TOPIC WISE REVIEW TEST-II -CB & S-BLOCK

SINGLE CORRECT CHOICE TYPE

1. Select the correct statement.
(A) If molecule has any polar bond then it is always polar
(B) Solubility of noble gases increases in water down the group when their size increases because London
dispersion force increases
(C) First ionisation energy of Al is greater than the gallium.
(D) XeF5 has distorted octahedral geometry.
2. Which is the correct order for different forces.
(A) ED (dipole-induced dipole interaction ) > EK(Dipole-dipole interaction) > EL (London force)
(B) EK(Dipole-dipole interaction) > ED (dipole-induced dipole interaction ) > EL (London force)
(C) ED (dipole-induced dipole interaction ) > EL (London force) > EK(Dipole-dipole interaction)
(D) All forces are equally strong.
3. The correct order of strength of H-bonding is
(A) AH ........ A < A1H ....... A1 < BH ....... B < B1H ...... B1
(B) A1H ........ A1 > AH ....... A < B1H ....... B1 < BH ...... B
(C) AH ........ A > BH ....... B > A1H ....... A1 > B1H ...... B1
(D) A1H ........ A1 > B1H ....... B1 > BH ....... B > AH ...... A
Where B = First element of group 15
B1 = First element of group 16
A1 = First element of group 17
A = Second element of group 17
4. The total right angled  ClPCl are present in PCl5, PCl4+, PCl6¯ _ , _ , _ respectively.
(A) 0, 1, 4 (B) 6, 0, 4 (C) 2, 4, 0 (D) 6, 0, 12
5. Two ice cubes are pressed over each other and unite to form one cube, which force is responsible for holding
them together?
(A) Vander Waal's forces (B) Covalent attraction (C) Hydrogen bond formation (D) Ion - Dipole
attraction
6. Choose the correct ionisation energy order.
(A) Li < B < Be < C < N < O < F (B) Na < Mg < Al < Si < S < P < Cl
(C) K < Ga < Ca < Ge < As < Se < Br (D) Rb < Sr < In < Sn < Sb < Te < I
7. The compound in which the mentioned bond angle in parenthesis is found to be greater than expected not due
to back bonding.
(A) H3SiNCS (Si–N–C) (B) BI3 ( I–B–I) (C) MeNCS (CNC) (D) None of these
8. Find the incorrect match.
(A) Al2Cl6 : 3c-4e bond is present
(B) Al2(CH3)6 : All carbon atoms are sp3-hybridised
(C) I2Cl6 : Nonplanar
(D) Al2Br6 : Nonpolar
9. Among the following species, identify the isostructural pairs : NF3 , NO3 , BF3 , H 3O  , HN 3
(A) [ NF3 , NO3 ] and [ BF3 , H 3O  ] (B) [ NF3 , HN 3 ] and [ NO3 , BF3 ]
(C) [ NF3 , H 3O  ] and [ NO 3 , BF3 ] (D) [ NF3 , H 3O  ] and [ HN 3 , BF3 ]
10. In which of the following molecule, the number of possible XAX angles is maximum in the anionic
part of their solid state. [A : Central atom; X : Surrounding atom]
(A) PBr5 (B) N2O5 (C) PCl5 (D) Cl2O6
11. Choose the correct statement:
(A) NH3 is having bond angle of 109°28'.
N
(B) The direction of the dipole moment of NF3 is as shown in the diagram F F
F
TOPIC WISE REVIEW TEST - II-CB & S-BLOCK
 (C) In the Lewis structure of SO32–, there is no  bond.
(D) sp2 hybrid orbital is consisting of 33.33 % ‘p’ character.
12. Arrange the following species according to their bond angle order.
(I) O3 (II) NO2– (III) FNO
(A) I > II > III (B) II > I > III (C) III > II > I (D) II > III > I
13. Choose the correct set from the following options regarding the hybridisation of central atom and shape.
(A) SnCl2, sp2 , linear (B) AlCl4¯, sp3, square planar
(C) SOCl2, sp2 , planar (D) COF2, sp2 , planar
REASONING TYPE
14. Statement - 1 : SiF4 undergoes partial hydrolysis.
Statement - 2 : Back bonding from F to Si increases the bond order of Si–F bond.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.
15. Statement-1: SbCl5 and IF5 are not isostructural.
Statement-2: These two molecules are isosteric to each other.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.

