JHARKHAND UNIVERSITY OF TECHNOLOGY

SUBJECT- CHEMISTRY
SEMESTER-1ST

Course Code BSC102

Category Basic Science Course
Course Title Chemistry-I
Contents
(i)Chemistry-I (Concepts in Chemistry for Engineering)
(i)Chemistry Laboratory
Scheme& Credits L T Credit Semester I
1
Pre-requisites Knowledge of Intermediate Level Chemistry

CHEMISTRY-I

CONCEPTS IN CHEMISTRY FOR ENGINEERING 42 Lectures

Module-1: Atomicand molecular structure [10Lectures]

Schrodinger equation. Particle in box solutions and their applications for conjugated
molecules. Molecular orbitals of diatomic molecules and plots of the multicentre orbitals.
Equations for atomic and molecular orbitals. Energy level diagrams of diatomics. Pi
molecular orbitals of butadiene and benzene and aromaticity. Crystal field theory and the
energy level diagrams for transition metal ions and their magnetic properties. Band
structure of solids and the role of doping on band structures.

Module-2 : Spectroscopic techniques and applications [6 Lectures]

Principles and Applications of Electronic spectroscopy and Nuclear magnetic resonance.

Vibrational and rotational spectroscopy of diatomic molecules and its applications.
Fluorescence and its applications in Medicine. Surface Characterisation Techniques
(Scanning Electron Microscopy and Transmission Electron Microscopy)
Module-3: Intermolecular forces [4 lectures]

Ionic, dipolar and van Der Waals interactions. Measurement of non-covalent interaction,
Hydrogen bond, Equations of state of real gases and critical phenomena.
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Module: 4: Use of free energy in chemical equilibria [8 Lectures]

Thermodynamic functions: energy, entropy and free energy. Estimations of entropy and
free energies. Free energy and emf. Cell potentials, the Nernst equation and applications.
Acid base, oxidation reduction and solubilityequilibria. Corrosion: Introduction, Causes,
consequences, Mechanism, Laws of Dry Corrosion, Wet Corrosion,Factors Influencing
Corrosion, Protective measures against corrosion. Use of free energy considerations in
metallurgy through Ellingham diagrams.
Module-5: Periodic properties and Stereochemistry [8 Lectures]
Effective nuclear charge, penetration of orbitals, variations of s, p, d and f orbital energies
of atoms in the periodic table, electronic configurations, atomic and ionic sizes,
ionization energies, electron affinity and electronegativity,polarizability, oxidation states,
coordination numbers and geometries, hard soft acids and bases.
Representations of 3 dimensional structures, structural isomers and stereoisomers,
configurations and symmetry and chirality, enantiomers, diastereomers, optical activity,
absolute configurations and conformational analysis.
Module-6: Polymer [6 lectures]
Classification of polymers, Mechanism of Polymerisation, structure-property
relationship, conductive polymers.
Books
University Chemistry, by B.H.Mahan
Chemistry, Second Edition, By Prasanta Ratha and S. Chakroborty -Cengage pub
Engineering Chemistry by Jaya Shree Anireddy, Wiley publication
Text book of Engineering Chemistry ,First Ed.2019, By Sashi Chawala, Dhanpat
Rai, publication
Chemistry: Principles and Applications, by M.J.Sienkoand R.A.Plane
Fundamentals of molecular Spectroscopy, by C.N.Banwell
Engg Chemistry(NPTEL Web Book),by B.L.Tembe, Kamaluddin and
M.S.Krishnan
Physical Chemistry, by P.W.Atkins
Organic Chemistry: Structure and Function by K.P.C. Volhardt and N.E. Schore,
sth Edition http://bcs.whfreeman.com/volhardtschoreSe/default,asp

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 102
AU

Jharkhand University of Technology, Ranchi

2nd Semester B.Tech. Examination, 2022
Subject : Chemistry SubjectCode :BSC-102
Time Allowed :3 Hours FullMarks : 70

Candidates are req1uired to give the answers in their own words as far as practicable.
Answer any five questions.
All the questions are equal value.
Question No. I is compulsory.

