Chemical Bonding PDF

CHEMICAL BONDING FINAL LAP - 2019
CHEMICAL BONDING
OBJECTIVE QUESTIONS BASED ON FUNDAMENTALS
EXERCISE - 1(ONLY ONE ANSWER IS CORRECT)
Q.1 Which of the following diagram / statement is correct for the hybrid orbitals.
(A) s + py  z z
2
(B) s + py + pz  sp orbitals lie in the xy plane
(C) ns + np3 + (n-1)d2  results octahedral geometry of sp3d2 hybrid orbitals.
(D) None of these
Q.2 The type of overlap in the bridge bond existing in Al2(CH3)6 is

(A) sp3 – sp3d – sp3 (B) sp3 – sp2 – sp3
3
(C) sp – s – sp3 (D) sp3 – sp3 – sp3
Q.3 Write the maximum number of atoms having same hybridisation in 2, 5-di-N-chloridothioimino-3, 4-
diagonothiophene as shown below : N N
C C
C=C
C C
N S N
S S
Cl Cl
(A) 4 (B) 5 (C) 6 (D) 8
Q.4 Which of the following statements are not correct?

(A) Hybridization is the mixing of atomic orbitals
(B) sp 2  hybrid orbitals are formed from two p - atomic orbitals and one s- atomic orbitals
(C) dsp 2  hybrid orbitals are at 90º to one another
(D) d 2 sp 3  hybrid orbitals are directed towards the corners of a regular octahedron
Q.5 Which of the following overlaps is incorrect [assuming z-axis to be the internuclear axis]
  2 py
(a) 2 py + 2 py   2 pz
(b) 2 pz + 2 pz 
 2 px
(c) 2 px + 2 px  1s2 py
(d) 1 s + 2 py 
(A) ‘a’ & ‘b’ (B) ‘b’ & ‘d’ (C) only ‘d’ (D) None of these
Q.6 The correct order of increasing X  O  X bond angle is ( X  H , F or Cl ) :

(A) H 2O  Cl 2O  F2 O (B) Cl 2O  H 2O  F2 O
(C) F2 O  Cl2 O  H 2 O (D) F2 O  H 2 O  Cl2O
Q.7 In the context of carbon, which of the following is arranged in the correct order of electronegativity :
(A) sp  sp 2  sp 3 (B) sp 3  sp 2  sp (C) sp 2  sp  sp 3 (D) sp 3  sp  sp 2
CENTERS : MUMBAI / DELHI /AKOLA / LUCKNOW /NASHIK / PUNE / NAGPUR / BOKARO / DUBAI # 248
Q.8 When 2s  2s, 2 p  2 p and 2 p  2s orbitals overlap, the bond strength decreases in the order :
(A) p  p  s  s  p  s (B) p  p  p  s  s  s
(C) s  s  p  p  p  s (D) s  s  p  s  p  p
Q.9 +
The bond energy order of He2 and HeH is +
(A) He2+ > HeH+ (B) HeH+ = He2+ (C) HeH+ > He2+ (D) Can't be predicted
Q.10 The maximum covalency is equal to

(A) the number of unpaired p-electrons
(B) the number of paired d-electrons
(C) the number of unpaired s and p-electrons
(D) total number of unpaired electron in ground state or in existence state
Q.11 Comment on the CNC and HNN in CH3NCS and HN3 respectively.
(A) less than 120° and less than 120° (B) Greater than 120° and less than 120°
(C) less than 120° and greater than 120° (D) Greater than 120° and greater than 120°
Q.12 Among the following, van der Waals forces are maximum in
(A) HBr (B) LiBr (C) LiCl (D) AgBr
Q.13 Among the following, the correct statement is :

(A) Between NH3 and PH3, NH3 is a better electron donor because the lone pair of electrons occupies
spherical ‘s’ orbital and is less directional
(B) Between NH3 and PH3, PH3 is a better electron donor because the lone pair of electrons occupies
sp3 orbital and is more directional
(C) Between NH3 and PH3, NH3 is a better electron donor because the lone pair of electrons occupies
sp3 orbital and is more directional
(D) Between NH3 and PH3, PH3 is a better electron donor because the lone pair of electrons occupies
spherical ‘s’ orbital and is less directional
Q.14 Oxidation state of ‘S’ in peroxodisulphuric acid and sodium tetrathionate

(A) + 6 , + 5 , 0 (B) + 6, + 6, + 6 (C) + 6, + 4, + 2 (D) + 6, + 2, + 0
Q.15 The bond angle in PH 3 is :

(A) Much lesser than NH 3 (B) Equal to that in NH 3
(C) Much greater than in NH 3 (D) Slightly more than in NH 3
Q.16 In a molecule of phosphorus (V)oxide, there are

(A) 4P–P, 10P–O and 4P=O bonds (B) 12P–O and 4P=O bonds
(C) 2P–O and 4P=P bonds (D) 6P–P, 12P–O and 4P=P bonds
Q.17 There is no S–S bond in:

