NATIONAL COACHING CENTRE Final-Term Paper

(Serving Education since 1992) XI CHEMISTRY

House # 154, P.I.B. Colony, Karachi – 2021
Tel: 34928070, 34928085
Marks: 85 Sir Inam Ul Haq Jazbi Time: 2 hours
Instructions
Attempt 7 questions in all ---- 5 from Section B, 1 from Section C and the compulsory question No. 1 (Section
A) of MCQs. Write down proper numbering according to question paper. Do not copy questions.

Section-A…MCQs (Compulsory Question) (43 Marks)

Q.1 Select the most suitable answer from the given ones in each question:
1. Rain drops have spherical shape because a sphere has the least
(A) Length (B) Surface to volume ratio (C) Volume (D) Area
2. The quantities relationship between the substances according to balance equation describes:
(A) Reversible reaction (B) Percentage compound (C) Limiting reactant (D) Stoichiometry
3. How many significant figures are there in 87006.0?
(A) 5 (B) 4 (C) 2 (D) 6
4. The number of orbitals in a shell can be determined by the formula
(A) (2l+1) (B) 2(2l+1) (C) n2 (D) 2n2

5. S2ˉ (Z = 16) is isoelectronic with

+
(A) 11Na1+ (B) 9F1ˉ (C) 19K
1+
(D) 20Ca

6. The most of the radiations coming out from pitch blend were
(A) Electron (B) Proton (C) X-rays (D) Neutron

7. How many sigma and pi bonds are present in ethene (C2H4) molecule respectively?
(A) 5 and 1 (B) 2 and 2 (C) 3 and 2 (D) 2 and 3

8. Which molecule has linear structure?

(A) CH4 (B) C2H2 (C) BF3 (D) NH3
9. Which of the following is intensive property of system?
(A) Energy (B) Density (C) Volume (D) Entropy

10. The product of pressure and volume, PV has the dimension

(A) Pressure (B) Volume (C) Energy (D) Temperature

11. For the reaction 2NH3 ⇌ N2 + 3H2 the relationship between Kc and Kp
(A) Kc > Kp (B) Kc < Kp (C) Kp = Kc (D) Kp = Kc/2
12. Which one of the following solution is basic?
(A) Na2CO3 (B) NH4Cl (C) KCl (D) NaCl

13. The oxidation number of Cr in

(A) +3 (B) +6 (C) +12 (D) -2

14. If the rate of reaction is independent of concentration of the reactant the reaction is of
(A) Zero order (B) 1st order (C) 2nd order (D) 3rd order
15. The branch of chemistry which deals with the study of reaction rates is known as
(A) Photochemistry (B) Chemical kinetics (C) Thermodynamics (D) Electrochemistry
16. The penetration power of β-particle in air as compare to α-particle is
(A) 100 times (B) 2 times (C) 1000 times (D) 200 times

17. A gas at zero kelvin:

(A) Is super cooled (B) freezes (C) liquefies (D) has zero volume

18. The molecular formula of vitamin C is C6H8O6, its Empirical formula is:
(A) C2H3O2 (B) C3H4O3 (C) CH2O (D) CHO2
19. E + PV is called:
(A) Entropy (B) Enthalpy (C) Free Energy (D) Internal Energy

Course Instructor: Sir Inam Ul Haq Jazbi, Solution by: Eshaal Fatima Haq
20. The quantum number values for 3p orbitals are:
(A) n=2, l=1 (B) n=3, l=0 (C) n=2, l=2 (D) n=3, l=1
21. Orbitals having same energy are called:
(A) Hybrid orbitals (B) Valence orbitals (C) Degenerate orbitals (D) Bonding orbitals

