XII Chemistry Formulae

zM 1. z = no. of atom in unit cell

1. Density of unit cell = kg / m3
a  NA
3
2. M = molar mass
3. a = edge length
zM
g cm –3 4. NA=Avogadro’s No. (6.022×1023)
a  N A 10
3 –30

5. P= pressure
2. P = K H . xB – Henry's Law
6. KH = Henry’s Constant
PA – PA
0
7. xB=mole fraction of solute
3. = ixB
PA0
8. PA0 = vapour pressure of pure solvent
4. Tb = iK b . m 9. PA = Vapour pressure of solvent in solution
5. T f = iK f . m 10. Tb = elevation in boiling point

6.  = CRT 11. T f = Depression in freezing point

Normal molar mass (M n )
7. i= 12. Kb = Molal elevation constant
Observed molar mass (M o )
13. K f = Molal depression constant
0.0591 conc n of reactant
8. E cell =E 0cell + log 14. C = Concentration
n conc n of product
15. i = van't Hoff factor
κ×1000 
9. m = Scm 2 mol –1 κ=G×G 16.  = osmotic pressure
C
 cm 17.  m = Molar conductivity
10. = o
m 18.  = Specific conductance/conductivity
11.  om = v+ +0 + v– –0 19. G = Conductance
12. m = Z  I t 20. G* = Cell constant (l /a)

13. k=
 R0  –  R  t1/2 =
 R0  21.  = Degree of dissociation
t 2 22. v+ / v– = No. of ions

14. k=
2.303 R 
log 0 t1/2 =
0.693
23. +0 / −0 = Limiting conductivity of ions
t  R k
24. Z = Chemical equivalent
k Ea  T2 – T1 
15. log 2 =   25. k = rate constant
k1 2.303R  T1T2 
26.  R0  = Initial concentration of reactant
27.  R  = Concentration of reactant
28. Ea = Activation energy
29. t1/2 = Half life

30.  0m = Limiting molar conductivity