PHASE TEST – 1 (CLASS XI)

FIRST FIVE CHAPTER

DATE: 18 SEPTEMBER, 2020 TIME: 2 ½ HOURS

CLASS: XI MAX. MARKS: 70
ONE MARK QUESTIONS
Q1. The density (in g mL1) of 3.60 M sulphuric acid solution that is 29% (H2SO4) (molar mass = 98 g mol2) by
mass will be:
(a) 1.45 (b) 1.64 (c) 1.88 (d) 1.22
Q2. The amount of copper that can be obtained from 100 g of copper sulphate (CuSO4) is (At. mass of Cu=63.5
amu)
(a) 37.8 g (b) 39.8 g (c) 41.2 g (d) 42.4 g

Q3. The group having isoelectronic species is (JEE Main 2017)

(a) O2, F, Na, Mg2+ (b) O, F, Na+, Mg+ (c) O2, F, Na+, Mg2+ (d) O, F, Na, Mg2+

Q4. If the de-Broglie wavelength of a particle of mass m is 100 times its velocity, then its value in terms of its
mass (m) and Planck’s constant (h) is

1 m h 1 h m
(a) (b) 10 (c) (d) 10
10 h m 10 m k

Q5. Which of the following will have the most negative electron gain enthalpy and which the least negative?
(a) F, Cl (b) Cl, F (c) Cl, S (d) Cl, P

Q6. Which of the following order is correct?

(a) O2 < F < Na+ < Mg2+ increasing Zeffective

(b) Mg++ < Na+ < O < F increasing size

(c) O2 < F < Na+ < Mg2+ increasing I.E.

(d) O2 < F < Na+ < Mg+2 increasing E.A.

Q7. Reducing the pressure form 1.0 to 0.5 atm would change the number of molecules in one mole of ammonia
to
(a) 75% of initial value (b) 50% of initial value

(c) 25% of initial value (d) none of these

Q8. At STP, 0.50 mol H2 gas and 1.0 mol He gas

(a) have equal average kinetic energies (b) have equal molecular speeds

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(c) occupy equal volume (d) have equal effusion rates

 
Q9. The formal charge of the O atoms in the ion [  O  N  O  ] is:

(a) 2 (b) 1 (c) 0 (d) +1

Q10. Which of the following does not contain coordinate bond?

(a) BH4 (b) NH2 (c) CO32 (d) H3+O

Q11. Square planar structure is predicted for:

(a) ICl4, ClO3 (b) PCl4+, PCl6 (c) ICl4, PCl4+ (d) ICl4, XeF4

Q12. The dipole moments of CCl4, CHCl3 and CH3 are in the order
(a) CH4 = CCl4 < CHCl3 (b) CHCl3 < CH4 = CCl4 (c) CH4 < CCl4 < CHCl3 (d) CCl4 < CH4 < CHCl3
Q13. The electron gain enthalpy (in kJ/mol) of fluorine, chlorine, bromine and iodine respectively, are
(a) 333, 349, 325 and 296 (b) 349, 333, 325 and 296
(c) 296, 325, 333 and 349 (d) 333, 325, 349 and 296
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Q14. The number of orbitals associated with quantum numbers n = 5, m s = + is
2
(a) 25 (b) 11 (c) 15 (d) 50
Q15. An electron falls from n=2 to n=1 which of the following will produce shortest wavelength?
(a) H atom (b) He+ (c) Li 2+ (d) Be 3+
Q16. The first ionization energy (in kJ / mol) of Na, Mg, Al and Si respectively, are:
(a) 496, 577, 737, 786 (b) 786, 737, 577, 496 (c) 496, 577, 786, 737 (d) 496, 737, 577, 786
Q17. Container A and B have same gas. Pressure, volume and temperature of A are all twice that of B. Then the
ratio of the number of molecules of A and B are
(a) 1 : 2 (b) 2 : 1 (c) 1 : 4 (d) 4 : 1
Q18. Which atomic orbital is always involved in sigma bonding only?
(a) p (b) d (c) s (d) none
Q19. How many moles of Helium gas occupy 22.4 L at 0oC at 1 atm. Pressure?
(a) 0.11 (b) 0.90 (c) 1.0 (d) 1.11
Q20. Arrange the following ions in order of their increasing ionic radii : Li+, Mg2+, K+, Al3+.
Q21. Justify the presence of 18 elements in 5th period of periodic Table.
OR
Why is 4 s-orbital filled before 3d – orbital?
Q22. Why dipole moment of CO2 is zero?
Q23. Can we apply Heisenberg’s uncertainty principle to a stationary electron? Why or why not?
Q24. What is the number of radial nodes for 3p orbital.
Q25. What is the ratio of average kinetic energy of oxygen molecules and to that of ozone molecules at 27 oC.
TWO MARKS QUESTIONS
Q26. (a) Out of Fluorine and Chlorine which will have more electron gain enthalpy and why?