1. Multiple Choice Type Questions: 2x7=14

(i) The sizes of the electron clouds of 3s, 3p and 3d are,

(a) 3s>3p>3d (b) 3s<3p>3d
(c) 3p>3s>3d (d) 3p>3d>3s
(ii) The Bond order of CN is.
(a) 1 (b) 2
(c) 3 (d) 0

(ii) Diagnosis of soft tissues of human body based on the principle of

(a) Pauli's (b) Transition method
(c) Hand's (d) NMR
(iv) The excluded volume for each molecule of the gas is
(a) two times of its actual volume. (b) three times of its actual volume.
(c) four times of its actual volume. (d) None of these
(v) Electrochemical corrosion occurs
(a) on homogeneous metal surface (b) on heterogeneous metal surface
(c) Both (d) None of these
(vi) Which of the following elements will have the highest electron affinity?
(a) (Ne] 3s3p (b) [Ne] 3s'3p
(c) [Ne] 3s3p (d) [Ne] 3s
(vii) Buna - S is
(a) Natural rubber (b) Sulphur rubber
(c) Synthetic rubber (d) None of these

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102 (2)
2. (a) Explain crystal field theory. How can it be utilised in explaining the octahedral complexes in
transition metal ion.

(b) With the help of M.O.theory. predict which of the following is diamagnetic:
Hj, 0, and 0 7+7=14

3. (a) Define the following terms: 4x2h=10

(i) Bathochromic shift
(i) Hypochromic shift
(iii) Chromophore
(iv) Hyperchromic efect
(b) Define NMR and MRI. 4

4. (a) Discuss in details the cause of Wet corrosion. Mention its mechanism.
(b) What is Nernst equation? Write is application. 10+4=14

5. (a) Define with suitable example: 4x2=8

(i)) lonisation Isomerism
(ii) Hydrate Isomerism
(ii) Linkage Isomerism
(iv) Co-ordination Isomerism
(b) Differentiate between structural isomerism and stereo isomerism. 6

6. (a) Define polymerization. Differentiate between addition and condensation polymerization.

(b) Write preparation. properties and application of PVC. 6+8=14

7. Write short notes on: 4x32=14

(a) Hydrogen bond
(b) Physical significance of wavefunction Yand y
(c) Hard, soft acids and bases
(d) Internal energy and enthalpy
 102
All

Jharkhand University of Technology, Ranchi

Ist Semester B.Tech. Examination, 2021
Subject : Chemistry-1 Subject Code : BSC-102
Time Alowed : 3 Hours Full Marks: 70
Pass Marks : 21

Cndidates are required to give the answers in their ownwords

as far as practicable.
Question No.l is compulsor and
answer any four from the rest.

1. Answer the following: 2x7=14

(i) In which of the following has highest magnetic moment?

ta) Fe'* (b) Ni
(d) Cu'

(ii) In doping the impurity is added to increase

(a) No. of protons b No. of electrons
(c) No. of neutrons (d) None of these

(ii) The region of electromagnetic spectrum for NMR is

(a) Infrared (b) Microwave
(CRadio wave dttv-rays
(iv) Which of the following is not an example of rubber?
(a) Polychloroprene (b) Buna-N
(c) Butadiene styrene copolymer Ad Polyacrylonitrite
(v) Which of the following is a type of thermodynamics system?
(a) Open system (b) Closed system
(c) Thermally Isolated System Led All of these
(n) Oxidation no. of Ni metal in [Ni(CO),] is

c) +2 (d) +1
(vii) Which of the following materials will undergo corrosion?
tay Metals only
(b) Metal and non-metals
(c) Metals, non-metals, ceramics and plastics
(d) Metals, non-metals, ceramics, plastics and rubber
Or.
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529
102 (2)

