CHEMISTRY

JEE-MAIN 2023

PHYSICAL CHEMISTRY CHAPTERWISE QUESTION BANK

MOLE CONCEPT
1. 5 g of NaOH was dissolved in deionized water to prepare a 450 mL stock solution.
What volume (in mL) of this solution would be required to prepare 500 mL of 0.1 M
solution ? Given : Molar Mass of Na, O and H is 23, 16 and 1 g mol–1 respectively
[24 Jan, Shift – 1 - 2023]
2. Uracil is base present in RNA with the following structure. % of N in uracil is _______.

NH

N O
H
Given : Molar mass N = 14 g mol–1; O = 16 g mol–1; C = 12 g mol–1; H = 1 g mol–1;
[24 Jan, Shift – 1 - 2023]
3. The number of units, which are used to express concentration of solutions from the
following is_________. Mass percent, Mole, Mole fraction, Molarity, ppm, Molality.
[24 Jan, Shift – 2 - 2023]
4. '25 volume' hydrogen peroxide means [25 Jan, Shift – 1 - 2023]
(1) 1 L marketed solution contains 250 g of H2O2.
(2) 1 L marketed solution contains 75 g of H2O2.
(3) 100 mL marketed solution contains 25 g of H2O2.
(4) 1 L marketed solution contains 25 g of H2O2.
5. What is the mass ratio of ethylene glycol (C2H6O2, molar mass = 62 g/mol) required for
making 500 g of 0.25 molal aqueous solution and 250 mL of 0.25 molar aqueous
solution? [25 Jan, Shift – 2 - 2023]
(1) 1 : 1 (2) 3 : 1 (3) 2 : 1 (4) 1 : 2
6. Number of hydrogen atoms per molecule of a hydrocarbon A having 85.8% carbon is
_________ (Given: Molar mass of A = 84 g mol–1) [25 Jan, Shift – 2 - 2023]

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7. When 0.01 mol of an organic compound containing 60% carbon was burnt completely,
4.4 g of CO2 was produced. The molar mass of compound is __________ g mol–1
(Nearest integer) [29 Jan, Shift - 2 - 2023]
8. Some amount of dichloromethane (CH2Cl2) is added to 671.141 mL of chloroform
(CHCl3) to prepare 2.6 × 10–3M solution of CH2Cl2 (DCM). The concentration of DCM is
______ ppm (by mass). Given: Atomic mass : C = 12; H : 1; Cl = 35.5 density of CHCl3
= 1.49 gcm–3 [30 Jan, Shift - 1 - 2023]
9. The strength of 50 volume solution of hydrogen peroxide is ______ g/L
(Nearest integer). Given:
Molar mass of H2O2 is 34 g mol–1
Molar volume of gas at STP = 22.7 L. [30 Jan, Shift - 2 - 2023]
10. On complete combustion, 0.492 g of an organic compound gave 0.792 g of CO2.
The % of carbon in the organic compound is _____ (Nearest integer)
[31 Jan, Shift - 1 - 2023]
11. Zinc reacts with hydrochloric acid to give hydrogen and zinc chloride. The volume of
hydrogen gas produced at STP from the reaction of 11.5 g of zinc with excess HCl is
______ L (Nearest integer) (Given: Molar mass of Zn is 65.4g mol–1 and Molar volume
of H2 at STP = 22.7L) [31 Jan, Shift - 1 - 2023]
12. Assume carbon burns according to following equation:
2C s O2 g 2CO g When 12 g carbon is burnt in 48 g of oxygen, the volume of

carbon monoxide produced is ______ 10–1 at STP [nearest integer [Given : Assume
1 1
CO as ideal gas, Molar Mass of C is 12 g mol , Molar Mass of O is 16 g mol and
molar volume of an ideal gas at STP is 22.7 L mol–1] [31 Jan, Shift - 2 - 2023]
13. The density of 3 M solution of NaCl is 1.0 g mL–1. Molality of the solution is
__________ × 10–2 m. (Nearest integer). Given: Molar mass of Na and Cl is 23 and
35.5 g mol–1 respectively.
[1 Feb, Shift – 1 - 2023]
14. Given below are two statements : one is labelled as Assertion (A) and the other is
labelled as Reason (R).
Assertion (A) : An aqueous solution of KOH when for volumetric analysis, its
concentration should be checked before the use.
Reason (R) : On aging, KOH solution absorbs atmospheric CO2.
In the light of the above statements, choose the correct answer from the options given
below. [1 Feb, Shift – 2 - 2023]
(1) (A) is not correct but (R) is correct
(2) Both (A) and (R) are correct but (R) is not the correct explanation of (A)
(3) Both (A) and (R) are correct and (R) is the correct explanation of (A)
(4) (A) is correct but (R) is not correct

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15. The molality of a 10% (v/v) solution of di-bromine solution in CCl4 (carbon tetrachloride)
is 'x'. x = ________ × 10–2 M. (Nearest integer)
[Given : molar mass of Br2 = 160 g mol–1 atomic mass of C = 12 g mol–1
atomic mass of Cl = 35.5 g mol–1
density of dibromine = 3.2 g cm–3
density of CCl4 = 1.6 g cm–3] [1 Feb, Shift – 2 - 2023]
ATOMIC STRUCTURE
16. If wavelength of the first line of the Paschen series of hydrogen atom is 720 nm, then
the wavelength of the second line of this series is _______ nm. (Nearest integer)
[24 Jan, Shift – 1 - 2023]
17. Following figure shows spectrum of an ideal blackbody at four different temperatures.
The number of correct statement/s from the following is _______.

