) Isopentane
(C) 3-Methylpentane
(D) 3-Methylhexane
18. Vvnat will be the most appropriate reagentfor the following transforiauon

(A) CHN2
(B) Ph P=CH2

(C) CH,Li
(D) (CH),CuLi
19. Which one ofthe following carbocations is the most stable ?

(A)

(B)

3 H

(C)

( D ) + t R a m

20. Name the process associated with

acylation of benzene
(AFriedel craftreaction
(B) Wurtz reaction
(C) Wurtz fitting reaction
(D) Aldol reaction

XL-25/10
(8)
(Continued)
 21. Nhich one of the
Wh
(A) First following statementsIsis incorrect
i ?
step in
(B) When a photochemis
emistry is the excitation of electron
olecule or atom the
excited to a higher in ground state (S) absorbslight, one electron is
orbital level
C)Photochemical
(D) Itis possible for reactions are caused by absorption of ultraviolet
light only
the
excited state S, to undergo spin inversion
22. Arrange the
following intermediates in the
descending order of thelr sla
HO H, H,N H, H,
(1) (1)
H, C C
(11) (V
(A) 1>1>Ill >V
(B) ll>>||l>I
(C)I11>IV>ll (D) Il>1>ll>V
23 The IUPAC name
of the following compound is:
C

Br
A) 5-bromo-4-chlorohept-1-en-6-yne
(B) 5-bromo-4-chlorohept-6-en-1-yne
(C) 3-bromo-4-chlorohept-6-en-1-yne
(D) 3-bromo-4-chlorohept-1-en-6-yne
24. Which type of macromolecule carries out catalysis in biological systems?
(A) Proteins (B) Carbohydrates
(C) Lipids (D) Nucleic acids

25. Anucleotide is constituted from which ofthe following units?

(A) Nitrogen base and phosphate

(B) Nitrogen base, sugar and phosphate

(C) Nitrogen base and sugar
(D) Sugar and phosphate
at equilibrium is:
26 The change in free energy ofareacton
(B) Positive
(A) Negative
(D) Difficult to predict
(C) Zero
(9) (Turn over)
XL-25/10
 2
L a ' j l
2

reactant doubles the half-life period ("1/2) of

21 doubling the initial concentration of a
the reaction, then the order the reaction is
of
(A) 3 P 2
(C) 1 (D)
28. If Is the wave function, then what is the probability offinding an electron in a given

region within the atom?

(A) (B)
(C) (D) 12
29 One coulomb is the charge of
(A) One mole of electron (B) 1/96500 mole of electron
(C) 96500 mole of electron (D) None of these
an
30 The pressure correction in the
der Waals equation is due to the
van
P

(A)Attractive force of the molecules toward the interior

p - =n

(B) Attractive force of the moleculestoward the boundary wall P n r

(C) Repulsive force of the molecules toward the interior

(D) Repulsive force of the molecules toward the boundary wall
31 The relationship between Cp and Cyfor n mole ofidealgas is
(A) C,C, +nR (BC=C,+nR
(C) C, C,+nRT D) C= C, +nRT
32. Therelationship between the contact angle and wettability of a liquidis:
(A) Proportional B)Anversely proportional
(C) Independent (D) None of these 729
33 What will be the amount of work done if 10 moles of an ideal monoatomic gas at 10
a t m pressure and 27 C temperature is allowed to expand isothermally against a
3
constant pressure of 1 atm ? W P A V

(A) -5.36 kcal B 5.36 kcal

(C)-4.32kcal (D) 4.32 kcal 2x10 ' 1

34. Which of the following is not applicable to the adsorption

phenomena? a l D l o g t d

(A) Langmuir equation (B) BET equation

CHenderson equation (D) Freundlich equation
35 Which one ofthe following terms is not associated with phase rule?
(A) Triple point (B) Eutectic point
(C) Critical point (D) Plait point
XL-25/10 (10) (Continued)
 aCt D,

36. Which of the following is an intensive

(A) Speific heat property (B) Molar volume
C P+1

()SurfaceTension (DY All ofthese

37
37 What is the degree of freedom of 0.1N aqueous solution of NaCl ?
(A) 3 B) 2 ,

(C) 0
)1 2Na HPO

38. What is the ionic strength of 0.2 M of

Na, HP0,? 2
(A) 0.4 M (B) 0.5 M mia
CD.6 M (D) 0.8 M 1 -
39. Which ofthe following is not the rate expression for a reaction A+28

dA 1 dB
(A) dt
(B) 2 dt
(C)
A

(D)
dP AH T 3
dt 3 dt

40. At equilibrium, the process of adsorption involves

v I Y o

(A) AH >>0 (B) AH=TAS

(D)AH TAS
(C) AH> TASS
colour ofthe solution of Awillbe
41 lf molecule Aabsorbs light energy around 630 nm, the