22. The net enthalpy change in a chemical reaction is same, whether it is brought about in two or more different
ways in one or several steps. It is known as:
(A) Henry’s Law (B) Joule’s Principle (C) Hess’s Law (D) Dalton’s law
23. Which of the following compound does not contain hydrogen bonding?
(A) CH4 (B) H2O (C) NH3 (D) HF
24. Which of the following molecules has the largest bond angle?
(A) H2O (B) NH3 (C) CH4 (D) BeCl2
25. The e ⁄m value of electron is :
(A) 1.758x108 C/g (B) 0.000550 C/g (C) 1.008 C/g (D) 9.11x10-28 C
26. The reaction which involves both oxidation and reduction is called:
(A) Addition reaction (B) Substitution reaction (C) Elimination reaction (D) Redox reaction
27. Heat absorbed or released during a chemical process at constant pressure is equal to:
(A) ∆E (B) ∆H (C) q (D) w
28. Which of the following molecules has two pi bonds?
(A) CH4 (B) C2H4 (C) N2 (D) O2
29. No two electrons in an atom can have a same set of four quantum number is called
(A) Newton’s first law (B) Hund’s Rule (C) Pauli Exclusion Principle (D) Aufbau rule
30. Alpha rays are
(A) Neutron (B) Helium Nuclei (C) Electron (D) Proton
31. The surface tension of liquid is independent of:
(A) Temperature (B) Nature of Liquid (C) Intermolecular forces (D) Amount of Liquid
32. The tendency of liquid to cling together is called:
(A) Surface Tension (B) Cohesion (C) Adhesion (D) Viscosity
33. The No of waves travel per one centimeter distance is :
(A) wavelength (B) Wave number (C) wave function (D) frequency
34. The total number of ions in CaCl2 is
(A) 6.02x1023 (B) 12.04x1023 (C) 18.06x1023 (D) 24.08x1023
35. The oxidation number of Ni in Ni(CO)4 is
(A) +4 (B) 0 (C) -2 (D) +2
36. The incompleteness in Bohr’s atomic theory is explained by
(A)Rutherford’s model (B) Uncertainty principle (C) de-Broglie’s concept (D) Quantum theory
37. Which of the following compounds has/have sp2 hybridization?
(A) CO2 (B) CH4 (C) C2H4 (D) C2H2
38. In which compound, nitrogen is present in LEAST oxidation state?
(A) N2H4 (B) NH4+ (C) NH3 (D) HNO3
39. If the volume of gas increases twice on increasing temperature 4 times, pressure will be
(A) Increased twice (B) Increased 4 times (C) Decreased by one half (D) Remains same
40. This ion has greatest degree of hydration
(A) Al3+ (B) Mg2+ (C) K+ (D) Na+
41. Which of the following transformations described below take place with the absorption of heat?
(A) Hydration (B) Fusion (C) Condensation (D) Vaporization
42. Which one of the following is NOT an iso electronic pair?
(A) Ca2+, K (B) Na+, Ne (C) K+, Cl- (D) O2-, Al3+
43. Compound composed of C and H in the ratio of 1:1 with molecular mass 78 amu, its molecular formula is:
(A) C6H6 (B) C2H6 (C) C2H2 (D) C2H4