T1

T2
Energy distribution

T3
T4

Wavelength

[24 Jan, Shift – 2 - 2023]

A. T4> T3> T2> T1
B. The black body consists of particles performing simple harmonic motion.
C. The peak of the spectrum shifts to shorter wavelength as temperature increases.
T1 T2 T3
D. cons tan t
v1 v 2 v3

E. The given spectrum could be explained using quantisation of energy.

18. The radius of the 2nd orbit of Li2+ is x. The expected radius of the 3rd orbit of Be3+ is
[25 Jan, Shift – 1 - 2023]
9 4 27 16
(1) x (2) x (3) x (4) x
4 9 16 27
19. The number of given orbitals which have electron density along the axis is _______
px ,py ,pz ,dxy ,dyz ,dxz ,dz2 ,dx2 y2
[25 Jan, Shift – 2 - 2023]

20. The shortest wavelength of hydrogen atom in Lyman series is . The longest
+
wavelength in Balmer series of He is [29 Jan, Shift - 1 - 2023]
5 9 36 5
(1) (2) (3) (4)
9 5 5 9

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21. Assume that the radius of the first Bohr orbit of hydrogen atom is 0.6 Å. The radius of
the third Bohr orbit of He+ is ________ picometer. (Nearest Integer)
[29 Jan, Shift - 2 - 2023]
22. The energy of one mole of photons of radiation of frequency 2 1012 Hz in Jmol-1 is
_______. (Nearest integer) (Given: h = 6.626 × 10–34 Js NA 6.022 × 1023 mol–1)
[30 Jan, Shift - 1 - 2023]
23. Maximum number of electrons that can be accommodated in shell with n = 4 are:
[30 Jan, Shift - 2 - 2023]
(1) 16 (2) 32 (3) 50 (4) 72
1/2
1 1 r r /2a0
24. The wave function ( ) of 2s is given by 2s 2 e
2 2 a0 a0

At r = r0, radial node is formed. Thus, r0 in terms of a0

[30 Jan, Shift - 2 - 2023]
a0
(1) r0 = a0 (2) r0 = 4a0 (3) r0 (4) r0 = 2a0
2
25. Which transition in the hydrogen spectrum would have the same wavelength as the
Balmer type transition from n=4 to n = 2 of He+ spectrum
[31 Jan, Shift - 1 - 2023]
(1) n = 2 to n = 1 (2) n = 1 to n = 3
(3) n = 1 to n = 2 (4) n = 3 to n = 4
26. Arrange the following orbitals in decreasing order of energy?
[31 Jan, Shift - 2 - 2023]
(A) n = 3, l = 0, m = 0 (B) n = 4, l = 0, m = 0
(C) n = 3, l = 1, m = 0 (D) n = 3, l = 2, m = 1
The correct option for the order is:
(1) B > D > C > A (2) D >B > C > A
(3) A > C > B > D (4) D > B > A > C
27. Electrons in a cathode ray tube have been emitted with a velocity of 1000 ms–1. The
number of following statements which is/are true about the emitted radiation is
_________ . Given : h = 6 × 10–34 Js, me = 9 × 10–31 kg.
(A) The de Broglie wavelength of the electron emitted is 666.67nm.
(B) The characteristic of electrons emitted depend upon the material of the electrodes
of the cathode ray tube.
(C) The cathode rays start from cathode and move towards anode.
(D) The nature of the emitted electrons depends on the nature of the gas present in
cathode ray tube.
[1 Feb, Shift – 1 - 2023]

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 GASEOUS STATE
28. The number of statement's, which are correct with respect to the compression of
carbon dioxide from point (a) in the Andrews isotherm from the following is _________.

Pressure c b a
Volume

A. Carbon dioxide remains as a gas up to point (b)

B. Liquid carbon dioxide appears at point (c)
C. Liquid and gaseous carbon dioxide coexist between points (b) and (c)
D. As the volume decreases from (b) to (c), the amount of liquid decreases
[24 Jan, Shift – 2 - 2023]
29. For 1 mol of gas, the plot of pV vs p is shown below. p is the pressure and V is the
volume of the gas.

B
pV
A

What is the value of compressibility factor at point A?

[29 Jan, Shift - 1 - 2023]
a b b a
(1) 1 (2) 1 (C) 1 (D) 1
RTV v v RTV
30. A 300 mL bottle of soft drink has 0.2 M CO2 dissolved in it. Assuming CO2 behaves as
an ideal gas, the volume of the dissolved CO2 at STP is _________ mL. (Nearest
1
integer) Given: At STP, molar volume of an ideal gas is 22.7 L mol
[30 Jan, Shift - 1 - 2023]
31. The total pressure of a mixture of non-reacting gases X (0.6 g) and Y (0.45 g) in a
vessel is 740 mm of Hg. The partial pressure of the gas X is _________ mm of Hg.
(Nearest Integer) (Given: molar mass X = 20 and Y = 45 g mol–1)
[31 Jan, Shift - 1 - 2023]

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32. Given below are two statements: One is labelled as
Assertion A and the other is labelled as Reason R.
Assertion A: Amongst He, Ne, Ar and Kr, 1 g of activated charcoal adsorbs more of Kr.
3 –1
Reason R : The critical volume Vc (cm mol ) and critical pressure Pc (atm) is highest
for Krypton but the compressibility factor at critical point Zc is lowest for Krypton.
In the light of the above statements, choose the correct answer from the options given
below. [1 Feb, Shift – 1 - 2023]
(1) A is true but R is false
(2) A is false but R is true
(3) Both A and R are true but R is NOT the correct explanation of A
(4) Both A and R are true and R is the correct explanation A
CHEMICAL EQUILIBRIUM
33. Consider the following reaction approaching equilibrium at 27ºC and 1 atm pressure
K f 103
A B C D
Kb 102

