GT GROUP OF INSTITUTIONS

CHEMISTRY-Revision Worksheet

CLASS 11 Chemistry worksheet 12/02/2021

One Marks:

1. Boron exists as two stable isotopes; 10B(19%) and 11B(81%). Find out the average atomic weight of boron in
the periodic table

(a) 10.0 (b) 11.2 (c) 10.2 (d) 10.8

2. Maximum number of electrons in a subshell can be

(a) 4l + 2 (b) 4l – 2 (c) 2n2 (d) 2l + 1

(OR)
3p orbital has _____ radial nodes
(a) three (b) two (c) one (d) none

3. What are the conditions for gas like Carbon monoxide to obey the ideal gas laws?
(a) low temperature and low pressure (b) low temperature and high pressure
(c) high temperature and low pressure (d) high temperature and high pressure

4. ΔH for the reaction N2(g) + 3H2(g) ⇋ 2NH3(g)

(a) ΔU – 2RT (b) ΔU + 2RT (c) ΔU – RT (d) ΔH = RT
5. Find the equilibrium constant of the reaction
If the equilibrium constant for the following reactions are given

The equilibrium constant of the 2NH 3+2 𝑂2 ⇌ 2𝑁𝑂 + 3𝐻2𝑂, in terms of K1, K2 and K3 is:

(a) K2K3/K1
(b) K1K33/K2
(c) K2K33/K1
(d) K23K3/K1
(OR)
Solubility(s) of CaF2 in terms of its solubility product is given as a) s = (K sp)1/3

b) s = (K sp/2)1/3

c) s = (K sp/4 )1/3

d) s = (K sp/2)1/4

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6. The stability of +1 oxidation state increases in the sequence

a)Al<Ga <In <Tl b)Tl <In <Ga <Al

c) In<Tl <Ga<Al d)Ga<In <Al <Tl

7. The displacement of electrons in a multiple bond in the presence of attacking reagent is called
(a) Inductive effect (b) Electromeric effect

(c) Resonance (d) Hyper conjugation.

8. Which one is strongest acid among following options?

(a) CH2FCOOH
(b) CH2ClCOOH
(c) CHCl2COOH
(d) CHF2COOH
9. Isopropyl iodide is formed after reaction of propene with HI, this is due to
(a) more stable free radical
(b) homolysis
(c) more stable carbanion
(d) more stable carbocation
In the following questions (Q. No. 12 - 16) a statement of assertion followed by a statement of reason is
given. Choose the correct answer out of the following choices.
a) Assertion and reason both are correct statements and reason is correct explanation for assertion.

b) Assertion and reason both are correct statements but reason is not correct explanation for assertion.

c) Assertion is correct statement but reason is wrong statement.

d) Assertion is wrong statement but reason is correct statement.

10. Assertion (A) : Tin exhibits +2 and +4 oxidation states only and not +3 oxidation state.

Reason (R) : Inert pair effect of the s-orbital is responsible.

11. Assertion (A): Ionisation energy decreases on moving down the group

Reason (R) : Force of attraction between electrons and nucleus decreases on moving down the group.

12. Assertion (A): Li is used in photoelectric cells.

Reason(R): Cs has lower ionization energy than Li.

13. Assertion (A): Among alkali metals lithium salts exhibit the least electrical conductivity in aqueous
solutions.

Reason : Smaller the radius of the hydrated cation lower is the electrical conductance in aqueous
solutions.

14. Assertion (A): Large number of organic compounds are formed with long carbon-chain.

Reason (R) : Maximum catenation occurs in carbon atoms.

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 Two Marks:

15. On the basis of VSEPR theory discuss the shape of BF 3 and SF6
16. Explain VSEPR theory. Give various assumptions of VSEPR theory.
17. Give reason:
(a) Dipole moment of BeF2 and BF3 is zero.
18. What do you meant by dipole moment? Give its units.
19. Find the bond order of CO and NO using VBT theory.
20. Consider the following species : N3-, O2-, F–, Na+, Mg2+ and Al3+
(a) What is common in them?

