NARAYANA IIT ACADEMY 12-01-20_JR-N-SUPERCHAINA(R)_Jee-Adv_2014-P2_CAT-11_Qp

19. A body of mass M and radius R is as shown in figure.

The body can be a ring, a disc, a hollow sphere or a solid sphere. I x , I y and I z are the moments of
inertia about x, y and z axis respectively. Origin coincides with center of mass of the body.

Column-I Column-II
i. Ix  Iy  Iz a. Possible for ring or disk
ii. Ix  Iy  Iz b. Possible for hollow sphere or solid sphere
iii. I y  Iz  Ix c. Possible for all of the bodies mentioned
iv. Iz  Ix  Iy d. possible for any of the body mentioned

(A) i  c, a; ii  c; iii  b; iv  d (B) i  a , d ; ii  d ; iii  b; iv  c

(C) i  b; ii  d ; iii  d ; iv  a (D) i  c; ii  a; iii  d ; iv  b
20. In column I, nature of collision between two bodies is given while in column II some physical
quantity that may remain conserved during the collision is given. Match the entries of column I with
the entries of column II

Column-I Column-II
i. Elastic collision a. Kinetic energy is conserved
ii. Inelastic collision b. Kinetic energy of the system may increase
iii. Perfectly inelastic collision c. Kinetic energy is not conserved
iv. Collision between two cars moving at Total
d. energy is conserved
high speeds

(A) i  c, a; ii  c; iii  b; iv  d (B) i  a, d ; ii  c, d ; iii  c, d ; iv  c, d

(C) i  b; ii  d ; iii  d ; iv  a (D) i  c; ii  a; iii  d ; iv  b

CHEMISTRY Max Marks: 60

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 10 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
21. Which of the following molecules are expected to exhibit intermolecular H-bonding
I. Acetic acid II. O-nitro phenol
III. M-nitro phenol IV. O-boric acid
(A) I, II, III (B) I, II, IV (C) I, III, IV (D) II, III, IV

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22. Consider the given reaction:

In the above reaction which one of the given ring will undergo reduction?
(A) A (B) B (C) C (D) D
23. The number of cis-trans isomer possible for the following compound

(A) 2 (B) 4 (C) 6 (D) 8

24.

Total number of products obtained when this substrate is subjected to E2 reaction will be (including
stereoisomer)
(A) 3 (B) 4 (C) 5 (D) 6
25.

Name of intermediate produced during given reaction will be

(A) Arenium ion
(B)  –complex/wheel and intermediate
(C) Non aromatic cyclohexadienyl carbocation
(D) All of these
26. A 100 ml solution of H2O2 having volume strength equal to 44.8 volume is left open due to which
H2O2 dissociates giving water and O2 gas. IF there is no change in volume of solution but volume
strength decreases to 11.2 volume, then mass of O2 gas Obtained in this duration will be :
(A) 4.8 gram (B) 9.6 gram (C) 48 gram (D) 96 gram
27. Aluminum and Fe2O3 are used as a fuel to produce energy according to given reaction
2Al(s) + Fe2O3 (s)  Al2O3 (s)+2Fe(s)
o
Given: H f [Al 2O3 ]  100 kcal / mole

H of [Fe2 O3 ]  50 kcal / mole

Density of Al = 2.7 gram/c.c
Density of Fe2O3 = 3.2 gram /c.c

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NARAYANA IIT ACADEMY 12-01-20_JR-N-SUPERCHAINA(R)_Jee-Adv_2014-P2_CAT-11_Qp
Select the correct statements
(I) Enthalpy change for the given reaction is -50 k cal.
(II) 1.07 kg of mixture can produce maximum 200 k cal heat.
(III) Maximum Calorific value of the fuel is 0.432 k cal / gram.
(IV) Maximum Calorific value of the fuel is 0.714 k cal /c.c
(A) I (B) I, II (C) I, II, III (D) I, IV
28. N2H4 (g) undergoes following reactions, when heated at 1000k
N 2 H 4 (g)  N 2  g  +2H 2  g   K p1 

N 2 H 4 (g)  H 2  g   2NH3  g  K p 2 

In a rigid vessel N2H4(g) was introduced at 1 atm. Pressure and 1000k. Total pressure at equilibrium
was found to be 1.4atm and partial pressure of H2 was 0.3atm.
Select the correct options
(I) Partial pressure of N2H4(g) at equilibrium is 0.7atm.
(II) Partial pressure of NH3(g) at equilibrium is 0.2atm.
18 2
(III) K p   atm 
1
700
4
(IV) K p2 
21
(A) I (B) I, II (C) I, II, III (D) I, II, III, IV
29. A 2.5 gram Impure sample containing a weak monoacidic base (M.wt = 45) is dissolved in 100 ml
th
1
water and titrated with 0.5 M HCl at 25 C. When   of the base was neutralized, the PH was
o

5
found to be 9 and at the equivalent point PH of solution is 4.5.Which of the following statement is
not correct.
(A) PKb of the base is 5.6
(B) Concentration of salt at equivalent point is 0.25 M.
(C) Volume of HCl used at equivalent point is 100 ml.
(D) Mass percent of the base in given sample is 80%
30. The polarimeter readings in an experiment to measure the inversion of cane sugar
were as follows
Time (minutes) 0 30 
Rotation due to solution 30 20 -15
(degree)
Given
 log 2  0.3 , log 3  0.48
 log 7  0.84, 
 
Identify the correct statements
(A) The half life of the reaction is 50 minutes
(B) The half life of the reaction is 60 minutes
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(C) The solution is optically inactive at 120 minutes.
(D) The solution is optically inactive at 90 minutes.
SECTION - II
(PARAGRAPH TYPE)
This section contains 3 Paragraph of questions. Each paragraph has 2 multiple choice questions based on
a paragraph. Each question has 4 choices A), B), C) and D) for its answer, out of which ONLY ONE IS correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.