(A) S2O42– (B) S2O52– (C) S2O32– (D) S2O72–
Q.18 The presence of lone pair in NH3 can change its :

(A) shape (B) angle as per hybridisation
(C) (A) & (B) both (D) Neither (A) nor (B)
Q.19 In ICl -4 , the shape is square planar. The number of bond pair-lone pair repulsion at 90° are:
(A) 6 (B) 8 (C) 12 (D) 4
Q.20 Arrange the following in order of decreasing N  O bond length : NO2 , NO2 , NO3
(A) NO3  NO2  NO2 (B) NO3  NO2  NO2
  
(C) NO2  NO3  NO2 (D) NO2  NO3  NO2
Q.21 Which of the set of isomers of C6H4Cl2 is having equal dipole moment with C6H5Cl and C6H6 respectively
(A) ortho and meta (B) meta and para
(C) ortho and para (D) para and ortho
Q.22 In which of following cases C–C bond length will be highest.

(A) CH3–CF3 (B) FCH2–CH2F (C) F2CH–CHF2 (D) CF3–CF3
Q.23 The cationic part of solid Cl2O6 is having the "___________" shape.
(A) linear (B) angular (C) Tetrahedron (D) undefined
Q.24 Borax is actually made of two tetrahedra and two triangular units joined together and should be written
as: Na2[B4O5(OH)4]·8H2O
Consider the following statements about borax:
a. Each boron atom has four B–O bonds
b. Each boron atom has three B–O bonds
c. Two boron atoms have four B–O bonds while other two have three B–O bonds
d. Each boron atom has one –OH groups
Select correct statement(s):
(A) a, b (B) b, c (C) c, d (D) a, c
Q.25 Hybridization of carbon in C3O2 is :

(A) sp (B) sp 2 (C) sp 3 (D) sp 3d
Q.26 Which of the following has been arranged in order of decreasing bond length ?
(A) P  O  Cl  O  S  O (B) P  O  S  O  Cl  O
(C) S  O  Cl  O  P  O (D) Cl  O  S  O  P  O
Q.27 The shapes of PCl 4 , PCl 4 and AsCl 5 are respectively :

(A) square planar, tetrahedral and see-saw
(B) tetrahedral, see-saw and trigonal bipyramidal
(C) tetrahedral, square planar and pentagonal bipyramidal
(D) trigonal bipyramidal, tetrahedral and square pyramidal
Q.28 PCl 5 exists but NCl 5 does not because :

(A) Nitrogen has no vacant d-orbitals (B) NCl 5 is unstable
(C) Nitrogen atom is much smaller than p (D) Nitrogen is highly inert
Q.29 The correct order of increasing s-character (in percentage) in the hybrid orbitals of following molecules/
ions is:
(I) CO 32 (II) XeF4 (III) I3 (IV) NCl3 (V) BeCl2
(A) II < III < IV < I < V (B) II < IV < III < V < I
(C) III < II < I < V < IV (D) II < IV < III < I < V
Q.30 Molecular shapes of SF4, CF4 and XeF4 are:

(A) the same, with 2, 0 and1 lone pair of electrons respectively
(B) the same, with 1, 1 and 1 lone pair of electrons respectively
(C) different with 0, 1 and 2 lone pair of electrons respectively
(D) different with 1, 0 and 2 lone pair of electrons respectively
Q.31 Which has higher bond energy :

(A) F2 (B) Cl 2 (C) Br2 (D) I 2
Q.32 C—H bond distance is the longest in:

(A) C2H2 (B) C2H4 (C) C2H6 (D) C2H2Br2
Q.33 Maximum bond energy is in :

(A) F2 (B) N 2 (C) O2 (D) equal
Q.34 In the cyanide ion the negative charge is on

(A) C (B) N (C) Both C and N (D) Resonate between C and N
Q.35 The bond angle and hybridization in ether (CH 3OCH 3 ) is :

(A) 106º51, sp 3 (B) 104º31, sp 3 (C) 110º , sp 3 (D) None of these
Q.36 A: tetracyanomethane B: Carbondioxide C: Benzene D: 1, 3–buta–di–ene

Ratio of  and  bonds is in order:
(A) A=B<C<D (B) A=B<D<C (C) A=B=C=D (D) C<D<A<B
Q.37 The enolic form of acetone contains :

(A) 9 sigma, 1 pi bond and 2 lone pairs (B) 8 sigma, 2 pi bond and 2 lone pairs
(C) 10 sigma, 1 pi bond and 1 lone pairs (D) 9 sigma, 2 pi bond and 1 lone pairs
Q.38 The number of -bond and -bond in HCP are respectively

(A) 2 and 2 (B) 1 and 3 (C) 2 and 1 (D) None
Q.39 (C—Cl) bond in CH2=CH–Cl (vinyl chloride) is stabilised in the same way as in:
(A) benzyl chloride (B) ethyl chloride (C) chlorobenzene (D) allyl chloride
Q.40 The correct order of acidic strength of oxy-acids of chlorine is