The standard Gibbes energy change rG at 27ºC is (–) _______ kJ mol–1

(Nearest integer). (Given : R = 8.3 J K–1mol–1 and ln 10=2.3) [29 Jan, Shift - 1 - 2023]
34. Water decomposes at 2300 K
1
H2O g H2 g O2 g
2
The percent of water decomposing at 2300 K and 1bar is ________ (Nearest integer).
Equilibrium constant for the reaction is 2×10–3 at 2300 K [29 Jan, Shift - 1 - 2023]
35. At 298 K
N2 g 3H2 g 2NH3 g ,K1 4 105

N2 g O2 g 2NO g ,K 2 1.6 1012

1 13
H2 g O2 g H2O g ,K 3 1.0 10
2
Based on above equilibria, the equilibrium constant of the reaction,
5 33
2NH3 g O2 g 2NO g 3H2O g is _____ 10 Nearest int eger
2
36. Consider the following equation :
2SO2 g O2 g 2SO3 g , H 190 kJ The number of factors which will

increase the yield of SO3 at equilibrium from the following is_______

A. Increasing temperature B. Increasing pressure C. Adding more SO2
D. Adding more O2 E. Addition of catalyst [30 Jan, Shift - 2 - 2023]

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37. i X g Y g Z g Kp1 3

ii A g 2B g Kp2 1
If the degree of dissociation and initial concentration of both the reactants X(g) and
p1
A(g) are equal, then the ratio of the total pressure at equilibrium is equal to x : 1.
p2
The value of x is ________ (Nearest integer) [1 Feb, Shift – 1 - 2023]
38. The effect of addition of helium gas to the following reaction in equilibrium state, is :
PCI5(g) PCI3(g) + CI2(g) [1 Feb, Shift – 2 - 2023]
(1) the equilibrium will shift in the forward direction and more of Cl2 and PCl3 gases will
be produced.
(2) the equilibrium will go backward due to suppression of dissociation of PCl5.
(3) helium will deactivate PCl5 and reaction will stop.
(4) addition of helium will not affect the equilibrium.
REDOX REACTION
39. When a hydrocarbon A undergoes combustion in the presence of air, it requires 9.5
equivalents of oxygen and produces 3 equivalents of water. What is the molecular
formula of A? [29 Jan, Shift - 2 - 2023]
(1) C8H6 (2) C9H9 (3) C6H6 (4) C9H6
40. H2O2 acts as a reducing agent in
[31 Jan, Shift - 1 - 2023]
2
(1) 2NaOCI H2O2 2NaCI H2O O2 (2) 2Fe 2H H2O2 2Fe3 2H2O
(3) Mn2 2H2O2 MnO2 2H2O (4) Na2S 4H2O2 Na2SO4 4H2O
41. When a hydrocarbon A undergoes complete combustion it requires 11 equivalents of
oxygen and produces 4 equivalents of water. What is the molecular formula of A?
[31 Jan, Shift - 2 - 2023]
(1) C9H8 (2) C11H4 (3) C5H8 (4) C11H8
IONIC EQUILIBRIUM
42. The dissociation constant of acetic is x × 10–5. When 25 mL of 0.2 M CH3COONa
solution is mixed with 25 mL of 0.02 M CH3COOH solution, the pH of the resultant
solution is found to be equal to 5. The value of x is _______.
[24 Jan, Shift – 1 - 2023]
43. If the pKa of lactic acid is 5, then the pH of 0.005M calcium lactate solution at 25° C is
–1
__________ × 10 (Nearest integer)

H
|
Lactic acid CH3 – C – COOH
|
OH
[24 Jan, Shift – 2 - 2023]

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44. A litre of buffer solution contains 0.1 mole of each of NH3 and NH4Cl. On the addition
of 0.02 mole of HCl by dissolving gaseous HCl, the pH of the solution is found to
be_________× 10–3
(Nearest integer) [Given : pKb(NH3) = 4.745
log 2 = 0.301 log 3 = 0.477 T = 298 K] [25 Jan, Shift – 1 - 2023]
45. When the hydrogen ion concentration [H+] changes by a factor of 1000, the value of
pH of the solution _______. [25 Jan, Shift – 2 - 2023]
(1) increases by 1000 units (2) decreases by 3 units
(3) decreases by 2 units (4) increases by 2 units
46. Millimoles of calcium hydroxide required to produce 100 mL of the aqueous solution of
pH 12 is x × 10–1. The value of x is _______ (Nearest integer). Assume complete
dissociation. [29 Jan, Shift - 1 - 2023]
47. The volume of HCl, containing 73 g L–1, required to completely neutralize NaOH
obtained by reacting 0.69 g of metallic sodium with water, is _______ mL. (Nearest
–1
Integer) (Given : molar Masses of Na, Cl, O, H are 23, 35.5, 16 and 1 g mol
respectively) [29 Jan, Shift - 2 - 2023]
48. 600 mL of 0.01M HCl is mixed with 400 mL of 0.01M H2SO4. The pH of the mixture is
________ × 10–2. (Nearest integer)
[Given log 2 = 0.30, log3 = 0.48 log5 = 0.69 log7 = 0.84 log11 = 1.04]
[30 Jan, Shift - 1 - 2023]
49. Incorrect statement for the use of indicators in acid-base titration is:
[31 Jan, Shift - 2 - 2023]
(1) Methyl orange may be used for a weak acid vs weak base titration.
(2) Methyl orange is a suitable indicator for a strong acid vs weak base titration
(3) Phenolphthalein is a suitable indicator for a weak acid vs strong base titration
(4) Phenolphthalein may be used for a strong acid vs strong base titration.
–3 –1
50. At 298 K, the solubility of silver chloride in water is 1.434 × 10 g L . The value of –
log Ksp for silver chloride is ______.
(Given mass of Ag is 107.9 g mol–1 and mass of Cl is 35.5 g mol–1)
[31 Jan, Shift - 2 - 2023]
THERMODYNAMICS
51. For independent process at 300 K.
Process H/kJ mol-1 S/J K-1
A –25 –80
B –22 40
C 25 –50
D 22 20

