ERDMANN EXAM 3 SPRING 2019 CH 117 Name__________________________________

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THERE ARE 20 MULTIPLE CHOICE QUESTIONS, EACH WORTH 5 POINTS.
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ERDMANN EXAM 3 SPRING 2019 CH 117 Name__________________________________

k2 Ea 1 1
ln = ( − )
Quadratic formula: x =  b  b  4ac k1 R T1 T2
2

2a
 Ea k2 Ea 1 1
Arrhenius Equation: k = A e RT ln = − ( − )
k1 R T2 T1
[A]t = kt + [A]o
ln[A]t = kt + ln[A]o K T2 ∆H o 1 1
1/[A]t = kt + 1/[A]o ln ( )= ( − )
K T1 R T1 T2
0.693
t½ = 𝑘 for a first-order reaction
R = 8.31 J/mol [𝑐𝑜𝑛𝑗. 𝑏𝑎𝑠𝑒]
𝑝𝐻 = 𝑝𝐾𝑎 + log ( )
R = 0.0821 L*atm/mol*K [𝑐𝑜𝑛𝑗. 𝑎𝑐𝑖𝑑]

Tb = Kb*m*i Go = Ho  TSo

Tb = Kf*m*i 
 = iMRT Go = RTlnK
Kw = Ka*Kb
G = Go + RTlnQ

Go = nFEo

0.0257
𝐸𝑜 = 𝑙𝑛𝐾
𝑛

0.0592
𝐸 = 𝐸𝑜 − 𝑙𝑜𝑔𝑄
𝑛

1C = 1A*1sec
1F = 1mol e/96500 C

Standard Reduction Potentials V

F2(g) + 2e  2F-(aq) +2.87
Cl2(g) + 2e  2Cl-(aq) +1.36
Ag+(aq) + e  Ag(s) +0.80
Fe3+(aq) + 2e Fe2+(aq) +0.77
I2(g) + 2e  2I-(aq) +0.54
Cu2+(aq) + 2e  Cu(s) +0.34
2H+(aq) + 2e  H2(g) 0
Pb2+(aq) + 2e  Pb(s) -0.13
Fe2+(aq) + 2e  Fe(s) -0.44
Cr3+(aq) + 3e  Cr(s) -0.73
Zn2+(aq) + 2e  Zn(s) -0.76
Mg2+(aq) + 2e  Mg(s) -2.36
 ERDMANN EXAM 3 SPRING CH 117 Name__________________________________

1. Which of the following describes what happens to 6. Which of the following salts is most soluble in pure
the solubility of a slightly soluble ionic compound water?
when a common ion is added to the solution? A. AgI, Ksp = 8.5×10-17
A. There is no effect on the solubility of the B. ZnS, Ksp = 1.6×10-24
ionic compound. C. CuS, Ksp = 8.7×10-36
D. HgS, Ksp = 2.0×10-53
B. The solubility of the ionic compound is
reduced.
7. What conditions would apply to a reaction that is
C. The solubility of the ionic compound is not spontaneous at low temperature but becomes
increased. spontaneous at higher temperatures?
D. The ionic compound dissolves more rapidly. A. It is exothermic and decreases in entropy.
B. It is exothermic and increases in entropy.
2. Which of the following reactions leads to an C. It is endothermic and decreases in entropy.
increase in entropy of the system? D. It is endothermic and increases in entropy.
A. CH4(g) + 2O2(g) ⇌ CO2(g) + 2H2O(l) 8. Which of the species in the following
B. CaO(s) + CO2(g) ⇌ CaCO3(s) electrochemical reaction is oxidized?
C. 2HI(g) + Cl2(g) ⇌ 2HCl(g) + I2(s) Mg(s) + Cu2+(aq) ⇌ Mg2+(aq) + Cu(s)
D. NH4Cl(s) ⇌ HCl(g) + NH3(g) A. Cu(s) B. Mg(s)
2+
C. Mg (aq) D. Cu2+(aq)
3. Above what temperature, in °C, will the following
reaction become spontaneous? Assume free energy, 9. In the titration of 20.0 mL of 0.200 M HOBr with
enthalpy, and entropy are not temperature 0.100 M NaOH, what is the pH after 20.0 mL of the
dependent. NaOH solution is added? (Ka HOBr = 2.5×10-9)
N2O4(g) ⇌ 2 NO2(g) G° = 4.801 A. 8.60 B. 7.00
C. 4.65 D. 5.74
Hf° kJ/mol 9.16 33.18
S° J/mol 304.2 240.0
10. What mass, in g, of copper will be deposited from
A. 325.4 B. 52.4
C. 4.80 D. 0.32 a solution of Cu2+ by a current of 2.50 A in
*I gave credit for both the K and C answers. 2.00 h?
A. 0.187 B. 1.65
4. Which of the following mixtures/solutions could C. 5.93 D. 11.9
produce a buffer solution?
A. 50 mL 1 M HCl + 50 mL 1 M NH3 11. Refer to the standard reduction table located on
B. 50 mL 1 M HCl + 50 mL 1 M NaOH the equation sheet. Calculate the value of Keq at 25°
C. 25 mL 1 M NaOH + 50 mL 1 M CH3COOH C for the reaction:
D. 25 mL 1 M NaOH + 50 mL 1 M NH3
F2(g) + 2I-(aq) ⇌ 2F-(aq) + I2(g)
A. 5.3×1039 B. 1.4×10-79
5. A saturated solution of AB2 contains 8.60x10-4 39
C. 2.6×10 D. 5.6×1078
moles AB2 per liter. Determine Ksp.
A. 6.36x10-10 B. 1.27x10-9
-7
12. Refer to the standard reduction table located on
C. 7.40x10 D. 2.54x10-9
the equation sheet. Which species below is the most
easily oxidized?
A. H+ B. Mg
C. Fe D. Cu
 ERDMANN EXAM 3 SPRING CH 117 Name__________________________________

