CPP FIITJEE CHEMICAL BONDING

SECTION A (Only One Option is Correct)

1. Which of the following compounds has zero dipole moments?
(A) PCl2F3 (B) PClF4
(C) PCl3F2 (D) PFCl4

2. Which of the following contains compounds in decreasing order of bond angle ?

(A) H2O > OCl2 > OF2 > HOCl (B) OCl2 > HOCl > H2O > OF2
(C) H2O > OF2 > OCl2 > HOCl (D) OCl2 > H2O > HOCl > OF2

3. Arrange the following compounds in decreasing order of N–N bond energy

H H F F
N N N N
H H F F
(I) ( II )
Cl Cl O O
N N N N
Cl Cl O O
( III ) ( IV )
(A) II > I > III > IV (B) II > III > I > IV
(C) IV > II > III > I (D) IV > III > II > I
4. Which of the following compounds is paramagnetic in nature ?
(A) Na2C2 (B) Na2O
(3) K2O2 (D) KO2

O
H O S O H

5. O
How many atoms in a molecule of H2SO4 undergo (es) sp3- hybridisation?
(A) 1 (B) 2
(C) 3 (4) 5

Cl

6. The dipole moment of is similar to that of

Cl Cl
Cl
(A) (B)

Cl Cl Cl
Cl
Cl

(C) (D) None

Cl

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7. Arrange the following compounds in decreasing order of basic nature.
P P P

H3C CH3 CH3 SiH 3 SiH 3 SiH 3 Ph Ph Ph

(I) ( II ) ( III )
(A) I > II > III (B) III > II > I
(C) II > I > III (D) I > III > II

8. The number of bond angles present in a molecule of PCl5 is

(A) 2 (B) 3
(C) 1 (4) None of these.

9. What is the bond order of Li2 molecule?

(A) 1 (B) 2
(C) 3 (D) 4

10. Which of the following molecules forms most stable addition compound with CH3NH2?
(A) BF3 (B) BCl3
(C) BBr3 (D) BI3

Section-B (More than one option may be correct)

11. The central atom of which of the following compound (s) undergo(es) sp2- hybridization?
(A) CO2 (B) SO2
(C) SO3 (D) NO2

12. Which of the following compound(s) is/are more covalent than MgCl2 according to Fajan’s
rule?
(A) NaCl (B) CaCl2
(C) AlCl3 (D) SiCl4

13. Choose correct statement(s) regarding the compound O2BF4

(A) It is paramagnetic in nature (B) Boron undergoes sp2-hybridization
(C) It’s aqueous solution conducts electricity (D) It behaves as a Lewis acid.
14. Which of the following compound(s) do/does not exist?
(A) SF4 (B) CF4
(C) OF4 (D) BF4

15. In which of the following, the dipole moment of the first member is greater than that of the
second member?
(A) NH3, NF3 (B) H2O, OF2
(C) CH4, CF4 (D) BH3, BF3

Section-C (Matrix Matching)

16. Match the species mentioned in column –I with their properties mentioned in column-II
Column-1 Column-II
(A) SO32  (B) The central atom can expand covalency
through d-orbitals by excitation of electrons
(B) PO34 (Q) Central atom undergoes sp3- hybridization
(C) CO32 (R) The central atom follows octet rule if the
double bonds are replaced by dative bonds.
(D) ClO (S) Has distorted octahedral or pyramidal shape
3
(T) Has triangular planar shape

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17. Match the compounds mentioned in column-I with their properties mentioned in column-II
Column-1 Column-II
(A) BF3 (B) Possesses zero dipole moment
(B) NF3 (Q) p – p back bonding takes place
(C) CF4 (R) Lone pair moment is opposed by bond pair
moment
(D) OF2 (S) Geometry and shape are same
(T) Geometry and shape are different

Section-D (Subjective Type)

18. How many non-polar covalent bond(s) is/are present in hydrogen peroxide(H2O2)?

19. A mixed halide of phosphorus is P(Cl)m(F)n. What will be the value of ‘m’ if the dipole
moment of the molecule is zero?

20. What is the dipole moment in debye of PF5 if the axial and equatorial bond lengths are

ANSWERS
1. C 2. B 3. D 4. D
5. C 6. C 7 A 8. B
9. A 10. D 11. BC 12. CD
13. AC 14. CD 15. AB
16. A  P,Q,R,S B  Q,R CT D  P,Q,R,S
17. A  P,Q,S B  R,T C  P,S D  R,T
18. 1 19. 3 20. Zero

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