(A) HCIO < HCIO2 < HCIO3 < HCIO4 (B) HCIO4 < HCIO3 < HCIO2 < HCIO
(C) HCIO > HCIO4 > HCIO3 > HCIO2 (D) HCIO4 < HCIO2 > HCIO3 > HCIO
COOH
Q.41 CH2 P4O10 , 150C
   X
COOH
Compound (X) is
(A) malonic acid (B) carbon suboxide (C) tartaric acid (D) acetic acid
Q.42 Mg2C3 reacts with water forming propyne, C34– has:

(A) two sigma and two pi bonds (B) three sigma and one pi bonds
(C) two sigma and one pi bonds (D) two sigma and three pi bonds
Q.43 How many sigma and pi bonds are present in tetracyanoethylene ?
(A) Nine  and nine  (B) Five  and nine 
(C) Nine  and seven  (D) Eight  and eight 

Q.44 H  B  H bond angle in BH 4 is :
(A) 180º (B) 120º (C) 109º (D) 90º
Q.45 The hydration of ionic compounds involves :

(A) Evolution of heat (B) Weakening of attractive forces
(C) Dissociation into ions (D) All of these
Q.46 For which of the following crystalline substances does the solubility in water increase upto 32º C and
then decrease rapidly ?
(A) CaCl2 .2H 2O (B) Na 2SO 4 .10H 2O (C) FeSO4 .7 H 2O (D) Alums
Q.47 Among KO2 , AlO2 , BaO2 and NO2 unpaired electron is present in :
(A) KO2 only (B) NO2 and BaO2 (C) KO2 and AlO2 (D) BaO2 only
Q.48 If a molecule MX 3 has zero dipole moment, the sigma bonding orbitals used by M (atm. no. < 21) are :
(A) pure p (B) sp hybrid (C) sp 2 hybrid (D) sp 3 hybrid
Q.49 Identify isostructural pairs from NF3(I) , NO3-(II) , BF3(III) , H3O+(IV), HN3 (V)
(A) I & II, III & IV (B) I & V, II & III (C) I & IV, II & III (D) I & IV, III & V
Q.50 Which of the following species are hypervalent?

1. ClO4–, 2. BF3, 3. SO42– , 4. CO32–
(A) 1, 2, 3 (B) 1, 3 (C) 3, 4 (D) 1, 2
Q.51 Boron forms BX3 type of halides. The correct increasing order of Lewis-acid strength of these halides is
(A) BF3 > BCl3 > BBr3 > BI3 (B) BI3 > BBr3 > BCl3 > BF3
(C) BF3 > BI3 > BCl3 > BBr3 (D) BF3 > BCl3 > BI3 > BBr3
Q.52 Which one of the following statements is not true regarding diborane?
(A) It has two bridging hydrogens and four perpendicular to the rest.
(B) When methylated, the product is Me4B2H2.
(C) The bridging hydrogens are in a plane perpendicular to the rest.
(D) All the B–H bond distances are equal.
Q.53 The structure of diborane (B2H6) contains

(A) Four (2C–2e–) bonds and two (2C–3e–) bonds
(B) Two (2C–2e–) bonds and two (3C–2e–) bonds
(C) Four (2C–2e–) bonds and four (3C– 2e–) bonds
(D) None
Q.54 The molecular shapes of diborane is shown:

Consider the following statements for diborane:
1. Boron is approximately sp3 hybridised
2. B–H–B angle is 180°
3. There are two terminal B–H bonds for each boron atom
4. There are only 12 bonding electrons available
Of these statements:
(A) 1, 3 and 4 are correct (B) 1, 2 and 3 are correct
(C) 2, 3 and 4 are correct (D) 1, 2 and 4 are correct
Q.55 Select correct statement about hydrolysis of BCl3 and NCl3
(A) NCl3 is hydrolysed and gives HOCl but BCl3 is not hydrolysed.
(B) Both NCl3 and BCl3 on hydrolysis gives HCl
(C) NCl3 on hydrolysis gives HOCl but BCl3 gives HCl.
(D) Both NCl3 and BCl3 on hydrolysis gives HOCl.
Q.56 Which of the following properties describes the diagonal relationship between boron and slicon?
(A) BCl3 is not hydrolysed while SiCl4 can be hydrolysed
(B) Both form oxides; B2O3 is amphoteric; SiO2 is acidic
(C) Both dissolve in cold and dilute nitric acid
(D) Borides and silicides are hydrolysed by water
Q.57 Type of hybridisation in transition state of SeF4, when it undergoes in hydrolysis

(A) sp3d (B) sp3d2 (C) dsp3 (D) sp3
Q.58 Which of the following halides cannot be hydrolysed?

