DPP No. B1 To B23 E Physical and Inorganic Chemistry

DPPs BOOKLET-2 VIJETA (JP) | CHEMISTRY
DPP No. # B1 (JEE-MAIN)

Total Marks : 100 Max. Time: 55 min.
Single Choice Objective ('–1' negative marking) Q.1 to Q.20 (4 marks, 2 min.) [80, 40]
Numerical Value Questions ('0' negative marking) Q.21 to 25 (4 marks, 3 min.) [20, 15]
1. The enthalpy of neutralisation of acetic acid and sodium hydroxide is – 55.4 kJ. What is the enthalpy of
ionisation of acetic acid ?
(A) –1.9 kJ (B) + 1.9 kJ (C) + 5.54 kJ (D) – 5.54 kJ
2. The burning of solid Caffeine {C8H10N4O2} in gaseous oxygen to produce gaseous CO2, N2O3 & H2O
takes place. {No other oxide is formed}. The maximum mass of N 2O3 that can be produced from
burning of 9.7 g of caffeine is :
(A) 3.6 g (B) 5.6 g (C) 7.6 g (D) 9.6 g
3. Equal amount (mass) of methane and ethane have their total translational kinetic energy energy in the
ratio 3 : 1 then their temperatures are in the ratio.
(A) 5 : 8 (B) 45 : 8 (C) 15 : 8 (D) 8 : 5
4. A solution saturated in lime water has a pH of 12.4. Then the Ksp for Ca(OH)2 is -
(A) 3.2 × 10–3 (B) 7.8 × 10–6 (C) 7.8 × 10–28 (D) 3.2 × 10–4
5. One mole of an ideal monoatomic gas expands isothermally against constant external pressure of 1
atm from initial volume of 1L to a state where its final pressure becomes equal to external pressure. If
initial temperature of gas is 300 K then total entropy change of system in the above process is :
[R = 0.082 L atm mol–1 K–1 = 8.3 J mol–1K–1].
(A) 0 (B) Rn (24.6) (C) R n (2490) (D)
3 Rn (24.6)
2
6. Which of the following diatomic molecules would be stabilised by the removal of an electron ?
(A) O2 (B) CN– (C) N2 (D) C2
7. Diatomic molecule has a dipole moment of 1.2 D. If is bond length is 1.0 Å, what fraction of an
electronic charge exists on each atom ?
(A) 11% (B) 20% (C) 25% (D) None of these
8. Dihydrogen gas may be prepared by heating caustic soda on
(A) Cu (B) Zn (C) Fe (D) Ag
9. Potassium is _________, __________ and _________ than sodium.
(A) lighter, softer and more reactive (B) heavier, softer and less reactive
(C) lighter, harder and more reactive (D) None of the above
10. Which of the following on thermal decomposition yields a basic as well as an acidic oxide ?
(A) KCIO3 (B) Na2CO3 (C) NaNO3 (D) CaCO3
11. Which of these is not a monomer for a high molecular mass silicone polymer?
(A) Me3SiCl (B) PhSiCl3 (C) MeSiCl3 (D) Me2SiCl2
12. Electrolytic reduction of 6.15 g of nitrobenzene using a current effeciency of 40% will require which of
the following quantity of electricity. [C = 12, H = 1, N = 14, O = 16]
(A) 0.75 F (B) 0.15 F (C) 0.75 C (D) 0.125 C
13. What will happen to the state of a substance represented by this phase diagram when its temperature
and pressure are changed from 60ºC and 0.2 atm to 40ºC and 1.0 atm ?
(A) liquid to solid (B) gas to solid (C) solid to liquid (D) solid to gas
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14. The passage of a constant current through a solution of dilute H 2SO4 with ‘Pt’ electrodes liberated 336
cm3 of a mixture of H2 and O2 at S.T.P. The quantity of electricity that was passed is
(A) 96500 C (B) 965 C (C) 1930 C (D)

1 faraday
100
15. What is not true about borax ?
(A) Molecular formula is Na2B4O7.10H2O.
(B) Crystallic borax contains tetrahedral unit of [B4O5(OH)4]2–.
(C) It hydrolyses to give an acidic solution.
(D) White crystalline solid.
16. Dry air was passed through a solution of 5 g of a solute in 90 g of water & then it is passed through
pure water. Loss in wt. of solution was 2.50 g & that of pure solvent was 0.05 g. Then molecular weight
of solute is :
(A) 5 (B) 10 (C) 50 (D) 100
17. The molar solubility of AgCl in 2.5 M NH3 solution is nearly: [Given: KspAgCl = 10–10, Kf[Ag(NH3)2]+ =
106]
(A) 0.025 mol/L (B) 0.2 L mol–1 (C) 0.4 L mol–1 (D) none of these
18. Which of the following reactions of potassium superoxide supply oxygen gas in the breathing
equipments used in space and submarines ?
(A) reaction of superoxide with nitrogen in the exhaled air
(B) reaction of superoxide with moisture in the exhaled air
(C) reaction of superoxide with carbon dioxide in the exhaled air
(A) (A), (B) and (C) (B) (B) and (C) only (C) (B) only (D) (A) and (B) only
19. The following electrochemical cell is taken.

Cu | Cu2+(aq) || Ag+ (aq) | Ag, and has emf E1 > 0. By which of the following actions, E1 increases?
(A) Adding NH3 to the cathodic chamber. (B) Adding HCl to the cathodic chamber.
(B) Adding AgNO3 to the anodic chamber. (D) Adding NH3 to the anodic chamber.
20. Select the incorrect statement(s).

(A) [Co(EDTA)] – has two optical isomers.
(B) [Co(NH3)5(NO2)]2+ show linkage isomerism.
(C) For [Pt(NH3)BrCl(NO2)py], theoretically fifteen different geometrical isomers are possible.
(D) [Cr(H2O)4Cl2]Cl2.2H2O is an example of hydrate as well as ionisation isomerism.
21. How many P—O—P bonds are present in tricyclometaphosphoric acid, (HPO 3)3 ?
22. Consider the following reversible reactions :

A+B P; KC = 6
2B + C 2D ; KC = 4
C
Hence, what will be the KC for the reaction, A + D P+ .
2
23. How many next nearest neighbours are present for Zn+2 ions in FCC arrangement of ZnS.
24. How many of the following metals have positive standard oxidation potential (SOP) ?
Zn, Cu, Mg, Rb, Al, Ag
25. SO2 at STP contained in a flask was replaced by O 2 under identical conditions of pressure,
temperature and volume. Then the ratio of mass of SO2 and O2.
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DPP No. # B2 (JEE-ADVANCED)

Total Marks: 50 Max. Time: 30 min.
Single choice Objective ('–1' negative marking) Q.1 (3 marks, 2 min.) [03, 02]
Multiple choice objective ('–1' negative marking) Q.2 to Q.6 (4 marks, 2 min.) [20, 10]
Comprehension: 2 Questions ('–1' negative marking) Q.7 to Q.8 (3 marks, 2 min.) [06, 04]
Integer Type Questions Q.9 to Q.15 (3 marks, 2 min.) [31, 14]
1. Match Column-I with Column-II and select the correct answer with respect to hybridisation using the
codes given below :
Column-I Column-II
(Complex) (Hybridisation)
(I) [Ni(CN)4]2– (p) dsp2 hybridisation
(II) [Cu(CN)4]3– (q) sp3 hybridisation
(III) [Co(C2O4)3]3– (r) sp3d2 hybridisation
(IV) [Fe(H2O)5NO]2+ (s) d2sp3 hybridisation
Codes :
(I) (II) (III) (IV) (I) (II) (III) (IV)
(A) q p r s (B) p q s r
(C) p q r s (D) q p s r
2. In which of the following molecule(s) / ion(s) are all the bonds not equal ?
(A) SiF4 (B) ICl4– (C) SF4 (D) PCl5
3. Which of the following statements is/are incorrect ?

(A) Some of the four-coordinated complexes of Ni2+ ion are square planar and some are tetrahedral.
(B) The [Fe(H2O)6]3+ ion is more paramagnetic than the [Fe(H2O)6]2+ ion
(C) CFSE of square planar complexes are more than octahedral complexes for Pt.
(D) The [Fe(CN)6]4– ion is paramagnetic but [Fe(CN)6]3– is diamagnetic
4. Which of the following plots represent the correct variation of of strong electrocyte ?
m m
(A) (B) (C) (D)
dilution dilution
5. The correct statement(s) regarding defects solids is (are)

(A) Schottky defect is usually favoured by small difference in the sizes of cation and anion.
(B) Schottky defect lowers the density of solids.
(C) Compounds having F-centres are diamagnetic.
(D) Frenkel defect is a dislocation defect.
6. Solid ammonium carbamate, NH4CO2NH2 (s), dissociates into ammonia and carbon dioxide in a closed
rigid vessel when it evaporates as shown by H4CO2NH2(s) 2NH3(g) + CO2(g). At 25ºC, the total
pressure of the gases in equilibrium with the solid is 0.116 atm. If 0.1 atm of CO 2 is introduced at 25ºC
after equilibrium is reached then :
(A) final pressure of CO2 will be less than 0.1 atm
(B) final pressure of CO2 will be more than 0.1 atm
(C) pressure of NH3 will decrease due to addition of CO2
(D) pressure of NH3 will increase due to addition of CO2
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Comprehension #
The Ellingham diagram for zinc, aluminium and carbon converting into corrosponding oxide as shown
below:
7. At 1000º, Gº for Al  Al2O3 is –910 kJ/mole of O2 and Gº for C CO is –430 kJ/mole of O2. What
will be Gº of reduction of 1 mole Al2O3 by carbon at 1000ºC
(A) + 720 kJ (B) + 480 kJ (C) + 960 kJ (D) +240kJ
8. At what temperature zinc has more affinity for oxygen than carbon :
(A) 1000ºC (B) 1500ºC (C) 500ºC (D) All have equal affinity
9. The resistance of a

N KCl solution is 250 . Calculate the specific conductance and the equivalent
10
conductance of the solution if the electrodes in the cell are 7 cm apart and each has an area of 7 sq.
cm.
10. The conductivity of an aqueous solution of a weak monoprotic acid is 0.000032 ohm –1cm–1 at a
concentration, 0.2 M. If at this concentration the degree of dissociation is 0.02, calculate the value of 0
(ohm–1 cm2 /eqt).
11. The equilibrium constant for the reaction 2X(g) + Y(g) 2Z(g) is 2.25. What would be the
concentration of Y at equilibrium with 2.0 mole of X and 3.0 mole of Z in one litre vessel at equilibrium.
12. 3.24g of Hg(NO3)2 (molar mass = 324) dissolve in 1000g of water having freezing point of –0.0558ºC
Calculate degree of ionisation of Hg(NO3)2.(The Kf for water is 1.86 K–Kgmol–1)
13. (a) The maximum number of atoms which are lying in same plane passing through central atom of
P(CH3)3(CF3)2 is (x).
(b) The maximum number of halogen atoms which are present in one plane for dimer of Cl3 {2Cl6} is
(y). Determine value of (x+y).
14. An aqueous solution contains 6% and 4% by weight weak acid (HA) and urea respectively. Depression
in freezing point of solution is

13.6 ºC. If K of HA is x, then fill the value of 100x. [K = 1.8 K-Kg/mole]
a f
3
(Molecular weight of HA = 60, dsolution = 1gm/ml). Assume no reaction between HA and urea.
15. Among the following metals how many metals are extracted by self-reduction method from their
respective ores. Hg, Zn, Cu, Al, Mg, Pb, Fe, Sn.
PAGE NO.-4

1. A very thin copper plate is electro-plated with gold using gold chloride in HCl. The current was passed
for 20 min. and the increase in the weight of the plate was found to be 2g. [Au = 197]. The current
passed was -
(A) 0.816 amp (B) 1.632 amp (C) 2.448 amp (D) 3.264 amp
2. The total no. of triple points in the phase diagram given below is/are :
(A) 1 (B) 2 (C) 3 (D) No triple point

3. Identify the INCORRECT statement      
(A) Orbitals of a subshell have same value of ( n + ) but the orbitals having same (n + ) value may not
belong to same subshell.
(B) The orbital having value of  = 2 will have 2 orientations in space.
(C) 3p and 3d orbitals have directional character.
(D) Orbits in Bohr’s model are two dimensional in nature.
4. Which complex is likely to show optical activity:
(A) Trans-[Co(NH3)4Cl2]+ (B) [Cr(H2O)6]3+
(C) Cis-[Co(NH3)2(en)2]3+ (D) Trans-[Co(NH3)2(en)2]3+
5. Which of the following statements is correct with respect to the metal carbonyls of Ist transition series?
(A) As M–C bonding increases, the C–O bond length increases.
(B) As positive charge on the central metal atom increases, the C–O bond length increases.
(C) As electron density on the central metal atom increases, the C–O bond length increases.
(D) (A) and (C) both
6.
Consider the cyclic process ABCDEFGA. The area of the two circles are equal. The net work done
during ABCDEFGA is :
(A) positive
(B) negative
(C) Zero
(D) work cannot be determined in a cyclic process from S vs T diagram.
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7. The conductivity of 0.1 N NaOH solution is 0.022 S cm –1. To this solution equal volume of 0.1 N HCl
solution is added which results into decrease of conductivity of solution to 0.0055 S cm –1. The
equivalent conductivity of NaCl solution in S cm 2 equiv–1 is :
(A) 0.011 (B) 110 (C) 0.0055 (D) 55.0
8. In the following compounds :

(i) O2 (ii) O2[BF4] (iii) KO2
Identify the incorrect statement :
(A) O–O bond length order is ii < i < iii
(B) O–O bond order is iii < i < ii
(C) O–O bond energy order is ii < iii < i
(D) Unpaired electrons in antibonding molecular orbitals of species of O 2 involved in i, ii and iii are 2 ,1,
1 respectively
9. In what ratio by mass should a 15% solution of acetic acid be mixed with a 3% solution of the acid to
prepare a 10% solution(all percentages are mass/mass percentages) :
(A) 7 : 3 (B) 5 : 7 (C) 7 : 5 (D) 7 : 10
10.
2H+ + Zn Zn2+ + H2(g)

If at equilibrium of this solution, inert gas is passed to maintain constant pressure then which statement
is correct
(A) Sum of Concentration of Zn2+ and H+ will remain same.
(B) Concentration of Zn+2 will increase but less faster then decrease in concentration of [H +].
(C) Partial pressure of H2 at equilibrium will remain same, [Zn2+] will increase.
(D) Both (B) and (C).
11. In electrolysis of NaCl, when platinum electrode is taken then H 2 is liberated at the cathode while with
mercury cathode it forms sodium amalgam. This is because
(A) Hg is more inert than Pt
(B) More voltage is required to reduce H+ at Hg than at Pt
(C) Na is dissolved in Hg while it does not dissolve in Pt
(D) Conc. of H+ ions is larger when Pt electrode is taken
12. When an acid cell (lead storage battery or cell) is charged then :
(A) voltage of cell increases (B) electrolyte of cell dilutes
(C) resistance of cell increases (D) none of the above
13. Match correctly

I Bauxite (a) Lead
II Carnallite (b) Copper
III Malachite (c) Magnesium
IV Galena (d) Hall Process
(A) I – a, II – b, III – c, IV – d (B) I – d, II – c, III – b, IV – a
(C) I – b, II – a, III – d, IV – c (D) I – d, II – b, III – c, IV – a
PAGE NO.-6
14. Which of the following expressions correctly represents the equivalent conductance at infinite dilution of
º 3 º
Al2(SO4)3. Given that 2Al and3SO24 are the equivalent conductances at infinite dilution of the
respective ions?
º 3 º º 3 º 2
(A) 2Al 3SO24 (B) Al SO4
º 3
( º 1º 3 1 º 2
 
(C) Al 3SO24 ) 6 (D)
3 Al 2 SO4
15. To a solution of acetic acid, solid sodium acetate is gradually added. When x grams of the salt have
been added, the pH has a certain value. When total of y grams of the salt have been added, the pH has
been further raised by 0.6 units. Then the ratio of x : y is (take log 2 = 0.3)
(A) 1 : 4 (B) 1 : 2 (C) 2 : 3 (D) 1 : 8
16. (I) When copper ore is mixed with silica, in a reverberatory furnace copper matte is produced. The
copper matte contains sulphides of copper (II) and iron (II).
(II) Zone refining is based on the principle that impurities are more soluble in molten metal than in solid
metal.
(III) In the metallurgy of aluminium, graphite anode is oxidised to carbon monoxide and carbon dioxide.
Correct statements amongs the following are-
(A) I, II (B) II, III (C) I, III (D) I, II
17. In the process of extraction of silver,
Identify the complexes [P] and [Q]

(A) P = [Ag(CN)4]–, Q = [Zn(CN)4]2– (B) P = [Ag(CN)4]–, Q = [Zn(CN)6]4–
(C) P = [Ag(CN)4]3–, Q = [Zn(CN)4]2– (D) P = [Ag(CN)2]–, Q = [Zn(CN)4]2–
18. In a face centred lattice of X and Y, X atoms are present at the corners while Y atoms are at face
centres. Then the formula of the compound would be if two atoms of X are missing from the corners :
(A) X4Y (B) X3Y4 (C) XY4 (D) X2Y4
19. Aqueous solution of orthoboric acid can be titrated against sodium hydroxide using phenolphthalein
indicator only in presence of :
(A) trans-glycerol (B) catechol (C) cis-glycerol (D) both (B) and (C)
20. In the synthesis of sodium carbonate by Solvay (or ammonia soda) process the recovery of ammonia is
done by treating NH4Cl with Ca(OH)2. The by-product obtained in this process is
(A) CaCl2 (B) NaCl (C) NaOH (D) NaHCO3
21. Calculate EAN of the following complex [Cr(CO)3(NO)2]
22. The number of different metals present in the ore copper pyrites is :
23. At very low temperature, SO2 crystallizes in a hexagonal lattice. If the cross-section area of unit cells is
16.7 × 10–16 cm2, the lattice constant ‘C’ is 8.0 Å and density is 0.8 gram/cm 3 then the number of SO2
molecule per unit cell is :
24. How long will it take to produce 0.3 mole of HNO2 by following reaction if an average current of 1 amp
passes through the cell ? NO3– + 3H3O+ + 2e–  HNO2 + 4H2O, Eº = 0.94 V
25. How many of the following have ionisation energy greater than the Phosphorous atom?
N O F Ne Cl
S Si Al C
PAGE NO.-7
DPP No. # B4 (REVISION DPP)

Total Marks : 87 Max. Time : 54 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.6 (3 marks, 2 min.) [18, 12]
Multiple choice objective ('–1' negative marking) Q.7 to 13 (4 marks, 2 min.) [28, 14]
Comprehension ('–1' negative marking) Q.14 to 17 (3 marks, 2 min.) [12, 08]
Match the Following (no negative marking) Q.25 (8 marks, 6 min.) [08, 06]
1. Calculate H° for this reaction.