Paragraph for Question Nos. 31 & 32

Four elements, P, Q, R & S have ground state electronic configuration as:
P  1S2 2S2 2P6 3S2 3P3
Q  1S2 2S2 2P6 3S2 3P1
R  1S2 2S2 2P6 3S2 3P 6 3d10 4S2 4P3
S  1S2 2S2 2P 6 3S2 3P6 3d10 4S2 4P1
31. Comment which of the following option represent the correct order of true (T) & false (F) statement.
I. Size of P < size of Q
II. Size of R < size of S
III. Size of P < size of R (appreciable difference)
IV. Size of Q < size of S (appreciable difference)
(A) TTTT (B) TTTF (C) FFTT (D) TTFF
32. Order of IE1 value among the following is
(A) P > R > S > Q (B) P < R < S < Q (C) R > S > P > Q (D) P > S > R > Q
Paragraph for Question Nos. 33 & 34
10 mole of liquid (A) and 20 mole of liquid (B) is mixed in a cylindrical vessel containing a piston
arrangement. Initially a pressure of 2atm. is maintained on the solution. Now the piston is raised
slowly and isothermally. Assume ideal behavior of solution.
PAo  0.6atm PBo  0.9atm
33. The pressure at which evaporation of the liquid solution will start:-
(A) 0.6atm (B) 0.7atm (C) 0.8atm (D) 0.9atm
34. The minimum pressure for the existence of liquid solution is:-
(A) 0.6atm (B) 0.77atm (C) 0.88atm (D) 0.98atm

Paragraph for Question Nos. 35 & 36

Always enthalpy is not enough to talk about the spontaneity of a process or even entropy alone. Hence
new term Gibb's energy has been introduced that explains the spontaneity of a process by making use of
both enthalpy and entropy alongwith temperature and they are related as: G  H  T S . A decrease
in Gibb's energy is a measure of useful work that a system can do. A decrease in Gibb's energy is a
measure of spontaneity . Gibb's energy change is zero for a system in equilibrium. Keeping these points
in mind answer the following questions.
35 The lattice energy of a salt AB is 764 kJ and the hydration energy of the salt is 755 kJ. If entropy of
dissolution of AB in water is 40 J/K/mol at 298 K, the Gibb's energy change of dissolution is :
A) 9.0 kJ B) -2.92 kJ C) -11.2 kJ D) -9.0 kJ
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36. If 20 g argon is compressed from 10 L to 5 L under reversible isothermal conditions at 300 K, the
Gibb's energy change would be
[R=8.3J ; Atomic mass of Argon = 40 ]
A) -2.59kJ B) 0.863 kJ C) -0.863kJ D) 1.98kJ

SECTION - III
(Matching List Type)
This section contains four questions, each having two matching lists (List-1 & List-II). The options for the correct
match are provided as (A), (B),(C) and (D) out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.

37. Match the column

Column-I Column-II

P) I2Cl6 1) all atoms are SP3 hybridized

Q) SiC 2) have non planar structure

R) Al2(CH3)6 3) have 3c-4e bonds

S) S3O9 4) have 3c-2e bonds

Code:
P Q R S P Q R S
A) 1 2 3 4 B) 3 1 4 2
C) 2 3 4 1 D) 3 4 1 2

38. Match the compounds listed in column-I with the characteristics listed in column-II
Column-I Column-II

P) BeO (s) 1) Amphoteric nature

Q) NaHCO3 (crystalline) 2) Impart no colour in Bunsen flame

Produce H2O2 and O2 on reaction with
R) BeCl2 3)
water
S) CsO2 4) Show hydrogen bonding

Code:
P Q R S P Q R S
A) 1 4 2 3 B) 2 3 1 4
C) 1 2 4 3 D) 1 4 3 2

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39. Match the column

Column-I Column-II

P) Boron 1) Cross linked polymer

Q) Graphite 2) Alluminium

R) CH3SiCl3 3) Van-Arkel method

S) Bauxite 4) Layer structure

Code:
P Q R S P Q R S
A) 3 4 2 1 B) 4 1 2 3
C) 3 2 4 3 D) 3 4 1 2

40. Match the effect of addition of 0.1 M KOH to 0.1 M, 50 ml H 3 PO4 . K a1 , K a 2 , K a 3

Are I, II, III ionization constant of H 3 PO4
Column-I Column-II

P) 75 ml of KOH 1) P H  P Ka1
Q) 25 ml of KOH 2) P H  P Ka 2
H P Ka 2  P Ka 3
R) 150 ml of KOH 3) P 
2
1
S) 100 ml of KOH 4)
2

P H  7  P Ka3  log C 
Code:
P Q R S P Q R S
A) 2 1 4 3 B) 3 2 4 1
C) 4 3 1 2 D) 2 4 1 3

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