(I) TeF6 (II) SF6 (III) NCl3 (IV) NF3
Choose the correct code :
(A) III & IV (B) I, II & III (C) I, II & IV (D) II & IV
Q.59 The critical temperature of water is higher than that of O2 because the H 2 O molecule has :
(A) fewer electrons than O2 (B) two covalents bonds
(C) V - shape (D) dipole moment
Q.60 Ethanol has a higher boiling point than dimethyl ether though they have the same molecular weight. This
is due to :
(A) resonance (B) coordinate bonding
(C) hydrogen bonding (D) ionic bonding
Q.61 Arrange the following in order of decreasing boiling point :

(I) n-Butane (II) n-Butanol (III) n-Butyl chloride (IV) Isobutane
(A) IV  III  II  I (B) IV  II  III  I (C) I  II  III  IV (D) II  III  I  IV
Q.62 Which of the following compounds would have significant intermolecular hydrogen bonding ?
HF , CH 3OH , N 2O4 , CH 4
(A) HF , N 2O4 (B) HF , CH 4 , CH 3OH
(C) HF , CH 3OH (D) CH 3OH , CH 4
Q.63 Which of the following molecules are expected to exhibit intermolecular H–bonding
I. Acetic acid II. o-nitrophenol III. m–nitrophenol IV. o–boric acid
(A) I, II, III (B) I, II, IV (C) I, III, IV (D) II, III, IV
Q.64 Intramolecular hydrogen bonding is found in :
(A) Salicylaldehyde (B) Water (C) Acetaldehyde (D) Phenol
Q.65 The pairs of bases in DNA are held together by :

(A) Hydrogen bonds (B) Ionic bonds (C) Phosphate groups (D) Deoxyribose groups
Q.66 The volatility of HF is low because of :

(A) its low polarizability (B) the weak dispersion interaction between the molecules
(C) its small molecular mass (D) its strong hydrogen bonding
Q.67 Which one of the following does not have intermolecular H-bonding?
(A) H2O (B) o-nitro phenol (C) HF (D) CH3COOH
Q.68 Which of the following exhibit/s H-bonding?

(A) CH4 (B) H2Se (C) N2H4 (D) H2S
Q.69 Two ice cubes are pressed over each other and unite to form one cube. Which force is responsible for
holding them together :
(A) van der Waal’s forces (B) Covalent attraction
(C) Hydrogen bond formation (D) Dipole-dipole attraction
Q.70 Which has maximum dipole moment?
(A) (B) (C) (D)
Q.71 Which of the following has been arranged in order of decreasing dipole moment ?
(A) CH 3Cl  CH 3 F  CH 3 Br  CH 3 I (B) CH 3 F  CH 3Cl  CH 3 Br  CH 3 I
(C) CH 3Cl  CH 3 Br  CH 3 I  CH 3 F (D) CH 3 F  CH 3Cl  CH 3 I  CH 3 Br
Q.72 The experimental value of the dipole moment of HCl is 1.03 D. The length of the H  Cl bond is
1.275 Å . The percentage of ionic character in HCl is :
(A) 43 (B) 21 (C) 17 (D) 7
Q.73 The total number of valence electrons in 4.2g of N 3 ion are :

(A) 2.2 N (B) 4.2 N (C) 1.6 N (D) 3.2 N
Q.74 Which of the following has the least dipole moment

(A) NF3 (B) CO2 (C) SO2 (D) NH 3
Q.75 Amongst LiCl , RbCl , BeCl 2 and MgCl 2 , the compounds with the greatest and the least ionic character,,
respectively are :
(A) LiCl and RbCl (B) RbCl and BeCl 2 (C) RbCl and MgCl 2 (D) MgCl 2 and BeCl 2
Q.76 The polarizibility of the following compounds is/are

(A) I- > Br - > Cl- > F- (B) I- > Br - > F- > Cl-
- -
(C) I < Br < Cl < F- - (D) I- < Br - < F- < Cl-
Q.77 Compound with maximum ionic character is formed from :
(A) Na and Cl (B) Cs and F (C) Cs and I (D) Na and F
Q.78 The melting point of AlF3 is 104º C and that of SiF4 is - 77º C (it sublimes) because :
(A) there is a very large difference in the ionic character of the Al  F and Si  F bonds
(B) in AlF3 , Al 3 interacts very strongly with the neighbouring F  ions to give a three dimensional
structure but in SiF4 no such interaction is possible
(C) the silicon ion in the tetrahedral SiF4 is not shielded effectively from the fluoride ions whereas in
AlF3 , the Al 3 ion is shielded on all sides
(D) the attractive forces between the SiF4 molecules are strong whereas those between the AlF3 molecules
are weak
Q.79 Which of the following equilibria would have the highest value of K p at a common temperature ?
(A) MgCO3  MgO  CO2 (B) CaCO3  CaO  CO2
(C) SrCO3  SrO  CO2 (D) BaCO3  BaO  CO2
Q.80 Which of the following sets of characteristics leads to the increase in solubility of ionic substances ?
(A) High dipole moment, strong attraction by an ion and large solvation energy
(B) Low dipole moment, weak attraction by an ion and high solvation energy
(C) High dipole moment, strong attraction by an ion and low solvation energy
(D) High dipole moment, weak attraction by an ion and large solvation energy
Q.81 The solubility of anhydrous AlCl3 and hydrous AlCl3 in diethyl ether are S1 and S2 respectively. Then
(A) S1 = S2 (B) S1 > S2 (C) S1 < S2 (D) S1 < S1 but not S1 = S2
Q.82 During the formation of a molecular orbital from atomic orbitals, probability of electron density is:
(A) minimum in the nodal plane (B) maximum in the nodal plane
(C) zero in the nodal plane (D) zero on the surface of the lobe
Q.83 Pick out the incorrect statement?