The number of non-spontaneous process from the following is _______.

[24 Jan, Shift – 1 - 2023]

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52. One mole of an ideal monoatomic gas is subjected to changes as shown in the graph.
The magnitude of the work done (by the system or on the system) is _______ J
(nearest integer).

1.0

Pr Pressure (bar)
0.5

20 2020 40
c Volume (L)
FG Given: log2 = 0.3, In 10 = 2.3 [24 Jan, Shift – 2 - 2023]
53. An athlete is given 100 g of glucose (C6H12O6) for energy. This is equivalent to 1800 kJ
of energy. The 50% of this energy gained is utilized by the athlete for sports activities
at the event. In order to avoid storage of energy, the weight of extra water he would
need to perspire is _______g.
(Nearest integer)
Assume that there is no other way of consuming stored energy.
Given : The enthalpy of evaporation of water is 45kJ mol–1
Molar mass of C, H & O are 12.1 and 16 g mol–1.
[25 Jan, Shift – 1 - 2023]
54. 28.0 L of CO2 is produced on complete combustion of 16.8 L gaseous mixture of
ethene and methane at 25º C and 1 atm. Heat evolved during the combustion process
is ________ kJ.
Given : HC (CH4) = –900 kJ mol–1
HC (C2H4) = –1400 kJ mol–1
[25 Jan, Shift – 2 - 2023]
55. Which of the following relations are correct?
qrev
(1) U q p V (2) G H T S (3) S (4) H U nRT
T
Choose the most appropriate answer from the options given below:
[29 Jan, Shift - 2 - 2023]
(1) C and D only (2) B and C only
(3) A and B only (4) B and D only
56. When 2 litre of ideal gas expands isothermally into vacuum to a total volume of 6 litre,
the change in internal energy is ______ J. (Nearest integer)
[30 Jan, Shift - 1 - 2023]

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57. 1 mole of ideal gas is allowed to expand reversibly and adiabatically from a
temperature of 27°C. The work done is 3 kJ mol-1. The final temperature of the gas
is _______K (Nearest integer). Given Cv = 20 J mol–1 K–1. [30 Jan, Shift - 2 - 2023]
THERMOCHEMISTRY
1
58. The enthalpy change for the conversion of CI2 g to CI aq is _______
2
1
kJmol Nearest int eger

EGE H CI g 350kJmol 1,
1
hydH CI
380kJmol [31 Jan, Shift - 1 - 2023]
g

59. Enthalpies of formation of CCI4 g ,H2O g ,CO2 g and

1
HCI g are 105, 242, 394and 92kJmol respectively. The magnitude of enthalpy
of the reaction given below is ______ kJ mol–1 (nearest integer)
CCI4 g 2H2O g CO2 g 4HCI g [31 Jan, Shift - 2 - 2023]
o
60. At 25 C, the enthalpy of the following processes are given:
H2(g) + O2(g) 2OH(g) Ho = 78kJ mol-1
H2(g) + ½ O2(g) H2O(g) Ho = –242 kJ mol-1
H2(g) 2H(g) Ho = 436 kJ mol-1
½ O2(g) O(g) Ho = 249 kJ mol-1
What would be the value of X for the following reaction? _____ (Nearest integer)
H2O(g) H(g) + OH(g) Ho = X kJ mol-1 [1 Feb, Shift – 1 - 2023]
61. 0.3 g of ethane undergoes combustion at 27°C in a bomb calorimeter. The
temperature of calorimeter system (including the water) is found to rise by 0.5°C. The
heat evolved during combustion of ethane at constant pressure is ________kJ mol–1.
(Nearest integer)
[Given : The heat capacity of the calorimeter system is 20 kJ K–1, R = 8.3 JK–1 mol–1.
Assume ideal gas behaviour.
Atomic mass of C and H are 12 and 1 g mol–1 respectively] [1 Feb, Shift – 2 - 2023]
SURFACE CHEMISTY
62. Statement I : For colloidal particles, the values of colligative properties are of small
order as compared to values shown by true solutions at same concentration.
Statement II : For colloidal particles, the potential difference between the fixed layer
and the diffused layer of same charges is called the electrokinetic potential or zeta
potential.
In the light of the above statements, choose the correct answer from the options given
below. [24 Jan, Shift – 1 - 2023]
(1) Statement I is true but Statement II is false
(2) Statement I is false but Statement II is true
(3) Both Statement I and Statement II are true
(4) Both Statement I and Statement II are false

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63. The number of statement/s which are the characteristics of physisorption is
___________.
A. It is highly specific in nature
B. Enthalpy of adsorption is high
C. It decreases with increase in temperature
D. It results into unimolecular layer
E. No activation energy is needed [24 Jan, Shift – 2 - 2023]
64. The variation of the rate of an enzyme catalyse reaction with substrate concentration is
correctly represented by graph [25 Jan, Shift – 1 - 2023]
Rate of reaction