C2H2 (g) + 2H2 (g)  C2 H6 (g)
Hcombustion, kJ mol–1 
C2H2(g) –1300
H2(g) –286
C2H6 (g) –1560
(A) – 312 kJ (B) – 26 kJ (C) + 26 kJ (D) + 312 kJ
2. S1 : (a)NH3 > (a)H2O [(a) is Vanderwaal's constant]
S2 : Pressure of the real gas is more than the ideal gas for same temperature and volume of the
container.
S3 : Compresssibilty factor for H2 (g) is never less than unity at any temperature.
S4 : The value of critical temperature (T C) is greater for H2O than O2.
(A) T F F T (B) F F F T (C) F T T F (D) T T T F
3. At 298K the standard free energy of formation of H 2O() is –257.20 kJ/mole while that of its ionisation
into H+ ion and hydroxyl ions is 80.35 kJ/mole, then the emf of the following cell at 298 K will be
(Take F = 96500 C] H2(g,1 bar) | H+ (1M) || OH¯ (1M) | O2 (g, 1bar)
(A) 0.40 V (B) 0.50 V (C) 1.23 V (D) – 0.40 V
4. The following electrochemical cell is taken.
Cu | Cu2+(aq) || Ag+ (aq) | Ag, and has emf E1 > 0. By which of the following actions, E1 increases?
(A) Adding Ag+ to the cathodic chamber. (B) Adding Ag(s) to the cathodic chamber.
(C) Adding Cu2+ to the anodic chamber. (D) Adding Cu(s) to the anodic chamber.
5. Henry's law constant for CO2 in water is 1.67 × 108 Pa at 298 K. Calculate the quantity of CO2 in 500
mL of soda water when packed under 1.67 atm CO2 pressure at 298 K (Take 1 atm  105 Pa).
(A) 8.6 g (B) 2.9 g (C) 5.3 g (D) 1.2 g
6. Match list I with list II and select the correct answer using the codes given below the lists :
Column-I Column-II
(A) Van Arkel method (1) Manufacture of caustic soda
(B) Solvay process (2) Purification of Titanium
(C) Cupellation (3) Manufacture of Na2CO3
(D) Poling (4) Purification of copper
(5) Refining of silver
Codes:
A B C D A B C D
(A) 2 1 3 4 (B) 4 3 2 5
(C) 2 3 5 4 (D) 5 1 3 4
7. Which of the following is/are incorrect for Rock salt crystal :
(A) If all Na+ ions occupied at body centre are removed according to schottky defect then formula of
resulting ionic compound would be Na3Cl4.
(B) If Na+ ions would be present in alternate tetrahedral voids then formula would be Na2Cl.
(C) If some Cl– get displaced from the lattice in the presence of Na vapours then colour of compound
will change.
(D) If interionic distance in crystal is 4.2 Å then edge length of unit cell becomes equal to 8.4 Å.
8. Out of Cu2S, HgS, Ag2S, PbS and ZnS, roasting will convert the minerals into metal in case of :
(A) Cu2S, PbS (B) HgS,ZnS (C) Cu2S, Ag2S (D) HgS, Cu2S.
PAGE NO.-8
9. Which one of the following statements is/are correct ?
(A) In the aluminothermite process, aluminium acts as reducing agent.
(B) Lead is extracted from its chief ore by both carbon reduction and self reduction.
(C) Zinc is extracted from its chief ore by carbon reduction.
(D) Extraction of gold involves the leaching of ore with cyanide solution followed by reduction with zinc.
10. Indicate the correct statements :
(A) conductivity cells have cell constant values independent of the solution filled into the cell
(B) DC (direct current) is not used for measuring the resistance of a solution.
(C) Kohlrausch law is valid both for strong and weak electrolytes.
(D) The k decreases but M and E increase on dilution.
11. Which one of the following statements are correct ?
(A) Tin is extracted by carbon reduction (smelting)
(B) Aluminium is extracted by Hall’s process which involves carbon reduction.
(C) Extraction of lead does not involve bessemerisation
(D) Gold is extracted by cyanide process
12. Assume ideal gas behaviour for all the gases considered and neglect vibrational degrees of freedom.
Separate equimolar samples of Ne, O2, CO2 and SO2 were subjected to a two process as mentionel.
Initially all are at same state of temperature and pressure.
Step I : All undergo reversible adiabatic expansion to attain same final volume, which is double the
original volume thereby causing the decreases in their temperature.
Step II : After step I all are given appropriate amount of heat isochorically to restore the original
temperature.Mark the correct option(s) :   
(A) Due to step I only, the decrease in temperature will be maximum for Ne
(B) During step II, heat given will be minimum for SO2
(C) There will be no change in internal energy for any of the gas after both the steps of process are
competed
(D) The P–V graph of O2 and CO2 will be same
13. The tetrahedral and paramagnetic unit amongs given pair of species is/are:
(A) [MnO4]2–,[NiCl4]2– (B) [MnBr4]2–, [CoCl4]2–
(C) [CrO2F2], [Cr2O7]2– (D) [Ni(CO)4], [Ni(dmg)2]
Comprehension #
If an electrolytic solution consists of more than two ions and electrolysis is done, it is observed that all
the ions are not discharge at the electrodes simultaneously but certain ions are liberate at the
electrodes in perferential discharge theory. It states that if more than one type of ions are attracted
towards a particular electrode, then the one discharged is the ion which required least energy. The
potential at which the ion is discharge or deposited on the apropriate electrode is termed as discharge
or depositon potential (E). If current of 1 ampere is passed through an aqueous (1 litre) electrolytic
solution having [Zn2+] = [Cu2+] = [Mn2+] = 0.03 M. The standard electrode potential, E0 2 = 0.34 V,
Cu /Cu
0 0
EZn/Zn2 = 0.762 V and EMn/Mn2 = 1.8 V are observed and 1 Faraday = 96500 coulomb.
14. Which of the following metal is almost first deposited at cathode ?
(A) Cu (B) Zn (C) Mn (D) All of these.
15. What would be the approximate concentration of metal ions Cu2+, Zn2+ and Mn2+ after 96.5 min
respectively?
(A) 0.01 M , 0.03 M, 0.001 M (B) 0.01 M, 0.03 M, 0.03 M
(C) 0 M, 0.03 M, 0.03 M (D) 0.003 M, 0.03 M, 0 M.
16. After 106.5 minute the metal deposited is approximately ?
(A) 0.012 mole of Cu (B) 0.03 mole of Zn (C) 0.03 mole of Mn (D) 0.003 mole of Zn
17. If current efficiency is 50%, what volume of O2 gas evolved at NTP after 96.5 minutes ?
(A) 332 mL (B) 168 mL (C) 84 mL (D) 42 mL
PAGE NO.-9
18. For the hypothetical reaction A2(g) + B2(g) 2AB(g). If rGº and rSº are 20 kJ/mol and –20 JK–1
mol–1 respectively at 200 K.
 H
rCp is 20 JK–1 mol–1 then value r of kJ/mol. at 400 K is :
10
19. How many of the following metals will displace Hydrogen (H2) from HCl ?
Zn, Hg, Fe, Ag, Mg, Au, Cu, Li, Cs.
20. Argon crystallizes in fcc arrangement, and the density of solid and liquids Ar is 1.59 g cm –3 and
1.42 g cm–3 respectively find the approximate percentage of empty space in liquid Ar.
21. Number of chelate rings in [Cr(ox)3]3– = a

Number of chelate rings in [Co(en) (NH3)2(Py)2]3+ = b
Number of chelate rings in [Fe(EDTA)]– = c
Number of chelate rings in brown ring complex [Fe(H2O)5(NO)]SO4 = d
Calculate the value of (a + b + c + d) is..........
22. How many Bravais lattices have edge length a  b  c & angles  =  =  = 90° ?
23. How many of the following dissolve in water to produce an aqueous solution?
Ca(NO3)2, CaCO3, Na2CO3, BaSO4, Mg3(PO4)2, Mg(NH4)PO4, FeSO4, Na2[Fe(CN)5(NO)], AgBr, PbS
24. In a cubic lattice, the closed packed structure of mixed oxides of the lattice is made up of oxide ions ;
one eighth of the tetrahedral voides are occupied by divalent ions (A 2+) while one half of the octahedral
voids are occupied by trivalent ions (B3+). What is the formula of the oxides ?
25. 1 mole of A is added in 1 kg water. Volume is nearly 1L. To this mixture , small amount of B is added
such that it act as limiting reagent. Match the effect of addition of B in Column I with entries in column II
Column-I Column-II
A B
(A) KCN + AgCN(s) (p) Boiling point increase
(B) CuS(s) + Conc. HNO3 (q) Freezing point does not increase
CH3COOH + Ba(OH)2
(C) (r) Osomotic pressure is unchanged
( < 0.1)
(D) HgI2 + KI (s) Vapor pressure decreases

1. Which of the follwoing statements are correct:
When ice melts at 1ºC under normal condition then
(A) an increase in entropy (B) a decrease in enthalpy
(C) a decrease in free energy (D) process is spontaneous
2. Which of the following statement(s) is/are correct ?

(A) (SiH3)3N is weaker base than (CH3)3N.
(B) Amongst Cl–Cl, N–F, C–F and O–F, the C–F bond is most polar.
(C) OF2 has higher dipole moment than H2O.
(D) An alcohol is less volatile than ether having same molecular formula on account of intermolecular
hydrogen bonding.
PAGE NO.-10
3. Which of the following is/are correct :
(A) Carbon-carbon bond length in CaC2 will be more than that in CH2CCH2
(B) O–O bond length in KO2 will be more than that in Na2 O2 .
(C) O–O bond length in O2 [PtF6] will be less than that in KO2
(D) N–O bond length in NO gaseous molecule will be smaller than that bond length in NOCl gaseous
molecule.
4. Which one of the following statements is/are correct ?
(A) Tin is extracted by carbon reduction (smelting)
(B) Aluminium is extracted by Hall’s process which involves carbon reduction.
(C) Extraction of lead does not involve bessemerisation
(D) Gold is extracted by cyanide process
5. Suppose Bohr theory is applicable to a negative charged particle of mass me (mass of an electron) and
charge 2e– (twice the charge of electron) revolving around the nucleus of charge Ze (Z = atomic number
of atom). Let r1, V1, J1 and E1 be the radius, speed, angular momentum and energy of the particle in the
orbit respectively. The value of these variables for an electron revolving in the corresponding Bohr's
orbit are r, V, J and E respectively. Then which of the following is / are incorrect :
(A) r1 = r (B) V1 = V (C) J1 = J2 (D) E1 = E
6. A Daniel Cell is made at 25ºC by connecting Zn/Zn+2 (0.1 M, 1 litre) & Cu/Cu+2(0.9 M, 1 litre) electrodes.
The cell is discharged when its emf reaches 1.10 volt, then it is charged (reversing the discharge
process) by passing 0.6 F charge. Assume volume remains constant.
[Given: EºZn/ Zn2 0.76 º
V, ECu V, 2.303
/ Cu2 0.34
RT0.06V, log20.30]
F
Select the correct option(s) :
(A) Concentration of Zn+2 becomes 1 M when EMF reach 1.10 volt.
(B) Concentration of Cu+2 becomes 0.5 M when EMF reach 1.10 volt.
(C) EMF of the cell just after charging is 1.118 volt
(D) Just after charging concentration of Cu+2 becomes 0.8 M
Comprehension #
rG = rGº + RT n Q.
Above relation is applicable to chemical reaction.
If Q > K, rG is positive and forward reaction is non-spontaneous. If Q = K, rG is 0 and reaction is at
equilibrium. However, if rG is negative than the forward reaction is spontaneous.
The process H2O () H2O(g) is at equilibrium at 1 atm and 100ºC.
7. What is the sign of G, H and S at 1 atm and 300 K for vaporisation process of water ?
  G H S
(A) – – +
(B) + + +
(C) + – +
(D) – + +
8. CaCO3(s) CaO(s) + CO2(g) ; Gº = – 5.76 kJ/mol.
Find the partial pressure of CO2 in the above equilibrium at 300 K. (R
25J/mol K).
3
(A) 10 atm (B) 1 atm (C) 100 atm (D) 5 atm
9. Consider a substance X. For the fusion of X at 300 K and 1 atm, find Gº.
X(s) X () ; Gº (300 K)?
(Given : fusion Hº (at 400 K, melting point) = 20 kJ/mol.
CP, m (X, s) = 3 J/mol – K.
CP, m (X, ) = 2 J/mol – K.
Sº(X, ) = 15 J/mol – K. (at 300 K)
Sº(X, s) = 5 J/mol – K. (at 300 K)
(A) 17.1 kJ/mol (B) 20.1 kJ/mol (C) 23.1 kJ/mol (D) None of these
PAGE NO.-11
10. The active ingredient in aspirin is acetyl salicylic acid,
HC9H7O4 + H2O H3O+ + C9H7O4–, Ka = 6.25 × 10–9
What is the pH of the solution obtained by dissolving two aspirin tablets in 250mL of water ? Assume
that each tablet contains 0.36 g of acetyl salicylic acid.
11. Equivalent conductance of 0.2 M aqueous solution of a weak monobasic acid (HA) is 10 S cm 2 equiv–1
and that at infinite dilution is 200 S cm 2 equiv–1. Hence pH of this solution is.
12. Conductivity of a saturated solution of Cu2[Fe(CN)6] after subtracting the conductivity of water is
1.28 × 10–5 –1 cm–1. Calculate value of solubility of Cu2[Fe(CN)6].
[m(CuSO4) = 260 S cm2 mol–1, m(K2SO4) = 300 S cm2 mol–1, m(K4Fe(CN)6) = 720 S cm2 mol–1]
Report your answer as (solubility ) × (105)
13. If the slope of Z (compressibility factor) v/s P curve is

 atm–1 at 300 K for a gas which shows
492
.6
negligible intermolecular force then the diameter of the gas molecule is ______ Å. (N A = 6 × 1023, R =
1 atm L–1mol–1K–1)
12
14. Find the number of ores which can be roasted or calcined followed by reduction with carbon to give
respective metal. FeO 3HO
2 3 2 , ZnS, SnO2 , ZnCO3, PbS (low grade )
15. Match the column-
Column – I Column – II
(Quantities) (Factors on which dependency exist)
(A) Molar conductance (p) Temperature
(B) emf of a cell in operation (q) Concentration of species involved
Gibbs energy change (G) for a
(C) (r) Nature of substance involved
cell
(D) Conductivity (s) Stoichometric coefficient of the cell reaction.
Presence of complex forming ligand in sufficient
(t)
concentration.

1. A 20 g non volatile solute X (Molecular weight = 50 g/mol) trimerises, when dissolved in 1 kg benzene,
If degree of trimerisation is 1/4, find abnormal molar mass of X ?
(A) 200 (B) 150 (C) 120 (D) 60
2. What is van't Hoff factor if benzoic acid forms dimer to the extent of 50% in benzene
(A) 1 (B) 0.8 (C) 0.65 (D) 0.75
3. In which of the following complexes  (Crystal field splitting) does not exceeds pairing energy?
(A) [PtCl4]2– (B) [AgF4]– (C) [Co(ox)3]3– (D) [CoF6]3–
4. What is the value of pKb(CH3COO-), if m = 390 and m = 7.8 for 0.04 M of a CH3COOH solution at
25ºC?
(A) 9.3 (B) 9.2 (C) 4.7 (D) 4.8
5. The weight ratio of AI and Ag deposited using the same quantity of current is:
(A) 9 : 108 (B) 2 : 12 (C) 108 : 9 (D) 3 : 8
6. The minimum voltage required to electroyse alumina in the Hall-Heroult process is :
(Given, G0f (Al2O3) = – 1520 kJmol–1 ; G0f (CO2) = – 394 kJmol–1)
{In Hall-Heroult process, the following reactions occur 3C + 2Al2O3  4Al + 3CO2 }
(A) 1.575 V (B) 1.60 V (C) 1.312 V (D) – 2.62 V
PAGE NO.-12
7. Kohlrausch's law states that at :
(A) Finite dilution, each ion makes definite contribution to equivalent conductance of an electrolyte,
whatever be the nature of the other ion of the electrolyte.
(B) Infinite dilution, each ion makes definite contribution to equivalent conductance of an electrolyte
depending on the nature of the other ion of the electrolyte.
(C) Infinite dilution, each ion makes definite contribution to conductance of an electrolyte, wheatever be
the nature of the other ion of the electrolyte.
(D) Infinite dilution, each ion makes definite contribution to equivalent conductance of an electrolyte,
whatever be the nature of the other ion of the electrolyte.
8. The equivalent conductance of

M solution of a weak monobasic acid is 8.0 mho cm 2 and at infinite
32
dilution is 400 mho cm2. The dissociation constant of this acid is :
(A) 1.25 × 10–5 (B) 1.25 × 10–6 (C) 2.4 × 105 g (D) 1.3 × 10–4 g
9. An increase in equivalent conductance of a strong electrolyte with dilution is mainly due to:
(A) increase in ionic mobility of ions.
(B) 100% ionisation of electrolyte at normal dilution.
(C) increase in both i.e. number of ions and ionic mobility of ions.
(D) increase in number of ions.
10. Which process involves corrosion ?

(A) Brown deposits on iron articles (B) Green deposits on battary terminals
(C) Black deposits on silver coin (D) All of the above
11. When haematite ore is burnt in air with coke along with lime at 200°C, the process not only produces
steel but also produces an important compound (A), which is useful in making building materials. The
ompound (A) is
(A) SiO2 (B) CaSiO3 (C) FeO (D) Fe2 O3
12. The following diagram shows arrangement of lattice point with a = b = c and  =  =  = 90º.
Choose the correct options.