Course Instructor: Sir Inam Ul Haq Jazbi, Solution by: Eshaal Fatima Haq
 NATIONAL COACHING CENTRE Final-Term Paper
(Serving Education since 1992) XI CHEMISTRY
House # 154, P.I.B. Colony, Karachi Tel: 2021
34928070, 34928085
Marks: 85 Sir Inam Ul Haq Jazbi Time: 2 hours
Section-B (Short-Answer Questions) 5 Questions 5 marks each (25 marks)
Q2 (i) Define any 5 of the following:
Enthalpy, Chemical equilibrium, Gay-Lussac Law, molar volume, significant figures, stoichiometry, bond
length, macroscopic properties, debye, unit cell, Radioactivity, standard heat of formation, anisotropy,
activation energy, bond energy, internal energy and lattice energy
(ii) Write down 2 differences between any TWO of the following:
(i) Crystalline and amorphous solid (iii) -bond and -bond (iii) VBT and MOT
(iv) BMO and AMO (v) Continuous and line spectrum (vi) alpha and beta rays
(iii) Define Dipole moment. Give its units with relations. Why dipole moment of CO2 and CCl4 is zero.
(iv) Find the oxidation number of the following: (Write only value of oxidation numbers)
(i). Cl in Ca(ClO4)2 (+7) (ii). P in K2MgP4O7 (+2.5)
2-
(iii). S in S2O7 (+6) (iv). Fe in K4[Fe(CN)6] (+2)
(v) 1.367 g of an organic compound containing C, H and O was combusted in a stream of air yield 3.002g CO2
and 1.64g H2O. What is the empirical formula?
OR
280 g of NH3 are allowed to react with 820 g of O2 according to following equation. Calculate number of
moles, number of molecules, mass in gram and volume in dm3 of nitric oxide (NO) evolved at STP.
4NH3 + 5O2  4NO + 6H2O
(vi) Write down the electronic configuration for ground sates of each of the following.
Cr (Z = 24), Cu (Z = 29), Fe3+ (Z = 26) * N3- (Z = 7)
(vii) 200 cm3 of gas A diffuses in the same time as 300 cm3 of gas B. If the molecular mass of gas B is 32;
calculate the molecular mass of gas A.
OR
The rate of diffusion of gas A & B are 15 dm3/sec & 10 dm3/sec respectively. If molecular mass of gas A is 17
amu, find the molecular mass of gas B.
(viii) What is hydrogen bond? How does it effect on physical properties of a molecule?
(ix) Give 2 differences between hydration & hydrolysis. Explain why aqueous solution of ammonium chloride is
acidic while aqueous solution of sodium acetate is alkaline in nature.
(x) Do as directed (any 4 of the following)
(a) Calculate pH of 10-5 M KOH solution
(b) Calculate oxidation number of B in B4O72- and Cl in HClO4
(c) Convert 4.2 cal into joule.
(d) Calculate wave number of an electron when it jumps from orbit 5 to orbit 2.
(e) Simplify according to rule of significant figures.
8.751 x 2.96
3.4
(f) Arrange the following energy levels in ascending order using (n+l) rule:
5d, 3s, 4f, 7s, 6p, 2p
Q(v) 1.367 g of an organic compound containing C, H and O was combusted in a stream of air yield 3.002g CO 2
and 1.64g H2O. What is the empirical formula?
Element C H O
Atomic mass 12 1 16
Mass of Elements 12 2 1.367 – (0.819 +
x Mass of CO2 x Mass of H2O
Molar Mass of element 44 18 0.182) = 0.366 g
x Mass of comp. 12
Molar Mass of compound x 3.002  0.819 g 2
x 1.64  0.182 g
44 18
% of Elements Mass of element 0.819 0.182 0.366
x 100 x 100  59.91 x 100  13.31 x 100  26.77
Mass of compound 1.367 1.367 1.367
Relative number of atoms (Mole ratio) 59.91 13.31 26.77
 4.992  13.31  1.67
MR = %/Ar 12 1 16
Simplest atomic ratio 4.992 13.31 1.67
 2.98  3  7.97  8  1
SAR = MR/Least MR 1.67 1.67 1.67
Ratio of atoms/ Simplest integer ratio 3 8 1
Empirical formula C3H8O

Course Instructor: Sir Inam Ul Haq Jazbi, Solution by: Eshaal Fatima Haq
Q(v). 280 g of NH3 are allowed to react with 820 g of O2 according to following equation. Calculate number of moles,
number of molecules, mass in gram and volume in dm3 of nitric oxide (NO) evolved at STP.
4NH3 + 5O2  4NO + 6H2O
Solution
(I) Conversion of mass of each reactant into moles
Mass of NH3 = 280 g Mass in g
No. of moles of substance = molar mass
Mass of O2 = 820 g
Molar mass of NH3 = 14 + 3 = 17 g/mole No. of moles (n) of NH3 = 280 = 16.47 mole
Molar mass of O2 = 16 + 16 = 32 g/mole 17

No. of moles (n) of O2 = 820 = 25.625 mole

32

(II) Calculation of molar amount of product from molar amount of each reactant
4NH 3 + 5O2  4NO + 6H2O
4 mole 5 mole  4 mole
16.47 mol 25.625 mol  mol=?