Rate of reaction
(a) (b)
O Substrate concentration O Substrate concentration

Rate of reaction
Rate of reaction

(c) (d)
O Substrate concentration O Substrate concentration
(1) b (2) c (3) d (4) a
65. The density of a monobasic strong acid (Molar mass 24.2 g mol) is 1.21 kg/L. The
volume of its solution required for the complete neutralization of 25 mL of 0.24 M
NaOH is_____________×10–2 mL (Nearest integer) [25 Jan, Shift – 1 - 2023]
66. Based on the given figure, the number of correct statement/s is/are _______

[25 Jan, Shift – 2 - 2023]

A. Surface tension is the outcome of equal attractive and repulsion forces acting on the
liquid molecule in bulk.
B. Surface tension is due to uneven forces acting on the molecules present on the
surface.
C. The molecule in the bulk can never come to the liquid surface.
D. The molecules on the surface are responsible for vapour pressure if the system is a
closed system.

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67. The number of incorrect statement/s from the following is/are _______
A. Water vapours are adsorbed by anhydrous calcium chloride.
B. There is a decrease in surface energy during adsorption.
C. As the adsorption proceeds, H becomes more and more negative.
D. Adsorption is accompanied by decrease in entropy of the system.
[25 Jan, Shift – 2 - 2023]
68. Which of the following salt solutions would coagulate the colloid solution formed when
FeCl3 is added to NaOH solution, at the fastest rate? [29 Jan, Shift - 1 - 2023]
(1) 10 mL of 0.2 mol dm-3 AlCl3 (2) 10 mL of 0.1 mol dm-3 Na2SO4
(3) 10 mL of 0.1 mol dm-3Ca3(PO4)2 (4) 10 mL of 0.15 mol dm-3 CaCl2
69. Match List-I and List-II.
List-I List-II
A. Osmosis I. Solvent molecules pass through semi permeable
membrane towards solvent side.
B. Reverse osmosis II. Movement of charged colloidal particles under the
influence of applied electric potential towards
oppositely charged electrodes.
C. Electro osmosis III. Solvent molecules pass through semi permeable
membrane towards solution side.
D. Electrophoresis IV. Dispersion medium moves in an electric field.
Choose the correct answer from the options given below: [29 Jan, Shift - 2 - 2023]
(1) A-I, B-III, C-IV, D-II (2) A-III, B-I, C-IV, D-II
(3) A-III, B-I, C-II, D-IV (4) A-I, B-III, C-II, D-IV
x
70. The graph of log vs log p for an adsorption process is a straight line inclined at an
m
angle of 45° with intercept equal to 0.6020. The mass of gas adsorbed per unit mass
of adsorbent at the pressure of 0.4 atm is ______×10–1 (Nearest integer)
Given : log 2 = 0.3010 [30 Jan, Shift - 2 - 2023]
71. Adding surfactants in non polar solvent, the micelles structure will look like
[31 Jan, Shift - 1 - 2023]

(1) b (2) c (3) a (4) d

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72. Match List-I with List-II
List-I List-II
(A) Physisorption I Single layer adsorption
(B) Chemisorption II 20-40 kJ mol–1
(C) N2 g 3H2 g
Fe s
2NH3 g III Chromatography

(D) Analytical Application or Adsorption IV Heterogeneous atalysis

Choose the correct answer from the options given below: [31 Jan, Shift - 2 - 2023]
(1) A – II, B – III, C – I, D – IV (2) A – III, B – IV, C – I, D - II
(3) A – IV, B – II, C – III, D – I (4) A – II, B – I, C – IV, D – III
73. In figure, a straight line is given for Freundlich Adsorption (y = 3x + 2.505). The value
1
of and log K are respectively. [1 Feb, Shift – 2 - 2023]
n

Y
Log I

log K

log P X
(1) 0.3 and log 2.505 (2) 0.3 and 0.7033
(3) 3 and 2.505 (4) 3 and 0.7033
LIQUID SOLUTION
74. In the depression of freezing point experiment
A. Vapour pressure of the solution is less than that of pure solvent
B. Vapour pressure of the solution is more than that of pure solvent
C. Only solute molecules solidify at the freezing point
D. Only solvent molecules solidify at the freezing point [24 Jan, Shift – 1 - 2023]
(1) A and D only (2) B and C only (3) A and C only (4) A only
75. The total pressure observed by mixing two liquid A and B is 350 mm Hg when their
mole fractions are 0.7 and 0.3 respectively. The total pressure becomes 410 mm Hg if
the mole fractions are changed to 0.2 and 0.8 respectively for A and B. The vapour
pressure of pure A is ______ mm Hg. (Nearest integer) Consider the liquids and
solutions behave ideally. [24 Jan, Shift – 2 - 2023]
76. The osmotic pressure of solutions of PVC in cyclohexanone at 300 K are plotted on
the graph. The molar mass of PVC is ___________g mol–1 (Nearest integer)

C (g L–1)
(Given : R = 0.083 L atm K–1mol–1) [25 Jan, Shift – 1 - 2023]

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77. The number of pairs of the solution having the same value of the osmotic pressure
from the following is ________. (Assume 100% ionization) [25 Jan, Shift – 2 - 2023]
A. 0.500 M C2H5OH (aq) and 0.25 M KBr (aq)