(A) The arrangement is SC with each lattice point surrounded by 6 nearest neighbours.
(B) The arrangement is SC with each lattice point surrounded by 8 nearest neighbours.
(C) The arrangement is FCC with each lattice point surrounded by 12 nearest neighbours.
(D) The arrangement in BCC with each lattice point surrounded by 8 nearest neighbours
13. The kinetic energy for 14 grams of nitrogen gas at 127°C is nearly (mol. mass of nitrogen = 28 and gas
constant = 8.31 JK–1 mol–1)
(A) 1.0 J (B) 4.15 J (C) 2493 J (D) 3.3 J
14. An element (with atom. mass = 250 g) crystallises in a simple cubic. If the density of the unit cell is 7.2
g cm–3, what is the radius of the element ?
(A) 1.93  10–6 cm (B) 1.93  10–8 cm (C) 1.93  10–8 Å (D) 1.93  10–8 cm
PAGE NO.-13
15. Which of the following is incorrect
(A) The defect is known as schottky defect

(B) Density of compound in the defect decreases
(C) NaCl(s) is example which generally shows this defect.
(D) Stoichoimetry of compound will change slightly.
16. The pH value will be highest for the aqueous solution of :
(A) NaCl (B) KCN (C) C6H5NH3+Cl– (D) NaHCO3
17. A hypothetical ionic compound AB (mol. wt. = 240 g/mole), having co-ordination number of anion equal
to 6, has a closest anion-anion distance of 4 24Å . Determine the density of ionic compound AB in
gm/cc.
(A) 6.24 (B) 3.12 (C) 1.56 (D) 0.78
18. Borax on heating strongly above its melting point melts to a liquid, which then solidifies to a transparent
mass commonly known as borax-bead. The transparent glassy mass consists of :
(A) sodium pyroborate (B) boric anhydride
(C) sodium meta-borate (D) boric anhydride and sodium metaborate
19. At 900ºC Kp = 1.04 atm for the reaction CaCO3(s)   CaO(s) + CO2(g). At low temperature 58.4 g
CO2, 655 g CaO and 95 g CaCO3 are introduce in 50 L reaction chamber. The temperature is raised to
900ºC amount of CaO will ……..
(A) increase (B) decrease (C) remain same (D) none
20. Which of the following statement is not correct about Ellingham diagram?
(A) G increases with an increases in temperature
(B) It consists of plots of fG vs T for formation of oxides
(C) A coupling reaction can be well expressed by this diagram
(D) It express the kinetics of the reduction process
21. The number of electrons in 24Cr for which + m = 2.
22. For the reaction A C, the concentration and time is shown as
what is the value of Kc for the reaction 2 C 2 A ?
23. A sample of H2SO4 (density 1.8 g mL–1) is labelled as 74.66% by weight. What is molarity of acid ? (Give
answer in rounded digits)
24. For the formation of AB4 solid, reaction is followed as
A (s) + B2 (g)  AB4 (s) ; H1
where H1 = Hsub + HI.E + x HB.D.E. + y He.g. + HLE
[sub = sublimation energy, BDE = Bond dissociation energy and eg = electron gain enthalpy]
what will be the value of (x + y).
25. A solution of Hg2+ ion on treatment with a solution of cobalt(II) thiocyanate gives rise to a deep blue
crystalline precipitate. The coordination number of mercury in the deep blue coloured compound is.
PAGE NO.-14

1. Which of the following is/are ionic in solid state?
(A) BeCl2 (s) (B) CaC2 (s) (C) PF5 (s) (D) XeF6(s)
2. Select the correct statements about the electrolysis
(A) Electric current is used to drive a non spontaneous reaction
(B) G is positive for chemical process during electrolysis
(C) cations and anions move towards the anode and cathode respectively
(D) over voltage is generally associated with anode in the electrolysis of NaCl (aq)
3. Select the incorrect statement(s)
(A) Gases ‘X’ and ‘Y’ having similar intermolecular forces, have their critical volume related as
(VC)Y
 1. Therefore, gas ‘Y’ is more compressible than gas ‘X’ under similar conditions.
(VC)X
(B) Under normal conditions, helium gas shows positive deviation from ideal behaviour.
(C) Value of third virial coefficient of Z vs Vm equation for a gas is zero at Boyle’s temperature.
(D) At very high molar volume, behaviour of gas becomes ideal.
4. Which is/are true about the Buckminster fullerene ?
(A) Carbon atoms are sp2 hybridised.
(B) Electrons are delocalised in the molecular orbitals of different carbon atom.
(C) It contains two type of C-C bond length.
(D) Thermodynamically it is less stable than diamond and graphite.
5. Which of the following statements is/are correct ?
(A) The shape of compound XeF6 is regular octahedron.
(B) According to MOT, mixing of s and p orbitals takes place in the formation of N 2 molecule.
(C) In complex ion [PtCl4]2– the orbitals of central atom involved in hybridisation are 5dx 2–y2, 6s, 6px
and 6py.
(D) In liquid H2O2, both hydrogen bonds and covalent bonds are present.
Comprehension #
Following flow chart describes the scheme of classification of anions on the basis of the nature of the
products or nature of reaction with chemical reagents and acids.
6. A salt on reaction with dil H2SO4 produces a colourless gas which turns lime water milky and an
acidified orange coloured potassium dichromate solution green. The salt may be -
(A) a carbonate (B) a sulphite (C) a sulphide (D) acetate.
7. A solution of a salt in concentrated H2SO4 turns white paste of starch containing potassium iodide blue.
The salt may be a :
(A) chloride (B) carbonate (C) bromide (D) acetate
PAGE NO.-15
8. Which of the following statement is incorrect ?
(A) Metal iodide with excess chlorine water forms colourless iodic acid.
(B) Nitrates on gentle warming with aluminium powder and sodium hydroxide produces ammonia gas.
(C) Mercury nitrate solution produces yellow precipitate of basic mercury (II) sulphate with sodium
sulphate solution.
(D) A deep red solution of complex ion [Fe 3(OH)2(CH3COO)6]+ on boiling with water produces a
greenish-yellow precipitate.
9. How many of the following can dissolve in aqueous HCl as well as NaOH solution to liberate H2 ?
B, Al, B2H6, B2O3, NaAlH4, Al2O3, AlCl3, BF3
10. Out of following how many species do not exist ?
PH3, PH5, SF6, PbI4, NCl5, OF2, OF4, HFO4, FeI3, KF3
11. 2 moles of an ideal monoatomic gas undergoes a reversible process for which P 2V = constant. The gas
sample is made to expand from initial volume of 1L to final volume of 4L starting from initial temperature
of 300K. Find the value of Ssys for the above process. Report your answer as 'X' where Ssys = XRn2.
12. How many of the following liberate coloured vapours/gas with concentrated H 2SO4?
(i) KBr (s) + K2Cr2O7 (s) (ii) KNO2 (s) (iii) KI (s) (iv) K2S (s)
(v) KCl (s) (vi) KBr (s) + MnO2 (s) (vii) KNO3 (s) (viii) KCI(s) + MnO2 (s)
(ix) K2SO3 (s)
13. How many of the following species on mixing with water produce acidic solutions ?
FeCl3 ; CuSO4 ; CO2 ; NaCl ; KCN ; NH4Cl ; C6H5NH3+Cl– ; BCl3, CaCO3;
14. Total number of anions which can give precipitate with Ag+ ion are -
CO32 , S2 , SO 2  2 3  
3 OO , I , Br
2 3 , NO3 , C2O4 , BO3 , CHC

15. Match the column

Column-I Column-II
200ºC
(A) B2H62NH3   (P) H2
B2H6  
(B) Red heat (Q) B3N3H6
(C) B2H6 + H2O  (R) H3BO3
(D) B2H6 + HCl  (S) B

ChemINFO : 4 Questions ('–1' negative marking) Q.22 to Q.25 (3 marks, 2 min.) [12, 08]
1. Match the ores listed in column I with the type of ores listed in column II and select the correct.
alternate.
Column I Column II
(a) Limonite. (p) Carbonate ore.
(b) Argentite. (q) Halide ore.
(c) Carnallite (r) Sulphide ore.
(d) Calamine. (s) Oxide ore.
(a) (b) (c) (d) (a) (b) (c) (d)
(A) (s) (r) (q) (p) (B) (p) (s) (q) (r)
(C) (p) (q) (r) (s) (D) (s) (r) (p) (q)
2. Colourless salt + dil H2SO4 Y (colourless gas), Y 

Starchpaper
iodateBlue colouration
(X)
Y can be :
(A) SO2 , H2S (B) Cl2, Br2 (C) SO2, NO2 (D) Cl2, NO2
PAGE NO.-16
3. A salt (X) is heated in a dry test tube. Reddish brown fumes (Y) are evolved which turn potassium
dichromate paper green and starch iodide paper blue (Y) is found to be paramagnetic. Then :
(A) X may be KNO3 (B) X may be ZnBr2
(C) X may be Mg(NO3)2 (D) Y turns red litmus blue
4. Which is not an irreversible process

(A) Mixing of two gases
(B) Evaporation of water at 373 K and 1 atm in a closed system.
(C) Dissolution of NaCl in water
(D) H2O(s) at –4°C
5. X(s) A(g) + 2B(g) KP1 = 9  10–3 atm3

Y(s) 2B(g) + C(g)
If the ratio of KP1 :KP2 = 2 atm3. The total pressure of gases over a mixture of X and Y is
(A) 4.5 atm (B) 0.45 atm (C) 0.6 atm (D) none of these
6. Consider the following complex :

[Cr(NH3)4(NO2)2] : inner orbital complex.
The oxidation number, number of d-electrons, number of unpaired d-electrons on the metal ion and
number of isomers are respectively :
(A) 3, 3, 3, 2 (B) 2, 4, 0, 6 (C) 2, 4, 2, 6 (D) 2, 4, 4, 4
7. What is the correct order from the weakest to the strongest carbon-oxygen bond for the following
species ? CO, CO2, CO32– , CH3OH.
(A) CH3OH < CO32– < CO2 < CO (B) CO < CO2 < CO32– < CH3OH
2–
(C) CH3OH < CO3 < CO < CO2 (D) CH3OH < CO2 < CO32– < CO
8. A sulphite on treatment with dilute H2SO4 liberates a colourless gas in presence of zinc. The gas
liberated may be identified by one of the test.
(A) A filter paper moistened with cadmium nitrate solution turns yellow.
(B) A filter paper moistened with sodium nitroprusside turns purple.
(C) Gives white precipitate with BaCl2 solution.
(D) All of these.
9. A substance on treatment with dilute H2SO4 liberates an irritating colurless gas which produces a blue
colour on a filter paper moistened with potassium iodate and starch solution and white precipitate with
baryta water. These reactions indicate the presence of :
(A) CO32– (B) SO32– (C) S2– (D) NO2–
10. The vapour pressure of a 0.05 molal solution of a weak acid HA in water at a temperature T is 50 mm of
Hg. If aqueous tension at temperature T is 50.054 Torr, then the degree of dissociation of HA at the
given temperature is :
(A) 0.2 (B) 0.8 (C) 0.25 (D) 0.1
11. Molar volume of an Ideal gas is 0.45 dm 3/mol. The molar volume of air (assuming as real gas) under
the same condition is 0.9 dm 3/mol. The point which corresponds to air in the given graph is :
2.0 D
Z 1.5 C
(Compressibility 1.0 B
factor)
0.5 A
P
(A) B (B) D (C) A (D) None of these
PAGE NO.-17
12. S1 : Magnitude of first electron gain enthalpy of an atom is the same as the first ionization energy of the
monovalent anions.
S2 : Aqueous solution of Al2O3 can react with both H2SO4 and NaOH.
S3 : Electronegativity of phosphorus is greater than that of sulphur, due to its stable half filled
configuration.
S4 : Ionic size of isoelectronic species increases as nuclear charge of ion increases.
(A) T F T T (B) T F F F (C) T T F F (D) F T F F
13. The lattice energy of solid NaCl is 772 KJ mol–1 and enthalpy of solution is 2 KJ mol–1. If Hydration
energy of Na+ and Cl– are in the ratio of 6 : 5 the, enthalpy of hydration of Na+ is (in KJ mol–1)
(A) –350 (B) –420 (C) –148 (D) None
14. On sparking, the volume of 1 litre of dioxygen reduces to 0.8 litre. The mol fraction of ozone in the
resulting mixture is
(A) 0.5 (B) 0.4 (C) 0.2 (D) 1
15. Which of the following processes are used for the extraction of Mg and Ag respectively?
(A) Carbon reduction and cyanide process. (B) Cyanide process and electrolytic reduction.
(C) Electrolytic reduction and cyanide process. (D) Carbon monoxide reduction and cyanide process.
16. MnO2(s) and conc. H2SO4 is added to NaCl(s). The greenish yellow gas liberated is :
(A) Cl2 (B) HCl (C) SO3 (D) ClO2
17. A metal exist in BCC structure and has a density of 7.5 g /cc. If edge length of unit cell 5 Å, how many
atoms are present in 15 g metal ?
(A) 3.2 × 1022 (B) 1.66 ×1022 (C) 1.66× 1024 (D) None
18. What is the coordination number of aluminium in mineral cryolite ?
19. In a certain reaction at equilibrium X moles of the reactant A decompose to give 1 mole each of C and
D . It has been found that fraction of A decomposed at equilibrium is independent of initial concentration
of A . Calculate X .
20. The concentration of K+ in interior and exterior of a Nerve cell are 500 mM and 25 mM respectively. The
electrical potential (in volt) exists across the membrane is : [log102 = 0.3, 2.303 RT/F = 0.06] (Give
answer be multiplying with 1000)
21. In modern periodic table let, a = Group number of a hypothetical element having atomic number 'z' =
120.
b = Period number of the element 'Pd'.
c = Atomic number of last element of lanthanide series.
Find (a + b + c)
ChemINFO p-Block Element

Daily Self-Study Dosage for mastering Chemistry Topic : Comparision between white and Red phosphorus
Property White prosphorus Red prosphorus

(1) Physical state Soft waxy solid Brittle powder
(2) Colour White when pure Attains, yellow colour on standing Red
(3) Odour Garlic Odourless
(4) Solubility in H2O Insoluble Insoluable
(5) Solubility in CS2 Soluable Insoluable
(6) Physiological Action Poisonous Non poisonous
(7) Chemical activity Very Active Less active
(8) Stability Unstablae Stable
(9) Phosphorescence Glows in dark Does not glow in dark
(10) Reaction with NaOH Evolves phosphine No action
(11) Molecular Formula P4 Complex polymer
Note : Order of stability : Black phosphorus > R.P. > W.P.
Order of Reactivity : B.P. < R.P. < W.P.
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
PAGE NO.-18
22. White phosphorus is :
(A) A monoatomic gas (B) P4 a tetrahedral solid
(C) Pgas a crown (D) A linear diatomic molecule
23. White phosphorus when boiled with strong solution of caustic soda produces.
(A) Phosphine (B) Phosphoric acid (C) Phosphorus Acid (D) No reaction
24. Which of the following properties of white phosphorus are shared by red phosphorus.
(A) It show phosphorescenes in air
(B) It reacts with hot aqueous NaOH to give phosphine.
(C) It dissolve in carbon disulphide
(D) It not dissolve in H2O.
25. Phosphorus is used in :

(A) Photography (B) Cement Industry (C) Rubber industry (D) Match industry

Comprehension : 3 Questions ('–1' negative marking) Q.6 to Q.8 (3 marks, 2 min.) [09, 06]
1. In electrolysis of Al2O3 by Hall-Heroult process:
(A) cryolite Na3[AlF6] lowers the melting point of Al2O3 and increases its electrical conductivity.
(B) Al is obtained at cathode and probably CO2 at anode
(C) electrolysis is carried out in aqueous medium
(D) anode consist of graphite

(A) Main function of the collectors in metallurgy is make the ore hydrophobic.
(B) Silver is obtained by a hydrometallurgical operation.
(C) Lime stone is used as flux in the extraction of iron from haematite ore.
(D) None of these
3. Which of the following complexe(s) is/are diamagnetic ?

[Pt (NH3)4]2+ [Co (SCN)4]2– [Cu (en)2]2+ [Hg4]2–
square planar tetrahedral square planar tetrahedral
(i) (ii) (iii) (iv)
(A) (i) (B) (ii) (C) (iii) (D) (iv)
4. BCI3 does not exist as dimer but BH3 exist as dimer (B2H6) because:
(A) Chlorine is more electronegative than hydrogen
(B) There is p-p back bonding in BCI3 but BH3 does not contain such bonding
(C) Large sized chlorine atoms do not fit between the small boron atoms whereas small sized hydrogen
atoms get fitted between boron atoms
(D) All are correct reason
5. Select the correct statements if -

EºMg2/Mg2.4V, EºSn4/Sn2 0.1 V, EºMnO –,H/Mn2 1.5 V, Eº2/– 0.5 V
4
Here,
(A) MnO4– is the strongest Oxidizing Agent and Mg is the strongest Reducing Agent.
(B) Sn4+ + 2– Sn2+ + 2 is a nonspontaneous reaction.
(C) Mg2+ + Sn2+   Mg + Sn4+ is a spontaneous reaction.
(D) Here, Weakest oxidizing agent is Sn4+ and weakest reducing agent is Mn2+
PAGE NO.-19
Comprehension #
Take two sealed glass bulbs A and B with same sample of oxide of nitrogen at same pressure. At room
temperature both the bulb have light reddish brown colour because of components in A and B bulbs are
at equilibrium. When bulb 'B' is heated at 883 K, then gas becomes colourless due to formation of
another oxide of nitrogen (X). Compound of bulb (B) can be prepared by oxidation of (X) by air.
Compound (X) is slightly heavier than water and when dissolved in acidified FeSO 4 solution a dark
colour nitrosyl complex of iron (Y) is obtained.
6. The IUPAC name of (Y) is :
(A) Tetraaquonitrosyliron (I) ion (B) Pentaaquonitrosoniumiron (I) ion
(C) Pentaaquonitrosyliron (II) ion (D) Pentaaquonitroiron (I) ion
7. The (X) is -
(A) N2O3 (B) N2O4 (C) NO (D) NO2
8. Which of the following is/are correct when the bulb (A) is placed in ice -
(A) The intensity of brown colour will be greatly reduced due to decomposition to the lower oxide.
(B) The intensity of brown colour will be greatly reduced due to dimersation.
(C) The intensity of brown colour will be increased.
(D) The colour of the complex change from brown to pale blue.
9. How many of the following ores do not contain more than one metal in their composition. Argentite,
Barytes, Magnesite, Fluorspar, Carnalite, Dolomite, Chalcocite, Asbestos, Calamine.
10. The dipole moment of XY is 1.6 × 10–30 C-m. If inter nuclear distance is 2 × 10–10 m then % ionic
character of XY is _____. (Charge of electron = 1.6 × 10–19 C)
11. A 200 ml aqueous solution of KCl was electrolysed for 16 min and 5 sec. If the pH of the final solution
was 13 and volume of solution remains practically unchanged, then the average current used in ampere
is:
12. Evolution of a colored gas / fumes is possible on heating which of the following with conc. H2SO4 ? You
may also add copper turnings, MnO2 or NaCl in any of these, if required.
KNO3, Mg2, ZnBr2 , K2Cr2O7, NaF, FeC2O4, NaNO2 , Cu(OH)2 , CoCO3
13. In how many of the following reactions atleast one product is formed which is gaseous at room
temperature?
(a) Na + H2O() 
(b) Sodamide + H2O()  
(c) Sodium nitrite 
800

º

C
(d) Calcium hydride + H2O() 


(e) B2H6 + H2O() 

(f) Sodium peroxide + H2O() 

(g) Potassium superoxide + H2O() 

14. A solid A+B– having ZnS structure (zinc blende) is heated so that the ions along one of the body
diagonal are lost and trivalent ion(C) enters here to maintain the electrical neutrality, so that the new
formula unit becomes AxByCz. Report the value of (x + y + z).
15. Match the column-
(A) Chalcopyrites (p) Self – reduction
(B) Galena (q) Sulphur containing ore
(C) Argentite (r) Carbon reduction
(D) Malachite (s) Leaching followed by displacement method.
PAGE NO.-20

1. 'Spin only' magnetic moment of Ni in [Ni(dmg)2] is same as that found in :
(A) Ni in [NiCl2(PPh3)2] (B) Mn in [MnO4]2– (C) Co in [CoBr4]2– (D) Pt in [Pt(H2O)2Br2]
2. Starting with the same initial conditions one mole of an ideal monoatomic gas expands reversibly from
volume V1 to V2 in three different ways. The work done by gas is |W 1| if the process is purely
isothermal, |W 2| if purely isobaric and |W 3| if purely adiabatic, then
(A) |W 1| > |W 2| > |W 3| (B) |W 2| > |W 1| > |W 3|
(C) |W 2| > |W 3| > |W 1| (D) |W 1| > |W 3|> |W 2|
3. Which of the following is path function as well as extensive property?
(A) Molar heat capacity (B) Internal energy (C) Temperature (D) None of these
4. In the graph of Z vs P for a given gas, which of the following is INCORRECT ?
(A) At T > TC, Z>1 at all pressures .
(B) At T = TC, Z<1 at low pressures.
(C) At T = TB, the gas follows Boyle's law at low pressures.
(D) At T > TB, Z>1 at high pressures.
5. Hydrolysis constants of two salts KA & KB of weak acids HA and HB are 10–8 and 10–6. If the
dissociation constant of third acid HC is 10–2. The order of acidic strength of three acids will be
(A) HA > HB > HC (B) HB > HA > HC (C) HC > HA > HB (D) HA = HB = HC
6. The correct order of dipole moment is
(A) CH4 < NF3 < NH3 < H2O (B) NF3 < CH4 < NH3 < H2O
(C) NH3 < NF3 < CH4 < H2O (D) H2O < NH3 < NF3 < CH4
7. Which one of the following combination is not allowed in the LCAO method for the formation of a
molecular orbital (consider Z-axis as the molecular axis) ?
(A) s + px (B) s + pz (C) px + px (D) pz + pz
8. AlCl3 is an electron-deficient compound but AlF3 is not, due to
(A) Atomic size of F is smaller than Cl, which makes AIF3 more covalent.
(B) AlCl3 is a covalent compound while AlF3 is an ionic compound.
(C) Al in AlCl3 is sp3 hybridised but in AIF3, Al is sp2 hybridised.
(D) AlCl3 exists as a dimer but AIF3 does not.
9. In the reaction 4A + 2B + 3C   A4B2C3 what will be the number of moles of product formed.
Starting from 2 moles of A, 1.2 moles of B & 1.44 moles of C :
(A) 0.5 (B) 0.6 (C) 0.48 (D) 4.64
10. The preparation of SO3(g) by reaction : SO2 (g) +

