MONICA BEDI

Ph.D Chemistry
12+ Years of Teaching Experience
Trained Million+ students
Author - Top Ranker’s Series (TRS)
Atomic Structure
1. The photoelectric behavior of K, Li, Mg and Ag metals is shown in the
plot below. If light of wavelength 400 nm is incident on each of these
metals, which of them will emit photoelectrons?
[Planck's constant h = 6.626 × 10–34 Js; velocity of light c = 3 × 108 m
s–1; 1 eV = 1.6 x 10-19 J]

(a) K (b) K and Li

(c) K, Li and Mg (d) K, Li, Mg and Ag
2. The radii of the first Bohr orbit of H (rH), He+ (rHe+) and Li2+ (rLi2+)
are in the order
(a) rHe+ > rH > rLi2+ (b) rH < rHe+ < rLi2+

(c) rH > rHe+ > rLi2+ (d) rHe+ < rH > rLi2+
3. If the radius of first Bohr orbit of hydrogen atom is 53 pm, the radius
second Bohr orbit of the He+ ion is closest to
(a) 106 pm (b) 81 pm
(c) 27 pm (d) 13 pm
4. The value of Planck's constant is 6.63 × 10–34 Js. The velocity of light is 3
× 108 ms–1. Which value is closest to the wavelength in nanometer of a
quantum of light with frequency of 8 × 1015 s–1 ?
(a) 2 × 10–25 (b) 3 × 107
(c) 4 × 101 (d) 5 × 10–18
5. A plot of the kinetic energy of ejected electrons as a function

of the frequency (v) of incident radiation for four alkali metals (M1, M2,
M3, M4) is shown below.

The alkali metals respectively

M1, M2, M3 and M4 are respectively.
(a) Li, Na, K and Rb
(b) Rb, K, Na and Li
(c) Na, K, Li and Rb
(d) Rb, Li, Na and K
6. Number of photons having wavelength 632.8 nm, emitted by 5 mW laser
source in 1 second is
(A) 1.6 x 1019 (B) 1.6 x 1016
(C) 1.6 x 1025 (D) 1.6 x 1013
7. In a sample of excited hydrogen atoms, electrons make transition from n =
2 to n = 1 . Emitted quanta strike on a metal of work function [f] 4.2 ev.
Calculate the wavelength (in Å) associated with ejected electrons having
maximum kinetic energy.
8. The atomic masses of He and Ne are 4 and 20 a.m.u, respectively. The
value of the de Broglie wavelength of He gas at – 73°C is ‘M’ times that of
the de Broglie wavelength of Ne at 727°C . M is
9. The ratio of minimum to maximum wavelengths in Balmer series of H–
atom is
(A) 5 : 9 (B) 5 : 36
(C) 1 : 4 (D) 3 : 4
10. Spin only magnetic moment 2.84 BM is given by:
(Atomic Number of Ni = 28, Ti = 22, Cr = 24, Co = 27)
(A) Ni2+ (B) Ti3+
(C) Cr2+ (D) Co2+
Gaseous State
1. At a constant pressure p, the plot of volume (V) as a function of
temperature (T) for 2 moles of an ideal gas gives a straight line with a
slope 0.328 LK–1. The value of p (in atm) is closest to
[Gas constant, R = 0.0821 L atm mol–1 K–1]

(a) 0.25 (b) 0.5

(c) 1.0 (d) 2.0
2. A container of volume 2.24 L can with stand a maximum pressure of 2
atm at 298 K before exploding. The maximum amount of nitrogen (in g)
given below that can be safely put in this container at this temperature is
closest to
(a) 2.8 (b) 5.6
(c) 1.4 (d) 4.2
3. For four processes A, B, C and A loge p versus loge V graph are given
below.

Isothermal process is
(a) A
(b) B
(c) C
(d) D
4. A plot of volume (V) versus temperature (T) for a gas at constant pressure
is a straight line passing through the origin.

