CARMEL CONVENT SCHOOL , KUNJWANI

TERM-II SESSION -2023-24

CHEMISTRY THEORY (043)

CLASS:XI. M.M :70

TIME : 3Hrs
General instructions: Read the following instructions carefully.
(a) There are 33 questions in this question paper. All questions are compulsory.
(b) Section A: Question no. from 1 to 16 are MCQs & assertion reason type question
carrying 1 mark each
(c) Section B: Question no. 17 to 24 are short answer questions & carry 2 marks each.
(d) Section C: Question no. 25 to 29 are short answer questions & carry 3 marks each.
(e) Section D: Question no. 30 to 31 are Case based questions & carry 4 marks each
(f) Section E: Question no. 32 to 33 are long answer questions & carry 5 marks each

Section -A
[Very Short Answer Type Questions] 1 each
Q1: The pair of ions having same electronic configuration is;

a) Cr3+ , Fe3+

b) Fe3+ , Mn2+

c) Fe3+ , Co3+

d) Sc3+ , Cr3+

Q2: Bohr atomic model can explain

a) the spectrum of hydrogen atom only

b) spectrum of an atom orion containing one electron only

c) the spectrum of hydrogen molecule

d) the solar spectrum.

Q3: Among the following four elements, the ionisation potential of which one is the highest?
1. Oxygen. 2. Argon. 3. Barium. 4. Caesium
Q4: Mendeleev classified elements in:
1. Increasing order of atomic groups.
2. Seven periods and eight groups.
3. Seven periods and nine groups
4. Eight periods and seven groups.
Q5: For the reaction C(s) + O2(g) → CO2(g)

a) △H >△U

b) △H < △U

c) △H = △U

d) None

Q6:In which of the following pairs, the ions are iso- electronic?

a) Na+, Mg2+

b) Al3+, O2-

c) Na+, O-

d) N3- , Cl

Q7: Draw the structure of hex-3-en-1-ol ?

Q8 What is the order of the metallic character down the group?

a) It decreases as new shells are added to the element

b) It increases as electrons move away from the nucleus

c) It increases as new atoms are added to the same shell

d) It decreases as the effective nuclear charge on the electron increases

Q9 Which of the following statements concerning the quantum numbers are correct?
a) Angular quantum number determines the three dimensional shape of the orbital.
b) The principal quantum number determines the orientation and energy of theorbital.
c) Magnetic quantum number determines the size of the orbital.

d) Spin quantum number of an electron determines the orientation ofthe spin ofelectron relative to the
chosen axis.

Q10.Any p-orbital can accommodate up to:

(a) Four electrons. (b) Two electrons with parallel spins. (c) Six electrons. (d) Two electrons with
opposite spins.
Q11.The tendency of an species to lose electrons is known as
(a) Electrode Potential
(b) Reduction
(c) Oxidation
(d) E.M.F.

Q12.The number of elements in the 4th period of periodic table is:

(a) 8
(b) 10
(c) 18
(d) 32
Q13.Which expression represents de Broglie relationship?
(a) P = h/mv (b). λ = h\mv
(c)λ = h\mp. (d) λm= v/p

Q14 (A) Both A and R are correct and R is the correct explanation of A.
(B) Both A and R are correct but R is not the correct explanation of A.

(C) Both A and R are not correct.

(D) A is not correct but R is correct.

Assertion (A): Electron gain enthalpy becomes less negative as we go down agroup.
Reason (R): Size of the atom increases on going down the group and the added electron would be
farther from the nucleus.
Q15(A) Both A and R are correct and R is the correct explanation of A.

(B) Both A and R are correct but R is not the correct explanation of A.

(C) Both A and R are not correct.

(D) A is not correct but R is correct.

Assertion (A): Combustion of all organic compounds is anexothermic reaction.

Reason (R): The enthalpies of all elements in their standard state arezero.

Q16 (A) Both A and R are correct and R is the correct explanation of A.

(B) Both A and R are correct but R is not the correct explanation of A.

(C) Both A and R are not correct.

(D) A is not correct but R is correct.

Section-B
 [Short Answer Type Questions- Type-I] 2 Marks each
Q17. i. State Heisenberg uncertainty principle.
ii. Describe the first law of thermodynamics ?
Q18. Show that for an ideal gas Cp- Cv = R ?

Q19. For the general reaction derive the relationship between Kp & Kc ?