1 O2 (g) SO3 (g)
2
is an exothermic reaction. If the preparation follows the following
temperature-pressure relationship for its % yield, K1, K2 and K3 are the
equilibrium constant for the given reaction at temperature T 1, T2 and T3
respectively. The correct option is :
(A) T3 > T2 > T1
(B) T3 < T2 < T1
(C) K1 = K2 = K3
(D) Nothing could be predicted about temperature through given
information.
PAGE NO.-21
11. Brine   is

E lectrolys A + H2
incastner
(Products of cathode); A, B & C are
K ellner cell
P4
B + C
 A B C
(A) Na PH3 NaH2PO2
(B) NaOH PH3 NaH2PO2
(C) NaOH Na3P NaH2PO4
(D) NaOH PH3 NaH2PO3
12. PCl3, when dissolved in excess as NaOH, give :
(A) NaH2PO2 (B) Na3PO4 (C) Na3PO3 (D) Na2HPO3
13. In hexagonal close packing of sphere in three dimensions.
(A) In one unit cell there are 12 octahedral voids and all are completely inside the unit cell.
(B) In one unit cell there are six octahedral voids and all are completely inside the unit cell.
(C) In one unit cell there are six octahedral void and of which three are completely inside the unit cell
and other three are partially inside the unit cell.
(D) In one unit cell there are 12 tetrahedral voids, all are completely inside the unit cell.
14. Phosphine, acetylene and ammonia can be formed by treating water with
(A) Mg3P2, Al4C3.Li3N (B) Ca3P2, CaC2.NaN3
(C) Ca3P2, CaC2, CaCN2 (D) Ca3P2, Mg2C, NH4NO3
15. On the basis of following reactions, identify the correct matching
A(aq) + Al 
heat
(B)(gas). (Colorless combustible gas which is lightest)
A(aq) + C  PH3(gas).
heat
A(aq) + NH4Cl  (D)(gas) . (turns red litmus blue)

heat
(A) A = NaOH, C = P4 (B) A = CH3COOH, B = CH4
(C) A = KOH, D = NH3, C = H3PO4 (D) A = HCl, B - H2, C = H3PO4
(E) A = H2SO4, D = HCl, C = P4
16. A graph of molar conductivity of three electrolytes (NaCl, HCl and NH 4OH) is plotted against c.
m
1
2
3
C
Which of the following options is correct ?
(1) (2) (3) (1) (2) (3)
(A) NaCl HCl NH4OH (B) NH4OH NaCl HCl
(C) HCl NaCl NH4OH (D) NH4OH HCl NaCl
PAGE NO.-22
17. A solution is a mixture of 0.06 M KCl and 0.06 M KI. AgNO 3 solution is being added drop by drop till
AgCl starts precipitating (Ksp AgCl = 1 x 1010 and Ksp AgI = 4 x 1016). The concentration of iodide ion
at this instant will be nearly equal to :
(A) 4.0 x 105M (B) 4 x 108M (C) 2.4 x 108M (D) 2.4 x 107M
18. Pure benzene freezes at 5.3ºC. A solution of 0.223 g of phenylacetic acid in 4.4 g of benzene
(Kf = 5.12 K kg mol–1) freezes at 4.10ºC. From this observation, one can conclude that :
(A) phenylacetic acid undergoes partial ionization in benzene
(B) phenylacetic acid exists as such in benzene
(C) phenylacetic acid dimerizes in benzene
(D) phenylacetic acid undergoes complete (100%) ionization in benzene
19. For the chemical equilibrium, CaCO3(s) CaO(s) + CO2(g); H = +ve
Which of the following curve is correct
loge Pco2
loge Pco2
loge Pco2
loge Pco2
(A) (B) (C) (D)
1/T 1/T log T logT
20. A metal has a fcc lattice. The edge length of the unit cell is 404 pm. The density of the metal is
2.72 g cm–3. The molar mass of the metal is : (NA Avogadro's constant = 6.02  1023 mol–1)
(A) 30 g mol–1 (B) 27 g mol–1 (C) 20 g mol–1 (D) 40 g mol–1
21. How many of the following is correctly matched :
(a) 1 nm = 10–9 m
(b) 1 pm = 1012 m
(c) 1 m3 = 1000 dm3
(d) 1 m = 10–3 m
(e) 1mm of Hg = 1 torr = 0.1 cm of Hg.
(f) 105Nm–2 = 1 bar
22. If the number of N-atoms in 1 molecule of Hyponitrous acid is x and the basicity of Boric acid is y, find
the sum (x + y).
23. 4.90 g of KClO3, on heating, shows a weight loss of 0.384 g. What percent of the original KClO3 has
decomposed ?
x
24. The C.F.S.E value of [Cr(H2O)6]Cl2 is –  then what is the 'x' ?
10 0
25. An oxy–acid of phosphorus is prepared by hydrolysis and oxidation of red phosphorus by NaOCl or
yellow phosphorus by water and air. What is the basicity of the oxy-acid.
DPP No. # B11 (REVISION DPP)

1. Which of the following is not correctly matched with the flame colour in flame test?
(A) K-violet (B) Na-yellow (C) Ba-no colour (D) Ca-brick red
2. A barium salt [X] insoluble in dilute HCl on heating in a reducing flame with charcoal and sodium
carbonate gives a salt. An aqueous solution of this salt produces yellow precipitate with cadmium
acetate solution.
The anion of [X] is :
(A) S2– (B) SO32– (C) SO42– (D) All of these
PAGE NO.-23
3. When a nitrate is boiled with aluminium turnings and con. NaOH solution, the gas liberated is:
(A) NO2 (B) NH3 (C) NO (D) N2O
4. Vapour pressure & temperature relationship is shown as, log P 500

(K) 15. Heat of vapourisation
T
will be :
(A) 2.303 Kcal. (B) 4.606 Kcal. (C) 500 Kcal. (D) 550 Kcal.
5. (I) [ Co(EDTA)] – has two optical isomers.
(II) [Co(NH3)4 (NO2)2 ]+ show linkage isomers.
(III) For [Pt (py)(NH3)(NO2) Cl BrI], theoretically fifteen different geometrical isomers are possible.
(IV) [ Cr(H2O)4Cl2] Cl2.2H2O can show hydrate as well as ionisation isomerism.
Amongs the following correct statements are :
(A) II, III (B) III (C) I, III (D) I, II & III
6. Which of the following statement(s) is/are correct?
(A) Sulphide gives black precipitate with AgNO3 solution and is soluble in hot concentrated nitric acid.
(B) Sulphide gives no precipitate with barium chloride solution.
(C) Sulphide ions react with sodium nitroprusside giving a purple colouration.
(D) Free H2S gas form white precipitate with tetrahydroxo plumbate (II) solution.
7. Which of the following statement(s) is/are true ?
(A) Soluble bicarbonates gives white precipitate with MgCl2 in cold.
(B) Soluble calcium bicarbonate gives white precipitate with dilute ammonia solution.
(C) All bicarbonates are generally soluble in water
(D) Hg(II) chloride forms a reddish brown precipitate in a solution of soluble carbonate.
8. When CO2 is passed through lime water, it first turns milky and then it becomes clear. The turbidity
reappears if :
(A) Solution of MgCl2 is added. (B) More CO2 bubbled through it.
(C) The clear solution is boiled. (D) Fresh lime water is added.
(A) Sulphide gives black precipitate with AgNO3 solution and is soluble in hot concentrated nitric acid.
(B) Sulphide gives no precipitate with barium chloride solution.
(C) Sulphide ions react with sodium nitroprusside giving a purple colouration.
(D) Free H2S gas form white precipitate with tetrahydroxo plumbate (II) solution.
10. Which of the following statement(s) is (are) correct when a mixture of NaCl and K 2Cr2O7 is gently
warmed with concentrated H2SO4?
(A) A deep red vapour is evolved.
(B) The vapour when passed into NaOH solution gives a yellow solution of Na2CrO4.
(C) Chlorine gas is evolved.
(D) Intensity of deep red vapours increases if dil H2SO4 is used instead of concentrated H2SO4.
Comprehension #
0.6 mole of K2MnO4 is hydrolysed by dilute H2SO4 to produce KMnO4 along with dark brown precipitate
of MnO2, according to following reaction :
MnO42– + H+  MnO4– + MnO2 + H2O
The MnO2 obtained is fused with KOH in presence of O2 to give K2MnO4 according to the reaction :
MnO2 + KOH + O2  K2MnO4 + H2O
Now, answer the following questions :
11. Number of moles of MnO2 produced according to first reaction is :
(A) 0.3 (B) 0.2 (C) 0.1 (D) 0.4
12. Volume of H2S gas at STP required to completely react wtih KMnO 4 produced in first reaction in acidic
medium to get converted into elemental sulphur is :
(A) 22.4 L (B) 11.2 L (C) 5.6 L (D) 2.8 L
13. How many geometrical isomers are possible for complex [Pt(gly) 2Cl2] ? The coordination number of
platinum in complex is six.
PAGE NO.-24
14. A fresh radioactive mixture containing short-lived species A and B. Both emitting -particles initially at
rate 8000 -particles per minute. 20 minutes later they emits at the rate of 3500 -particles per minute.
If the half lives of the species A and B are 10 minute and 500 hrs respectively then determine the ratio
of activities of A : B in the initial mixture ?
15. At 25ºC, 3 mole of aqueous HNO2 undergoes disproportionation reaction to form NO and NO 3– . The
standard potential for the change HNO2 to NO and NO3– to HNO2 is 0.999 V and 0.940 V respectively.
The value of log KC of 3HNO2  2NO + HNO3 + H2O is :
16. How many of the following compounds do not impart characteristic colour to the Bunsen flame :
NaCl , BeCl2 , KOH , BaSO4 , MgCl2 , CsCl , Na2SO4 , Mg(OH)2 , K2CO3
17. 1.0 gram of a monobasic acid HA in 100 gram H 2O lower the freezing point by 0.155 K. 0.45 gram of
same acid require 15 ml of
1 M KOH solution for complete neutralisation. If the degree of dissociation
5
of acid is , then value of ‘20’ is : (Kf for H2O = 1.86 K.Kg/mole)
18. How many of the following will liberate reddish brown gas with conc. HNO3, undergoing complete
reaction?
H2C2O4, Fe, Cu, AgNO3, Ag, FeSO4, S8, Na2S2O3, PbO.
19. How many among the following species contain P–P bond(s) :
(i) P (red) (ii) H4P2O5 (iii) H4P2O7 (iv) (PO3–)3 (v) (PO3–)4
(vi) P4O10 (vii) P4S3 (viii) P4O6 (ix) P4
20. Match the column :
Column-I Column-II
(Reactions) (Type of reaction/process involved)
(A) P4  PH3 + H2PO2– (p) Hydrolysis
(B) [B4O5(OH)4]2– B(OH)3 (q) Addition of KOH
(C) (CH3)2 SiCl2  [(CH3)2 SiO]n (r) Condensation
(D) [Al(OH)4]– Al(OH)3 (s) Redox reaction
(t) Acidificaton

1. NaOH + N2O5  Product of this reaction are

(A) NaNO2, H2O (B) NaNO3, H2O (C) HNO3, Na2O (D) HNO2, Na2O
2. Calculate the solubility of A2X3 (producing A3+ & X2– ions in aqueous solution) in pure water, assuming
that neither kind of ion reacts with water. For A2X3, Ksp = 1.08 x 10–23.
(A) 8 × 10–7 mol L–1 (B) 10–5 mol L–1 (C) 6.4 × 10–5 mol L–1 (D) 2 × 10–5 mol L–1
3. At 727 C, N2(g) + 3H2(g)   2NH3(g);  H = –123.77 KJmol–1
Substance N2 H2 NH3
Cp 3.5R 3.5R 4R
The heat of formation of ammonia at in KJ mol–1 at 27 C is :
(A) + 44.42 (B) – 44.42 (C) + 88.85 (D) – 88.85
4. How many elements would be in the II nd period of the Periodic Table if the spin quantum numbers could
have the value +
1 , 0, – 1 ?
2 2
(A) 18 (B) 12 (C) 10 (D) 8
PAGE NO.-25
5. 1 mol CH3COOH is added in 250 g benzene. Acetic acid dimerises in benzene due to hydrogen bond.
Kb of benzene is 2 K kgmol–1. The boiling point has increased by 6.4K. % dimerisation of acetic acid is :
(A) 50 (B) 40 (C) 30 (D) 20
6. H2S reacts with lead acetate forming a black compound which reacts with H2O2 to form another
compound. The colour of the compound is :
(A) pink (B) black (C) yellow (D) white
7. (I) [MnCl6]3–, [FeF6]3– and [CoF6]3– are paramagnetic having four, five and four unpaired electrons
respectively.
(II) Valence bond theory gives a quantitative interpretation of the thermodynamic stabilities of
coordination compounds.
(III) The crystal field splitting 0, depends upon the field produced by the ligand and charge on the metal
ion.
Amongs the following correct statements are :
(A) I, II (B) I, III (C) I, II, III (D) II, III
8. Carbon suboxide (C3O2) can be obtained by strongly heating which of the following acid with P4O10 :
(A) Oxalic acid (B) Malonic acid (C) Maleic acid (D) Adipic acid
9. Which of the following statement is correct?
(A) S–S bond is present in H2S2O6.
(B) In peroxosulphuric acid (H2SO5) sulphur is in +8 oxidation state.
(C) Copper powder along with Al2O3 and K2O is used as a catalyst in the preparation of NH 3 by Haber’s
process.
(D) Change in enthalpy is positive for the preparation of SO 3 by catalytic oxidation of SO2.
10. 1 g sample of alkaline earth metal react completely with 4.08 g H2SO4 and yield an ionic product MSO4.
Then find out the atomic mass of Alkaline earth metal (M) ?
(A) 9 (B) 24 (C) 40 (D) 87
11. Pt (H2) | pH = 2 | pH = 3 | Pt (H2)
1 atm 1 atm
The cell reaction for the given cell is
(A) spontaneous (B) non-spontaneous (C) equilibrium (D) None of these
12. At constant P of 0.0821 atm log V v/s log T graph is plotted for 3 samples of ideal gas as shown. Value
of moles of gas in these three samples is respectively :
log V
2
0.4771
0.3010 log T
(A) 3, 1,
1 (B)
1 , 1, 3 (C) 1,
1 ,3 (D)
1 , 3, 1
2 2 2 2
13. Calculate the lattice energy of LiF(s), given that :
(i) Hsub for Lithium is 155.2 kJ mol–1 (ii) Hdiss of
1 mole of F (g) is 75.3 kJ
2
2
(iii) I.E of Lithium = 520 kJ mol–1 (iv) E.A. of Fluorine = 333 kJ mol–1
(v) Hf for LiF(s) = – 594.1 kJ mol-1.
(A) – 1011.6 kJ mol–1. (B) + 2056.6 kJ mol–1. (C) – 906.6 kJ mol–1. (D) –573.6 kJ mol–1.
PAGE NO.-26
14. Which bond angle  would result in maximum dipole moment for the triatomic molecule XY2 shown
below :
(A)  = 90° (B)  = 120° (C)  = 150° (D)  = 180°

15. When one mole NO3– is converted into 1 mole NO2, 0.5 mole N2 and 0.5 mole N2O respectively, it
accepts x, y and z mole of electrons. Then, x , y and z are respectively :
(A) 1, 5, 4 (B) 1 ,2 , 3 (C) 2 , 1 , 3 (D) 2, 3, 4
16. The sodium salt of a certain weak monobasic organic acid is hydrolysed to an extent of 3% in its 0.1M
solution at 250C. Given that the ionic product of water is 10 14 at this temperature, what is the
dissociation constant of the acid?
(A)  1 x 1010 (B)  1 x 109 (C) 3.33 x 109 (D) 3.33 x 1010
17. A complex containing K+, Pt(IV) and Cl¯ is 100% ionised giving i = 3. Thus, complex is :
(A) K2[PtCl4] (B) K2[PtCl6] (C) K3[PtCl5] (D) K[PtCl3]
18. It requires 20 ml of 1 M X3+ to titrate 10 ml of 2 M Sn2+ to Sn4+. What is the oxidation state of the 'X' in
the product.
19. Find the valency factor (n) for NH2OH in given reaction :
Fe3+ + NH2OH 
Fe2+ + N2O + H+ + H2O
20. Number of rectangular faces in a monoclinic unit cell are ______ .
21. An ammeter and a copper coulometer are connected in series in an electric circuit through which a
constant direct current flows. The ammeter shows 0.547 A. 0.635 g of copper is deposited in 1 hr. What
is the percentage error of the ammeter at the given value ?
22. The number of ions formed on dissolving one molecule of Mohr's salt in water is
ChemINFO Special Concentration Units

Daily Self-Study Dosage for mastering Chemistry Topic: I. Volume Strength for H2O2
Volume strength (or volumetric conc.) of H2O2 is represented as 10 V, 20 V, 30 V etc. 20 V H2O2
means one litre of this sample of H2O2 on decomposition gives 20 L of O2 gas at STP.
Decomposition of H2O2 is given as :
H2O2  H2O +
1 O2
2
1 mole
1 × 22.4 L O2 at STP
2
= 34g = 11.2 L O2 at STP
For 20 L O2 , we should decompose atleast
34 × 20 g H2O2
11.2
Ex. Relationship between volume strength and Molarity for H2O2.
Assume ‘V’ volume H2O2. It means
34V 34
At STP 1 Lit H2O2 Soln  V Lit O2  H2O2 (by equation). or Molarity = 11.2
1
Volumestrengthof HO
2 2
 Molarity of H2O2 (M) =
11.2
PAGE NO.-27
23. Find the volume strength of H2O2 solution prepared by mixing of 250 mL
3 of M H2O2 & 750 mL of
2
M H2O2 solution :
2
(A) 1.5 V (B) 8.4 V (C) 5.6 V (D) 11.2 V
24. A fresh H2O2 solution is labelled 11.2 V. This solution has the same concentration as a solution which
is:
(A) 3.4% (wt/wt) (B) 3.4% (vol/vol) (C) 3.4% (wt/vol) (D) None of these
25. Hydrogen peroxide in aqueous solution decomposes on warming to give oxygen according to the
equation : 2H2O2(aq)  2H2O() + O2(g)
under conditions where 1 mole of gas occupies 24 dm 3. 100 cm3 of XM solution of H2O2 produces 3
dm3 of O2. Thus X is................
(A) 2.5 (B) 1 (C) 0.5 (D) 0.25

ChemINFO: 4 Questions ('–1' negative marking) Q.13 to Q.16 (3 marks, 2 min.) [12, 08]
1. Consider a mixture of O2 and He gas kept in a container at 27°C. Then which of the following
statements are correct. When O2 is compared with He ?
(A) O2 molecule will hit the wall of the container with smaller average speed as compared to He
(B) O2 will hit the wall of the container with the less kinetic energy as compared to He
(C) O2 molecule will hit the wall of container with the greater kinetic energy as compared to He.
(D) O2 molecule will hit the wall of the container with equal average kinetic energy as compared to He.
2. A graph is shown on P Vs T
Which of the following graphs is/are wrong corresponding to the above graph.
(A) (B) (C) (D)
3. Select the correct statement(s) about the compound NO[BF4] :