B. 0.100 M K 4 Fe CN 6
(aq) and 0.100 M FeSO4 . NH4 2
SO4 aq

C. 0.05 M K 4 Fe CN 6 aq and 0.25 M NaCl (aq)

D. 0.15 M NaCl (aq) and 0.1 M BaCl2 (aq)

E. 0.02 M KCl. MgCI2. 6H2O (aq) and 0.05 M KCI (aq)
78. Solid Lead nitrate is dissolved in 1 litre of water. The solution was found to boil at
100.15ºC. When 0.2 mol of NaCl is added to the resulting solution, it was observed
that the solution froze at –0.8º C. The solubility product of PbCl2 formed is ______ ×
10–6 at 298 K. (Nearest integer)
Given : Kb = 0.5 K kg mol–1 and Kf = 1.8 K kg mol–1. Assume molality to be equal to
molarity in all cases. [29 Jan, Shift - 1 - 2023]
79. Match List I with List II.
List I List II
A. van’t Hoff factor, i I. Cryoscopic constant
B. kf II. Isotonic solutions
C. Solutions with III. Normal molar mass
same osmotic Abnormal molar mass
pressure
D. Azeotropes IV. Solutions with same composition of
vapour above it
Choose the correct answer from the options given below:
[29 Jan, Shift - 2 - 2023]
(A) A-III, B-I, C-II, D-IV (B) A-III, B-II, C-I, D-IV
(C) A-III, B-I, C-IV, D-II (D) A-I, B-III, C-II, D-IV
80. A solution containing 2 g of a non–volatile solute in 20 g of water boils at 373.52 K.
The molecular mass of the solute is _______ 1 gmol 1 . (Nearest integer)
1
Given, water boils at 373 K, Kb for water 0.52K kgmol
[30 Jan, Shift - 1 - 2023]
81. Lead storage battery contains 38% by weight solution of H2SO4. The van’t Hoff factor
is 2.67 at this concentration. The temperature in Kelvin at which the solution in the
battery will freeze is ____ (Nearest integer).
Given Kf = 1.8 K kg mol–1]
[30 Jan, Shift - 2 - 2023]

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82. At 27°C, a solution containing 2.5 g of solute in 250.0 mL of solution exerts an osmotic
pressure of 400 Pa. The molar mass of the solute is ____ g mol–1
(Nearest integer) [31 Jan, Shift - 1 - 2023]
83. 25 mL of an aqueous solution of KCl was found to require 20 mL of 1 M AgNO3
solution when titrated using K2CrO4 as an indicator. What is the depression in freezing
point of KCl solution of the given concentration? ____________ (Nearest integer).
(Given : Kf = 2.0 K kg mol-1) Assume
1) 100% ionization and
2) density of the aqueous solution as 1 g mL-1 [1 Feb, Shift – 1 - 2023]
84. 20% of acetic acid is dissociated when its 5 g is added to 500 mL of water. The
depression in freezing point of such water is _______ × 10–3 °C. Atomic mass of C, H
and O are 12, 1 and 16 a.m.u. respectively.[Given: Molal depression constant and
density of water are 1.86 K kg mol–1 and 1 g cm–3 respectively.
[1 Feb, Shift – 2 - 2023]
CHEMICAL KINETICS
85. The number of correct statement/s from the following is _______.
A. Larger the activation energy, smaller is the value of the rate constant.
B. The higher is the activation energy, higher is the value of the temperature
coefficient.
C. At lower temperatures, increase in temperature causes more change in the value of
k than at higher temperature.
1 Ea
D. A plot of ln k vs is a straight line with slope equal to
T R
[24 Jan, Shift – 1 - 2023]
86. A student has studied the decomposition of a gas AB3 at 25°C. He obtained the
following data.
p (mm Hg) 50 100 200 400
Relative t1/2 (s) 4 2 1 0.5
The order of the reaction is
[24 Jan, Shift – 2 - 2023]
(1) 0.5 (2) 2 (3) 1 (4) 0 (zero)
87. For the first order reaction A B the half life is 30 min. The time taken for 75%
completion of the reaction is _____min. (Nearest integer)
Given : log 2 = 0.3010
log 3 = 0.4771, log 5 = 0.6989
[25 Jan, Shift – 1 - 2023]

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88. For certain chemical reaction X Y, the rate of formation of product is plotted against
the time as shown in the figure. The number of Correct statement/s from the following
is _______ [29 Jan, Shift - 1 - 2023]
y

Rate of
formation
of product
I II III
Linear Asymptotic Constant
x
Time
(A) Over all order of this reaction is one
(B) Order of this reaction can’t be determined
(C) In region-I and III, the reaction is of first and zero order respectively
(D) In region-II, the reaction is of first order
(E) In region-II, the order of reaction is in the range of 0.1 to 0.9.
89. For conversion of compound A B, the rate constant of the reaction was found to be
–5 –1 –1
4.6 × 10 L mol s . The order of the reaction is ______ . [29 Jan, Shift - 2 - 2023]
90. If compound A reacts with B following first order kinetics with rate constant 2.011×10-3
s-1. The time taken by A (in seconds) to reduce from 7g to 2g will be
[log5 0.698, log7 0.845, log2 0.301] [30 Jan, Shift - 1 - 2023]
91. An organic compound undergoes first order decomposition. If the time taken for the
60% decomposition is 540 s, then the time required for 90% decomposition will be is
_______
(Nearest integer).
Given : ln 10 = 2.3; log 2 = 0.3 [30 Jan, Shift - 2 - 2023]
92. A B
The rate constants of the above reaction at 200 K and 300K are 0.03 min–1 and 0.05
–1
min respectively. The activation energy for the reaction is _______ J
(Nearest integer)
(Given : In 10 = 2.3
K–1 –1
R = 8.3 J mol
log5 = 0.70
log3 = 0.48
log2 = 0.30 [31 Jan, Shift - 1 - 2023]
1
93. For reaction: SO2 g O2 g SO3 g KP 2 1012 at 27 C and 1 atm pressure.
2
The Kc for the same reaction is _______ × 1013.
(Nearest integer)
(Given R = 0.082 L atm K–1) mol–1) [31 Jan, Shift - 1 - 2023]