4 moles of NH3 produces 4 moles of NO 5 moles of O2 produces 4 moles of NO

4 4
1 mole of NH3 produces 4 mole of NO 1 mole of O2 produces 5 mole of NO

16.43 mol mol of NH3 produces = 4 x 16.47 mole of NO 25.625 mol of O2 produces 
4
x 25.625 mole of NO
4 5
= 16.47 mol NO = 20.5 mol NO
(III) Determination of Limiting Reactant
From above calculation, it is clear that least amount of product (NO) is produced by NH3 so NH3 is a limiting reactant and
amount of product is calculated from its amount.
(IV) Conversion of Molar Amount of Product into Number of molecules
Number of molecules = n x NA  16.47 x 6.02 x 1023 = 9.91 x 1024 molecules of NO
(V) Conversion of Molar Amount of Product into Gram
Molar amount of NO = 1.869 moles
Molecular mass of NO = 14 + 16 = 30 g/mole
Amount of NO in g = moles x molar mass  16.47 x 30 = 491.4 g NO
(VI) Conversion of Molar Amount of Product into Volume
Volume of gas in dm3 = n x molar volume  16.47 x 22.4 = 368.928 dm3 NO

Q(vii).200 cm3 of gas A diffuses in the same time as 300 cm3 of gas B. If the molecular mass of gas B is 32; calculate the
molecular mass of gas A.
Solution
According to Graham’s Law:
r1 M2 V1 / t 1 M2 V V1 t 2 M2 V1 M2 VA MB
    x  
V2 / t 2 M1
 r =
t 1 V2 M1   (  t1 = t 2 ) tB MA
r2 M1 t V2 M1
Here;
t1 = t 2
3
V1 = VA = 200 cm
3
V2 = VB = 300 cm
M1 = M A = ?
M2 = MB = 32 amu

2
200 32 32  32  32 32 MA = 73.56 a.m.u
 0.66   (0.66) = 2
  0.435 = MA MA = 0.435
300 MA  MA 
 MA 

Q(vi).Write down the electronic configuration for ground sates of each of the following.
2 2 6 2 6 5 1
Cr (Z = 24) e = Z = 24 eˉ = 1s , 2s 2p , 3s 3p , 3d , 4s
2 2 6 2 6 10 1
Cu (Z = 29)e = Z = 29 eˉ = 1s , 2s 2p , 3s 3p , 3d , 4s
3+ 2 2 6 2 6 5 0
Fe (Z = 26)e = Z – charge = 26-3 = 23eˉ = 1s , 2s 2p , 3s 3p , 3d , 4s
3- 2 2 6
N (Z = 7)e = Z + charge = 7 + 3 = 10eˉ = 1s , 2s 2p

Course Instructor: Sir Inam Ul Haq Jazbi, Solution by: Eshaal Fatima Haq
Q2 (x) Do as directed (any 4 of the following)
(a) Calculate pH of 10-5 M KOH solution
(b) Calculate oxidation number of B in B4O72- and Cl in HClO4
(c) Convert 4.2 cal into joule.
(d) Calculate wave number of an electron when it jumps from orbit 5 to orbit 2.
(e) Simplify according to rule of significant figures.
8.751 x 2.96
3.4
(f) Arrange the following energy levels in ascending order using (n+l) rule:
5d, 3s, 4f, 7s, 6p, 2p
5
(a) Calculate pH of 10¯ M KOH solution
Solution
5
[KOH] = [OH¯] = 10¯ M
= –log [OH¯]  pOH = –log (10 ) = 5
–1
pOH
Now,
pH + POH =14 pH  pH = 14 – pOH  pH = 14 – 5  pH = 9

(b) Calculate oxidation number of B in B4O72¯ and Cl in HClO4

Solution

(c) Convert 4.2 cal into joule.

Solution
1 cal = 4.2 J
4.2 cal = 4.2 x 4.2 = 17.64 J

(d) Calculate wave number of an electron when it jumps from orbit 5 to orbit 2.
Solution
1 1 
  RH  2  2 
 n1 n2 
Here;
7 -1
RH = 1.0968553 x 10 m
n1 = 2
n2 = 5
1 1  1 1   25  4 
  1.0968553 x 107 m1  2  2     1.0968553 x 107 m1   1
    1.0968553 x 10 m 
7

2 5  4 25   100 

  1.0968553 x 107 m1 0.21     0.230339613 x 107 m1    2.30339613 x 106 m1

(e) Simplify according to rule of significant figures.