(A) It has 5 and 2 bond
(B) Nitrogen-oxygen bond length is higher than nitric oxide (NO)
(C) It is a diamagnetic species
(D) B—F bond length in this compound is lower than that in BF 3
PAGE NO.-28
4.
For a gas ‘X’ the Z v/s P plots are observed as shown. If Boyle's temperature (T b) is 267°C, then which
of the following options are true
(A) T1 = 300 K (B) T2 may be 280 K
(C) TC would be 160 K (D) The gas can be liquified below – 1130C
5. A white solid [P] is stored under water, because it spontaneously ignites in air to form a mixture of
oxides [Q] and [R]. [Q] and [R] react with water to form respective oxy-acids [S] and [T] . Oxyanion of
[S] is present in our bones and teeth enamel.
[P] was first isolated in the 17th century from human urine. Which of the following option(s) is/are
correct?
(A) Oxidation state of central atom in oxy-acid [S] is +3
(B) The structure of [R] is planar.
(C) [P] reacts with NaOH solution in inert atmosphere to give off a gas
(D) (T) reacts with excess NaOH to give an oxyanion that contains an H-atom.
6. A sample of one mole of an ideal gas having 7 is heated at a constant pressure. If the heat
5
absorbed by the gas is 21 J. Determine the work done by the gas in Joule?
7. A sample of pure NO2 gas heated to 1000 K decomposes : 2NO2 (g) 2NO(g) + O2(g). The
1
equilibrium constant KP is atm. Analysis shows that the partial pressure of O 2 is 0.25 atm at
100
equilibrium. Calculate the sum of partial pressures of NO2 and NO at equilibrium.
8. How many of the following reagents will liberate at least one oxide of nitrogen in significant quantity?
(i) Ag + conc. HNO3 (ii) Sn + cold, dil. HNO3 (iii) heated Cu + HNO3 vapors.
(iv) Zn + conc. HNO3 (v) Al + conc. HNO3 (vi) Fe + dil. HNO3
(vii) P4 + conc. HNO3 (viii) S8 + conc. HNO3 (ix) Cu + dil. HNO3
9. Identify no. of  particles emitted when 92U238 changes into radioactive 82Pb206.
10. How many of the following liberate O2 on heating in a dry test tube?
CaO, Fe2O3, Fe3O4, FeO, Cr2O3, XeF4, Al2O3, MgO, Na2O
11. Match the following (one or more than one)
Column - I Column - II
(A) H3PO2  

(i) 415K
 (p) One of the products acts as reducing agent.
(ii) 435K
(B) PCl3 + H2O  

435K
 (q) One of the products is tribasic and non reducing.
(C) NO2 + H2O 

 (r) Dehydration

(D) HNO3 + P4O10  (s) In one of the products the central atom is in +5 oxidation state.
PAGE NO.-29

Daily Self-Study Dosage for mastering Chemistry Topic: Hardness of Water
Hardness of water (Hard water does not give lather with soap)
Temporary hardness - due to bicarbonates of Ca & Mg
Permanent hardness - due to chlorides & sulphates of Ca & Mg. There are some method by which we can
soften the water sample.
(a) By boiling : 2HCO3–  H2O + CO2 + CO32– or
By Slaked lime : Ca(HCO3)2 + Ca(OH)2 CaCO3 + 2H2O
Ca + CO3 
2+ 2– CaCO3
(b) By Washing Soda : CaCl2 + Na2CO3  CaCO3 + 2NaCl
(c) By ion exchange resins : Na2R + Ca2+  CaR + 2Na+
(d) By adding chelating agents like (PO3–)3 etc.
Ex. Temporary hardness is due to bicarbonates of Mg2+ and Ca2+. It is removed by addition of CaO as
follows Ca(HCO3)2 + CaO   2CaCO3 + H2O
Mass of CaO required to precipitate 2 g CaCO3 is :
(A) 2 g (B) 0.56 g (C) 0.28 g (D) 1.12 g
Sol. mole of CaCO3 = 2/100 = 0.02 ; so mole of CaO =
1 × 0.02 = 0.01
2
so mass of CaO = 0.01 × 56 = 0.56 g
12. One litre of a sample of hard water contain 4.44 mg CaCl2 and 1.9 mg of MgCl2. What is the total
hardness in terms of ppm of CaCO3 ?
(A) 6 (B) 3 (C) 1 (D) 10
13. One litre hard water contains 1 mg CaCI2 and 1 mg MgSO4 . Find hardness of water sample (in ppm).
(A) 1.734 ppm (B) 1.934 ppm (C) 1.534 ppm (D) 1.334 ppm
14. Calculate the amount of Ca(OH)2 required to remove the hardness in 60 litre of pond water,containing
1.62 mg of calcium bicarbonate per 100 mL of water.
(A) 0.246 g (B) 0.897 g (C) 0.444 g (D) 1.286 g
15. If 100 Kg of a hard water sample contains 5g MgSO4, find hardness of water (in ppm).
(A) 33.46 ppm (B) 52.24 ppm (C) 64.26 ppm (D) 41.66 ppm

1. A + H2O  B + HCl

B + H2O  C + HCl
Compound (A), (B) and (C) will be respectively :
(A) PCl5, POCl3, H3PO3 (B) PCl5, POCl3, H3PO4
(C) SOCl2, POCl3, H3PO3 (D) PCl3, POCl3, H3PO4
2. Select the incorrect reaction(s) :
(A) K2Cr2O7(s) + 4NaCl(s) + 3H2SO4(conc.)  2CrO2Cl2 + 2Na2SO4 + K2SO4 + 3H2O
(B) K2Cr2O7(s) + 6K(s) + 7H2SO4(conc.)  3I2 + Cr2(SO4)3 + 4K2SO4 + 7H2O
(C) MnO2(s) + NaCl(s) + 2H2SO4 (conc.)  NaHSO4 + MnSO4 + HCl + H2O + 1/2O2
(D) KI(s) + H3PO4(conc.)  HI + KH2PO4
3. 100 mL of 0.1N I2 oxidizes Na2S2O3 in 50 ml solution to Na2S4O6. The normality of this hypo solution
against KMnO4 (which oxidizes it to Na2SO4) would be
(A) 0.1 (B) 0.2 (C) 1.0 (D) 1.6.
PAGE NO.-30
4. 0.185 g of an iron wire containing 99.8% iron is dissolved in an acid to form ferrous ions. The solution
requires 29.3 mL of K2Cr2O7 solution for complete reaction. The normality of the K 2Cr2O7 solution is :
(A) 0.05 (B) 0.02 (C) 0.20 (D) 0.10
5. Which one of the following statements about H3BO3 is not correct ?
(A) It is a strong tribasic acid
(B) It is a prepared by acidifying an aqueous solution of borax
(C) It has a layer structure in which planar BO3 units are joined by hydrogen bonds
(D) It doesnot act as proton donor as it acts as a Lewis acid by accepting hydroxyl ions
6. Which of the two ions from the list given below that have the geometry that is explained by the same
hybridization of orbitals, NO2–, NO3–, NH2–, NH4+, SCN– ?
(A) NO2– and NO3– (B) NH4+ and NO3– (C) SCN– and NH2– (D) NO2– and NH2–
7. Which of the following compounds has the lowest melting point ?
(A) CaCl2 (B) CaBr2 (C) Ca2 (D) CaF2
8. The radius of hydrogen in ground state is 0.53 Å. The radius of Li2+ in ground state will be –
(A) 1.06 Å (B) 0.265 Å (C) 0.17 Å (D) 0.53 Å
9. Pure ammonia is placed in a vessel at a temperature where its degree of dissociation () is
appreciable. At equilibrium -
(A) Kp does not change with pressure
(B)  does not change with pressure
(C) Concentration of ammonia does not change with pressure
(D) Concentration of H2 is less than concentration of N2.
10. If 0.224 litre of H2 gas is formed at the cathode, in the electrolysis of water the volume of O 2 gas formed
at the anode under identical conditions, is
(A) 0.224 L (B) 0.448 L (C) 0.112 L (D) 1.12 L
11. In H2 – O2 fuel cell a reaction occuring at cathode is :
(A) 2H2O + O2 + 4e  4 OH 
(B) 2H2 + O2  2 H2 O (l)
(C) H+ + OH H2O (D) H+ + e  1 H2 .
2
12. The solubility of calomel (mercurous chloride) in pure water is equal to
(A) 1/4 (2Ksp)1/3 (B) 1/2(Ksp)1/2 (C) Ksp1/2 (D) (Ksp/4)1/3
13. Solvay process is used for the manufacture of
(A) NaOH (B) Na2CO3.10H2O (C) K2CO3 (D) Na2 O2
14. Enthalpy change for the reaction, 4H(g) 2H2(g) is – 869.6 kJ.
The dissociation energy of H–H bond is :
(A) – 434.8 kJ (B) – 869.6 kJ (C) + 434.8 kJ (D) + 217.4 kJ
15. The freezing point depression constant for water is –1.86º Cm–1. If 5.00 g Na2SO4 is dissolved in 45.0 g
H2O, the freezing point is changed by – 3.82ºC. Calculate the van’t Hoff factor for Na2SO4.
(A) 2.05 (B) 2.63 (C) 3.11 (D) 0.381
16. X, Y and Z are elements in the same short period. The oxide of X is a giant molecule, the oxide of Y is a
simple molecule and the oxide of Z is ionic. The arrangement of the elements in order of increasing
atomic number would be
(A) X, Y, Z (B) X, Z, Y (C) Z, X, Y (D) Y, Z, X
17. Which of the following anions is not easily removed from aqueous solutions by precipitation?
(A) Cl   (B) SO42  (C) NO3  (D) CO3 2
18. 2.68 × 10–3 mol of a solution containing an ion A+n+ to AO3– in acid medium. What is the value of n?
19. What volume of water is required to make 0.20 M solution from 16 mL of 0.5 M solution ?
20. Calculate ratio of wavelength for a proton and -particle. If their K.E. are same. If ratio is X/Y then value
of X – Y is :
PAGE NO.-31
21. The equivalent conductance of 0.01 M solution of weak acid HA is 19.6 S cm 2 eq–1. The equivalent
conductance of the electrolyte at infinite dilution 392 S cm 2 eq–1 then pH of the solution will be :
22. In the disproportionation reaction of NaOH with one molecule of P4, number of molecules of NaOH
reacting are .............. .

Daily Self-Study Dosage for mastering Chemistry Topic: Strength of Oleum
Oleum is SO3 dissolved in 100% H2SO4. Sometimes, oleum is reported as more than 100% by weight,
say y% (where y > 100). This means that (y100) grams of water, when added to 100 g of given oleum
sample, will combine with all the free SO3 in the oleum to give 100% sulphuric acid.
Hence, weight % of free SO3 in oleum = 80(y100)/18
Ex. What is the % of free SO3 in an oleum sample that is labelled as '104.5% H2SO4' ?
(A) 30% (B) 15% (C) 20% (D) 25%
Sol. SO3 + H2O   H2SO4. ;
18 g water combines with 80 g SO3
4.5 g of H2O combines with
80 4.5 = 20 g of SO
3
18
100 g of oleum contains 20 g of SO3 or 20% free SO3 in oleum sample.
or % of free SO3 =
80 × (104.5 – 100) = 20%
18
23. Maximum labelling of oleum is :
(A) 109% (B) 100% (C) 122.5% (D) 112%
24. Similar to the % labelling of oleum, a mixture of H3PO4 and P4O10 is labelled as (100 + x)% where x is
the maximum amount of water which can react with P4O10 present in the mixture. If such a mixture is
labelled as 127%. The mass of P4O10 in 100 gm of mixture is :
(A) 71 g (B) 47 g (C) 83 (D) 35 g
25. What is the % of free SO3 in an oleum sample that is labelled as '109% H2SO4' ?
(A) 30% (B) 15% (C) 20% (D) 40%

Comprehension ('–1' negative marking) Q.7 to Q.8 (3 marks, 2 min.) [06, 04]
1. For a hypothetical H like atom which follows Bohr's model, some spectral lines were observed as
shown in figure. If it is known that line 'E' belongs to the visible region, then the lines possibly belonging
to ultraviolet region will be:
[Given: n1, n2, n3 and n4 are consecutive orbits & n1 = 3]

(A) D (B) C (C) B (D) A
PAGE NO.-32
2. Which of the following sample of reducing agents is/are chemically equivalent to 25ml of 0.2 N KMnO 4
to be reduced to Mn2+ and H2O?
(A) 25 mL of 0.2M FeSO4 to be oxidized to Fe3+
(B) 50 mL of 0.1M H3AsO3 to be oxidized to H3AsO4
(C) 25 mL of 0.1 M SnCl2 to be oxidized to Sn4+
(D) 25 mL of 0.2M H2O2 to be oxidized to H+ and O2
3. Which of the following statement(s) is (are) correct ?
(A) The coordination number of each type of ion in CsCl is 8
(B) A metal that crystallizes in bcc structure has a coordination number of 12
(C) A unit cell of an ionic crystal shares some of its ions with other unit cells
(D) The length of the unit cell in NaCl is 552 pm. ( rNa = 95pm; rCl = 181 pm)
4. A mixture of two inorganic salts give following chemical reactivity.

(i) Mixture on reaction with dilute H2SO4 and zinc dust produces a colourless and unpleasant gas which
turns acidified lead acetate solution black.
(ii) Mixture on reaction with concentrated. H2SO4 gives reddish brown gas which does not produce
orange red spots on starch paper.
(iii) The mixture gives white precipitate with barium chloride solution which is soluble in dilute HCl.
(iv) The sodium carbonate extract of mixture responds to brown rings test.
The mixture contains :
(A) SO32– and NO3– anions (B) S2– and NO3– anions
2– –
(C) SO3 and NO2 anions (D) SO32– and Br– anions
5. KBr + MnO2 + H2SO4 (conc.)  KHSO4 + MnSO4 + H2O + [X] (unbalanced equation)
(A) X turns starch paper orange red
(B) X with AgNO3 solution gives a pale yellow ppt which is completely soluble in dilute ammonium
hydroxide.
(C) X produces violet colour in organic layer in KI solution
(D) X is liberated when a mixture of KBr, K2Cr2O7 and conc. H2SO4 is heated
6. Which of the following is/are correct statement(s) ?
‫׳‬
(A) In general interhalogen compounds (XX ) are more reactive than its elemental form.
(B) BrF5 hydrolyses to give HF and HBrO3
(C) Chlorine can reduce ferric ion into ferrous ion.
(D) When ammonia reacts with excess of chlorine, an unstable compound is formed
Comprehension #
Disproportionation reactions :
Disproportionation reactions are a special type of redox reactions. In a disproportionation reaction an
element in one oxidation state is simultaneously oxidised and reduced. One of the reacting substances
in a disproportionation reaction always contains an element that can exist in at least three oxidation
states. The element in the form of reacting substance is in the intermediate oxidation state; and both
higher and lower oxidation states of that element are formed in the reaction.
7. Which of the following disproportionate(s) on heating with sodium hydroxide ?
(A) P4 (B) S8 (C) F2 (D) NO2
8. Select the correct statement(s) :
(A) Cl2 disproportionate in basic as well as in neutral medium.
(B) K2MnO4 disproportionate in acidic as well as in neutral medium.
(C) I2 disproportionate in acidic medium.
(D) NaNO2 disproportionate in acidic medium.
9. How many of the following molecules are polar?
(i) CO2 (ii) SO2 (iii) NO2 (iv) SOCl2 (v) COCl2 (vi) BeCl2(g)
(vii) TeCl4 (viii) CCl4 (ix) ClO2
10. Hybridisation state of Xe and number of lone pair of electron in Xe in
XeO3, XeO2F2, XeF2 are spxda, spydb, spzdc, p, q and r respectively, the sum of a + b + c + p + q + r is :
PAGE NO.-33
11. NH3 can be nearly entirely liberated on boiling which of the following aqueous solutions with NH4Cl?
NaNO2, HNO3, HCl, Ca(OH)2, NaOH, CaC2, NaCl
12. The compressibilty factor of N2 at 330K & 800 atm is 1.90 and at 570K & 200 atm is 1.10. A certain
mass of N2 occupies a volume of 1dm 3 at 330K and 800 atm. Calculate the volume of N2 gas at 570K
and 200 atm.
13. Consider the equilibrium Ni(s) + 4CO(g) Ni(CO)4(g) ; Kp = 0.125 atm–3.
If equal number of moles of CO and Ni(CO) 4 (ideal gases) are mixed in a small container fitted with a
piston, if the maximum total pressure is P (in cm of Hg) to which this mixture must be brought in order
to just precipitate out metallic Ni then report your answer as P/4.
14. A vanadium electrode is oxidized electrically, if the magnetic moment (spin only) of the vanadium
product is 1.73 B.M. and the mass of electrode decreases by 102 mg during the process, then what will
be the amount of current in ampere if it flowed for 8 seconds? (Assume current efficiency 100%, At. wt.
of V = 51)
15. Reactions are listed in column-I. Match the result of the respective reactions with the appropriate
options listed in column-II.
Column-I Column-II
(A) P4 + SOCl2   (p) Prepperation of diamer of halide
(B) KI + H2O + O3   (q) Preperation of dioxygen
Preperation of cyclic compound at room
(C) SO2 + O2  VO2 
5/heat (r)
temperature
(D) H3PO3 + Br2  
heat in asealedtube
 (s) Preperation of acidic oxide
(t) Zero oxidation state od minimum two products

1. In the metallurgy of iron, the upper layer obtained in the bottom of blast furnace mainly contains
(A) CaSiO3 (B) FeSiO3 (C) Fe3C (D) Pig iron
2. Chlorine gas is obtained by various reactions but not by–


(A) KMnO4 + Conc HCl (B) KCl + F2 

 

(C) KCl + K2Cr2O7 + Conc. H2SO4 (D) MnO2 + Conc HCl
3. Which will give maximum [H+] ion concentration by dissolving equal moles in water
(A) LiOH (B) NaOH (C) KOH (D) RbOH
4. A chloride dissolves appreciably in cold water. When placed on a platinum wire in Bunsen flame, no
distinctive colour is noticed. The cation is :
(A) Ca2+ (B) Mg2+ (C) Ba2+ (D) Pb2+
5. Which of the following will not be dissolved in aqueous NaOH solution ?
(A) Al(OH)3 (B) Zn(OH)2 (C) Mg(OH)2 (D) Be(OH)2
6. Which of the following property is not similar in the pair of complex [Fe(CN) 6]3– and [Co(NH3)6]+3
(A) Magnetic moment (B) Geometry (C) Hybridization (D) All of these
7. A complex organic compound contains 21 atoms of carbon per molecule. The percentage of carbon in
the compound is 70%. If 36 gram of the substance is dissolved in 100 mL of water then the molarity of
the solution will be-
(A) 1 (B) 0.1 (C) 1.43 (D) 0.143
PAGE NO.-34
8. Standard molar enthalpy of formation of CO2 is equal to -
(A) zero
(B) the standard molar enthalpy of combustion of gaseous carbon
(C) the sum of standard molar enthalpies of CO & O2
(D) the standard molar enthalpy of combustion of C(s)
9. A 0.1 M sodium acetate solution was prepared. The Kh = 5.6 × 10–10. The correct statement is
(A) Degree a hydrolysis is 7.48 × 10–4 (B) [OH–] = 7.48 × 10–5
(C) [OH–] = 7.48 × 10–6 M (D) pH is approximately 7
10. For the reaction 2H(g) H2(g) + I2(g), the degree of dissociation () of HI(g) is related to
equilibrium constant kp by expression-
1 2 kp 1 2kp 2kp 2 kp
(A) (B) (C) (D)
2 2 1 2kp 1 2 kp
11. Which one is incorrect statement among the following?
(A) PH5, SCl6 and FCl3 do not exist. (B) p-d bond is present in SO2 molecule.
(C) 12 P–O bonds are present in P4O6 molecule. (D) Bond angle in SiH4 less than that in CH4.
12. For a reaction Fe0.9O  Fe2O3. What is the equivalent weight of Fe0.9O [molar mass = M]
(A)
M (B)
M (C)
M (D)
M
0.8 0.7 0.9 0.8 5
13. Which statement is incorrect about the following graph :
(A) It is an exothermic reaction (B) Number of reaction intermediate = 3