(A) N2 has greater dissociation energy than N2+
(B) O2 has lower dissociation energy than O2+
(C) Bond length in N2+ is less than N2
(D) Bond length in NO+ is less than in NO.
Q.84 Which of the following species is paramagnetic ?

(A) NO  (B) O22 (C) CN  (D) CO
Q.85 Bond order of Be2 is :

(A) 1 (B) 2 (C) 3 (D) 0
Q.86 A simplified application of MO theory to the hypothetical ‘molecule’ OF would give its bond order as :
(A) 2 (B) 1.5 (C) 1.0 (D) 0.5
Q.87 Number of anti bonding electrons in N 2 is :

(A) 4 (B) 10 (C) 12 (D) 14
Q.88 The bond order depends on the number of electrons in the bonding and antibonding orbitals. Which of
the following statements is /are correct about bond order?
(A)Bond order cannot have a negative value.
(B) It always has an integral value.
(C) It is a nonzero quantity.
(D) It can assume any value-positive or negative, integral or fractional, including zero.
Q.89 In the formation of N 2 from N 2 , the electron is removed from :

(A)  orbital (B)  orbital (C)  * orbital (D) * orbital
Q.90 Which of the following is true ?

1 1
(A) Bond order  bond length  bond energy (B) Bond order  bond length  bond energy
1 1
(C) Bond order  bond length  bond energy (D) Bond order  bond length  bond energy
Q.91 Which of the following has fractional bond order :

(A) O22 (B) O22 (C) F22 (D) H 2
Q.92 How many unpaired electrons are present in N 2 :

(A) 1 (B) 2 (C) 3 (D) 4
Q.93 Si2O76– anion is obtained when

(A) no oxygen of a SiO4 tetrahedron is shared with another SiO4 tetrahedron.
(B) one oxygen of a SiO4 tetrahedron is shared with another SiO4 tetrahedron.
(C) two oxygen of a SiO4 tetrahedron are shared with another SiO4 tetrahedron.
(D) three or all four oxygens of a tetrahedron are shared with other SiO4 tetrahedron.
Q.94 Match list I with list II and select the correct answer:
List I (species) List II (O–N–O angle)
A. NO2 + 1. 180°
B. NO 2 2. 134°
C. NO 2 – 3. 120°
D. NO 3 – 4. 115°
5. 109°
A B C D A B C D
(A) 5 4 3 2 (B) 5 2 4 3
(C) 1 2 4 3 (D) 1 4 3 2
MISCELLANEOUS QUESTIONS
EXERCISE - 2 (ONE & MORE ANSWER IS CORRECT)
Q.1 The experimental result says that two iodine atoms are in different environments and predict the all
possible incorrect arrangement for I2Cl4Br2.
Cl Cl Br Br Cl Br
(A) I I (B) I I
Cl Cl Br Cl Cl Cl
Cl Cl Br Cl Br Cl
(C) I I (D) I I
Br Cl Cl Cl Br Cl
Q.2 Choose the correct order for the given properties.
(A) MgSO4 < SrSO4 < BaSO4 : Thermal stability order
(B) BeC2O4 < CaC2O4 < BaC2O4 : Solubility in water
(C) LiCl > NaCl > KCl : Melting point order
(D) BeF2 > CaF2 > SrF2 : Covalent character order
Q.3 Which have fractional bond order?

(A) O2+ (B) O2 (C) NO (D) H2+
Q.4 Which has (have) zero value of dipole moment?

(A) XeF4 (B) CHCl3 (C) CO2 (D) Cl Cl
Q.5 Which of the following have planar structure?

(A) I3 (B) H2O (C) PCl5 (D) XeF4
Q.6 Which of the following have dipole moment ?

(A) nitrobenzene (B) p-chloronitrobenzene
(C) m-dichlorobenzene (D) o-dichlorobenzene
Q.7 In the structure of H2CSF4, which of the following statement is/are correct?
(A) Two C–H bonds are in the same plane of axial S–F bonds.
(B) Two C–H bonds are in the same plane of equitorial S–F bonds.
(C) Total six atoms are in the same plane.
(D) Equitorial S–F plane is perpendicular to nodal plane of –bond.
Q.8 Which of the following compounds contain/s both ionic and covalent bonds?
(A) NH4Cl (B) KCN (C) CuSO4·5H2O (D) NaOH
Q.9 Which of the following statements are not correct?