The plot of different values of pressure are shown in figure. Which of the
following orders of pressure is correct?
(a) p1 > p2 > p3 > p4 (b) p1 = p2 = p3 = p4
(c) p1 < P2< P3< P4 (d) p1 < p2 = pq < p4
5. According to Graham's law, the rate of diffusion of CO, O2, N2 and
CO2 follows the order
(a) CO = N2 > O2 > CO2
(b) CO = N2 > CO2 > O2
(c) O2 > CO = N2 > CO2
(d) CO2 > O2 > CO = N2
6. At room temperature, the average speed of helium is higher than
that of oxygen by a factor of
(a) 22 (b) 6/2
(c) 8 (d) 6
7 An isolated box, equally partitioned contains two ideal gases A and B as
shown

When the partition is removed, the gases mix. The changes in enthalpy
(DH) and entropy (DS) in the process, respectively, are
(a) zero, positive (b) zero, negative
(c) positive, zero (d) negative, zero
8. Consider two sealed jars of equal volume. One contains 2 g of hydrogen
at 200 K and the other contains 28 g of nitrogen at 400 K. The gases in
the two jars will have
(a) the same pressure
(b) the same average kinetic energy
(c) the same number of molecules
(d) the same average molecular speed
9. For one mole of a van der Waals gas when b = 0 and T = 300 K, the PV
vs. 1/V plot is shown below. The value of the van der Waals constant a
(atm. Litre2 mol–2) is

(A) 1.5

(B) 2.5

(C) 1.75

(D) 1.0
10. The density of O2 is 16 at NTP. At what temperature(in °C) its
density will be 14? Consider that the pressure remains constant.
Thermodynamics
1. Combustion of Hydrogen in a fuel cell at 300 K is represented as
2H2 (g) + O2 (g) ------------> 2H2O (g).
If DH and DG are –241.60 kJ mol–1 and –228.40 kJ mol–1 are respectively
for H2O then the value of DS for the above process is
(A) 4.4 JK–1 (B) – 88 JK–1
(C) +88 JK–1 (D) – 44JK–1
2. In a process, 701 J of heat is absorbed by a system and 394 J of work is
done by the system. What is the change in internal energy (in J) for the
process?
3. A gas occupies 2 litres at STP. It is provided 58.63 joule heat so that its
volume becomes 2.5 litre at 1 atm. Change in its internal energy in joules is
(A) 8.63 (B) 7.62
(C) 12.9 (D) 5.54
4. The work done in an open vessel at 300 K, when 112 g iron reacts with dil.
HCl is ( R = 2 cal mol–1 K–1 )
(A) 1200 cal (B) 600 cal
(C) 300 cal (D) 200 cal
5. Consider the reaction 2NO(g) + O2(g) -------> 2NO2(g); Predict whether the
reaction is spontaneous at 298 K.
(Given: DfG (NO) = 86.69 kJ/mol, DfG (NO2) =51.84 kJ/mol )

(A) Yes, spontaneous

(B) No, the reaction is Non-spontaneous
(C) Equilibrium
(D) Cannot predict
8. One mol of an ideal gas was taken from A ---> B as shown in given figure.
 25 J 
Magnitude of work involved in process is  R  
 3 mol K 

(A) 5 kJ (B) 7.5 kJ

(C) 2.5 kJ (D) None of these
7. The standard molar heat of formation of ethane, CO2 and water are
respectively –21.1, –94.1 and – 68.3 kcal. The standard molar heat of
combustion of ethane will be:
(A) – 372 kcal/mol (B) 162 kcal/mol
(C) – 240 kcal/mol (D) 183.5 kcal/mol
8. Which of the following is an intensive property?
(A) Volume (B) Enthalpy
(C) Surface tension (D) Free energy
9. The P-T graph as given below was observed for a process of an ideal
gas, which of the following statement is true?

(A) w = +ve, DH = +ve (B) w = -ve, DH = -ve

(C) w = -ve, DH = +ve (D) w = +ve, DH = -ve
10. 2 moles of solid benzoic acid undergoes combustion at 300 K.
C6H5COOH(s) + 15/2 O2(g) -----> 7CO2(g) + 3 H2O (l).
The value of DH – DU value is

(A) – 1.247 kJ (B) – 2.494 kJ

(C) +2.494 kJ (D) +1.247 kJ
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