UNIT TEST 1 – JUNE 2021

GRADE 11

CHEMISTRY
Class:11 Duration: 1 ½ Hrs
Date: 16/06/2021 Max Marks: 40
-----------------------------------------------------------------------------------------------------------------------
General Instructions. Read the following instructions carefully.
• There are 21 questions in this question paper. All questions are
compulsory.
• Section A: Q. No. 1 to 2 are case-based questions having four MCQs or
Reason Assertion type based on given passage each carrying 1 mark.
• Section A: Q. No. 3 to 12 are MCQs and Reason Assertion type questions
carrying 1 mark each.
• Section B: Q. No. 13 to 17 are short answer questions and carry 2 marks
each.
• Section C: Q. No. 18 to 20 are short answer questions and carry 3 marks
each.
• Section D: Q. No. 21 is a long answer question carrying 5 marks.
• There is no overall choice. However, internal choices have been provided.
• Use of calculators and log tables is not permitted

Section-A
1. Read the passage given below and answer the following
questions:
The mole concept is defined as the amount of substance of a
system which contains as many elementary entities (atoms,
molecules, ions, electrons, quanta, or other entities) as there are
carbon atoms in 0.012kg of C-12 isotope (Fang, Hart & Clark,
2014; Furio et al., 2000). The concept makes it possible to count
the microscopic entities taking part in chemical processes by
carrying out chemical reactions at macroscopic level using
volumes and masses of reacting substances (Furio et al., 2000;
Furio, Azcon & Guisasola, 2002). Thus an understanding of the
mole concept is key in laying a strong foundation in chemistry.
The following questions are multiple choice questions.
Choose the most appropriate answer:

(i) Calculate the number hydrogen atoms in 18 moles of water 1

(a) 36 atoms
(b) 18 atoms
 (c) 36 moles of atoms
(d) 18 moles of water
(ii) Which one of the following will have the largest number of 1
atoms?
(a) 1 g Au (s)
(b) 1 g Na (s)
(c) 1 g Li (s)
(d) 1 g of Cl2(g)
(iii) How many moles of alanine, C3H7NO2, are there in 159 g of alanine? 1
(a) 1.42 x 104
(b) 1.78
(c) 0.992
(d) 0.560
(e) 3.31
(iv) Calcium carbide and water react to produce ethyne and calcium 1
hydroxide
CaC2(s) + 2H2O(l) → C2H2(g) +Ca(OH)2(s)
What is the mass of ethyne produced when 45g of water
reacts completely with calcium carbide.
(a) 45g
(b) 32.5g
(c) 26g
(d) 50g

2. Read the passage given below and answer the following

questions:

Atoms consist of three basic particles: protons, electrons, and

neutrons. The nucleus (center) of the atom contains the protons
(positively charged) and the neutrons (no charge). The outermost
regions of the atom are called electron shells and contain the
electrons (negatively charged). Atoms have different properties
based on the arrangement and number of their basic particles.
The hydrogen atom (H) contains only one proton, one electron,
and no neutrons. This can be determined using the atomic
number and the mass number of the element.

In these questions, a statement of assertion followed by a

statement of reason is given. Choose the correct answer out
of the following choices.

a) Assertion and reason both are correct statements and reason

is correct explanation for assertion.
b) Assertion and reason both are correct statements but reason
is not correct explanation for assertion.
c) Assertion is correct statement but reason is wrong statement.
d) Assertion is wrong statement but reason is correct statement
 (i) Assertion: Atom is electrically neutral. 1
Reason: A neutral particle, neutron is present in the nucleus of
atom
(ii) Assertion: Bohr’s orbits are called stationary orbits. 1