(A) All C–O bonds in CO 32 are equal but not in H2CO3.
(B) All C–O bonds in HCO 2 are equal but not in HCO2H
(C) C–O bond length in HCO 2 is longer than C–O bond length in CO 32 .
(D) C–O bond length in HCO 2 and C–O bond length in CO 32 are equal.
Q.10 Resonance occurs due to the
(A) delocalization of a lone pair of electrons (B) delocalization of sigma electrons
(C) delocalization of pi electrons (D) migration of protons
Q.11 Which of following stability order is/are correct due to inert pair effect.
(A) Hg° > Hg2+ (B) Bi3+ < Bi5+ (C) Pb2+ > Pb4+ (D) Fe2+ < Fe3+
Q.12 Which of the following statements is/are true?

(A) Covalent bonds are directional
(B) Ionic bonds are nondirectional
(C) A polar bond is formed between two atoms which have the same electronegativity value.
(D) The presence of polar bonds in a polyatomic molecule suggests that it has zero dipole moment
Q.13 Which of the following have identical bond order?

(A) O22 (B) NO  (C) CN  (D) CN 
Q.14 Which of the following statement is/are correct

(A) The peroxide ion has a bond order of 1 while the oxygen molecule has a bond order of 2
(B) The peroxide ion has a weaker bond than the dioxygen molecule has.
(C) The peroxide ion as well as the dioxygen molecules are paramagnetic
(D) The bond length of the peroxide ion is greater than that of the dioxygen molecule
Q.15 Given the species : N 2 , CO, CN  and NO  . Which of the following statements are true for these
(A) All species are paramagnetic (B) The species are isoelectronic
(C) All the species have dipole moment (D) All the species are linear
Q.16 Which of the following have unpaired electron(s)

(A) O2 (B) O2 (C) NO (D) H 2
Q.17 Colour of which of the following is attributed to charge transfer spectrum ?

(A) KMnO 4 (B) KO2 (C) K 2 Cr2 O7 (D) AgI
Q.18 What is the state of hybridisation of Xe in cationic part of solid XeF6.

(A) sp3d3 (B) sp3d2 (C) sp3d (D) sp3
Q.19 Rotation around the bond (between the underlined atoms) is restricted in :
(A) C 2 H 4 (B) H 2 O 2 (C) C 2 H 2 (D) C 2 H 6
Q.20 According to MOT (Molecular Orbital Theory), the molecular orbitals are formed by mixing of atomic
orbitals through LCAO (linear combination of atomic orbitals). The correct statement(s) about molecular
orbitals is/are
Statement (a) :bonding molecular orbitals are formed by addition of wave-functions of atomic
orbitals of same phase
Statement (b) : anti-bonding molecular orbitals are formed by subtraction of wave-functions of
atomic orbitals of same phase
Statement (c) : non-bonding molecular orbitals do not take part in bond formation because they
belong to inner shells
Statement (d) : anti-bonding molecular orbitals provide stability to molecules while bonding
molecular orbitals make the molecules unstable.
(A) Statement a, d (B) Statement a, b, c (C) Statement a, b, d (D) Statement a, b
Q.21 No X  X bond exists in which of the following compounds having general form of X 2 H 6 ?
(A) B2 H 6 (B) C 2 H 6 (C) Al 2 H 6 (D) Si2 H 6
Q.22 Which of the following species is (are) isostructural with XeF4 ?

(A) ICl4 (B) I 5 (C) BrF4 (D) XeO4
Q.23 Which one of the following compounds has bond angle as nearly 90º ?
(A) NH 3 (B) H 2 S (C) H 2 O (D) SF6
Q.24 The linear structure is assumed by :

(A) SnCl 2 (B) NCO  (C) CS 2 (D) NO2
Q.25 Which of the following statements is/are correct ?

(A) NH 2 shows sp 2  hybridisation whereas NH 2 shows sp 3  hybridisation
(B) Al (OH ) 4 has a regular tetrahedral geometry
(C) sp 2  hybridized orbitals have equal s- and p- character
(D) Usually hybridized orbitals form  - bonds
Q.26 Choose the correct option for the following molecule in view of chemical bonding
(A) non-planar (B)   0 (C) A & B both (D)  = 0
Q.27 Of the following isoelectronic & isostructural species are

NO3—, ClO3—, SO3 & CO32—
(A) NO3— & CO32— (B) SO3 & CO32
(C) NO3 & ClO3— (D) CO32— & ClO3—
Q.28 Shape of NH 3 is very similar to :

(A) SeO32 (B) CH 3 (C) BH 3 (D) CH 3
Q.29 Polarization may be called the distortion of the shape of an anion by an adjacently placed cation. Which
of the following statements is/are incorrect:
(A) Minimum polarization is brought about by a cation of low radius
(B) A large cation is likely to bring about a large degree of polarization
(C) Maximum polarization is brought about by a cation of high charge
(D) A small anion is likely to undergo a large degree of polarization
Q.30 Pick out among the following species isoelectronic with CO2 :
(A) N 3 (B) (CNO)  (C) (NCN ) 2 (D) NO2
Q.31 Which is correct statement?

