Solaris public school

chap: 1,2,5,6,7,8 11TH CHEMISTRY

2nd prelim
Section A
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• Write the answer of the following questions. [Each carries 1 Mark] [25]

1. What degree Fahrenheit will be equivalent to 293 K ?

(A) 273° F (B) 68° F (C) 293° F (D) 77° F

2. .......... is used in treatment of cancer.

(A) Paracctamol (B) Taxol (C) Aspirine (D) Peniciline

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3. Which one used instead of CFC in refrigerator ?

(A) 1, 1, 2, 2 Tetrafloroethane (B) Chloroform
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(C) 1, 1, 1, 2 Tetrachloroethane (D) CCl4

4. 293 K = .......... oF.

(A) 273 (B) 68 (C) 293 (D) 77

5. The mass of one atom of C12 = ..........

(A) 1.992648 ´ 1023 gm (B) 6.022 ´ 1023 gm (C) 1.992648 ´ 10–23 gm (D) None of these
6. State the species in which electron, proton and neutron are 10, 8, 8 respectively ?
(A) 128 O2– (B) 168 O (C) 168 O2– (D) 168 O–

7. How many orbitals are there if n = 3, l = 2 ml = +2 ?

(A) 1 (B) 2 (C) 3 (D) 4

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8. The Uncertainty principle is important for....

(A) moving a-particle (B) Rocket (C) Electron (D) All
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9. How many maximum number of electrons in 3p orbital have spin quantum number S = – ?
2
(A) 0 (B) 6 (C) 3 (D) 2

10. In which of the following reaction, entropy is decreasing ?

(A) Melting of ice (B) Crystalisation of sucrose from solution
(C) Vaporisation of camphor (D) Rusting of iron
11. State the unit of molar entropy.
(A) Joule / Kelvin (B) kJ / kelvin mole (C) Joule/Kelvin mole (D) Calory / Kelvin

12. Change in heat at constant volume (qv) = .......

(A) DU (B) DH (C) RT (D) DG

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13. Which equation from the following is right ?

(A) DU = q – w (B) w = DU + q (C) DU = w + q (D) none of above
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14. In the following which situation precipitation will be occurs ?

(A) Qsp = Ksp (B) Qsp > Ksp (C) Qsp < Ksp (D) None of these

15. Which is the equation showing the relation between Kp and Kc ?

(A) Kp = Kc(RT)Dn (B) Kp = KcRn (C) Kp = Kc(PT)Dn (D) Kp = Kc(RT)฀–Dn
16. For spontaneous reaction what is the value of DG ?
(A) Positive (B) Negative (C) Zero (D) Any

17. What is the pH value of human blood ?

(A) 7.4 (B) 8.0 (C) 6.4 (D) 8.4

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18. Mention Na2CrO4 by stock notation method.
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(A) Sodium dichromate (VI) (B) Sodium chromate (VI)

(C) Chromium (VI) oxide (D) Sodium chromate (VI)
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19. Which compound is reducing agent in the following equation ?

CH3CHO (s) + Ag2O (s) —® CH3COOH + 2Ag
(A) CH3COOH (B) Ag2 O (C) CH3 CHO (D) Ag

20. In the following reaction which element’s oxidation number is decreasing ?

MnO4– + 5Fe+2 + 8H+ ® Mn+2 + 5Fe+3 + 4H2O
(A) Mn (B) Fe (C) O (D) H2
21. From the following which reaction is redox reaction ?
(A) NaOH(aq) + HCl(aq) ® NaCl(aq) + H2O(l) (B) CH3COOH + CH3OH ® CH3COOCH3 + H2O
(C) K2SO4(aq) + BaCl2(aq) ® 2KCl(aq) + BaSO4(l) (D) H2S(aq) + 3H2SO4(aq) ® 4SO2(g) + 4H2O(l)

22. How many no. of s and p-bond are in ethene respectively ?

(A) 5 and 1 (B) 1 and 5 (C) 6 and 1 (D) 4 and 2
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23. The hybridisation of carbon in alkane series is which type ?

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(A) sp2 (B) sp3 (C) sp (D) dsp2

24. IUPAC name of CH º C – CH = CH – CH = CH2 is ............ .

(A) Hexa-5-yne-1, 3-dine (B) Hexa-1, 3-dine-5-yne
(C) Hexa dine-yne-1, 3, 5 (D) Hexa-1-ene-1-yne-3-en
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25. Give correct IUPAC name of

(A) Cyclohex-1-ene-1-3-nitro (B) 1-nitro-cyclohex-2-ene

(C) 3-nitro-cyclohexene (D) 1-ene-3-nitrocyclohexane

Section B
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• Write the answer of the following questions. [Each carries 2 Marks] [30]

26. What is homologous series ? Give example.

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27. Write about Inductive effect.