(C) Number of transition state = 4 (D) None of these
14. A 5.0 cm3 solution of H2O2 liberates 0.508 g of l2 from an acidified Kl solution. The strength of H2O2
solution in terms of volume strength at STP is :
(A) 2.24 V (B) 1.12 V (C) 4.48 V (D) 8.96 V
15. Minimum amount of Ag2CO3(s) required to produce sufficient oxygen for the complete combustion of
C2H2 which produces 11.2 ltr of CO2 at S.T.P after combustion is: [Ag = 108]
Ag2CO3(s)  2Ag (s) + CO2 (g) + 1/2O2 (g)
C2H2 + 5/2O2  2CO2 + H2O
(A) 276 g (B) 345 g (C) 690 g (D) 1380 g
16. Calcium imide on hydrolysis gives gas (B) which on oxidation by bleaching powder gives gas (C). Gas
(C) on reaction with magnesium give compound (D) which on hydrolysis gives again gas B. Identify (B),
(C) and (D).
(A) NH3, N2 and Mg3N2 (B) N2, NH3, MgNH
(C) N2, N2O5, Mg(NO3)2 (D) NH3, NO2,Mg(NO2)2
17. Consider the plane shown in the figure. A rock salt (NaCl) lattice is cut across
this plane in which anions occupy fcc positions. It passes through centers of how
many cations?
(A) zero (B) 4 (C) 6 (D) 12
18. NH4ClO4 + HNO3(dilute)  HClO4 + [X]


[X]  Y(g)
[X] and [Y] are respectively.
(A) NH4NO3 and N2O (B) NH4NO2 and N2 (C) HNO4 and O2 (D) None
PAGE NO.-35
19. Cl2O6 reacts with sodium hydroxide solution to yield :
(A) NaClO3 and NaClO4 (B) NaCl and Cl2
(C) NaOCl and NaClO3 (D) NaClO2
20. Mark the wrong statement. Halogens are all coloured -
(A) This is due to absorption of visible light by their molecules resulting in the excitation of outer
electrons to higher energy levels
(B) The small F2 molecules absorb high energy violet radiation and appear yellow
(C) Large I2 molecule absorb low energy yellow and green radiations and appear violet in colour
(D) The excitation energy required by the small fluorine atoms is smaller than required by the large
iodine atoms.
21. When 100 ml of a O2 – O3 mixture was passed through turpentine, there was reduction of volume by 20
ml. If 50 ml of such a mixture is heated, what will be the increase in volume ?
22. For a saturated solution of AgCl at 25°C,  = 3.4 × 10–6 ohm–1 cm–1 and that of H2O () used is
2.02 × 10–6 ohm–1 cm–1. m for AgCl is 138 ohm –1 cm2 mol–1 then the solubility of AgCl in moles per liter
will be X × 10–5. Find out X :
23. How many of the following metals will displace Hydrogen (H2) from HCl ?
Zn, Hg, Fe, Ag, Mg, Au, Cu, Li, Cs.
24. When  particles were bombarded on 9Be nucleus,
4 a new particle was discovered. If the reaction is .
94 Be 12
6 C X
Find charge on X.
25. Salt AB undergoes anionic hydrolysis and its 0.1 M solution has pOH as 5. Determine pH of 0.1 M
HB.

Comprehension : 2 Questions ('–1' negative marking) Q.7 to Q.8 (3 marks, 2 min.) [06, 04]
1. An ideal gas undergoes a process in which T = T 0 + aV3, where T0 and ‘a’ are positive constants and V
is molar volume. The molar volume for which pressure will be minimum is
 T0 1/3  T0 1/3  a 2/3
(A)
 2a
(B)
 3a
(C)  3T0  (D) None of these
2. Consider the following first order decomposition and the accompanying concentration – time plot:
A4(g) 4 A(g)
[A]
Conc.
[A4]
30 hrs Time
Which of the following statements regarding the decomposition reaction is/are true ?
(A) At 30 hrs, only 20 %reaction is complete.
(B) Half –life of the reaction is 90 hrs (approximately).
(C) Rate of decomposition decreasing linearly with time.
(D) Changing initial concentration will change the time at which the two curves are intersecting.
3. Which of the reaction defines molar Hf°?

(A) H+(aq) + OH–(aq) H2O() (B) 1/2 Br2() + 1/2 H2(g) HBr(g)
(C) N2(g) + 2H2(g) +
3 O (g) NH NO (s) (D) H2(g) + Smonoclinic + 2O2(g) H2SO4()
2 4 3
2
PAGE NO.-36
4. To a 25 mL H2O2 solution excess acidified solution of KI was added. The iodine liberated rquired 20 mL
of 0.3 N sodium thiosulphate solution. Use these data to choose the correct statements from the
following :
(A) The weight of H2O2 present in 25 ml solution is 0.102 g.
(B) The molarity of H2O2 solution is 0.12 M.
(C) The weight of H2O2 present in 1 L of the solution is 0.816 g.
(D) The volume strength of H2O2 is 1.344.
5. Identify incorrect statement/statements :
(A) In adiabatic free expansion, heat involved is zero and therefore entropy change Ssys. will be zero
(B) The heat absorbed during isothermal expansion of an ideal gas against vaccum is zero
(C) For irreversible cyclic process Ssurr. = 0
(D) Intensive properties are additive properties
6. SOCl2 + HOH  [X] + [Y]
Which of the following is/are incorrect statement(s) ?
(A) Anhydride of one of the product is a gas having sp3d hybridization.
(B) Both the products are strong acids.
(C) One of the product has one p–d bond.
(D) One of the product when react with NH3 gives white fumes.
Comprehension #
A definite volume of H2O2 undergoing decomposition required 22.8 mL of standard KMnO 4 solution for
titration. After 10 and 20 min, the volumes of permanganate required were 13.8 and 8.25 mL,
respectively.
7. Find order of reaction.
(A) 1 (B) 2 (C) 3 (D) 3/2
8. Calculate the time (in. min) required for the decomposition to be half completed.
(A) 1.8 (B) 7.6 (C) 13.7 (D) 20.4
9. For the reaction A  products, the following data is given for a particular run.
time (min.) : 0 5 15 35
1 (M–1) : 1 2 4 8
[A]
Determine the order of the reaction.
10. 10 mL of a H2SO4 solution is diluted to 100 mL. 25 mL of this diluted solution is mixed with 50 mL of
0.5 N NaOH solution. The resulting solution requires 0.265 gm Na 2CO3 for complete neutralization. The
normality of original H2SO4 solution is :
11. 1.575 g of (COOH)2.XH2O are dissolved in water and the volume is made up 250 mL. On titration 16.68
ml of this solution are required for the neutralisation of 25 mL of
N NaOH calculate the value of X :
15
12. How many of the following metallurgies involve leaching?
Al2O3 Al; Ag2S Ag; Au  Au; CuFeS2 Cu; PbS Pb
MgCl2 Mg; FeCO3 Fe; Low grade copper ore  Cu; HgS Hg
13. How many of the following dissolve in conc. NaOH?
SnO2, Pb3O4, Al2O3, dolomite, CuFeS2, Ag2S, siderite, gold nuggets.
14. Electrolysis of a solution of HSO4 ions produces S2O82–. Assuming 80 % current efficiency, what
current in ampere should be employed to achieve a production rate of 1 mole of S 2O82– per hour ?
15. Match the following
Column A Column B
(Reagent) (Acid radical)
(A) Neutral ferric chloride (p) NO3 –
(B) Ferrous sulphate (freshly prepared) (q) S2–
(C) Lead acetate (r) CH3COO–
(D) Sodium nitroprusside (s) SO42–
PAGE NO.-37

1. Match list-I with list-II and select the correct answer :
List -I (Molecule/ion) List-II (Bond angles)
(I) N O  (1) 180º
2
(II) NO2 (2) 134º
(III) N O  (3) 120º
2
(IV) N O3 (4) 115º
(5) 109º
Code :
I II III IV I II III IV
(A) 5 4 3 2 (B) 5 2 4 3
(C) 1 2 4 3 (D) 1 4 3 2
2. For the reaction 2HI(g) H2(g) + I2(g). The degree of dissociation () of Hl(g) is related to
equilibrium constant KP by the expression :
1 2 KP 1 2KP 2KP 2 KP
(A) (B) (C) (D)
2 2 12KP 12 KP
3. In the quantitative determination of nitrogen, N2 gas liberated from 0.42 g of a sample of organic
compound was collected over water. If the volume of N2 gas collected is
100ml at total pressure 860
11
mm of Hg, 250 K, then % by mass of nitrogen in the organic compound is :
[Aqueous tension at 250 K is 24 mm of Hg and R = 0.08 L-atm mol-1K–1]
(A)
1 0% (B)
5% (C)
2 0% (D)
1 0 0%
3 3 3 3
4. If equilibrium constant of CH3COOH + H2O CH3COO– + H3O+ is 1.8×10–5, equilibrium constant
for CH3COOH + OH– CH3COO– + H2O is :
(A) 1.8 × 10–9 (B) 1.8 × 109 (C) 5.55 × 10–9 (D) 5.55 × 1010
5. When excess chlorine reacts with a gas X, and explosive inorganic compound Y is formed. Then X and
Y are :
(A) X = O2 and Y = NCl3 (B) X = NH3 and Y = NCl3
(C) X = O2 and Y = NH4Cl (D) X = NH3 and Y = NH4Cl
6. One mole of an ideal monoatomic gas expanded irreversibly in two stage expansion :
State–1 (8.0 bar, 4.0 litre, 300 K)
State–2 (2.0 bar, 16.0 litre, 300 K)
State–3 (1.0 bar, 32.0 litre, 300 K)
Total heat absorbed by the gas in the process is:
(A) 116 J (B) 40 J (C) 4000 J (D) None of these
7. When heated above 918°C, iron changes its crystal structure from bcc to ccp structure without any
change in the radius of atom. The ratio of density of the crystal before heating to its density after
heating is:
(A) 1.890 (B) 0.918 (C) 0.725 (D) 1.231
8. The vapour pressure of a solution of a non-volatile, non-electrolyte solute B in a solvent A is 95% of the
vapour pressure of the solvent at the same temperature. If the molecular weight of the solvent is 0.3
times the molecular weight of solute, the weight ratio of the solvent and solute are :
(A) 0.15 (B) 5.7 (C) 0.2 (D) 4.0
PAGE NO.-38
9. Figure graphically illustrates plots of the kinetic energies of the electrons photoelectrically ejected from
cesium, Cs and tungsten, W, versus the frequency , of the incident light. Which one of the following
statement is incorrect?
Kinetic energy (KE) of

ejected electrons
Cs
W
Frequency ( ) of
incident light
(A) The threshold frequency for tungsten (0)W is higher than that for cesium (0)Cs
(B) The threshold wavelength for cesium (0)Cs is shorter than that for tungsten (0)W
(C) It takes less energy to eject an electron photoelectrically from cesium than from tungsten.
(D) As the frequency of incident light increases, maximum kinetic energy of the ejected electrons also
increases
10. For a given reaction A  Product, rate is 1 × 10–4 Ms–1 when [A] = 0.01 M and rate is 1.41 × 10–4 M s–1
when [A] = 0.02 M. Hence, rate law is :
(A)  d[A] = k [A]2 (B)  d[A] = k[A] (C)  d[A]  k [A] (D)  d[A] = k[A]1/2
dt dt dt 4 dt
11. Three moles of electrons are passed through three solutions in succession containing AgNO 3, CuSO4,
and AuCl3, respectively. The molar ratio of amounts of cations reduced at cathode will be respectively:
(A) 1 : 2 : 3 (B) 2 : 1 : 3 (C) 3 : 2 : 1 (D) 6 : 3 : 2
12. Electron gain enthalpy (magnitude wise) of first element in the following pairs is higher?
(A) F, Cl (B) Se, O (C) O, F (D) S, Cl
13. Sodium carbonate is manufactured by Solvay process. The products that are recycled in this process
are :
(A) CO2 and NH3 (B) CO2 and NH4Cl (C) NaCl, CaO (D) CaCl2, CaO
14. Which of the following complexes is paramagnetic?
(A) [Mn(CN)6]3– (B) [Ni(CO)4] (C) [Fe(CN)6]4– (D) [Co(CN)6]3–
15. Two glass bulb A and B are connected by a very small tube of negligible volume having stopcock. Bulb
A has a volume of 100 cm3 and contains a certain amount of gas while bulb B is empty initially, with
stopcock closed. On opening the stopcock for considerable time period, the pressure in A fell down by
60%. The volume of bulb B is (assume temperature to remain constant) :
 (A) 200 mL (B) 150 mL (C) 250 mL  (D) 100 mL
16. Which of the following statements are correct?
(I) B2O3 is an anhydride of boric acid
(II) B2O3 on heating with metal oxide can form salt called metaborate
(III) Orthoboric acid is weak monobasic protonic acid
(IV) Orthoboric acid is more soluble in hot water
(A) I, II, III, IV (B) I, II (C) I, II, IV (D) II, IV
17. The spin only magnetic moment of following, arranged in increasing order will be :
(I) Co3+ (octahedral complex with CN– ligand)
(II) Co3+ (octahedral complex with F– ligand)
(III) Co2+ (tetrahedral complex)
(IV) Co2+ (square planar complex)
(A) I > II > III > IV (B) II > III > IV > I (C) III > II > IV > I (D) II > IV > III > I
PAGE NO.-39
18. For a certain reaction involving a single reactant, it is found that Co T is constant, where Co is the
initial concentration of the reactant and T is the half-life. What is the order of the reaction?
(A) 1 (B) 1.5 (C) 2 (D) 3
19. Calculate acid dissociation constant for 0.1 M HCOOH if its solution shows a resistance of 50  when
filled in a cell having separation between parallel electrodes 4 cm and cross section area of electrode
10 cm2.
Given, m 
[Ca (HCOO )2] = 230 Scm2 mol–1
m

[CaCl 2] 280 Scm2 mol–1
m [H C]=l 425 Scm2 mol–1
(A) 5 × 10–5 M (B) 4 × 10–2 M (C) 4 × 10–4 M (4) 5 × 10–3 M
20. On hydrolysis of P4O6 with hot water following are obtained:
(A) H3PO3 and PH3 (B) H3PO4 and H3PO3 (C) H3PO4 and PH3 (D) H4P2O7 and H2
21. Identify the reaction order from the following rate constant :
k = 2.3 × 10–5 L mol–1 s–1.
22. Atomic Number of the stable nuclide obtained after radioactive decay of 1 2B is_____.
5
23. Time required to deposite one millimole of aluminium metal by the passage of 9.65 ampere through
aqueous solution of aluminium ion is (in sec)
24. If the density of a gas sample is 4 g/L at pressure 1.2  105 Pa. Find out the value of vRMS (in m/s)
25. The filter paper dipped in acidified K2Cr2O7 turns green when SO2 is passed through it. What is
oxidation number of Cr in this green product?

1. Which of the following pair(s) of metals is/are correctly matched with their purification methods?
(A) Si, B – Zone refining (B) Ni, Zr – Vapour phase refining
(C) Zn, Hg – Distillation (D) Cu, Ag – Electrolytic refining
2. Which of the following are part of the blood buffer?
(A) HCO3– (B) CO32– (C) H2CO3 (D) CH3COO–
3. Names of which of the following end in-ous acid?
(A) HNO2 (B) H2CO3 (C) H2SO3 (D) HBO2
4. Correct order of boiling point is/are :
(A) CH3 – O – CH3 < CH3 – CH2 – OH (B) O2 < Cl2 < Br2 < IBr
(C) HCl < HBr < HF > HI (D) SbH3 > NH3 > PH3 > AsH3
5. For the given reaction, A(g)  2B (g); rH = 30 kJ/mole, rS = 150 J/mol at 300 K.
If CP, A = 20 J/Kmol and CP, B = 20 J/Kmol. (n 3/2 = 0.4)
Which of the following statement is/are correct?
(A) H will increase on increasing temperature (B) H will decrease on increasing temperature
(C) At 300 K, G is negative (D) At T = 200 K, G is zero
PAGE NO.-40
Comprehension #
In the following graph are presented potential energy curves of H 2 molecule and its cation H2 . Using
the informations provided on this graph answer the following questions.
–600
–800
–1000
–1200 H+2 H+H+
–1300
–1400
–1600
–1800
Energy in kJ/mol –2000
–2200
–2400
H+H
–2600
–2700 H2
–2800
–3000
–3200
–3300
0.0 0.25 0.5 0.75 1.0 1.25 1.5 2.0 2.5 3.0 3.5
rH–H(Å)
6. What is the bond length and bond order of H2 and H2 ?

(A) Species : H2 H2 (B) Species : H2 H2
Bond length : 0.75 Å 1.25 Å Bond length : 0.75 Å 1Å
Bond order : 1 3/4 Bond order : 1 1/2
(C) Species : H2 H2 (D) Species : H2 H2
Bond length : 0.75 Å 1.5 Å Bond length : 0.75 Å 1.25 Å
Bond order : 1 2 Bond order : 1 1/2
7. What is the ionisation energy of H atom ?
(A) 200 kJ/mol (B) 1300 kJ/mol (C) 1500 kJ/mol (D) 1400 kJ/mol
8. How many of the following ores are oxide ores?
haematite, limonite, magnetite, magnesite, cuprite, argentite, bauxite, sphalerite, zincite
9. How many of the following compounds liberate NH3 on heating ?
(NH4)2SO4 ; NH4HCO3 ; NH4Cl; NH4NO3 ; (NH4)2 Cr2O7; FeSO4· (NH4)2SO4· 6H2O;
(NH4)2SO4· Al2(SO4)3 · 6H2O; Mg(NH4)PO4 ; NH4ClO4
10. One mole each of benzene (PB0 = 600 torr), toluene (PT0 = 400 torr) and mercury (Pm0 = 100 torr) are
mixed in a well-stirred container and allowed to reach equilibrium with their vapors.The vapors are
formed in very little amount. Vapor pressure of this mixture is 100 x (torr). Find x.
11. Let Z be the compressibility factor for a real gas at critical conditions and Vander Waal constant be is
RTC , then find the product (Z × m).
mPC
dipendent as b =
12. A reaction between substances A and B is represented stochiometrically by A + B  C. Observations

on the rate of this reaction are obtained in three separate experiments as follows: {(CHK-CORL(P)-M)}
S.N. Initial Initial Duration of Final
concentration concentration Experiment Concentration
[A]0, M [B]0, M (in hrs) [A]f, M
(1) 0.1000 1.0 0.50 0.0975
(2) 0.1000 2.0 0.50 0.0900
(3) 0.0500 1.0 2.00 0.0450
The value of the rate constant is P × 10–2 M–2hr–1. Value of P is -
PAGE NO.-41
13. 10% sites of a catalyst bed have adsorbed H2. On heating H2 gas is evolved from sites and collected at
0.03 atm and 300 K in a small vessel of 2.46 cm 3. Number of sites available is 5.4 × 1017 per cm2 and
surface area is 1000 cm 2. Find out the number of surface sites occupied per molecule of H 2 (R = 0.082
atm L/ mol K, NA = 6 × 1023)
–4 –1
 
14. Conductivity of an aqueous solution of 0.1 M HX (a weak mono-protic acid) is 5 × 10 Sm .
Given :  
m H = 0.04 Sm mol ;
2 –1 m X = 0.01 Sm2mol–1
Find pKa[HX] .
15. Match the following (one or more than one).