As the s-character of a hybrid orbital decreases
(I) The bond angle decreases (II) The bond strength increases
(III) The bond length increases (IV) Size of orbital increases
(A) (I), (III) and (IV) (B) (II), (III) and (IV)
(C) (I) and (II) (D) All are correct
Q.32 Resonating strctures of a molecule should have:

(A) identical bonding (B) identical ararngement of atoms
(C) nearly the same energy content (D) the same number of paired electrons
Q.33 Which of the following conditions apply to resonating structures ?

(A) The contributing structures should have nearly similar energies
(B) The contributing structures should be represented such that like charges reside on atoms that are far
apart
(C) The more electropositive element should preferably have positive charge and the more electronegative
element have negative charge
(D) The contributing structures must have the same number of unpaired electrons
Q.34 A -bond may between two p x orbitals containing one unpaired electron each when they approach
each other appropriately along :
(A) x - axis (B) y - axis (C) z - axis (D) any direction
Q.35 During the complete combustion of methane CH4, what change in hybridisation does the carbon atom
undergo?
(A) sp3 to sp (B) sp3 to sp2 (C) sp2 to sp (D) sp2 to sp3
Q.36 The octet rule is not obeyed in :
(A) CO2 (B) BCl3 (C) PCl 5 (D) SiF4
Q.37 A, B, C are three substances. A does not conduct electricity in the soild, molten state and aqueous solution.
B conducts electricity both in the fused and aqueous states, while C conducts electricity only in the aqueous
state. In solid state neither B nor C conducts electricity. Which of the following statements is/are true regarding
A, B and C ?
(A) A has polar covalent linkage (B) A has nonpolar covalent linkage
(C) B is ionic in nature (D) Cation formed by C is highy polarizing
Q.38 Three centre – two electron bonds exist in :
(A) B2H6 (B) Al2(CH3)6 (C) BeH2(s) (D) BeCl2(s)
Q.39 Which of the following statement(s) is/are correct regarding ionic compounds ?
(A) They are good conductors of electricity at room temperature
(B) They are always more soluble in polar solvents than covalent compounds
(C) They consists of ions
(D) They generally have high melting and boling points
Q.40 Most ionic compounds have :
(A) high melting points and low boiling points
(B) high melting points and nondirectional bonds
(C) high solubilities in polar solvents and low solubilities in nonpolar solvents
(D) three-dimentional network structures, and are good conductors of electricity in the molten state
Q.41 When an inorganic compound (X) having 3e-2e as well as 2e-2e bonds reacts with ammonia gas at a
certain temperature, gives a compound (Y) iso-structural with benzene. Compound (X) with ammonia
at a high temperature, produces a hard substance (Z). Then
(A) (X) is B2H6 (B) (Z) is known as inorganic graphite
(C) (Z) having structure similar to graphite (D) (Z) having structure similar to (X)
Q.42 Select correct statement about B2H6
(A) Bridging groups are electron-deficient with 12 valence electrons
(B) It has 2c - 2e B–H bonds
(C) It has 3c - 2e B–H–B bonds
(D) All of above are correct statements
Q.43 Which of the following pairs of nitrates gives the same gaseous products on thermal decomposition?
(A) KNO3 and Pb(NO3)2 (B) KNO3 and NaNO3
(C) Pb(NO3)2 and Cu(NO3)2 (D) NaNO3 and Ca(NO3)2
ANSWER KEY
EXERCISE–I
Q.1 D Q.2 D Q.3 C Q.4 A Q.5 C Q.6 B Q.7 A
Q.8 B Q.9 C Q.10 D Q.11 B Q.12 D Q.13 C Q.14 A
Q.15 A Q.16 B Q.17 D Q.18 B Q.19 B Q.20 B Q.21 B
Q.22 B Q.23 B Q.24 C Q.25 A Q.26 B Q.27 B Q.28 A
Q.29 A Q.30 D Q.31 B Q.32 C Q.33 B Q.34 A Q.35 C
Q.36 A Q.37 A Q.38 A Q.39 C Q.40 A Q.41 B Q.42 A
Q.43 A Q.44 C Q.45 D Q.46 B Q.47 A Q.48 C Q.49 C
Q.50 B Q.51 B Q.52 D Q.53 D Q.54 A Q.55 C Q.56 D
Q.57 B Q.58 D Q.59 D Q.60 C Q.61 D Q.62 C Q.63 C
Q.64 A Q.65 A Q.66 D Q.67 B Q.68 C Q.69 C Q.70 A
Q.71 A Q.72 C Q.73 C Q.74 B Q.75 B Q.76 A Q.77 B
Q.78 B Q.79 A Q.80 A Q.81 B Q.82 C Q.83 C Q.84 A
Q.85 D Q.86 B Q.87 A Q.88 D Q.89 A Q.90 A Q.91 D
Q.92 A Q.93 B Q.94 C
EXERCISE–II
Q.1 B,C,D Q.2 A,D Q.3 A,B,C,D Q.4 A,C,D
Q.5 A,B,D Q.6 A,B,C,D Q.7 A,C,D Q.8 A,B,C,D
Q.9 C,D Q.10 A,C Q.11 A,C Q.12 A,B
Q.13 A,B,C Q.14 A,B,D Q.15 B,D Q.16 A,B,C,D
Q.17 A,C Q.18 B Q.19 A,B,C Q.20 D
Q.21 A,C Q.22 A,C Q.23 B,D Q.24 B,C,D
Q.25 A,B,D Q.26 D Q.27 A Q.28 A,B
Q.29 A,B,D Q.30 A,B,C Q.31 A Q.32 B,C,D
Q.33 A,B,C,D Q.34 B,C Q.35 A Q.36 B,C
Q.37 B,C,D Q.38 A,B,C Q.39 C,D Q.40 B,C,D
Q.41 A,B,C Q.42 B,C Q.43 B,C