13. The following redox reaction is conducted with 17. What statement is NOT TRUE regarding the
[Al3+] = 0.01 M and [Mn2+] = 3.0 M. What is the new following curve?
Ecell?
2Al(s) + 3Mn2+(aq)  2Al3+(aq) + 3Mn(s) E°cell = 0.48 V
A. 0.32 V B. 0.53 V
C. 0.43 V D. 0.60 V

14. Write the balanced net equation for the redox A. The graph depicts a polyprotic acid.
reaction that occurs in the voltaic cell. B. Point 2 on the graph depicts the point at
Cu(s) I Cu2+(aq) II Ag+(aq) I Ag(s) which ALL protons associated with the
A. 2Ag+(aq) + Ag(s)  Cu(s) + Cu2+(aq) acid have been neutralized.
B. Cu(s) + 2Ag+(aq)  Cu2+(aq) + 2Ag(s) C. The pKa at point 1 is larger than the pKa at
C. Cu2+(aq) + 2Ag(s)  Cu(s) + 2Ag+(aq) point 3.
D. Cu(s) + Cu2+(aq)  2Ag+(aq) + Ag(s) D. The graph depicts the titration of a weak
acid with a stronger base.
15. KNO3 is commonly used as a salt-bridge in voltaic
cells. Which statement is true regarding the salt 18. What will the pH be if 0.08 moles of sodium
bridge for the battery depicted below? formate (NaHCOO) is added to 1.0 L of a solution of
0.10 M formic acid (HCOOH)?
(Ka for formic acid = 1.8x10-4)
A. 3.82 B. 3.84
C. 3.74 D. 3.64

19. What is the most effective pH buffering range for

A. The nitrate ions react with the electrode at a benzoic acid/benzoate buffer?
the anode. (benzoic acid Ka = 6.3×10-5)
A. 3.2 - 5.2 B. 4.7 - 6.7
B. The potassium ions take part in the redox C. 5.3 - 7.3 D. 8.8 - 10.8
process.
C. The nitrate ions will flow from the cathode 20. 50 mL of 0.10 M KOH is added to 200 mL of
to the anode. NH3/NH4+ buffer solution (Kb NH3 = 1.8x10-5). Which
of the following statements is FALSE?
D. The potassium ions react with the electrode A. The added hydroxide ions will form
at the cathode. additional conjugate base.
B. The volume of KOH added is significant
16. A weak acid is titrated with a strong base. Which enough to change the concentration of all
of the following graphs would result from this species in solution.
titration?
C. The resulting pH can be calculated using the
Ka for NH3.
D. The resulting pH will be slightly higher than
A. B. that of the original buffer.

21. What type of process involves the transfer of

electrons?
C. D. A. Not this answer. B. Still not this answer.
C. Redox process D. Really?!?
ERDMANN EXAM 3 SPRING CH 117 Name__________________________________
ERDMANN EXAM 3 SPRING CH 117 Name__________________________________