(Reagent) (Anion)
(A) Silver nitrate solution (p) CO32–
(B) Barium chloride solution (q) SO32–
(C) Lead nitrate solution (r) S2–
(D) Acidified potassium permangnate solution (s) NO2–

1. In Freundlich Adsorption isotherm, the value of 1/n is :
(A) between 0 and 1 in all cases (B) between 2 and 4 in all cases
(C) 1 in case of physical adsorption (D) 1 in case of chemisorption
p
2. The variation of
 m
x
as a function of p, when Langmuir’s adsorption isotherm is valid is :
(A) (B) (C) (D)
3. Consider the plots for the types of reaction nA  B + C
–
d [A] [A]
1
dt [A]
These plots respectively correspond to the reaction orders :

(A) 0, 2, 1 (B) 0, 1, 2 (C) 1, 1, 2 (D) 1, 0, 2
4. PtCl4.6H2O can exist as a hydrated complex. 1 molal aq. solution has depression in freezing point of
3.72ºC. Assume 100% ionisation and Kf (H2O) = 1.86ºC mol–1Kg, then complex is:
(A) [Pt(H2O)6]Cl4 (B) [Pt (H2O)4Cl2]Cl2 . 2H2O
(C) [Pt(H2O)3Cl3]Cl. 3H2O (D) [Pt(H2O)2Cl4].4H2O
5. The number of P–O–P bonds in tricyclic metaphosphoric acid is :
(A) zero (B) two (C) three (D) four
6. Which the following molecules/species have identical bond order and same magnetic properties ?
(I) O2+ ; (II) NO ; (III) N2+
(A) (I), (II) only (B) (I) and I I I only (C) (I), (II) and (III) (D) (II) and (III) only
PAGE NO.-42
7. Give the correct order of initials T or F for following statements. Use T if statement is true and F if it is
false.
S1 : AgI is less soluble in water than AgF due to more polarisation of I- in comparison to F– ion.
S2 : LiI is less soluble in water than LiF due to more polarisation of I– in comparison to F– ion.
S3 : Melting point of BaCl2 is higher than the melting point of BeCl2 due to greater ionic nature of BaCl2.
S4 : Order of hydrated radii is : Al3+ (aq) > Mg2+ (aq) > Na+ (aq)
(A) T F T T (B) T T T T (C) T F F T (D) F F T T
8. Which of the following statement is not correct when a mixture of NaCl and K 2Cr2O7 is gently warmed
with concentrated H2SO4?
(A) A deep red vapour is evolved
(B) The vapour when passed into NaOH solution gives a yellow solution of Na2CrO4
(C) Chlorine gas is evolved
(D) Chromyl chloride is formed
9. The factor of G values is important in metallurgy. The G values for the following reactions at 800ºC
are given as :
S2(s) + 2O2(g)  2SO2(g) ; G = – 544 kJ
2Zn(s) + S2(s)  2ZnS(s) ; G = – 293 kJ
2Zn(s) + O2(g)  2ZnO(s) ; G = – 480 kJ
The G for the reaction 2ZnS(s) + 3O2(g)  2ZnO(s) + 2SO2(g) will be :
(A) – 357 kJ (B) – 731 kJ (C) – 773 kJ (D) – 229 kJ
10. A certain gas takes two times as long to effuse out as methane under identical conditions. The gas
could be:
(A) He (B) O2 (C) SO2 (D) None of these
11. The following equilibria are given :
N2 + 3H2 2NH3 K1
N2 + O 2 2NO K2
H2 +
1 O2 H2O K3
2
The equilibrium constant of the reaction: 2NH3 +
5 O2 2NO + 3H2O in terms of K1, K2 and K3 is:
2
(A)
K1 K2
(B)
K1 K2 K K3
(C) 2 3 (D) K1 K2 K3
K3 K3 K1
12. What is the activation energy for a reaction if its rate doubles when the temperature is raised from 20ºC
to 35ºC ? (R = 8.314 J mol–1 K–1)
(A) 269 kJ mol–1 (B) 34.6 kJ mol–1 (C) 15.1 kJ mol–1 (D) 342 kJ mol–1
13. Sodium metal shows bcc structure. The distance between nearest sodium atoms is 0.368 nm. The
edge length of unit cell is :
(A) 0.425 nm (B) 0.575 nm (C) 0.368 nm (D) 0.184 nm
14. F-centres are
(A) the electrons trapped in anionic vacancies
(B) the electrons trapped in cation vacancies
(C) non-equivalent sites of stoichiometric compound
(D) all of the above
15. Negatively charged colloidal solution is obtained from AgNO 3 & KI, when moles of :
(A) AgNO3 are more (B) KI are more
(C) both AgNO3 and K I are more (D) can't say
16. Which of the following is incorrect order ?
(A) F2 > Cl2 > Br2 > 2 (oxidising power) (B) F2 < Cl2 < Br2 < 2 (bond length)
(C) F2 > Cl2 > Br2 > 2 (bond energy) (D) F2 < Cl2 < Br2 < 2 (boiling point)
PAGE NO.-43
17. An ideal gas is taken around the cycle ABCA as shown in P-V diagram. The value of q for the cycle is
equal to :
(A) 7 P1V1 (B) –5 P1V1 (C) 5 P1V1 (D) None of these
18. The following structures represent various silicate anions. Their formulas are respectively
O
O = Oxygen
= Silicon
O O
(A) SiO4 4– & Si3O88– (B) SiO44– & Si3O108– (C) SiO42– & Si3O92– (D) SiO34– & Si3O108–
19. Consider the following chemical reaction and the corresponding kinetic data showing the initial reaction
rate as a function of the initial concentrations of the reactants :
H3AsO4(aq) + 2H3O+(aq) + 3I-(aq)  HAsO2(aq) + I3-(aq) + 4H2O(liq)
Initial Rate  10-5 (M/sec) [H3AsO4] [H3O+] [I-]
3.7 0.001 0.01 0.10
7.4 0.001 0.01 0.20
7.4 0.002 0.01 0.10
3.7 0.002 0.005 0.20
Using the data, establish the correct reaction composite order.
20. Find the value of E0ClO3– / ClO2–

given that : E0ClO3– / ClO– = + 0.50 V
E0ClO2– / ClO– = + 0.66 V
(Report your answer by multiplying 100)
21. The acid ionisation constant for

Zn2+ (aq) + H2O Zn(OH)+ (aq) + H+ (aq) kh = 10–9
Determine the pH of 10–3(M) aqueous solution of ZnCl2.
22. 1 L of 0.6 M acetic acid is shaken with 2 g activated carbon. Activated carbon absorbs some acetic acid
on its surface only. This process is called adsorption. The final concentration of the solution after
adsorption is 0.5 M. What is the amount of acetic acid adsorbed per gram of carbon.
23. Consider the following chemical reactions:

 (P) Major product
Na + O2(Excess)  
 (Q) Major product
K + O2(Excess) 
Determine the value of expression 5(x + 2y) (where x and y are the bond order of oxygen-oxygen
linkage in compound (P) and (Q) respectively).
PAGE NO.-44
ChemINFO SURFACE CHEMISTRY

Daily Self-Study Dosage for mastering Chemistry Iso, Neo, Secondary and Tertiary Alkyl Group
The methods for preparation of colloids depend on the nature of colloidal particles constituting the dispersed
phase. Some colloids, such as lyophilic colloids can be formed by dissolving the colloidal particles in
dispersion medium. For example, sols of gum, starch, gelatin, may be prepared in this manner.
However, substances that do not disperse easily in dispersion medium need special methods for
formation of their colloidal solutions. Some important methods are discussed as follows.
1. Chemical methods: In this method, the colloidal molecules or aggregates are formed by means of
chemical reactions such as decomposition, hydrolysis, oxidation or reduction. Some examples of each
type are:
As2O3 + 3H2S As2S3 3H2O
Double
decomposit
ion
Yellow
sol
FeCl3 + 3H2O Fe(OH)3 + 3HCl
Hydrolysis
SO2 + 2H2S 

3S (sol) + 3H2O
Oxidation
2AuCl3 + 3SnCl2  3SnCl4 + 2Au

Reduction
2. Electrical disintegration or Bredig’s arc method:
This method is used for prepration of colloids of
metals such as gold, silver, copper, platinum,
etc. In this method, the metal that needs to be
dispersed is made into two electrodes and
dipped in the dispersion medium. An electric
arc is struck between the electrodes and the
heat generated by the arc vaporizes the metal.
These vapors condencse when they come in
contact with dispersion medium cooled in an
ice-bath and form colloidal particles that get
dispersed to form a sol (Fig).
3. Peptization: This is a process where in a freshly generated precipitate is converted into a colloidal sol
by shaking it in a dispersion medium in the presence of an electrolyte which is called the peptizing
agent. For example, a dark red colored sol of Fe(OH) 3 is obtained when freshly prepared precipitate is
treated with small amount of FeCl3 solution. The precipitate adsorbs the Fe3+ ions from the electrolyte
on its surface and develops positive and negative charges. This causes the precipitate to disintegrate
into particles of colloidal size. In certain cases, the dispersion medium may act as peptizing agent
causing the precipitate to disperse in it. For example, ethanol used as dispersion medium causes
dispersion of cellulose nitrate.
24. Bredig arc method can not be used to prepare colloidal solution of which of the following ?
(A) Pt (B) Fe (C) Ag (D) Au
25. On adding a few drops of dil HCl to freshly precipitated ferric hydroxide, a red colored colloidal solution
is obtained, this is an example of
(A) Protective action (B) dissolution (C) peptisation (D) dialysis

1. XeF4 on reaction with H2O produces :
(A) Xe, XeO3, O2 and HF (B) XeO3, HF and O2 only
(C) Xe, XeO3 and F2 (D) Xe, XeO3 and O2 only
PAGE NO.-45
2. Ammonia gas is prepared by :
(A) heating ammonium dichromate.
(B) hydrolysis of calcium cyanamide.
(C) heating ammonium chloride with slaked lime.
(D) alkaline hydrolysis of aluminium nitride.
3. Which of the following mixtures cannot be separated by passing H 2S through their solutions containing
dilute HCl ?
(A) Cu2+ and Sb3+ (B) Pb2+ and Cd2+ (C) Pb2+ and Al3+ (D) Zn2+ and Mn2+
4. 50 mL of an aqueous solution of H2O2 was added into excess of a solution of KI in dil. H 2SO4. The
liberated iodine required 20 mL of 0.1 M Na2S2O3 solution for complete reaction. The same amount of
H2O2 with exactly titrate with :
(A) 25 mL of 0.016M KMnO4 solution in acidic medium
(B) 20 mL of
M K2Cr2O7 solution in acidic medium.
30
(C) 100 mL of 0.008M KMnO4 solution in acidic medium.
(D) 10 mL of
M K2Cr2O7 solution in acidic medium.
30
5. For a certain reaction A  products, the t½ as a function of [A]0 is given as below :
[A]0 (M) : 0.1 0.025
t1/2 (min.) : 100 50
Which of the following is/are true ?
(A) The order is
1 (B) t½ would be 100 10min for [A]0 = 1 M
2
(C) The order is 1 (D) t½ would be 100 min for [A]0 = 1 M
6. Which of the following statement(s) is/are true for a colloidal solution of gold in water (Gold sol.) ?
(A) The path of light beam is visible when passed through gold sol
(B) It is positively charged sol
(C) The colloidal solution can be preserved for long time if small amount of starch is added to sol
(D) The colloidal solution can be destroyed by prolonged electrophoresis of solution
7. Mixing which of the following combinations does not produce a gaseous product?
(A) Solid ammonium nitrate and solid calcium hydroxide and shaking.
(B) Copper metal and 0.10 M hydrochloric acid.
(C) Hypo solution and 0.1 M hydrochloric acid.
(D) Zinc metal and alkaline solution of aluminium nitrate.
(E) None of these
Comprehension #
At 100° C a gaseous reaction A B + 2C is observed to be of first order. On starting with pure A, at
the end of 10 minutes the total pressure was found to be 250 mm of Hg. After a long time the total
pressure of the system was 450 mm of Hg. Consider the volume and temperature to be constant.
8. Calculate initial pressure of A.
(A) 50 mm Hg (B) 100 mm Hg (C) 150 mm Hg (D) 200 mm Hg
9. Calculate rate constant of the reaction given : [ln10 = 2.3, log 2 = 0.3, log 3 = 0.48]
(A) 0.0214 min–1 (B) 0.0414 min–1 (C) 0.414 min–1 (D) 0.325 min–1
10. Calculate half life period of the given reaction : [ln2 = 0.693]
0.693 0.693 0.693 0.693
(A) min (B) min (C) min (D) min
0.0214 0.0414 0.414 0.325
11. How many oxides are soluble in moderately concentrated aqueous solution of NaOH.
SO3 , Cl2O7 , N2O5 , CO
(1) (2) (3) (4)
K2O , Cr2O3 , BaO , GeO2
(5) (6) (7) (8)
PAGE NO.-46
12. The plot of log (V – V) versus t (where V is the volume of nitrogen 1.75
collected under constant temperature and pressure conditions) for the
decomposition of C6H5N2Cl is given at 50°C with an amount of log(V – V)
C6H5N2Cl equivalent to 58.3 cc N2. Calculate the rate constant for the
1.0
reaction in hr–1 expressing your answer in a single significant digit.
5 10 15 20 25 30
time(min.)
13. For the just coagulation of 250 ml of Fe(OH) 3 sol, 2 ml of 1M Na2SO4 electrolyte is required. What is the
coagulating value of Na2SO4 electrolyte.
14. Rate constant of the reaction 2H2O2 (aq.) 2H2O () + O2(g) is 3 × 10–3 minute–1. At what
concentration of H2O2, the rate of reaction will be 2 × 10–4 ms–1.
15. Match the following for a 1st order reaction A  products with time on the x axis.
Column-I Column-II
(A) [A] v/s time (p)
d [A] v/s [A]

(B) (q)
dt
d [A] v/s time

(C) (r)
dt
(D) log [A] v/s time (s)

1. In diborane, boron involves
(A) no hybridization (B) sp hybridization (C) sp2 hybridization (D) sp3 hybridization
2. In the formation of HBr from H2 & Br2, following mechanism is observed.
(a) Br2 2Br Equilibrium step
(b) H2 + Br  HBr + H Slow step
(c) H + Br2 HBr + Br Fast step
Calculate the rate of reaction, if concentration of hydrogen is twice that of bromine and the rate constant
is equal to 1 M–1/2 Sec–1. Concentration of bromine is 1 M.
(A) 2 M Sec–1 (B) 3 M Sec–1 (C) 4 M Sec–1 (D) 5 M Sec–1
3. The substances, P, Q and R have coagulation values 3, 0.6, 0.08 for a metal sol respectively. Their
flocculating powers are in the ratio :
(A) 0.0267 : 5 : 1 (B) 1 : 5 : 37.5 (C) 0.08 : 0.6 : 3 (D) 1 : 0.2 : 0.0267
4. Under the influence of an electric field, the particles in a sol migrate towards cathode. The coagulation
of the same sol is studied using NaCl, Na2SO4 and Na3PO4 solutions. Their coagulating values will be in
the order.
(A) NaCl > Na2 SO4 > Na3 PO4 (B) Na2 SO4 > Na3 PO4 > NaCl
(C) Na3 PO4 > Na2 SO4 > NaCl (D) Na2 SO4 > NaCl > Na3 PO4
PAGE NO.-47
5. Which of the following is a mismatch :
(A) Lyophilic colloids – reversible sols
(B) Associated collides – micelles
(C) Tyndall effect – scattering of light by colloidal particle
(D) Electrophoresis – movement of dispersion medium under the influence of electric field
6. 200 mL of an aqueous solution of a protein contains its 1.26 g. The Osmotic pressure of this solution at
300 K is found to be 2.57 × 10–3 bar. The molar mass of protein will be (R = 0.083 L bar mol–1 K–1) :
(A) 51022 g mol–1 (B) 122044 g mol–1 (C) 31011 g mol–1 (D) 61038 g mol–1
7. Which of the following statement is INCORRECT :
(A) In general, adsorption of a gas on a solid involves H < 0 and S < 0.
(B) Chemisorption is much more specific than physisorption.
(C) Among common protective colloids, gelatin has the least gold number and thus, maximum
protective power.
(D) If critical temperature (TC) of gas increases then extent of adsorption decreases.
8. For the gaseous equilibrium, A2 (g) + B2(g) 2AB(g), the equilibrium constant at a certain
temperature is 49. If an equimolar mixture of A2 and B2 is heated in a closed container to this
temperature, the mole fraction of B2 in the equilibrium mixture is
(A)
2 (B)
1 (C)
3 (D)
1
9 9 8 8
9. In a saturated solution of the sparingly soluble strong electrolyte AgIO 3 (Molecular mass = 283) the
equilibrium which sets in is
AgIO3(s) Ag+(aq) + O–3(aq)
If the solubility product constant Ksp of AgO3 at a given temperature is 1.0 × 10–8, what is the mass of
AgO3 contained in 100 ml of its saturated solution?
(A) 1.0 × 10–7 g (B) 1.0 × 10–4 g (C) 28.3 × 10–2 g (D) 2.83 × 10–3 g
10. For first order parallel reaction k 1 and k2 are 4 and 2 min–1 respectively at 300 K. If the activation
energies for the formation of B and C are respectively 30,000 and 38,314 joule/mol respectively. The
temperature at which B and C will be obtained in equimolar ratio is : (log2 = 0.30)
(A) 757.48 K (B) 378.31 K (C) 600 K (D) None of these

11. S1 : The frequency factor has the same unit as the rate constant, k
S2 : A plot n rate vs n C for the nth order reaction gives a straight line with slope –n and intercept kn
S3 : The order of a reaction A  product in which half the reagent is reacted in half an hour, three
quarters in one hour and seven - eighth in one and half hours must be 1(unity).
S4 : The unit of rate constant for a second order reaction will be M–1s–1.( M is representing the molarity
of solution)
(A) T F T T (B) T T T T (C) F F T T (D) T F F T
12. At 25ºC molar conductance of 0.1 molar aqueous solution of ammonium hydroxide is 9.54 ohm –1 cm2
mol–1 and at infinite dilution its molar conductance is 238 ohm –1 cm2 mol–1. The degree or ionisation of
ammonium hydroxide at the same concentration and temperature is :
(A) 20.800% (B) 4.008% (C) 40.800% (D) 2.080%
13. Which of the following expected to exhibit optical isomerism ? (en = ethylenediamine)
(A) cis-[Pt(NH3)2Cl2] (B) cis-[Co(en)2Cl2] (C) trans-[Co(en)2Cl2] (D) trans-[Pt(NH3)2Cl2]
14. 5 g of H2O2 solution, containing x % H2O2 by weight, requires x mL of KMnO 4 for complete oxidation in
acidic medium. What is the normality of KMnO4 solution :
 (A) 0.588 (B) 1.47  (C) 0.312 (D) 2.94
PAGE NO.-48
15. The combustion of 0.2 mol of liquid carbon disulphide CS2 to give CO2(g) and SO2(g) releases 215 kJ
of heat. What is Ho for CS2(l) in kJ mol–1 :
Ho kJ mol–1
CO2(g) –393.5
SO2(g) –296.8
(A) 772.1 (B) 87.9 (C) –385 (D) – 475
air/
16. PbS X, X + PbS  Pb + SO2 ; ‘X’ is :
Roasting
(A) PbO (B) PbO2 (C) PbO and PbSO4 (D) PbO2 and PbO
17. The solubility of [Co(NH3)4Cl2] ClO4 if the CO(NH ) Cl   50 , ClO  70 and the measured resistance
34 2 4
was 33.5  in a cell with cell constant of 0.20 is ________
(A) 59.7 mmol/L (B) 49.7 mmol/L (C) 39.7 mmol/L (D) 29.7 mmol/L
18. Lime stone 

(p)
 Quick lime H

2O
Which of the following option describes the correct reactants, products and reaction conditions?
(p) (q) (r) (s)
(A) Strongly heating Slaked lime Ca(O2)2 Cold water
(B) Strongly heating Slaked lime CaO2 Cold water
(C) Strongly heating in presence of catalyst Slaked lime CaO Cold water
(D) Strongly heating under high pressure Slaked lime CaO2 Cold water
19. The acid which gives phosphine on heating is

(A) H3PO4 (B) HPO3 (C) H4P2O7 (D) H3PO3
20. When CaC2 is heated in atmospheric nitrogen in an electric furnace the compound formed is :
(A) Ca(CN)2 (B) Ca3N2 (C) CaNC2 (D) CaNCN
21. What volume in mL of 0.2 M Ba(OH)2 must be added to 300 mL of a 0.08 M HCl solution to get a
solution in which the molarity of hydroxyl (OH–) ions is

4 M:
190
22. Consider the following complex [Co(NH3)5Cl]ClO4
Determine the product of co-ordination number and oxidation number(magnitude) of the metal.
23. A hypothetical reaction X2 + Y2  2XY follows the mechanism given below.

