Code - A | IITJEE 2025 | 1 Year SET 2 | VIQ 5

SECTION - II [CHEMISTRY]

26. Two particles of masses ‘m’ and ‘2m’ have equal kinetic energies. Their de Broglie wavelengths are in
the ratio of:
(A) 2 :1 (B) 1: 2 (C) 1: 2 (D) 1:1
27. The orbital angular momentum of an electron in 2s orbital is:
h
(A) 4 (B) 1 (C) 0 (D)
2

28. O 2 gas at STP contained in a flask was replaced by SO 2 under same conditions. The weight of SO 2
will be:
(A) Equal to that of O 2 (B) Half that of O 2
(C) Twice that of O 2 (D) One-fourth of O 2

29. A sample of gas occupies 100 mL at 27°C and 740 mm pressure. When its volume is changed to 80 mL
at 740 mm pressure, the temperature of the gas will be:
(A) 21.6°C (B) 240°C (C) –33°C (D) 89.5°C

30. Identify intensive property from the following :

(A) Volume (B) Mass (C) Enthalpy (D) Temperature
Specific heat
capacity
Heat Molar heat
31. (H  U) for the formation of carbon monoxide (CO) from its elements at 298 K is:
(R  8.314 J K 1mol1 )
1
(A) 1238.78
9 J mol (B) 1238.789 J mol1
(C) 2477.57 J mol 1 (D) 2477.57 J mol1

32. The radius of which ion is closest to that of Li  ion?

(A) Na  (B) Be2 (C) Mg 2 (D) Al3

33. Among the following configurations, the element which has the highest electron affinity is:
(A) [Ne]3s1 3p 2 (B) [Ne]3s 2 3p5 (C) [Ne]3s 2 3p 4 (D) [Ne]3s 2 3p6 3d 5 4s1

34. If the uncertainty in the position of an electron is zero, the uncertainty in its momentum will be:
h h
(A)  (B)  (C) Zero (D) Infinity
4 4

35. V vs T curves at different pressures P1 and P2 for an ideal gas are shown below:

Which one of the following is correct?

P2 1
(A) P1  P2 (B) P1  P2 (C) P1  P2 (D) 
P1 2

Vidyamandir Classes | Gurukul for IITJEE & Medical Preparation

 6 VIQ | 1 Year SET 2 | IITJEE 2025 | Code - A

36. If the density of methanol is 0.8 kg L–1, then volume of ethanol needed for making 2.5 L of 0.5 M
solution is :
(A) 0.4 L (B) 4.0 L (C) 0.04 L (D) 40 L
37. Concentration of nitric acid in moles per litre in a sample which has density 1.41 g mL–1 and mass per
cent of nitric acid in it being 69 % is :
(A) 15.44 M (B) 10.24 M (C) 9.08 M (D) 12.5 M
38. For multielectron system the decreasing order of energy of given orbitals 5d, 4f, 5p, 5s is:
(A) 5d > 4f > 5p > 5s (B) 4f > 5d > 5p > 5s
(C) 5s > 5d > 5p > 4f (D) 4f > 5s > 5d > 5p
39. If a 60 watt bulb emits monochromatic radiation of wavelength 6623A° then number of photons emitted
per second by the bulb will be:
(A) 4 × 1021 (B) 2 × 1019 (C) 4 × 1020 (D) 2 × 1020
40. For given molecule, the decreasing order of dipole moment is:
(A) NH3 > H2O > H2S > NF3 (B) NH3 > NF3 > H2S > H2O
(C) H2O > NF3 > NH3 > H2S (D) H2O > NH3 > H2S > NF3

41. Which arrangement of electrons is most stable?

(A) (B)

(C) (D) All are equally stable

42. Which of the following conformers for ethylene glycol is most stable?

(A) (B) (C) (D)

43. In the given potential energy diagram the point X represents:

(A) a transition state (B) a reaction intermediate

(C) a resonance hybrid (D) a reactant

44. Balance the following reaction and find the value of a, b and g respectively:
aKMnO 4  bH 2O 2  6H 2SO4 
 dMnSO 4  eK 2SO 4  fO 2  gH 2O
(A) 2, 5, 8 (B) 4, 10, 16 (C) 10, 4, 16 (D) 8, 5, 2
45. How many grams of I2 are present in a solution which requires 40 mL of 0.11 N Na 2S2O3 to react with
it? (Molar mass of I2  254 )

Vidyamandir Classes | Gurukul for IITJEE & Medical Preparation

Code - A | IITJEE 2025 | 1 Year SET 2 | VIQ 7

S2O32  I2 
 S4O62  2I
(A) 12.7g (B) 0.558g (C) 25.4g (D) 11.4g

46. Consider the following gaseous equilibria given below:

(I)  2NH 3 ; Eqm. Constant = K1
N 2  3H 2 

(II)  2NO; Eqm. Constant = K 2

N 2  O 2 
1  H 2 O; Eqm. Constant = K 3
(III) H 2  O2 
2
5  2NO  3H 2O in terms of K1, K 2 and
The equilibrium constant for the reaction, 2NH3  O2 
2
K 3 will be:
K1K 2 K1K 32 K 2 K33
(A) K1K 2 K 3 (B) (C) (D)
K3 K2 K1

47.  2HI(g), the equilibrium constant changes with:

For the reaction H 2 (g)  I2 (g) 
(A) total pressure (B) catalyst
(C) concentration of H 2 and I 2 (D) temperature

48. 105 M NaOH solution at 25°C is diluted 1000 times. The pH of the resultant solution will:
(A) be equal to 8 (B) lie between 7 and 8
(C) lie between 6 and 7 (D) remain unchanged

49. 4.0 g of NaOH and 4.9 g of H 2SO 4 are dissolved in water and volume is made upto 250 mL. The pH of
this solution is:
(A) 7.0 (B) 1.0 (C) 2.0 (D) 12.0

50. Which of the following are isoelectronic and isostructural?

(A) SO3 , ClO3 (B) ClO3 , CO32 (C) NO32 , CO32  (D) CO32 , XeO3

Vidyamandir Classes | Gurukul for IITJEE & Medical Preparation