Solution
8.751( 4SF) x 2.96 (3SF)
 7.617647  7.6 (rounded off to 2 SF to Least Pr ecise factor )
3.4 (2SF, Least Pr ecise factor )

(f) Arrange the following energy levels in ascending order using (n+l) rule:
5d, 3s, 4f, 7s, 6p, 2p
Solution
5d 3s 4f 7s 6p 2p
(n+l) value 5+2=7 3+0=3 4+3=7 7+0=7 6+1=7 2+1=3
Ascending order 2p (3) 3s (3) 4f (7) 5d (7) 6p (7) 7s (7)
‘n’ value 2 3 4 5 6 7

Q(vii). The rate of diffusion of gas A & B are 15 dm3/sec & 10 dm3/sec respectively. If molecular mass of gas A is 17
amu, find the molecular mass of gas B.
Solution
r1 = rA = 15
r2 = rB = 10
M1 = MA = 17 amu
M2 = M B = ?
According to Graham’s Law:
2
r1 M2 rA MB 15 MB 15 
2
 MB  MB
 =>  =>  =>     => 2.25   MB = 2.25 x 17
r2 M1 rB MA 10 17 10   17  17

MB = 38.25 a.m.u

Course Instructor: Sir Inam Ul Haq Jazbi, Solution by: Eshaal Fatima Haq
Q3(b) Calculate the volume of Oxygen gas at 17°C and 800 torr that may be obtained by complete decomposition
of 50.5 g of KNO3. (8) 2KNO3  2KNO2 + O2
Solution
Calculation of moles of KNO3
Mass 100 50.5
Number of moles     0.5 mol
Molar mass 39  14  48 101

Calculation of Volume of O2
n = 0.25 mole PV = nRT
T = 17°C  17 + 273 = 290 K [ K = °C + 273] nRT
V
P
P = 800 torr  800 = 1.05 atm [ 1 atm = 760 torr] V 
0.25 mole x 0.0821atm  dm3  mole1  K 1 x 290 K
760 1.05 atm
3 –1 –1
R = 0.0821 atm-dm -mole -K V = 5.95 dm3
V = ?

Q4(b) Calculate heat of formation of naphthalene (C10H8) from the following data:
(i) C(s) + O2(g)  CO2 (g) H = –394 kJ/mol
(ii) H2(g) + 1 O
2 2(g)  H O
2 (l) H = –286 kJ/mol
(iii) C10H8(l) + 12O2(g)  10CO2(g) + 4H2O(l) H = –5153 kJ/mol
(iv) 10C(s) + 4H2(g)  C10H8(l) Hf = ?
Solution
1. Because the target equation has 10 mole of C as reactant we multiply equation # 1 and its H by 10.
2. Because the target equation has 4 mole of H2 as a reactant, we multiply equation # 2 and its H by 4.
3. Because the target equation has C10H8 as a product, we turn the equation # 3 around; the sign of H is therefore changed.
4. We then add the three equations with their enthalpy changes in accordance with Hess’s law.
Operation
(i) (C(s) + O2(g)  CO2(g) H = – 394 kJ/mole ) x 10
(ii) (H2(g) + ½O2(g)  H2O(g) H = – 286 kJ/mole ) x 4
(iii) (C10H8(l) + 12O2  10CO2(g) + 4H2O(g) H = – 5153 kJ/mole )FLIP

10C + 10O2  10CO2 H = – 3940 kJ/mole

4H2 + 2O2  4H2O H = – 1144 kJ/mole
10CO2 + 4H2O  C10H8(l) + 12O2 H = + 5153 kJ/mole
10C + 4H2  C10H8(l) H = + 69 kJ/mole

Q5(b) Calculate the number of moles of Cl2 produced at equilibrium when one mole of PCl5 is heated at 250 in vessel
having a capacity of 10 dm3 (Kc = 0.041) (6) PCl5 ⇌ PCl3 + Cl2

Course Instructor: Sir Inam Ul Haq Jazbi, Solution by: Eshaal Fatima Haq
 Section-C (Long-Answer Questions) 1 Questions (17 marks)
Q3 (a) What are the Bohr’s stationary states and Quantization of angular momentum? Derive the energy
expression of nth stationary state of hydrogen atom? (2 + 7 = 9)
OR
Write the postulates of electron pair repulsion theory. Draw the shape of the H2O, BF3 and NH3 on the
basis of electron pair repulsion theory. (3 + 6 = 9)
(b) Calculate the volume of Oxygen gas at 17°C and 800 torr that may be obtained by complete decomposition
of 50.5 g of KNO3. (8) 2KNO3  2KNO2 + O2
OR
Derive pressure volume work. In a certain process, 500 J of work is done on a system which gives off 200 J
of heat. What is the value of change in Internal energy for the process? (4 + 4 = 8)