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(b) Which of the following transition will have minimum wavelength and why?
(i) n=2→ n= 4 (ii) n= 2 → n= ∞
Q27. How many moles and how many grams of sodium chlorine are present in 250 cc of 0.5 M NaCl solution?
Q28. Derive de Broglie equation. How do wavelengths the moving objects vary with their masses?
OR
Find the de-Broglie wavelength of an e (mass9.11031 kg) moving at 1% of light.
(h=6.62  1034 kgm2 s1).
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Q29. What is the hybridization of every carbon is following molecules. CH4, C2H4, CH 3 C  CH 3 , CH  CH.

Q30. A vessel of 120 ml, capacity contains a certain amount of gas at 35 oC and 1.2 bar pressure. The gas is
transferred to another vessel of volume 180 ml of 35oC. What would be its pressure.
Q31. The density of 5M solution of HCl is 1.10 gm/ml. Calculate its molality.
Q32. A photon of wavelength 4  107 m strikes a metal surface, the work function of the metal being 2.13 eV.
Calculate. (i) the energy of the photon in eV
(ii) the kinetic energy of the emitted photoelectron (1 eV = 1.602  1019 J)
THREE MARKS QUESTIONS
Q33. (i) State and explain Planck’s Quantum Theory.
(ii) List important postulates of kinetic theory of gases. Label faulty postulates also
Q34. The complete designation of the electrons in an atom is given with the help of four quantum numbers.
They specify the shell, sub-shell and the orbital in which a particular electron can be present.
(i) Which quantum number describes the electron spin?
(ii) What is the significance of this quantum number?
(iii) What might happen if two electrons in an orbital posses the same value of spin quantum number?
Q35. Give the hybridization and the shapes of the (any three) following molecules:
(a) NH3 (b) XeO3 c) NH4+ (c) ClF3
Q36. Define hydrogen bonding? What is the cause of hydrogen bonding? What requirement should a molecule
fulfill for formation of hydrogen bond? Name different types of hydrogen bonding.
Q37. 1 litre of O2 at STP is made to react with 3 litres of CO at STP, according to the reaction:2CO(g) + O2(g) 
2CO2(g) Calculate the mass of each substance found after the reaction. Which one is the limiting reactant?
Q38. (i) 35 ml of oxygen was collected at 6oC and 758 mm pressure. Calculate its volume at STP.
(ii) What is the value of compressibility factor ‘Z’ for: (a) Ideal gas (b)Real gas above Boyle’s
temperature.
Q39. Calculate the wavelength and energy of radiation emitted for the electronic transition from infinity to
stationary state of the hydrogen atom. [Given R = 1.09677  107 m1].
OR
The longest wavelength doublet absorption transition is observed at 589 and 589.6 nm. Calculate the
frequency of each transition and the energy difference between the two excited states.
FIVE MARKS QUESTIONS

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Q40. (a) What do you mean by Dipole moment. Give its significance.
(b) Although geometries of NH3 and H2O are distorted tetrahedral, bond angle in H2O is less than
NH3. Explain.
(c) Draw energy level diagram of N2 molecule. Out of N2 and N2+ which is more stable and why.
Q41. (a) Define molarity. Calculate the molarity of pure water. (d = 1.0 g/ml).
(b) What transition in the hydrogen atom spectrum would have the same wavelength as the Balmer
transition n = 4 to n = 2 of He+ spectrum (R = 109678 Cm1)
(c) Draw resonating structure of SO3, NO2