28. ) What is the positive and negative resonance effect ? Explain with examples.
29. ) Assign oxidation number to the underline element in the following specie : K2MnO4

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30. 2) What is the oxidation number of the underlined element in the following and how do you rationalize
your result ? H2S4O6

31. 1) Predict the product of electrolysis in the following : An aqueous solution of AgNO3 with silver
electrodes.
32. Derive relation between equilibrium constant K, Reaction quotient Q and Gibbs energy change (DG).

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33. Write effect of concentration change on equilibrium and explain by suitable example.

34. Write Arrhenius concept of Acids and Bases.

35. Prove the relationship between Cp and Cv for an ideal gas.

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36. Describe Gibbs energy and spontaneity.

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1.2)
37. A compound contains 4.07% hydrogen, 24.27 % carbon and 71.65% chlorine. Its molar mass is 98.96
g. What are its empirical and molecular formulas ?
38. ) Calculate the molarity of NaOH in the solution prepared by dissolving its 4 g in enough water to
form 250 mL of the solution.

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39. ) The wavelength range of the visible spectrum extends from violet (400 nm) to red (750 nm). Express
these wavelengths in frequencies (Hz). (1 nm = 10–9 m)
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40. 2) What will be the wavelength of a ball of mass 0.1 kg moving with a velocity of 10 m s–1 ?
 Section C
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• Write the answer of the following questions. [Each carries 3 Marks] [36]

41. 8) Using s, p, d, f notations, describe the orbital with the following quantum numbers
(a) n = 2, l = 1 (b) n = 4, l = 0
(c) n = 5, l = 3 (d) n = 3, l = 2

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42. 6) A golf ball has a mass of 40g, and a speed of 45 m/s. If the speed can be measured within accuracy
of 2%, calculate the uncertainty in the position.
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1.8)
43. The density of 3 M solution of NaCl is 1.25 g mL–1. Calculate molality of the solution.
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44. ) How many moles of methane are required to produce 22 g CO2(g) after combustion ?

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45. 0) For oxidation of iron, 4Fe(s) + 3O2(g) ® 2Fe2O3(s)

entropy change is –549.4 JK–1 mol–1 at 298 K. Inspite of negative entropy change of this reaction,
why is the reaction spontaneous ? (DrH d– for this reaction is 1648 × 103 J mol–1)
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46. 1) Calculate DG d– for conversion of oxygen to ozone, O 2(g) ® O 3(g) at 298 K. If K for this conversion
p
2
S
is 2.47 × 10–29.
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47. 4) Classify the following species into Lewis acids and Lewis bases and show how these act as such :
(i) H2O (ii) HCO–3 (iii) HSO–4 (iv) NH3

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48. 7) Calculate pH of a 1.0 ´ 10–8 M solution of HCl.

49. 1) Balance the following equations in basic medium by ion-electron method and oxidation number
method and identify the oxidising agent and the reducing agent.
P4(s) + OH–(aq) ® PH3(g) + HPO–2(aq)

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50. 4) Balance the following redox reactions by ion – electron method :

Cr2O 72– + SO2(g) ® Cr3+(aq) + SO2–4(aq) (in acidic solution)
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8.1)
51. How many s and p bonds are present in each of the following molecules ?
(a) HC º CCH = CHCH3
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(b) CH2 = C = CHCH3

52.
8.2) What is the type of hybridisation of each carbon in the following compounds ?
(a) CH3Cl (b) (CH3)2CO (c) CH3CN
(d) HCONH2 (e) CH3CH = CHCN

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Section D
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• Write the answer of the following questions. [Each carries 5 Marks] [20]

53. What is isomerism ? Which are the types of isomerism ?

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54. 1) Balance the following redox reactions by ion – electron method :
MnO–4(aq) + I–(aq) ® MnO2(s) + I2(s) (in basic medium)

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55. Derive Ka ´ Kb = Kw equation.

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6.8)
56. 13.8 g of N2O4 was placed in a 1 L reaction vessel at 400 K and allowed to attain equilibrium,
N2O4(g) ƒ 2NO2(g)
The total pressure at equilibrium was found to be 9.15 bar. Calculate Kc, Kp and partial pressure at
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equilibrium.
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