16. Statement - 1 : The bond energy of C–O bond in CO molecule is greater than that of
N–N bond in N2.
Statement - 2 : CO and N2 both one having bond order of 3.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.
MORE THAN ONE CORRECT OPTION
17. The incorrect order of bond angle in the above molecule is/are

F
F
x
y S O
z
F
F
(A) y = z > x (B) z > y > x (C) y > x > z (D) x > y > z

18. An odd electron species like X–A, Where X and A both are p-block elements and multiplicity of X in ground
state is 4. If

(A) X–A undergoes heterolytic bond fission multiplicity of X is 3.


(B) X–A undergoes heterolytic bond fission then multiplicity of X is 1.

(C) X–A undergoes homolytic bond fission then multiplicity of X is 4.
(D) X–A undergoes homolytic bond fission then multiplicity of X  is 2.

TOPIC WISE REVIEW TEST - II-CB & S-BLOCK

19 The correct statement is/are
(A) BeCl2 is a covalent compound (B) BeCl2 is an electron deficient molecule
(C) BeCl2 can form dimer (D) the hybrid state of Be in BeCl2 is sp2

20 KO2 finds use in oxygen cylinders used for space and submarines. The fact(s) related to such use of KO2 is/
are
(A) it produces O2 (B) it produces O3
(C) it absorbs CO2 (D) it absorbs both CO and CO2
Q.21 The compound(s) which have –O–O– bond(s) is/are
(A) BaO2 (B) Na2O2 (C) CrO5 (D) Fe2O3

Q.22 Highly pure dilute solution of sodium in ammonia

(A) shows blue colouration due to solvated electrons
(B) shows electrical conductivity due to both solvated electrons as well as solvated sodium ions
(C) shows red colouration due to solvated electrons but a bad conductor of electricity
(D) produces hydrogen gas or carbonate
Q.23 Which of the following compounds are paramagnetic in nature?
(A) KO2 (B) K2O2 (C) Na2O2 (D) RbO2
Q.24 Which of the following substance(s) is/are used in laboratory for drying purposes?
(A) anhydrous P2O5 (B) graphite (C) anhydrous CaCl2 (D) Na3PO4
Q.25 Na2SO4 is water soluble but BaSO4 is insoluble because
(A) the hydration energy of Na2SO4 is higher than that of its lattice energy
(B) the hydration energy of Na2SO4 is less than that of its lattice energy
(C) the hydration energy of BaSO4 is less than that of its lattice energy
(D) the hydration energy of BaSO4 is higher than that of its lattice energy
Q.26 Which of the following statements are false?
(A) BeCl2 is a linear molecule in the vapour state but it is polymeric in the solid state
(B) Calcium hydride is called hydrolith.
(C) Carbides of both Be and Ca react with water to form acetylene
(D) Oxides of both Be and Ca are amphoteric.
Q.27 Which of the following are ionic carbides?
(A) CaC2 (B) Al4C3 (C) SiC (D) Be2C
Q.28 The compound(s) formed upon combustion of sodium metal in excess air is (are)
(A) Na2O2 (B) Na2O (C) NaO2 (D) NaOH
COMPREHENSION-1
Dipole moment of a molecule helps to predict different aspects of the molecule.
29. The µ values of HA, HB, HC and HD are 1.03, 1.92, 0.38 and 0.78 Debye respectively. The correct order of
electronegativity of A, B, C, D is
(A) A > B > C > D (B) B > A > C > D (C) B > A > D > C (D) A < B < C < D
30. Which of following linear molecule cannot have µ = 0?
(A) CS2 (B) BeH2 (C) COS (D) [ICl2]—
31. Which of the following molecule in the given options has equal dipole moment value with toluene (C6H5 –
CH3)?

CH3
CH3 CH3
(A) (B) (C) (D) None
CH3
CH3 CH3

TOPIC WISE REVIEW TEST - II-CB & S-BLOCK

 COMPREHENSION-2
Hybridisation is the measure to express the molecular shapes reasonably. Hybridisation, although theoretical,
but is highly correlated with molecular shapes or inter orbital angles .If there is any departure in geometry (on
the basis of VSEPR theory), the apparent departure in hybridisation can be observed. And the following
characteristic relationship is the easiest way to interpret that departure. Any hybrid orbital made by s and p
orbital is characterized by the following relationship.