(b) Arrange them in the order of increasing ionic radii.

21. What type of bond exist between H 2O, HF, NH3, C2H5OH ? Discuss its Nature.
22. How can the production of di hydrogen obtained from ‘coal gasification’ be increased?
23. A gaseous mixture contains 56g of N2, 44g of CO2 and 16g of CH4. The total pressure of mixture is
720 mm of Hg. What is the partial pressure of the Methane?
24. Assign oxidation numbers to the underlined elements in each of the following species
a) NaH2PO4 b) H2S2O7 (c) KAl(SO4)2.12 H2O d)Br3O8

25. . An alkene having molecular formula C 4H8 A contains three C−C, eight C−H σ bonds and one C−C π
bond. A on ozonolysis gives two moles of an aldehyde of molar mass 44 u. Write IUPAC name of A.

26. Deduce the ideal gas equation.

27. Write the electronic configuration of

(i) Mn4+ and Cr2+. Mention the number of unpaired electrons in each case.

Three Marks:

28. Calculate the heat of combustion of ethylene gas to form CO2 and H2O at 298K and
1atm pressure. The heats of formation of CO 2, H2O and C2H4 are -393.7,-241.8 and 52.3 kj mol-1
C2H4 + 3O2———>2CO2 + 2H2O

29. Explain open,Closed and isolated system with examples.

30. Distinguish between hard water and soft water

31. Write the structure of the following IUPAC nomenclature of the compound?

i) 2,3-Dimethyl-4-oxo-pent-2-en-1-oic acid ii) 3,3-

Dimethyl-1-Cyclohexanol

32 .a) Write the general combustion equation of any alkane?

b) Write any two reaction for the preparation of alkane?

33. Explain Born- Haber cycle with diagram.

34. Relationship between Cp and Cv.

Five Marks:

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35. (i) In what ways lithium shows similarities to magnesium in its chemical behaviour?

(ii) Beryllium and magnesium do not give color to flame whereas other alkaline earth metals do so. Why?

36. Calculate the heat of combustion of ethylene gas to form CO2 and H2O at 298K and
1atm pressure. The heats of formation of CO 2, H2O and C2H4 are -393.7,-241.8 and 52.3 kj mol-1
C2H4 + 3O2———>2CO2 + 2H2O

37. Two gases A & B having the same volume diffuses through a porous portion in 20 and 10 seconds respectively
molecular mass of A is 49g, what will be the molecular mass of B ?

38. Explain open,Closed and isolated system with examples.

39. Distinguish between hard water and soft water

40. (i) What are the demerits of mendeleev’s periodic table?

(ii)Why does hydrogen occupy unique position in the periodic table?

(iii) How much copper can be obtained from 100g of Copper Sulphate?

41. (i) Write Friedel-crafts acylation reaction ? Explain its mechanism by using benzene and acetyl chloride as an

example ?

(ii) Addition of HBr to propene yields 2-bromopropane, while in the presence of benzoyl peroxide, the same

reaction yields 1-bromopropane. Explain and give mechanism.

42. (i) Calculate the volume occupied by 8.8 g of CO 2 at 31.1OC and 1 bar pressure. (R = 0.083

bar L K-1 mol−1)

(ii) The number of atoms present in 4.25g of NH 3 is?

(iii) What is the expression for Ksp of Ag 2CrO4?

43. Depict the galvanic cell in which the reaction Zn (s) + 2Ag+ (aq) ----------  Zn2+ (aq) + 2Ag (s) takes place. Further
show:
(i) Which of the electrode is negatively charged.
(ii) the carries of the current in the cell, and
(iii) individual reaction at each electrode.
44. Permanganate ion reacts with bromide ion in basic medium to give manganese dioxide and bromate ion. Write
the balanced ionic equation for the reaction.

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