Chemistry (Full Test) Mains - Paper 3

FIITJEE Mumbai JEE Mains Mock Test
SECTION – A
Single Correct Choice Type
This section contains 30 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE is correct.
1. 112 mL of NO2 at NTP was liquefied, the density of the liquid being 1.15 g mL1 . The volume of
the liquid is:
(A) 0.1 mL (B) 0.2 mL
(C) 128.8 mL (D) 1.15 mL
2. A mixture of HCOOH and H 2 C2 O4 is heated with conc. H 2 SO4 . The gaseous mixture thus
produced is collected and passed through NaOH solution. The volume of the gaseous mixture
th
1
decreases by   . The molar ratio of HCOOH and H 2 C2 O4 in the mixture of acids is:
6
1
(A) (B) 6
4
1
(C) 4 (D)
6
3. Equal volumes of ethanoic acid and KOH are mixed, the heat evolved is:
(A) equal to heat of formation of water from H  and OH 
(B) less than the heat of formation of water from H  and OH 
(C) equal to heat of formation of water from H 2 and O2 in gaseous state
(D) equal to enthalpy of neutralization of KOH and HCl
4. Consider the following reaction,

A  g  
 2B  g 
The rate constant for this reaction is 2.30310 2 min 1 . The time in which the molar ratio of A to B
becomes 3 : 2 is equal to:
(A) 12.5 min (B) 2.303 min
(C) 5.12 min (D) 80 min
5. 
Consider the following gaseous phase equilibrium, A  g   2B  g  . The degree of dissociation
1 2
of A is and at P1 and P2 pressures respectively. The ratio of P1 and P2 is:
3 3
7 7
(A) (B)
4 32
8 32
(C) (D)
32 5
6. The pH of a H 2 SO4 solution is 2. The pH of this solution, if equal volume of 0.2 M NaCl
solution is added to it, will be:
(A) 1.7 (B) 2.3
(C) 3.2 (D) 2
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FIITJEE Mumbai 2 JEE Mains Mock Test
7. In a crystal structure of an element, atoms are present in ccp arrangement and tetrahedral voids,
which of the following relation between the atomic radius and edge length is correct for the unit
cell which is formed in this arrangement? (a is the edge length and R is the radius of atom):
(A) 2a  4R (B) 3a  8R
(C) 3a  4R (D) a  2R
8. 1000 g of 1 molal aqueous solution of sucrose is cooled and maintained at 3.534C . What is
the amount of ice separated out  K f for H 2 O is 1.86  :
(A) 353 g (B) 220 g
(C) 150 g (D) 510 g
9. Acidified water is electrolysed using inert electrodes. The total volume of gases collected at
cathode and anode is V mL at STP . The amount of charge passed in the electrolytic cell is equal
to:
(A)  5.74 103  V  C (B) 96500 C
(C) 1.72 103 V  C (D) 1.72103 C
10. The charge on As2 S3 may be due to the adsorption of:

(A) H  (B) OH 
(C) O2 (D) S 2
11. The magnetic moment of Cr x is 15 BM . The ratio of number of paired e  and unpaired e  in
Cr x is equal to:
(A) seven (B) six
(C) five (D) four
12. Find H in terms of KJ for the following reaction from the given data
 M 2  g   2X   g 
M  g   2X  g  
 IE 1 of M  g   705 KJ mol 1
 IE 2 of M  g   1151KJ mol 1
 IA1 of X  g   328 KJ mol 1
(A) 120 KJ (B) 512 KJ
(C) 1200 KJ (D) 110 KJ
13. Which of the following is not three dimensional network structures?

(A) SiO2 (B) CO2
(C) diamond (D) graphite
14. A 1g sample of H 2 O2 solution containing x% H 2 O2 by weight required x mL of KMnO4 for

complete oxidation in acidic medium. The normality of KMnO4 solution is approximately:
(A) 0.1 (B) 0.4
(C) 0.6 (D) 1.2
15. Consider the following statements about the structure of borax:
(i) number of B  O  B bonds is x
(ii) number of B  B bonds is y
(iii) number of sp 2 hybridized B atoms is z
The value of  x  y  z  is equal to
(A) 3 (B) 4
(C) 6 (D) 7
16. Which of the following has maximum dipole moment?