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 –1
94. The rate constant for a first order reaction is 20 min . The time required for the
1
initial concentration of the reactant to reduce to its level is ______ 10–2 min.
32
(Nearest integer) [31 Jan, Shift - 2 - 2023]
(Given: ln10 = 2.303
log 2 = 0.3010)

95. A and B are two substances undergoing radioactive decay in a container. The half life
of A is 15 min and that of B is 5 min. If the initial concentration of B is 4 times that of A
and they both start decaying at the same time, how much time will it take for the
concentration of both of them to be same? ____________ min.
[1 Feb, Shift – 1 - 2023]
96. A B
The above reaction is of zero order. Half life of this reaction is 50 min. The time taken
for the concentration of A to reduce to one-fourth of its initial value is________min.
(Nearest integer) [1 Feb, Shift – 2 - 2023]
ELECTROCHEMISTY
97. At 298 K, a 1 litre solution containing 10 mmol of Cr2O72– and 100 mmol of Cr3+ shows
a pH of 3.0.
Given : Cr2O72– Cr3+; E0 = 1.330 V and
2.303 RT
0.059 V
F
The potential for the half cell reaction is x × 10–3 V. The value of x is _______.
[24 Jan, Shift – 1 - 2023]
98. Choose the correct representation of conductometric titration of benzoic acid vs
sodium hydroxide. [24 Jan, Shift – 2 - 2023]
Conductance

Conductance

(1) (2)
VNaOH
VNaOH
Conductance

Conductance

(3) (4)
VNaOH VNaOH

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99. Pt s H2 g 1bar H aq 1m M3 ag ,M aq Pt s

M aq
The Ecell for the given cell is 0.1115 V at 298 K when 3
10a
M aq
The value of a is ________
Given : E M3 /M
0.2 V
2.303RT
0.059 V [25 Jan, Shift – 2 - 2023]
F
100. Choose the correct representation of conductometric titration of benzoic acid vs
sodium hydroxide.
[24 Jan, Shift – 2 - 2023]
Conductance

Conductance
(1) (2)
VNaOH VNaOH
Conductance

Conductance

(3) (4)
VNaOH VNaOH

101. Consider the cell

Pt s H2 s 1 atm H aq, H 1 || Fe
3
aq ,Fe2 aq | Pt s
o
Given : EFe3
/Fe2
0.771V and Eo 1 0V, T 298K
H / H2
2

If the potential of the cell is 0.712 V the ratio of concentration of Fe2+ to Fe2+
is________ [25 Jan, Shift – 1 - 2023]
(Nearest integer)
–3 –1
102. A first order reaction has the rate constant, k = 4.6× 10 s . The number of correct
statement/s from the following is/are ________.
A. Reaction completes in 1000 s.
B. The reaction has a half-life of 500 s.
C. The time required for 10% completion is 25 times the time required for 90%
completion.
D. The degree of dissociation is equal to (1 – e–kt).
E. The rate and the rate constant have the same unit. [25 Jan, Shift – 2 - 2023]

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103. Following figure shows dependence of molar conductance of two electrolytes on
0
concentration. m is the limiting molar conductivity. [29 Jan, Shift - 1 - 2023]

The number of Incorrect statement(s) from the following is ________

0
(A) m for electrolyte A is obtained by extrapolation
0
(B) For electrolyte B, m vs c graph is a straight line with intercept equal to m

(C) At infinite dilution, the value of degree of dissociation approach zero for electrolyte
B.
0 0
(D) m for any electrolyte A or B can be calculated using for individual ions.
104. The equilibrium constant for the reaction
Zn s Sn2 aq Zn2 aq Sn s is1 1020 at 298 K. The magnitude of standard
–2
electrode potential of Sn / Sn2 if EZn2 /Zn
0.76 V is _______ × 10 V.

(Nearest integer)
2.303RT
Given : 0.059 V [29 Jan, Shift - 2 - 2023]
F
105. Consider the cell

Pt s H2 g,1atm H aq, 1M Fe3 aq ,Fe2 aq Pt s

When the potential of the cell is 0.712 V at 298 K, the ratio Fe2 / Fe3 is

(Nearest integer)
[30 Jan, Shift - 1 - 2023]
2.303RT
Given: Fe3 e Fe2 ,E Fe3 ,Fe2 |Pt
0.771V 0.06 V
F
106. The electrode potential of the following half cell at 298 K. X | X2+ (0.001 M) || Y2+ (0.01
M) | Y is _____×10–2 V (Nearest integer).
Given : E0x2 |x
2.36 V