X2 X + X [Fast]
X + Y2  XY + Y [Slow]
X + Y  XY [Fast]
The order of overall reaction is
24. In F.C.C. arrangement of identical spheres, distance between two nearest octahedral void is 8.51Å. The
distance between two nearest tetrahedral voids would be (in Å) ?
25. The oxidation number of Cr in the product of the reaction of K2Cr2O7 with KOH is
PAGE NO.-49

1. ICl, when added to boiling NaOH, produces-
(A) NaI (B) I2 (C) NaCl (D) NaIO3
2. An inorganic lewis acid [X] gives gelatinous white precipitate with NH 4OH in presence of NH4Cl and its
aqueous solution in water gives white precipitate with AgNO 3 solution. [X] will respond to which of the
following characteristics ?
(A) X fumes in moist air.
(B) X on heating with solid K2Cr2O7 and conc. H2SO4 gives deep red fumes.
(C) X on addition of excess NaOH gives white precipitate.
(D) X on heating with Na2CO3 and cobalt nitrate gives a blue bead in oxidising flame.
3. Which of the following statement(s) is / are correct ?
(A) From a mixed precipitate of AgCl and AgI, dilute ammonia solution dissolves only AgCl
(B) Thiourea test is given by NO2– and not by SO32–
(C) On boiling a solution having K+, Ca2+ and HCO3– ions we get a precipitate of CaCO3
(D) Ag2SO3 is insoluble in dilute HNO3.
4. S1 : Silver iodide is fairly soluble in hypo solution.
 S2 : Heavy metal chlorides like AgCl, HgCl2 etc. also respond to Chromyl chloride test.
 S3 : Bromine reacts with K liberating violet vapours of iodine.
 S4 : Diphenylamine reagent test is also given by nitrites chlorates, bromates, iodates, etc. in addition to
NO3–
(A) T T T F (B) T F T T   (C) T T F F  (D) F F T T
5. Which of the following statement(s) is/are incorrect with reference to ammonium ion?
(A) Alkaline solution of ammonium salt on heating with sodium hydroxide liberates a gas which
produces dense white fumes with dilute HCl.
(B) It with potassium cobaltinitrite solution gives a yellow precipitate.
(C) It with alkaline K2Hg4 gives brown precipitate.
(D) It with chloroplatinic acid gives a red precipitate.
6. Which of the following statement(s) according to the Arrhenius equation is/are correct ?
(A) When the activation energy of the reaction is zero, the rate becomes independent of temperature
(B) The term Ea/RT represents the fraction of the molecules having energy in excess of the threshold
e
value
(C) Lower the magnitude of activation energy, stronger is the temperature dependence of the rate
constant
(D) The pre-exponential factor is a measure of the rate at which collisions occur, irrespective of their
energy
7. For a binary liquid solution obeying Raoult's law at 300 K,
Given : XA = 0.75, PA  = 400 mm of Hg ;  = 600 mm of Hg
PB
Then select correct statement(s) -
(A) Vapour pressure of solution will be 450 mm of Hg
(B) In distillate mole fraction of B will be 2/3
(C) If vapours are removed & condensed then it is redistilled, then mole fraction of A in second distillate
is 4/7
(D) Normal boiling point of liquid solution should be more than 300 K
PAGE NO.-50
Comprehension #
(A) + NaCl   (B)  (White ppt.)
(B) + KI  (C) (Green ppt)
(C)  + KI (D) (Colourless) + (E)
(C)  
Boiling with water
F + (E) 
8. Compound (A) and (B) are respectively :
(A) AgNO3 and AgCl (B) Pb(NO3)2 and PbCl2
(C) Hg2(NO3)2 and Hg2Cl2 (D) Cu2(NO3)2 and CuCl
9. Compound (E) is :
(A) Hg (B) Ag2O (C) HgCl2 (D) AgCl
10. When compound A reacts with Na2CrO4 solution, the colour of the compound formed is almost similar
to
(A) Hg (B) Hgl2 (C) PbCrO4 (D) BaCrO4
11. Cu2+ (aq) + CN– (aq)  complex
Aqueous solution of CN– is taken in excess.
What is the oxidation state of copper in the complex.
12. In how many of the following reactions, one of the products is obtained as a yellow precipitate ?
Ba2+ + CrO42– Product
Hg2+ + Co2+ + SCN– Product
NH4+ + [PtCl6]2– Product
Ag+ + CrO42– Product
NH4+ + [Co(NO2)6]3– Product
13. How many of the following pairs of ions can be separated by H2S in dilute HCl ?
Bi3+ and Sn4+, Al3+ and Hg2+, Cd2+ and Zn2+, Fe3+ and Cu2+, As3+ and Sb3+
14. A solution of Hg2+ ion on treatment with a solution of cobalt (II) thiocyanate gives rise to a deep blue
crystalline precipitate. The coordination number of mercury in the deep blue coloured compound is.
15. Match the following:
Column A Column B
(A) Na + Cl2 (water) + CCl4 - shake (p) yellow ppt
(B) CH3COO¯ + FeCl3 + H2O - boil (q) deep red colouration
(C) CoCl2 + KNO2 + CH3COOH - warm (r) purple colouration
(D) FeCl3 + NO2– + CH3COOH + CS(NH2)2 (s) red brown ppt
(t) green colouration
DPP No. # (REVISION DPP)

REVISION DPP FROM NCERT EXAMPLER (XII)
1. Which of the following is true about the value of refractive index of quartz glass?
(A) Same in all directions (B) Different in different directions
(C) Cannot be measured (D) Always zero
2. Which of the following solids is not an electrical conductor?
(a) Mg(s) (b) TiO(s) (c) I2(s) (d) H2O(s)
(A) (a) only (B) (b) Only (C) (c) and (d) (D) (b), (c) and (d)
3. Which of the following oxides behaves as conductor or insulator depending upon temperature?
(A) TiO (B) SiO2 (C) TiO3 (D) MgO
PAGE NO.-51
4. To get a n-type semiconductor from silicon, it should be doped with a substance with
valence__________.
(A) 2 (B) 1 (C) 3 (D) 5
5. Considering the formation, breaking and strength of hydrogen bond, predict which of the following
mixtures will show a positive deviation from Raoult’s law?
(A) Methanol and acetone. (B) Chloroform and acetone.
(C) Nitric acid and water. (D) Phenol and aniline.
6. In comparison to a 0.01 M solution of glucose, the depression in freezing point of a 0.01 M MgCl 2
solution is _____________.
(A) the same (B) about twice (C) about three times (D) about six times
7. Which of the following statements is false?

(A) Two different solutions of sucrose of same molality prepared in different solvents will have the same
depression in freezing point.
(B) The osmotic pressure of a solution is given by the equation =CRT (where C is the molarity of the
solution).
(C) Decreasing order of osmotic pressure for 0.01 M aqueous solutions of barium chloride, potassium
chloride, acetic acid and sucrose is BaCl2 > KCl > CH3COOH > sucrose.
(D) According to Raoult’s law, the vapour pressure exerted by a volatile component of a solution is
directly proportional to its mole fraction in the solution.
8. Consider the Figure and mark the INCORRECT option.

Piston (A) Piston (B)
SPM
Concentrated
Fresh water sodium chloride
(A) solution in water
(B)
(A) Water will move from side (A) to side (B) if a pressure lower than osmotic pressure is applied on
piston (B).
(B) Water will move from side (B) to side (A) if a pressure greater than osmotic pressure is applied on
piston (B).
(C) Water will move from side (B) to side (A) if a pressure equal to osmotic pressure is applied on
piston (B).
(D) Water will move from side (A) to side (B) if pressure equal to osmotic pressure is applied on piston
(A).
9. Which of the statements about solutions of electrolytes is not correct?

(A) Conductivity of solution depends upon size of ions.
(B) Conductivity depends upon viscosiy of solution.
(C) Conductivity does not depend upon solvation of ions present in solution.
(D) Conductivity of solution increases with temperature.
10. Using the data given below find out the strongest reducing agent.
ECr2O72/Cr3
 1.33 V ECl2/Cl
1.36 V

EM  1.51 V E  0.74 V
nO /Mn2
4 Cr3 /Cr
(A) Cl— (B) Cr (C) Cr3+ (D) Mn2+
PAGE NO.-52
11. Consider Figure and mark the correct option.
(A) Activation energy of forward reaction is E1 + E2 and product is less stable than reactant.
(B) Activation energy of forward reaction is E1 + E2 and product is more stable than reactant.
(C) Activation energy of both forward and backward reaction is E1 + E2 and reactant is more stable than
product.
(D) Activation energy of backward reaction is E1 and product is more stable than reactant.
12. According to Arrhenius equation rate constant k is equal to Ae –Ea/RT. Which of the following options
represents the graph of ln k v/s
1?
T
(A) (B) (C) (D)
13. Compounds ‘A’ and ‘B’ react according to the following chemical equation.
A(g) + 2B(g)  2C(g)
Concentration of either ‘A’ or ‘B’ were changed keeping the concentrations of one of the reactants
constant and rates were measured as a function of initial concentration. Following results were
obtained. Choose the correct option for the rate equations for this reaction.
Initial concentration Initial concentration Initial rate of formation
Experiment
of [A] / mol L–1 of [B] / mol L–1 of [C] / mol L–1 s–1
1. 0.30 0.30 0.10
2. 0.30 0.60 0.40
3. 0.60 0.30 0.20
(A) Rate = k[A]2 [B] (B) Rate = k[A] [B]2 (C) Rate = k[A] [B] (D) Rate = k[A]2 [B]0
14. Consider the reaction A B. The concentration of both the reactants and the products varies
exponentially with time. Which of the following figures correctly describes the change in concentration
of reactants and products with time?
(A) (B) (C) (D)
15. Arrange the following diagrams in correct sequence of steps involved in the mechanism of catalysis, in
accordance with modern adsorption theory.
(A) a b c d e (B) a c b d e (C) a c b e d (D) a b c e d
PAGE NO.-53
16. Which of the following curves is in accordance with Freundlich adsorption isotherm?
(A) (B) (C) (D)
log log log p log p
17. Zone refining is based on the principle that _________.

(A) impurities of low boiling metals can be separated by distillation.
(B) impurities are more soluble in molten metal than in solid metal.
(C) different components of a mixture are differently adsorbed on an adosrbent.
(D) vapours of volatile compound can be decomposed in pure metal.
18. In the metallurgy of aluminium ______________.
(A) Al3+ is oxidised to Al (s).
(B) graphide anode is oxidised to carbon monoxide and carbon dioxide.
(C) oxidation state of oxygen changes in the reaction at anode.
(D) oxidation state of oxygen changes in the overall reaction involved in the process.
19. Extraction of gold and silver involves leaching the metal with CN – ion. The metal is recovered
by___________.
(A) displacement of metal by some other metal from the complex ion.
(B) roasting of metal complex.
(C) calcination followed by roasting.
(D) thermal decomposition of metal complex.
20. In qualitative analysis when H2S is passed through an aqueous solution of salt acidified with dil. HCl, a
black precipitate is obtained. On boiling the precipitate with dil. HNO 3, it forms a solution of blue colour.
Addition of excess of aqueous solution of ammonia to this solution gives _________.
(A) deep blue precipitate of Cu(OH)2 (B) deep blue solution of [Cu(NH3)4]2+
(C) deep blue solution of Cu(NO3)2 (D) deep blue solution of Cu(OH)2.Cu(NO3)2
21. On heating with concentrated NaOH solution in an inert atmosphere of CO 2, white phosphorus gives a
gas. Which of the following statement is incorrect about the gas?
(A) It is highly poisonous and has smell like rotten fish.
(B) It’s solution in water decomposes in the presence of light.
(C) It is more basic than NH3.
(D) It is less basic than NH3.
22. Which of the following statements is wrong ?
(A) Single N–N bond is stronger than the single P–P bond.
(B) PH3 can act as a ligand in the formation of coordination compound with transition elements.
(C) NO2 is paramagnetic in nature.
(D) Covalency of nitrogen in N2O5 is four.
23. A black compound of manganese reacts with a halogen acid to give greenish yellow gas. When excess
of this gas reacts with NH3 an unstable trihalide is formed. In this process the oxidation state of nitrogen
changes from _________.
(A) –3 to +3 (B) –3 to 0 (C) –3 to +5 (D) 0 to –3
24. Metallic radii of some transition elements are given below. Which of these elements will have highest
density?
Element Fe Co Ni Cu
Metallic radii/pm 126 125 125 128
(A) Fe (B) Ni (C) Co (D) Cu
25. When KMnO4 solution is added to oxalic acid solution, the decolourisation is slow in the beginning but
becomes instantaneous after some time because
(A) CO2 is formed as the product. (B) Reaction is exothermic.
(C) MnO4– catalyses the reaction. (D) Mn2+ acts as autocatalyst.
PAGE NO.-54
26. Interstitial compounds are formed when small atoms are trapped inside the crystal lattice of metals.
Which of the following is not the characteristic property of interstitial compounds?
(A) They have high melting points in comparison to pure metals.
(B) They are very hard.
(C) They retain metallic conductivity.
(D) They are chemically very reactive.
27. The colour of the coordination compounds depends on the crystal field splitting. What will be the correct
order of absorption of wavelength of light in the visible region, for the complexes,[Co(NH 3)6]3+,
[Co(CN)6]3– , [Co(H2O)6]3+
(A) [Co(CN)6]3– > [Co(NH3)6]3+ > [Co(H2O)6]3+ (B) [Co(NH3)6]3+ > [Co(H2O)6]3+ > [Co(CN)6]3–
3+ 3+
(C) [Co(H2O)6] > [Co(NH3)6] > [Co(CN)6] 3– (D) [Co(CN)6]3– > [Co(NH3)6]3+ > [Co(H2O)6]3+
28. When 1 mol CrCl3.6H2O is treated with excess of AgNO3, 3 mol of AgCl are obtained. The formula of
the complex is :
(A) [CrCl3 (H2O)3].3H2O (B) [CrCl2(H2O)4]Cl.2H2O
(C) [CrCl(H2O)5]Cl2.H2O (D) [Cr(H2O)6]Cl3
29. The  for octahedral [CoCl6]4– is 18,000 cm–1. The  for tetrahedral [CoCl4]2– will be :
(A) 18,000 cm–1 (B) 16,000 cm–1 (C) 8,000 cm–1 (D) 20,000 cm–1
30. Due to the presence of ambidentate ligands coordination compounds show isomerism. Palladium
complexes of the type [Pd(C6H5)2(SCN)2] and [Pd(C6H5)2(NCS)2] are :
(A) linkage isomers (B) coordination isomers
(C) ionisation isomers (D) geometrical isomers
PAGE NO.-55

DPP No. B1 To B23 E Physical and Inorganic Chemistry

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DPP No. B1 To B23 E Physical and Inorganic Chemistry

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DPPs BOOKLET-2 VIJETA (JP) | CHEMISTRY

DPP No. # B1 (JEE-MAIN)

(A) 96500 C (B) 965 C (C) 1930 C (D)

19. The following electrochemical cell is taken.

20. Select the incorrect statement(s).

22. Consider the following reversible reactions :

DPP No. # B2 (JEE-ADVANCED)

3. Which of the following statements is/are incorrect ?

5. The correct statement(s) regarding defects solids is (are)

9. The resistance of a

in freezing point of solution is

DPP No. # B3 (JEE-MAIN)

(A) 1 (B) 2 (C) 3 (D) No triple point

8. In the following compounds :

2H+ + Zn Zn2+ + H2(g)

13. Match correctly

17. In the process of extraction of silver,

Identify the complexes [P] and [Q]

21. Calculate EAN of the following complex [Cr(CO)3(NO)2]

DPP No. # B4 (REVISION DPP)

1. Calculate H° for this reaction.

21. Number of chelate rings in [Cr(ox)3]3– = a

DPP No. # B5 (JEE-ADVANCED)

2. Which of the following statement(s) is/are correct ?

13. If the slope of Z (compressibility factor) v/s P curve is

DPP No. # B6 (JEE-MAIN)

8. The equivalent conductance of

10. Which process involves corrosion ?

Choose the correct options.

(A) The defect is known as schottky defect

22. For the reaction A C, the concentration and time is shown as

what is the value of Kc for the reaction 2 C 2 A ?

DPP No. # B7 (JEE-ADVANCED)

15. Match the column

DPP No. # B8 (JEE-MAIN)

2. Colourless salt + dil H2SO4 Y (colourless gas), Y 

4. Which is not an irreversible process

5. X(s) A(g) + 2B(g) KP1 = 9  10–3 atm3

6. Consider the following complex :

ChemINFO p-Block Element

Property White prosphorus Red prosphorus

25. Phosphorus is used in :

DPP No. # B9 (JEE-ADVANCED)

2. Which of the following statement(s) is/are correct ?

3. Which of the following complexe(s) is/are diamagnetic ?

5. Select the correct statements if -

(d) Calcium hydride + H2O() 

(A) Chalcopyrites (p) Self – reduction

(B) Galena (q) Sulphur containing ore

(C) Argentite (r) Carbon reduction

(D) Malachite (s) Leaching followed by displacement method.

DPP No. # B10 (JEE-MAIN)

10. The preparation of SO3(g) by reaction : SO2 (g) +

11. Brine   is

A(aq) + NH4Cl  (D)(gas) . (turns red litmus blue)

(A) (B) (C) (D)

1/T 1/T log T logT

DPP No. # B11 (REVISION DPP)

4. Vapour pressure & temperature relationship is shown as, log P 500

DPP No. # B12 (JEE-MAIN)

1. NaOH + N2O5  Product of this reaction are

(A)  = 90° (B)  = 120° (C)  = 150° (D)  = 180°

ChemINFO Special Concentration Units