CPP FIITJEE CHEMICAL BONDING

1. In which of the following species maximum atom can lie in same plane.
(A) XeF2O2 (B) PCl5

(C) AsH4 (D) XeF4

2. Among given species identify the isostructural pairs:

(A) [NF3 and BF3] (B) BF4 and NH4 
 
 
(C) [BCl3 and BrCl3] (D) NH3 and NO3
 

3. The correct order of Cl – O bond order is:

(A) ClO3 < ClO4 < ClO2 < ClO– (B) ClO– < ClO4 < ClO3 < ClO2
(C) ClO– < ClO2 < ClO3 < ClO4 (D) ClO4 < ClO3 < ClO2 < ClO–

4. The correct order of increasing C – O bond strength of CO, CO32 , CO2 is:
(A) CO32 < CO2 < CO (B) CO2 < CO32 < CO
(C) CO < CO32 < CO2 (D) CO < CO2 < CO32

5. The ratio of -bond and -bond in tetracyano ethylene is:

(A) 2 : 1 (B) 1: 1
(C) 1 : 2 (D) None of these

6. An ionic compound A+B– is most likely to be formed when:

(A) the ionization energy of A is high and electron affinity of B is low
(B) the ionization energy of A is low and electron affinity of B is high
(C) both, the ionization energy of A and electron affinity of B are high
(D) both, the ionization energy of A and electron affinity of B are low

7. The lattice energies of KF, KCl, KBr and KI follow the order:
(A) KF > KCl > KBr > KI (B) KI > KBr > KCl > KF
(C) KF > KCl > KI > KBr (D) KI > KBr > KF > KCl

8. The geometrical arrangement of orbitals and shape of I3 are respectively:

(A) trigonal bipyramidal geometry, linear shape
(B) hexagonal geometry, T-shape
(C) triangular planar geometry, triangular shape
(D) tetrahedral geometry, pyramidal shape

9. Which is the following pairs of species have identical shapes?

(A) NO2 and NO2 (B) PCl5 and BrF5
(C) XeF4 and ICl4 (D) TeCl4 and XeO4

10. Which one of the following compounds has the smallest bond angle?
(A) OH2 (B) SH2
(C) NH3 (D) SO2

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11. Which has maximum dipole moment?
Cl
Cl
Cl
Cl Cl
(A) (B)

Cl
Cl
Cl Cl

(C) (D)

Cl
Cl

12. The hybridization of central iodine atom in IF5, I3 and I3 are respectively;
(A) sp3d2, sp3d, sp3 (B) sp3d, sp3d, sp3
3 2 3 2 3
(C) sp d , sp d , sp (D) sp3d, sp3d2, sp3

13. The lowest O – O bond length in the following molecule is:

(A) O2F2 (B) O2
(C) H2O2 (D) O3

14. ˆ  O " bond angle is maximum in:

The " O  N
(A) N2O (B) NO2
(C) NO2 (D) NO3

15. Which of the following overlaps is incorrect(assuming Z-axis is internuclear axis)?

(I) 2py  2py    Bond formation
(III) 3dxy  3dpxy    Bond formation
(V) 3dxy  3dpxy    Bond formation
(A) I, II, III
(C) II, V
(II) 2p x  2p x    Bond formation
(IV) 2s  2py    Bond formation
(VI) 2pz  2p z    Bond formation
(B) III, VI
(D) II, III, IV

16. Which molecule does not exist?

(A) OF2 (B) OF4
(C) SF2 (D) SF4

17. Which of the following is incorrectly match?

Hybridisation Geometry Orbitals use
(A) sp3d Trigonal bipyramidal s + px + py + pz + dz2
(B) sp3d3 Pentagonal bipyramidal s + px + py + pz + dx2  y2  dz2  dxy
(C) sp3d2 Capped octahedral s + px + py + pz + dx2  y2  dz2
(D) sp3+ Tetrahedral s + px + py + p z
ANSWERS

1. D 2. B 3. C 4. A
5. B 6. B 7. A 8. A
9. C 10. B 11. B 12. A
13. B 14. B 15. D 16. B
17. C
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