Explain
(a) Hydrogen bond (b) Hyper chromic effect
(c) Gibbs free energy (d) Chemical corrosion

. Derive Schrödinger Wave equation. Describe physical significance of Wave Functions y and ñ.
8+6=14
3 (a) Differentiate between
(i) Atomic and Molecular orbitals

(ii) Bonding and Antibonding orbitals 7

by What is Band Theory? Differentiate between insulator, conductor and

semiconductor on the
basis of Band Theory. 7

A. (a) Discuss the principle of NMR spectroscopy and also discuss why methanol is a
good solvent
for UV but not for IR
spectroscopPy. 6

(b) erive expression for the calculation of Pe, Ve and T, in terms of van der Waal's constant. 8

S la) Derive Nernst equation for single electrode potential and explain the terms involved in it. 6

(b) Define corrosion of metals. What are different types of corrosion? Explain the
Electro-chemical Theory of wet corrosion. 8

6. (a) Define electron affinity, electronegativity, atomic radius and ionization energy and explain their
trends in a period and group in periodic table. 10

(b) Describe the conformational Isomer of n-butane. 4

7. (a) Define polymerization. Differentiate between addition and condensation polymerization.

(b) Define entropy. Derive expression of entropy change for an ideal gas.
 102
ALL
Jharkhand University of Technology, Ranchi
B.Tech. 1st Semester Examination, 2022
Subject :Chemistry
Time Allowed : 3 Hours Subject Code : BSC-102
FullMarks : 70
Candidates are requested togive the answers in their own words as far as
Answer any five questions in which Question No. 1 is practicable.
All questions are of equal value.
compulsory.
1. Answer the following questions : 2×7=14
(i) Which of the
following have identical bond orders?
(a) CN
(b) 07
(c) NO+
(d) CNt
(ii) In Insulator
tá) the valence band is completely filled and
conduction band is empty.
(b) conduction band is
completely filled and valence band is empty.
(c) both conduction band and
valence band are empty.
(d) both conduction band and valence
band are completely filled.
(iii) The region of
electromagnetic spectrum for NMR is
(a) Microwave
6) Radio frequency
(c) Infrared
(d) UV-rays
(iv) The behaviour of a real gas approaches ideal
behaviour at
(a) low temp., low pressure
(b) high temp., high
(c) low temp., high pressure pressure
kj high temp.,low pressure
(v) Which of the following is lewis acid?
(a) NH3
(b) H,0
(c) CN
Ad) AICl,
(vi) Which of the following
compounds well exhibit Optical Isomerism?
(I) CH,CH(OH) CH,
(II) CH,CH(OH)CI
(II) CzHsCH(Br) CH(CH;),
(IV) CH,(CI)CH,OH
ka) () and (III)
(b) (II) and (IV)
(c) Only (I)
(d) Only (IV)
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(2)

(vii) The S' in Buna-S represents to

(a) Sulphur 5) Styrene
(c) Sodium (d) None of these

2. Describe and compare the splitting of d-orbitals under the influence of octahedral and
tetrahedral Ligand fields.
(b) Calculate crystal field stabilisation energy of d, d5, d° configuration. 8+6=14

3. ( Discuss different kinds of electronic transitions. Explain chromophores and auxophores.

by Discuss the principle ofUV-visible spectroscopy. 7+7=14

4. ( Derive van der Waal's equation of state of n moles of a gas.

(b) What are the units of van der Waal's constants? 10+4=14

5. (a) Explain the term (i) internal energy, (ii) enthalpy. What is the difference between them?
(ey Define :
Chemical corrosion, Pitting corrosion, Stress corrosion 7+7=14

6. Define the following and explain their trends in a period and in a

group of periodic table : 14
(a) Electron affinity . (b) Electronegativity
(c) Atomic radius (d) Ionisation energy
7. Write short notes on:
14
(a) Homo polymer and copolymer
b) Addition polymerisation
(e Condensation polymerisation
(d) Industrial use of plastic