(A) O (B) O
(C) O (D) All have equal value
17. Mg / Ether
X

H 2O/ H
R  Cl Z   A
KCN
Y
What is ' A '?
(A) O (B)
R CHO
R C NH2
(C) R (D) R
C N
R C O
R OH
18. Which of the following will not convert R  C  N to R  CHO ?

(A)  i  SnCl2 / HCl (B)  i  RMgX  ii  H 2 O / H 
(C)  i  LiAlH 4  ii  H 2 O /  (D)  i  AlH  i  Bu 2  ii  H 2 O / 
19. O
COOC 2H 5
i H O  ii 

 3  
   ..........
The major product is:
(A) O (B) O
(C) O (D) O
O C
CH2
20.
O3 OH / 

Zn / H 2 O
X K Y ; the compound 'Y 'is :
(A) (B)
CHO CHO
x
(C) (D) OH
CHO
CHO
21. O
CH3 Zn
 Hg
/ HC
l  Product
OH
(A) CH3 (B) O
C
CH3
Cl
Cl
(C) CH3 (D)
CH2
OH Cl
22.
 EtO  Al
CHO 
3
 ......
The major product is:

(A) (B)
CH2OH CH2
CH3
(C) O (D) No reaction
C
O CH 2
23. Strongest base is:

(A) NH (B) H2 N

NH2 CNH2 C NH2
H2N
(C) H 2N (D) H2N

C O C OH
H2 N H2N 
24. aq.NaNO
NH2 
HCl

2
 P, P is :
(A) (B) +
Cl CH Cl 
(C) (D) None of these

OH
25. O
N H 1.
KNH 2 , DMF KOH , 
 A 1. 
B
2. PhCH Br 2 2. H O 3
O
The end product B of the above reaction is:
(A) Ph NH 2
(B)
Ph
Ph N H
(C) O (D) Ph
Ph N
Ph N Ph H
26. Marshall’s acid is:
(A) H 2 S2 O5 (B) H 2 S2 O8
(C) H 2 SO4 (D) H 2 S2 O7
27. The correct order of S  O bond in  I  SO2 ,  II  SO3 ,  III  SO42  is:
(A) I  II  III (B) III  I  II
(C) II  III  I (D) I  III  II
28. The following acids have been arranged in the order of increasing acid strength. Identify the
correct order:
 I  ClOH  II  BrOH
 III  IOH
(A) I  II  III (B) III  II  I
(C) II  I  III (D) III  I  II
29. The correct order of oxidizing power is:

(A) HOCl  HOClO  HOClO2  HOClO3 (B) HOClO3  HOClO2  HOClO  HOCl
(C) HOClO2  HOClO3  HOCl  HOClO (D) HOCl  HOClO2  HOClO  HOClO3
30. Shape of XeOF4 is:

(A) Trigonal bipyramid with lp at axial position
(B) Square pyramid with lp at axial position
(C) Distorted square pyramid with lp at axial position
(D) Square pyramid with lp at square plane.
Answer Key
S. No. CHEMISTRY
1. B
2. C
3. B
4. A
5. D
6. –
7. B
8. A
9. A
10. D
11. B
12. C
13. B
14. C
15. D
16. A
17. C
18. B
19. A
20. B
21. A
22. C
23. A
24. B
25. A
26. B
27. B
28. B
29. A
30. C

Chemistry (Full Test) Mains - Paper 3

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FIITJEE Mumbai JEE Mains Mock Test

4. Consider the following reaction,

10. The charge on As2 S3 may be due to the adsorption of:

13. Which of the following is not three dimensional network structures?

14. A 1g sample of H 2 O2 solution containing x% H 2 O2 by weight required x mL of KMnO4 for

16. Which of the following has maximum dipole moment?

(C) O (D) All have equal value

18. Which of the following will not convert R  C  N to R  CHO ?

The major product is:

23. Strongest base is:

(C) H 2N (D) H2N

(C) (D) None of these

29. The correct order of oxidizing power is:

30. Shape of XeOF4 is:

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