(A) Red (B) Blue

(D)Yellow C-hanare ) Ra Pthe
(C) Green
has a large negative reduction potential. The
42. The half cellA +e A
consequence will be:
(B) Ais readily oxidized A
(A Ais readily reduced
(D) ATis readily oxidized
A is readily reduced
(C)
titration involving a strong acid and a strong base using
43
43. Atthe end point of acid-base
of solution would be
the
an appropriate indicator,the pH
(B) Slightly acidic g
(A) Slightlyalkaline
(D) Strongly alkaline
(C) Neutral
bimolecular reaction, the activated complex has:
44. According to transition state theoryfor a
(A) Novibrational degrees of freedom
but never participate in product formation
(B) Vibrational degrees of freedom they
vibration that leads to product formation
(One high frequency
that leads to product formation
(D) One low frequency vibration
XL-25/10 (11) (Turn over)
 Yt
45. The unit of molarextinction coefficient is:
(A) Litmor cm (B) Lit.mol.cm
(C) Lit.mol.cm (D) Lir.mor".cm
46 Which of the following statements is correct?
A Hand ,He"are isotopes (B)Cand ,N are isotopes
(C) 19k and 20 Ca are isotones
(D)F and ,, Na"are isobars
47. Amolecule is Raman active, if:
the molecule is polarisable
(B) the molecule is paramagnetic
(C) the molecule contains non-bonding electrons
(DY the molecule contains centre of symmetry
48. Cathode rays are deflected towards
(A) Positive electrode (BNegative electrode
(C) Both (A) and (B) None ofthese 2P 0
49. Which is not a renewable energy ?
(A) Solar Energy (B) Wind Energy
(C) Tidal Energy
(LPG
50. After bubbling air through pure water
(pH 7.0), its pH decreased. Which of the following
is responsible for the pH change?
(A) N Y CO 8
(C) H2 (D) O 0
51. Which of the following is the correct order 0v
with respect to their relative stabilities ?
(A) OO2 >0~ >O2 (B) O> O2 > Og> O
(C) Op O>0z0 (b) o Oz>OO2
52. According to Bohr's theory, the angular momentum of an electron ON
in the 5" orbit is:
(A) 25 T () 10 %
Sqanmd
bnd
tr

bmeonelon
(C) 10 5

53 In a crystal lattice, the Madelung constant depends on the:

(A) lonic radius of the cation
(B) lonic radius of the anion
VSCr
(C) Nature of the crystal system
(D) lonic radius of both cation and anions
XL-25/10
(12) (Continued)
 INa A
54 Which of the following is
the correct order of ionic
(A) Na <Mg <AP <sit raa Na,moyM
(B) A<S <Na'>Mg 9 1 13Y
(C)si <A Mg >Na () Na>Mg">ASi
55. Which of the following pairs
A m

corresponds to soft base pair NA

(A) NO, (B) RS, 0
(C) CO,cH,COO
(D) SCN.S,03
56. The ionic compound which indicates
(A) (Sio
pyrosilicate is
C) [(Sio. 2n
(B) (Si,O
(D) (Si0,
57. he reaction of XeF; with CsF produces a compound that undergoes decomposition
after50 9C. The compound is:
(A) CsXeFs (B) CsXeFs
(C) CsXeF7 (D) Cs XeF15
58. What are the precursors used for the synthesis of borazine in Stock's process ?
(A) BH, and NHg B) NH,CIl and NaBH,
(C) NH,Cl and BCl (D) NH and BCl

59 Which type of isomerism exists between [Co(NH3),Br|SO, and [Co(NH3)s(SO15r

compounds?
(A) Linkage isomerism
(B) Coordination isomerism
Clonization isomerism yCo
(D) Coordination position isomerism
60. The primary and secondary valences ofcobalt atom in [Co(NH,),Cl,]Cl complex
are

1 and6 t H o

(A)3 and4
(C) 4 and 3 (D) 3 and 6

61. The rate of reversible hydration ofcarbon

dioxide is accelerated by which of the
followingbiomolecules? 0
(A) Carboxypeptidase (B)Carbonic an hydrase

(C) Haemoglobin (D) Catalase

one which shows zero crystal field stabilization
62. Among the following complexes, the
energy is
(A) [MnH,O)" FeH,o)
(C) [ColH,0)* (D) ICo(H,O)J"
XL-25/10 (13) 36 (Turnover)
 4+6 1

63 follows 18-electron rule. Which of thefollowing first

ne complex(n-C,H,)M(CO),
row transition metal is (M) present
in it ?
(A) Co N
(C) Mn
(B)Fe
(D) Ni
64. One mole of
[PtCiwhile reacting with two moles of NH,gives
(A) cis-P(NH),Cl}
8)trans-Pt(NH3),Cl
(C) Pt(NH),C
(D) [Pt(NH,) Cl
65. The reaction of NaCl and
K,Cr,0, in the presence of conc. H,SO, produces a vapo
that turns
aqueous solution of NaOH into yellow colour. While treating this yelloW
color solution with lead acetate
aqueous in the presence of excess
t gives yellow precipitate. CH,C00,
Which of the following compounds does correspond to
this vapor ?
(A) CrO,C (B) CrO,Clh
a d i d n - r

3-0-t
(C) Na,Cro (D) CrOClh 2

66. The number of

radial nodes present in 3s and 3d orbitalsrespectivelyare: 2
-1

(A) 2 and 0 (B) 0 and 2 O

(C) 3 and2 (D) 2 and 1

67. The brown ring complex compound is formulated as [Fe(H,0)5(NO)]SO The
oxidation state of iron in this compound is:
+3 (B) +2
(C) +1 (D) 0
Sp
68. Which of the following hybridization is present in CIF, molecule?
1 (A) dsp Bspd
F

sp'd (D) sp3

69 Which of the following sets of quantum numbers are correct for an
the 4f orbital ?
electron presentin
A) p4, l= 3, m = +4, s =+ ? (B) n 3, = 2, m =-2, S = +
Cn=4, (=3, m=+1,s=+ (D) n=4, = 4, m =-4, s=-
70. Which of the following is the incorrect statement
about Zeise's salt? n
L-3
(A) Zeise's salt is diamagnetic
(B) All the Pt-Cl bond lengths in Zeise's salt are equal
(C) Oxidation state of Pt in Zeise's salt is +2 X
(D) C-C bond length of ethylene moiety in Zeise's salt is longer than the free
ethylene molecule

XL-25/10 (14) (Continued)