Q20.Consider the following species:

N3-, O2- , F-, Na+ , Mg2+, and Al3+
a) What is common in them?
b) Arrange them in the order of increasing ionic radii.
Q21 Distinguish between Sigma(σ) and pi(π) bond.

Q22.Discuss PhotoElectric effect.What are the essential conditions required.?

Q23 Give two preparation of benzene .

Q24: Draw the molecular energy level diagram of O2 and Calculate it's Bond order ?

Section -C

[Short Answer Type Questions- Type-II] 3 Marks each

Q25: An organic liquid having carbon, hydrogen, nitrogen and oxygen as found to contain C = 41.37%;
H-5.75% N=16.09% and the rest oxygen. Calculate the molecular formula of the liquid if its Vapour
density is 43.3.

Q26: Permanganate ion reacts with bromide ion in basic medium to give manganese dioxide and
bromate ion. Write the balanced ionic equation for the reaction.

MnO4- (aq) + Br-(aq) → MnO2(s) + BrO3- (aq)

Q27 : i . State and explain the common ion effect.?

ii Give the concept of acid and base according to Arhenius.

Q28 : State Le chatelier’s principle. Apply it to the manufacture of ammonia.

Q29: How ionisation energy vary along the period and down the group?

Section-D
 [Case Based Questions]. 4 Marks each
Q30. Read the passage and choose the correct option in the following questions:

Atoms and molecules are so small in size that it is neither possible to count them individually
nor possible to determine their mass. These are counted collectively in terms of Avogadro’s
number. The mass of Avogadro’s number of atoms and molecules is known as gram atomic
mass and gram molecular mass respectively. A mole represents Avogadro’s number
(6.22x1023) NA. particles of substance.
Empirical formula gives the simplest whole number ratio of the atoms of various elements
presentin one molecule of compound. Molecular formula gives the actual ratio of various
elements present in one molecule of the compound.A limiting reactant limits the participation
of all other reactants in a chemical reaction.
(i) In the reaction mixture 2H2 + O2 --> 2H2O, H2 is 2.5g and O2 = 32g , the limiting reactant will be (a)
H2O. (b) O2. (c) H2. (d) All above
(ii) The empirical formula and molecular mass of a compound are CH2O and 180 g respectively. What
will be molecular formula of the compound?

(a) C9H18O9
(b) C2H4O2
(c) CH2O

(d) C6H12O6
(iii) The mass percent of carbon in carbon dioxide is:
(a) 0.034%
(b) 27.27%
(c) 3.4%
(d) 28.7%

(iv) Empirical formula is the _______ Ratio of the atoms .

(a) actual . (b) Simplest . (c) both a & b (d) None of the above

Q31 Read the given passage and answer the questions that follow based on passage and related studied
concepts.
Orbitals are region or space where there is maximum probability of finding electrons. Qualitatively,
these orbitals can be distinguished by their size, shape and orientation. An orbital of small size means
there is more chance of finding the electron near the nucleus. Shape and orientation means the
direction in which probability of finding electron is maximum. Atomic orbitals can be distinguished by
quantum numbers. Each orbital is designated by three quantum numbers n, l and ml (magnetic quantum
number) which define energy, shape and orientation but these are not sufficient to explain spectra of
multi-electrons atoms. Spin quantum number (ms) determines the spin of electron. Spin angular
momentum of electron has two orientations relative to chosen axis which are distinguished by spin
quantum numbers ms which can take values +1/2 and –1/2.
a. What is shape of 's' and 'p' orbitals ?
b. What subshells are possible in n = 3 energy level?
c. Give the sets of quantum numbers that describe an electron in a 3p orbital.
d. A sub shell with n=6, l=2, can accommodate a maximum of __________ electron.

Section-E

[Long Answer Type Questions] 5 Marks each

Q.32: Write the IUPAC name of the following organic compounds:

1) CH3-CH2-CH2-CH3

2) CH3-CH(CH3)-CH3-CH3

3) CH3=CH-CH3

4) CH3-CH=CH-CH2-CH3

5) CH≡CH
OR

b) Describe the valence shell electron pair repulsion theory., Explain the bond angle and shape of
BeF2 , BF3 ?

Q33: Describe the main postulates of Rutherford atomic model.Calculate the energy associated with
first orbit of H+ ion. What is the radius of this orbit?
OR

Describe briefly the quantum numbers.?

Q34. Describe the Markonikov rule and Anti-markonikov rule with examples .

OR

Describe the types of organic Reactions .?