1 i fp
fs = or fp = and i =
i 1 i 1 fs

for sp3, i = 3 and sp2 , i = 2; for an orbital fs + fp = 1 while all the s-p hybrids of given atom must satisfy the

condition,  fs = 1.00 and the inter orbital angle between two equivalent (same fs and same fp) hybrid orbitals

1
is given by cos  =
i
32. VSEPR theory suggests a small departure from 109°–28' for NH3 molecule. The H–N–H bond angle has
been found to be 107°. What kind of hybrid orbital will be occupied by the non bonding pair of electron.
(A) sp3 (B) sp3.4 (C) sp2.13 (D) sp2
33. What s-character is used by the carbon atom in the orbitals directed to hydrogen atom in CH2F2 molecule
[H–C–H bond angle in CH2F2 is 111.9° (cos 111.9° = – 0.3729)]
(A) 27.1 % (B) 37.29 % (C) 29 % (D) 29.99 %
34. In BFClBr molecule the minimum % 's'-character provided from the central atom is in the ____ bond.
(A) B – F (B) B – Cl (C) B – Br (D) Can't be predicted
MATRIX MATCH TYPE QUESTIONS
35. Match the column
Column I Column II

(A) Cr2O72– (P) Species having X–O–X linkage.

(B) Pyroxene chain silicate. (Q) Only one corner per tetrahedron is shared.

(C) Thiosulphite ion (R) All X-atom/s is/are sp3 hybridised.

(D) B3O63– (S) Overall species is planar.

(T) Only six number of X–O bonds are identical in length.

36. Match the column:
Column I Column II
(A) XeO3F2 (P) The species / compound is regular octahedral

(B) SF2 (CH3)2 (Q) 5 number of atoms may lie in the same plane within the species / compound
(C) XeO64– (R) The species/ compound utilises d x 2  y2 orbital in its formation.

(D) [I(CN)2]¯ (S) The species / compound utilises d orbital in its formation.
z2
(T) The dipole moment of the compound / species is zero.
INTEGER TYPE
37. Calculate the number of molecules of HF which are contained in gaseous form due to hydrogen bonding if the
density of HF in gaseous phase at 1atm, 300 K is 3.248 gm/lit.
38. The ratio of number of -bonds to -bonds in C2(CN)4 molecule is ______.
39. Calculate experimental bond moment (Approximate, in Debye) of A – B bond. If electronegativity of
element A & B is 2 and 3.5 respectively & bond length is 3.92 Å.
TOPIC WISE REVIEW TEST - II-CB & S-BLOCK
 ANSWER
SINGLE CORRECT CHOICE TYPE
1. D
2. B
3. D
4. D
5. C
6. D
7. C
8. C
9. C
10. C
11. C
12. A
13. D
REASONING TYPE
14. B
15. C
16. B
MORE THAN ONE CORRECT OPTION
17. A, C, D
18. A, C
19. A, B, C
20. A, C
21. A,B,C
22. A, B
23. A, D
24. A, C
25. A, C
26. C, D
27. A, B, D
28. A, B
COMPREHENSION-1
29. C
30. C
31. B
COMPREHENSION-2
32. B
33. A
34. A
MATRIX MATCH TYPE QUESTIONS

35. (A) P,Q,T (B) P,R (C) R , (D) P, S,T

36. (A) S,T (B) Q,S (C) P,Q,R,S,T (D) Q,S,T
INTEGER TYPE
37. 4
38. 1
39. 6
TOPIC WISE REVIEW TEST - II-CB & S-BLOCK
 SOLUTION-CB&S-BLOCK
SINGLE CORRECT CHOICE TYPE
1. D
2. B
3. D
[Sol. B = N, B1 = O, A1 = F, A = Cl
Hydrogen bond strength  polarity of the bond ]
4. D
[Sol. PCl5 = Trigonal bipyramidal
PCl 4 = Tetrahedral

PCl6 = Square bipyramidal ]

