SUBJECT : CHEMISTRY

TOPIC : CHEMICAL BONDING

Time : 1 hr. M.M. : 120

Instruction :
A. General %
1. The test paper is of 1 hour duration.
2. The Test Paper consists of 30 questions and each questions carries 4 Marks.
B. Test Paper Format and its Marking Scheme:
Section contains 30 multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONE is correct. For each question in Section, you will be awarded 4 marks if
you give the corresponding to the correct answer and zero mark if no given answers. In all other
cases, minus one (–1) mark will be awarded.
Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27,
Si = 28, P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65,
As = 75, Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207, Os = 190]

Straight Objective Type

This section contains 30 questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out
of which ONLY ONE is correct. Each question carry (4, – 1) Marks.

1. The nitrogen atoms in NH3, NH2– and NH4+ are all surrounded by eight electrons. When these species
are arranged in increasing order of H–N–H bond angle, correct order is –
(A) NH3, NH2–, NH4+ (B) NH4+, NH2–, NH3 (C) NH3, NH4+ NH2– (D) NH2–, NH3, NH4+

2. Hybridisation of the nitrogen atom and geometry around nitrogen atom in pyridine is –

N
(A) sp3, pyramidal (B) sp2, planar trigonal C) sp2, linear (D) sp3, tetrahedral

3. The structure and hybridisation of Si(CH3)4 is :

(A) bent, sp (B) trigonal, sp2 (C) octahedral, sp3d (D) tetrahedral, sp3

4. In the conversion of N2 into N2+ the electron will be lost from which of the following molecular orbitals ?
(A) *2PZ (B)  2 PZ (C)  2 PX (D) *2PX

5. A molecule which contain same number of and  bonds is/are :

(A) HNO2 (B) HCN (C) (CN)2 (D) HCCH

6. Which among the following is isostructural with XeF4 ?

(A) ICl3 (B) PCl4+ (C) ICl4– (D) XeO3

7. The bond orders in BN, BO and CO respectively are :

(A) 2, 3, 5/2 (B) 2, 5/2, 2 (C) 2, 5/2, 3 (D) 5/2, 2, 3

8. Which is a pair of paramagnetic species ?

(A) KO2, NO2 (B) K2O2, KO2 (C) K2O, NO2 (D) NO2, N2O2

9. The hybridisation of the central atom will change when -

–
(A) NH3 combines with H+ (B) H3BO3 combines with OH
–
(C) NH3 form NH2 (D) H2O combines with H+

10. Which of the following has greater bond length?

(A) P–O (B) S–O (C) Cl–O (D) O=O
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11. Which of the following statements is wrong regarding ionic compounds –
(A) These are generally in solid state at room temperature
(B) The force of attraction between ions is non directional
(C) Ionic compounds soluble in all solvents
(D) They conduct electricity in molten and solution state

12. The maximum covalency is equal to -

(A) The number of unpaired p-electrons
(B) The number of paired d-electrons
(C) The number of unpaired s-and p-electrons
(D) The actual number of s-and p-electrons in the outermost shell

13. NH3 and BF3 combine readily because of the formation of -

(A) a covalent bond (B) a hydrogen bond
(C) a co-ordinate bond (D) an ionic bond

14. Which can not be explained by VBT -

(A) Overlapping (B) Bond formation
(C) Paramagnetic nature of oxygen (D) Shapes of molecules.

15. -bond can not be formed between -

(A) C–C (B) O–O (C) N–N (D) hybrid orbitals

16. Match the items under list (1) with items under list (2) select the correct answers from the sets (a),
(b),(c) and (d) -
List (1) molecule List (2) shape
(a) PCl5 (i) V-shaped
(b) F2O (ii) Triangular planar
(c) BCl3 (iii) Trigonal bipyramidal
(d) NH3 (iv) Trigonal pyramidal
(v) Tetrahedral
(A) a - i, b - v, c - iv, d - iii (B) a -ii, b -iii, c - i , d - ii
(C) a - iv , b - iii, c - ii, d - v (D) a - iii, b - i, c - ii, d - iv

17. T-type of shape is exhibited by the molecule

(A) ICl3 (B) CHCl3 (C) CCl4 (D) PCl5

18. In an antibonding molecular orbital, electron density is minimum :

(A) Around one atom of the molecule
(B) Between the two nuclei of the molecule
(C) At the region away from the nuclei of the molecule
(D) at no place

19. Which of the following is incorrect for tetrathionic acid ?

(A) It has three S-S bonds. (B) Its basicity is 2.
(C) It contains S atom in single oxidation state (D) All are correct.

20. N2 and O2 are converted to monocations N 2 and O 2 respectively, which is wrong statement :
(A) In N 2 , the NN bond weakens (B) In O 2 , the OO bond order increases .
(C) In O 2 , the paramagnetism decreases (D) N 2 becomes diamagnetic.

21. The order of strength of H-bonds is :

(A) ClH – Cl > NH – N > OH – O > FH – F (B) ClH – Cl < NH – N < OH – O < FH – F
(C) ClH – Cl < NH – N > OH – O > FH – F (D) ClH – Cl < NH – N < OH – O > FH – F

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22. Which is steam volatile -
(A) o-nitrophenol (B) Aniline (C) Glycerol (D) p-nitrophenol

23. Every H2O molecule is surrounded by how many H2O molecule :

(A) 2 (B) 3 (C) 4 (D) 6

24. Which has maximum dipole moment ?

Cl Cl Cl
Cl Cl Cl Cl Cl
(A) (B) (C) (D)

Cl Cl Cl

25. Among LiCl, BeCl2, BCl3 and CCl4, the covalent bond character follows the order :
(A) LiCl < BeCl2 > BCl3 > CCl4 (B) LiCl > BeCl2 < BCl3 < CCl4
(C) LiCl < BeCl2 < BCl3 < CCl4 (D) LiCl > BeCl2 > BCl3 > CCl4

26. How many  and  bonds are there in the molecule of tetracyanoethylene :
NC CN
C=C
NC CN
(A) Nine  and nine  (B) five  and nine   (C) Nine  and seven  (D) Five  and eight 

27. The hybridization state of B in B2H6 is :

(A) sp (B) sp2 (C) sp3 (D) sp3d

28. The observed dipole - moment of HCl molecule is 1.03D. If H—Cl bond distance is 1.275 Å and
electronic charge is 4.8 x 10–10 esu. What is the percent polarity of HCl –
(A) 1.275 Å × 1.03 (B) 4.8  10 10  1.275  10 8
1.03

1.03  100  10 18 4.8  10 10

(C) (D) ×1
10 8
4.8  10  1.275  10 1.03

29. The structure of Br3¯ involves hybridisation of the type :

(A) sp3d (B) sp3d2 (C) dsp3 (D) d2sp3

30. Which of the following statement is/are not correct-

(A) CH3+ shows sp2–hybridisation whereas CH3¯ shows sp3-hybridisation.
(B) NH4+ has a regular tetrahedral geometry.
(C) sp2-hybridised orbitals have equal s and p character.
(D) Hybridised orbitals always form -bonds.

TOPIC : CHEMICAL BONDING

OBJECTIVE RESPONSE SHEET (ORS)
Que. 1 2 3 4 5 6 7 8 9 10
Ans.
Que. 11 12 13 14 15 16 17 18 19 20
Ans.
Que. 21 22 23 24 25 26 27 28 29 30
Ans.

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