E0Y2 |Y
0.36 V

2.303RT
0.06 V [30 Jan, Shift - 2 - 2023]
F

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107. Which one of the following statements is correct for electrolysis of brine solution?
[31 Jan, Shift - 1 - 2023]
(1) Cl2 is formed at cathode (2) O2 is formed at cathode
(3) H2 is formed at anode (4) OH– is formed at cathode
108. The logarithm of equilibrium constant for the reaction Pd2 4CI PdCI24 is ______
(Nearest integer)
2.303RT
Given : 0.06 V Pd2aq 2e Pd s E 0.83 V
F
PdCI24 aq 2e Pd s 4CI aq
E 0.65 V [31 Jan, Shift - 1 - 2023]
3
109. The resistivity of a 0.8 M solution of an electrolyte is 5 10 cm. Its molar
conductivity ___ 104 1
cm2 mol 1. (Nearest integer) [31 Jan, Shift - 2 - 2023]

110. At what pH, given half cell MnO4 0.1 M | Mn2 0.001 M will have electrode potential
of 1.282 V? __________ (Nearest Integer) Given [1 Feb, Shift – 1 - 2023]
–5
111. 1 × 10 M AgNO3 is added to 1 L of saturated solution of AgBr. The conductivity of this
solution at 298 K is ______× 10–8 S m–1.
[Given : Ksp(AgBr) = 4.9×10–13 at 298K
0
0
Ag
6 10 3 Sm2 mol 1
Br
8 10 3 Sm2 mol 1

0
NO3
7 10 3 Sm2 mol 1] [1 Feb, Shift – 2 - 2023]

SOLID STATE
112. When Fe0.93O is heated in presence of oxygen, it converts to Fe2O3. The number of
correct statement/s from the following is _______. [24 Jan, Shift – 1 - 2023]
Molecular weight
A. The equivalent weight of Fe0.93O is .
0.79
B. The number of moles of Fe2+ and Fe3+ in 1 mole of Fe0.93O is 0.79 and 0.14
respectively.
C. Fe0.93O is metal deficient with lattice comprising of cubic closed packed
arrangement of O2– ions.
D. The % composition of Fe2+ and Fe3+ in Fe0.93O is 85% and 15% respectively.
113. A cubic solid is made up of two elements X and atoms of X are present on every
rd
1
alternate corner and one at the centre of cube. Y is at of the total faces. The
3
empirical formula of the compounds [25 Jan, Shift – 1 - 2023]
(1) X2Y1.5 (2) X2.5Y (3) XY2.5 (4) X1.5Y2

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114. A metal M forms hexagonal close-packed structure. The total number of voids in 0.02
mol of it is __________ × 1021 (Nearest integer)
(Given NA = 6.02 × 1023) [29 Jan, Shift - 2 - 2023]
115. Iron oxide FeO, crystallises in a cubic lattice with a unit cell edge length of 5.0Å. If
density of the FeO in the crystal is 4.0 g cm–3, then the number of FeO units present
per unit cell is _____
(Nearest integer)
Given : Molar mass of Fe and O is 56 and 16 g mol–1 respectively.
NA = 6.0 × 1023mol–1 [30 Jan, Shift - 2 - 2023]
116. A sample of a metal oxide has formula M0.83 O. The metal M can exist in two oxidation
states + 2 and + 3. In the sample of M0.83 O, the percentage of metal ions existing in
+2 oxidation state is _____ % (nearest integer) [31 Jan, Shift - 2 - 2023]
117. Which of the following represents the lattice structure of A0.95O containing A2+, A3+ and
O2– ions?
A2+ A3+ O2–

A.

B.

C.
[1 Feb, Shift – 1 - 2023]
(1) B and C only (2) B only (3) A and B only (4) A only
118. A metal M crystallizes into two lattices :- face centred cubic (fcc) and body centred
cubic (bcc) with unit cell edge length of 2.0 and 2.5 Å respectively. The ratio of
densities of lattices fcc to bcc for the metal M is _______.
(Nearest integer) [1 Feb, Shift – 2 - 2023]

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 ANSWER KEY

1. (180) 2. (25) 3. (5) 4. (2) 5. (3) 6. (12.00)

7. (200) 8. (148) 9. (150) 10. (44) 11. (4) 12. (227)
13. (364) 14. (3) 15. (139) 16. (492) 17. (2) 18. (3)
19. (5.00) 20. (2) 21. (270) 22. (798) 23. (2) 24. (4)
25. (1) 26. (2) 27. (2) 28. (2) 29. (1) 30. (1362 ml)
31. (555) 32. (1) 33. (6) 34. (2) 35. (4) 36. (3)
37. (12) 38. (A & D) 39. (1) 40. (1) 41. (1) 42. (10)
43. (85) 44. (9079) 45. (4) 46. (5) 47. (15) 48. (186)
49. (1) 50. (10) 51. (2) 52. (620) 53. (360) 54. (925.00)
55. (2) 56. (0) 57. (150) 58. (610) 59. (173) 60. (499)
61. (1006) 62. (3) 63. (2) 64. (2) 65. (12) 66. (2.00)
67. (2.00) 68. (1) 69. (2) 70. (16) 71. (3) 72. (4)
73. (3) 74. (1) 75. (314) 76. (Bonus/41500) 77. (4.00)
78. (13) 79. (1) 80. (100g ) 81. (243) 82. (62250)
83. (3) 84. (372) 85. (3) 86. (2) 87. (60) 88. (1)
89. (2) 90. (623) 91. (1350) 92. (2520) 93. (1) 94. (17)
95. (15) 96. (75) 97. (917) 98. (2) 99. (3.00)100. (2)
101. (10) 102. (2.00) 103. (2) 104. (17) 105. (10) 106. (275)
107. (4) 108. (6) 109. (25) 110. (3) 111. (Bonus)
112. (4) 113. (2) 114. (36) 115. (4) 116. (59) 117. (4)
118. (4)

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