5. C
6. D
[Sol. (i) I.E. order : s>p>d>f
for a particular principal quantum number.
(ii) I.E. depends upon half filled & fully filled configuration.
Factor (i) & (ii) disappears in 5th & 6th period because Zeff dominates over all other. ]
7. C
+
N=C=S CH3 – N  C – S¯
[Sol. CH3 less than 120° 180° ]

~
~ 140°
8. C

Cl Cl Cl
[Sol. I I
Cl Cl Cl

3 2 3 2
sp d sp d

Square planar geometry for individual I-atoms and to minimize the repulsion of lone pair on I-atoms
overall molecule must be planar. ]
9. C
10. C
[Sol. PBr5 (s)  [PBr4]+ + Br¯
N2O5 (s)  NO2+ + NO3¯ (sp2)
PCl5 (s)  PCl4+ + PCl6¯ (sp3d2)

TOPIC WISE REVIEW TEST - II-CB & S-BLOCK

 Cl
Cl Cl
P
Cl2O6 (s)  ClO2+ + ClO4¯ (sp3) ]
Cl Cl
Cl
11. C
[Sol. (A) NH3 bond angle is 107.5°
–
O O O¯
O
+
+ ¯O — S — O¯ ¯O — S — O¯
N S or S
(B) (C)
F F – –
F O – O –
O O

1
(D) Percent ‘s’ character = × 100 = 33.33 %
3
Percent ‘p’ character = 66.67 % ]
12. A
13. D
Cl Cl¯
Sn Al
[Sol. (A) Cl Cl (B)Cl Cl
2 3
sp -bent sp ,tetrahedral

O
S C
(C) O Cl (D) F F
]
Cl 2
3
sp ,pyramidal sp & planar

REASONING TYPE
14. B
15. C

Cl F
Cl
F F

[Sol. Cl Sb I  Statement-1 is true, statement-2 is false.

F F
Cl
Cl sp3d2
sp3d

TOPIC WISE REVIEW TEST - II-CB & S-BLOCK

 Isosteric means having same number of atoms and same number of electrons.]

16. B
[Sol. – + NN
C O
B.O. = 3 B.O. = 3
BE is more because of electronegativity difference i.e. charge reparation in CO ]

MORE THAN ONE CORRECT OPTION

17. A, C, D
F
F Greater than 90°
x
[Sol. Less than 120° [Between of double and ]
y S O single bond repulsions]
z
F Greater than 120°
F

18. A, C
[Sol Since multiplicity = 4 = 2 | S | + 1
 S = 3/2 (three unpaired electron)
 Elements (X) will belong to 15th group.
19. A, B, C
20. A, C
21. A,B,C
22. A, B
23. A, D
24. A, C
25. A, C
26. C, D
27. A, B, D
28. A, B
COMPREHENSION-1
29. C
30. C
31. B
COMPREHENSION-2
32. B
33. A
34. A
MATRIX MATCH TYPE QUESTIONS

35. (A) P,Q,T (B) P,R (C) R , (D) P, S,T

TOPIC WISE REVIEW TEST - II-CB & S-BLOCK

 O¯ O¯

[Sol. (A) O Cr—O Cr O (B)

O O
3
ds
S 3
sp
S
(C)
¯O O¯

O
¯O B B O¯

O O
(D) B Aromatic, planar ]

O¯
36. (A) S,T (B) Q,S (C) P,Q,R,S,T (D) Q,S,T
INTEGER TYPE
37. 4
[Sol. It vapour state of HF be (HF)n
P × mol. wt. = dRT
1 × Mol.wt. = 3.248 × 0.0821 × 300
n(20) = mol. wt. = 79.9 ~ 80
n=4
hence vapour state is represented as (HF)4
38. 1

NC CN
[Sol.  bonds  nine
C=C
NC CN  bonds  nine
 9
 1 ]
 9
39. 6
[Sol. X = EN(B) – EN(A) = 3.5 – 2.0 = 1.5
% Ionic character = 16X + 3.5 (X)2
 exp
% Ionic character =   100
theo

1
 exp   10 29
16(1.5) + 3.5 (1.5)2 = 3  100
1.6  10 19  3.92  10 10
µexp = 5.99 approximate 6 ]

TOPIC WISE REVIEW TEST - II-CB & S-BLOCK