Reason: Electrons remain stationary in these orbits for

sometime.
Following questions (No. 3 -11) are multiple choice questions
carrying 1 mark each:
3. An atom having atomic mass number 13 has 7 neutrons. What is 1
the atomic number of the atom?
(a) 13
(b) 7
(c) 6
(d) 20
4. What will be the molarity of a solution, which contains 5.85 g of 1
NaCl(s) per 500 mL? (Na - 23g/mol Cl – 35.5g/mol)
(a) 4 mol L–1
(b) 20 mol L–1
(c) 0.2 mol L–1
(d) 2 mol L–1
5. Which of the following pairs are isoelectronic cations with argon? 1
(a) Na+,Mg2+
(b) K+, Ca2+
(c) Ca+, Mg2+
(d) K+, Mg2+
6. The de Broglie wavelength associated with a material particle 1
(a) Directly proportional to its energy
(b) Directly proportional to its momentum
(c) Inversely proportional to its energy
(d) Inversely proportional to its momentum

7. Which of the following quantum numbers governs the spatial 1

orientation of an atomic orbital?
(a) Magnetic quantum number
(b) Spin quantum number
(c) Azimuthal quantum number
(d) Principal quantum number
8. Which of the following will not show deflection from the path on 1
passing through an electric field?
(a) Proton
(b) Positron
(c) neutron
 (d) electron
9. The limiting reagent in a chemical reaction is one that: 1
(a) has the largest molar mass (formula weight).
(b) has the smallest molar mass (formula weight).
(c) is consumed completely.
(d) is in excess.

10. Assertion: An orbital cannot have more than two electrons, 1

moreover, if an orbital has two electrons they must have opposite
spins.
Reason : No two electrons in an atom can have same set of all the
four quantum numbers.
(a) Both A and R are true and R is the correct explanation of
A.
(b) Both A and R are true but R is not the correct explanation
of A.
(c) A is true but R is false.
(d) A is false but R is true.
11. Assertion: Filling of 3d takes place before 4s subshell. 1
Reason: The (n+l) value of 3d is greater than 4s.
(a) Both A and R are true and R is the correct explanation of
A.
(b) Both A and R are true but R is not the correct explanation
of A.
(c) A is true but R is false.
(d) A is false but R is true.
12. Assertion: Number of atoms of He in 60u of He is 15 1
Reason : Atomic weight of He is 4u.
(a) Both A and R are true and R is the correct explanation of
A.
(b) Both A and R are true but R is not the correct explanation
of A.
(c) A is true but R is false.
(d) A is false but R is true.
Section-B
13. Calculate the energy required for the process 2
He+(g) → He2+(g) + e–
The ionization energy for the H atom in the ground state is
2.18 ×10–18 J atom–1

14. (i) What is the lowest value of n that allows g orbitals to exist? 2
(ii) Using s, p, d notations, depict the orbital with the following
quantum numbers.
(a) n=1, l=0; (b) n = 4; l =2;

15. (i) What is the maximum number of emission lines when the 2
excited electron of a H atom in n = 6 drops to the ground
state?
(ii) What are degenerate orbitals?
16. Calculate the mole fraction of benzene and methane in a solution 2
containing 32g of methane and 39g of benzene.

17. An organic compound contains 69.77% carbon, 11.63% 2

hydrogen and rest oxygen. The molecular mass of the compound
is 86. Calculate the empirical formula and molecular formula.

Section-C
18. (i) Write two difference between an orbital and an orbit. 3
(ii) Explain, giving reasons, if the following sets of quantum
numbers are possible or not
(a) n = 0, l = 0, ml = 0, ms = + ½
(b) n = 3, l = 3, ml = –3, ms = + ½.
19. (i) State Hund’s Rule of maximum multiplicity. 3
(ii) How many electrons in an atom may have the following
quantum numbers?
(a) n = 4, ms = – ½ (b) n = 3, l = 0
(iii) Write the electronic configurations of the following ions:
(a) Na+ (b) S2– (Na -11, S -16)

20. Calculate the wavelength, frequency and wavenumber of a light 3

wave whose period is 2.0 × 10–10 s.

Section-D
21. (i) What is the consequence of Heisenberg’s uncertainty 5
principle?
(ii) State Pauli’s exclusion Principle.
(iii) If the kinetic energy of an electron is 18.2x10-25 J,
calculate the wavelength associated with it.
(Mass of an electron is 9.1x10-31kg)