Q4 (a) Derive Kc expression for a more general reversible reaction. Predict the effect of increase in temperature
and pressure on the following system at equilibrium state (only predict the direction) (5 + 4 = 9)
(i) N2 + 3H2 ⇌ 2NH3 + Heat (ii) N2 + O2 + Heat ⇌ 2NO
OR
Calculate heat of formation of naphthalene (C10H8) from the following data:
(i) C(s) + O2(g)  CO2 (g) H = –394 kJ/mol
(ii) H2(g) + 1 O
2 2(g)  H O
2 (l) H = –286 kJ/mol
(iii) C10H8(l) + 12O2(g)  10CO2(g) + 4H2O(l) H = –5153 kJ/mol
(iv) 10C(s) + 4H2(g)  C10H8(l) Hf = ?

(b) Balance the following equations by Ion electron method: (No description is required) (8)
Cl2 + OH1-  Cl-1 + ClO3- + H2O (Basic)
MnO41- + SO32-  MnO2 + SO42- (Acidic)

Q5 (a) What are redox reaction and oxidation number? State 7 rules of oxidation number with examples. (2 + 7 =
9)
OR
Explain 6 points of Arrhenius theory of ionization in detail. Write the factors affecting hydration ability of
ions. (6 + 2 = 8)
(b) What are cathode rays? How are they produced? Give the following properties of cathode rays
(i) Mass (ii) e/m ratio, (iii) material particle in nature (1 + 1 + 6 = 8)
OR
Calculate the number of moles of Cl2 produced at equilibrium when one mole of PCl5 is heated at 250 in
vessel having a capacity of 10 dm3 (Kc = 0.041) (6) PCl5 ⇌ PCl3 + Cl2

Q6 (a) State and explain Graham’s law. Calculate SI value and calorific value of molar gas constant, R. (5+4=9)
OR
What is atomic orbital hybridization? Explain sp hybridization with one example. Draw the hybrid orbital
structure of ethene. (1 + 4 + 4 = 9)
(b) State VESPER theory. Write the postulates of VESPER theory. Explain the shape of the NH3 and H2O on the
basis of electron pair repulsion theory

Q4 (b) Balance the following equations by Ion electron method: (No description is required) (8)
Cl2 + OH1-  Cl-1 + ClO3- + H2O (Basic)
MnO41- + SO32-  MnO2 + SO42- (Acidic)

Course Instructor: Sir Inam Ul Haq Jazbi, Solution by: Eshaal Fatima Haq
 MnO41- + SO32-  MnO2 + SO42- (Acidic)
Solution
Splitting of Ionic Equation into two Half-Reactions
After writing oxidation number of those species that undergo any change, split ionic equation into two half reactions:
7 4 –
(I) Mn O4  Mn O2 (Reduction; Mn from +7 to +4; 3e gain)
4 6 –
(II) S O32   S O24  (Oxidation; N from +4 to +6; 2e loss)

Balancing of Equation No. I

7
To balance O, add 2H2O on L.H.S. in eq # I Mn O 4  Mn O2 + 2H2O
+ 7 +
To balance H, add 3H on L.H.S Mn O 4 + 4H  Mn O2 + 2H2O
– 7 + –
To balance charge, add 3e on L.H.S Mn O 4 + 4H + 3e  Mn O2 + 2H2O

Balancing of Equation No. II

4
To balance O, add H2O on L.H.S. in eq # II: S O 32 + H2O  S O 24
+ 4 +
To balance H, add 2H on R.H.S: S O 32 + H2O  S O 24 + 2H
– 4 + –
To balance charge, add 2e on R.H.S: S O 32 + H2O  S O 24 + 2H + 2e
Overall Redox Reaction
7 + –
2( Mn O 4 + 4H + 3e  Mn O2 + 2H2O)
4 + –
3( S O 32 + H2O  S O 24 + 2H + 2e )
7 4 +
2 Mn O 4 + 3 S O 32 + 2H  2 Mn O 2 + 3S O 24 + 2H2O (-6 = -6)

Course Instructor: Sir Inam Ul Haq Jazbi, Solution by: Eshaal Fatima Haq