Chemical Bonding PDF

Uploaded by

Document Information

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Chemical Bonding PDF

Uploaded by

Copyright:

Available Formats

CHEMICAL BONDING FINAL LAP - 2019

EXERCISE - 1(ONLY ONE ANSWER IS CORRECT)

Q.2 The type of overlap in the bridge bond existing in Al2(CH3)6 is

(A) 4 (B) 5 (C) 6 (D) 8

Q.4 Which of the following statements are not correct?

Q.6 The correct order of increasing X  O  X bond angle is ( X  H , F or Cl ) :

Q.10 The maximum covalency is equal to

Q.13 Among the following, the correct statement is :

Q.14 Oxidation state of ‘S’ in peroxodisulphuric acid and sodium tetrathionate

Q.15 The bond angle in PH 3 is :

Q.16 In a molecule of phosphorus (V)oxide, there are

Q.17 There is no S–S bond in:

Q.18 The presence of lone pair in NH3 can change its :

Q.22 In which of following cases C–C bond length will be highest.

Q.25 Hybridization of carbon in C3O2 is :

Q.27 The shapes of PCl 4 , PCl 4 and AsCl 5 are respectively :

Q.28 PCl 5 exists but NCl 5 does not because :

Q.30 Molecular shapes of SF4, CF4 and XeF4 are:

Q.31 Which has higher bond energy :

Q.32 C—H bond distance is the longest in:

Q.33 Maximum bond energy is in :

Q.34 In the cyanide ion the negative charge is on

Q.35 The bond angle and hybridization in ether (CH 3OCH 3 ) is :

Q.36 A: tetracyanomethane B: Carbondioxide C: Benzene D: 1, 3–buta–di–ene

Q.37 The enolic form of acetone contains :

Q.38 The number of -bond and -bond in HCP are respectively

Q.40 The correct order of acidic strength of oxy-acids of chlorine is

Q.42 Mg2C3 reacts with water forming propyne, C34– has:

Q.45 The hydration of ionic compounds involves :

Q.50 Which of the following species are hypervalent?

Q.53 The structure of diborane (B2H6) contains

Q.54 The molecular shapes of diborane is shown:

Q.57 Type of hybridisation in transition state of SeF4, when it undergoes in hydrolysis

Q.58 Which of the following halides cannot be hydrolysed?

Q.61 Arrange the following in order of decreasing boiling point :

Q.65 The pairs of bases in DNA are held together by :

Q.66 The volatility of HF is low because of :

Q.68 Which of the following exhibit/s H-bonding?

Q.70 Which has maximum dipole moment?

(A) (B) (C) (D)

Q.73 The total number of valence electrons in 4.2g of N 3 ion are :

Q.74 Which of the following has the least dipole moment

Q.76 The polarizibility of the following compounds is/are

Q.83 Pick out the incorrect statement?

Q.84 Which of the following species is paramagnetic ?

Q.85 Bond order of Be2 is :

Q.87 Number of anti bonding electrons in N 2 is :

Q.89 In the formation of N 2 from N 2 , the electron is removed from :

Q.90 Which of the following is true ?

Q.91 Which of the following has fractional bond order :

Q.92 How many unpaired electrons are present in N 2 :

Q.93 Si2O76– anion is obtained when

EXERCISE - 2 (ONE & MORE ANSWER IS CORRECT)

Q.3 Which have fractional bond order?

Q.4 Which has (have) zero value of dipole moment?

Q.5 Which of the following have planar structure?

Q.6 Which of the following have dipole moment ?

Q.9 Which of the following statements are not correct?

Q.12 Which of the following statements is/are true?

Q.13 Which of the following have identical bond order?

Q.14 Which of the following statement is/are correct

Q.16 Which of the following have unpaired electron(s)

Q.17 Colour of which of the following is attributed to charge transfer spectrum ?