Total Pages-12 PG-IV-Sem

Chem-402

2022
PG FOURTH SEMESTER EXAMINATION,

CHEMISTRY

(Organic Chemistry- IV)

[Science
Paper-402
Full Marks: 80

Time: 3 hours
Answer all questions

Marks hae been mentioned in the right-hand corner

1. Answer all the questions (multiple choice

questions) Ix12
()Which regions of the light radiations of the
visible ultraviolet lying betwcen the follo-
wing wavelengths are chiefly concerned in
bringing about photochemical reactions?
(a) 1000 A and 2000 AA

TurnOver)
 2 3
b) Ph Ph
(6) 1500 A and 1000 A
(c) 8000 Å and 2000A
Ph Ph
(d) 19,000 A and 12,000 A ( ) O H Ph Ph
H
(i) Which following are the reactions in
ofthe
which molecules absorbing light do not Ph-
themselves react but induce other molecules
Ph
to react ?
(a) Free radical reactions (d) Ph
(b) Chain reactions
(c) Reversible reactions
Ph
(a) Photosensitized reactions
(iv) The Barton reaction involves the photolysis
(iii) What will be the probable product of the of an
following photochemical reaction?
(a) Alkyl nitrate
Ph
Cb) Alkyl nitrite
O Ph
Ph h (P (c)Alkylcyanide
(d) Alkyl sulphide
Ph
() Vision is initiated by a photochemical reac
(a) Ph Ph tion of
(a) Rhodopsin
PG-IV Sem/Chem-402 (Continued) PG-IV-Sem/Chem-402 Turn Over)
 4
5)
(b) Enzymes (a) Molecule
(c)Mercapton (b) Cofactors
(d) Hydrogen Chloride ()Enzyme
(d) None of these
(vi) Which of the following is impossible as a
resonance form of ozone? (ix) Pyridoxal phosphate is a coenzyme and
active form of
(a)
(a) Vitamin B
(b) (b) Vitamin B,
(c) Vitamin B
(d)VitaminB,
O=o
(c) O=0 o
()Chymotrypsin helps to break down
(d)o 0-6 (a) Fat
(b) Proteins
(vii) The ligand system present in vitaminB,, is () Carbohydrates
(a) Prophyrin (d) Nucleic acids
(6) Corrin
(c) Phthalocyanine (xi) One NADH approximately provides
( ) Crown ether number ofATPs through oxidative phos-
phorylation
(viii) Which of the following species brings
(a)1
substrate and catalytic group together ?
PG-IV-Sem/Chem-402 (Continued)
PG-IV-Sem/Chem-402 (Turn Over)
 6) 7)
of the
(8) 4 (i) Write down the probable product
Cc)3
following reaction:
Ph
() 6
(xi) Lactose is a disaccharide sugar formed
through condensation reaction of
Ph
(a) One glucose and one fructose
(b) Two fructose of the
(iii) Write down the probable product
(c) Two glucose followingreaction:
(a) One glucose and one galactose
tBu
2. Answer any eight questions selecting two hv
I atm O
questions from each Unit (Very short answer
type question within two tothree sentences): 2 x8
O
UNIT- I
UNIT I I
( Write down the probable product of the
() Discuss one example of photochemical
aro-
following reaction matic substitution reaction.
(i) What is Barton reaction?
hv
mechanism of vision.
(iii) Discuss the
Turn Over )
PG-IV- Sem/Chem-402 PG-IV Sem/Chem-402
(Continued)
 8
9
UNIT- II
UNIT- I
() Write down the structure ofNAD+. Write down the of the
) probable product
What is role of coenzymes ?
following reaction
(ii)
B hv
(ii) Write down the food sources of Vitamin 185 nm
and mention one abnormality associated due
todeficiency of Vit-B2
(ii) Discuss about photoisomerization of azo
UNIT- IV benzene.
What is the requirement ofATP hydrolysis
() (iii) What is Norris type II reaction? Explain with
in nitrogen fixation ? a suitable example.
How can you get a sucrose molecule from UNIT I I
(ii)
condensation reaction of D-glucose annd
D-fructose ? () Discuss the mechanism of photoiso-
merization of benzene to fulvene.
(iin What are cofactors ?
(i) How can you degrade polymers by light ?
fwo
3. Answer any eight questions selecting reaction of for-
questions from each Unit (Short answer type (ii) Discuss the photochemical
3x8 mation of smog.
question within 75 words)
(Turn Over)
PG-IV-Sem/Chem-402 (Continued) PG-IV-Sem/Chem-402
 11)
10
UNIT-III
hv hv
Discuss the role of
carboxypeptidase A. direct sens.
()
biochemical step involving
(i) Write down one
of the following
(i) Propose the mechanism
the FAD as oxidant. transfomations:
and holoenzyme. O
(ii) Distinguish apoenzyme hv
UNIT- IV
Discuss the mechanism
of isomerisation
() to fructose
reaction of glucose-6-phosphate O
-6-phosphate during glycolysis.
H
intermediate
(ii) Give one example of enolic
reaction.
produced during the isomerization
UNIT- II
(iii) Write down one example of biochemical
decarboxylation reaction.
() What is the structure of "A" in the following
reaction ? Discuss the mechanism of the
4. Answer any one question from each Unit. (Long following reaction.
answertype question): 7x4
UNIT - I
hv
( Discuss the mechanism of the following
reactions.
PG-IV-SemChem-402 (Continued) PG-IV-SemChem402 Tr Cer
 12

(i) ldentify (A), (B) and (C) and write down the
mechanism of their formation.

Ph hv

Ph
=0
A+B+C
UNIT - Il

() Establish the structure of vitamine-B

(ii) Write the structure of thiamine
pyrophos-
phate and identify its active site of reaction.
Describe its role in the mechanism of a
decarboxylation reaction.
UNIT - IV

() How fructose-6-phosphate is converted to

fructose-1,6-bisphosphate involving nucleo-
philic displacement at phosphorous in ATP?
Explain with mechanism.
(i) What is the difference between specific and
general acid catalyst? Explain by giving
suitable examples.

PG-IV SenmChen 402

MG-100