Annual Examination

Session: 2020-21
Class: [ XI ] MM: 70
Date: 05.03.2021 Subject: Chemistry Time: 3 hrs
Name : ……………… (Sub. Code: 043) Roll No: ……

(SET B)
General instructions :-
a. All questions are compulsory.

b. Section A: Q.no. 1 to 16 are very short answer questions and carry 1 mark each.
c. Section B: Q.no. 17 to 25 are short answer questions and carry 2 marks each.

d. Section C: Q.no. 26 to 30 are long answer questions and carry 3 marks each.
e. Section D: Q.no. 31 to 33 are also long answer questions and carry 5 marks each.
f. There is no overall choice. However an internal choice has been provided in two questions
of two marks, two questions of three marks and all the three questions of five marks
weightage. You have to attempt only one of the choices in such questions.
g. Use log tables if necessary, use of calculators is not allowed.

Q.1 Orbitals are region or space where there is maximum probability [4]
of finding electrons. Qualitatively, these orbitals can be
distinguished by their size, shape and orientation. An orbital of
small size means there is more chance of finding the electron near
the nucleus. Shape and orientation means the direction in which
probability of finding electron is maximum. Atomic orbitals can
be distinguished by quantum numbers. Each orbital is designated
by three quantum numbers n, l and ml (magnetic quantum number)
which define energy, shape and orientation but these are not
sufficient to explain spectra of multi-electrons atoms. Spin
quantum number (ms) determines the spin of electron. Spin
angular momentum of electron has two orientations relative to
chosen axis which are distinguished by spin quantum numbers ms
which can take values +1/2 and –1/2.

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 Value of 'l' 0 1 2 3 4
Notation for subshell s p d f g
(a) How many orbitals are associated with n = 3?
(b) Describe the orbitals represented by (i) n = 2, l = 1 (ii) n = 4, l = 0.
(c) How many electron are possible in an orbital? Why?
(d) What is shape of 's' and 'p' orbitals?
Q.2 Organic reactions can be classified into four main categories. [4]
Substitution reactions, addition reactions, elimination reactions
and rearrangement reactions. Substitution reactions can be further
classified into free radical, nucleophilic and electrophilic
substitution reactions. Addition reactions can be nucleophilic as
well as electrophilic addition reactions. Dehydration, dehydrohalo-
genation, dehalogenation are examples of elimination reactions.
Conversion by ammonium cyanate to urea is an example of
rearrangement reactions. Reactions are classified on the basis to
nature of intermediate species formed. Mechanism of reaction is
exact path followed by the reaction involving all steps showing
intermediates and slowest steps of the reaction which is rate
determining step. Oxidation, reduction, combustions reactions are
also important in hydrocarbons
(a) Halogenation of alkane is an example of which type of reaction?
(b) What happens when 2-methyl propane is heated with KMnO4?
(c) What type of reaction takes place when n-hexane is heated in
presence of AlCl3(anhy.) and HCl?
(d) CH3CH2Cl + KOH(alc) → CH2==CH2 + KCl + H2O
What is the type of reaction?

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 Q.3 Conjugate base of NH2- is- [1]
a) NH3 (b) NH- (c) NH2- (d) NH4+
Q.4 The first ionization enthalpy of Na, Mg, Al and Si are in the [1]
order-
a) Na ˂ Mg ˃ Al ˂ Si b) Na ˃ Mg ˃ Al ˃ Si
c) Na ˂ Mg ˃ Al ˂ Si d) Na ˃ Mg ˃ Al ˂ Si
Q.5 The IUPAC name of CH3 – CH = CH – C ≡ CH2OHis: [1]
a) pent-3-en-1-yne 1-ol b) pent-3-en-4-yne 1-oic acid
c) pent-2-en-4-yne d) pent-2-en-3-yne1-al
Q.6 The electronic configuration of K is [1]
a) (Ne) 3s2 3p5 4s2 b) (Ne) 3s2 3p6 4s1
c) (Ar) 4s1 d) (Ar) 4s2

Q.7 Which of the following is a transition element [1]

a) Sc b) Na c) Ca d) Fr
Q.8 The element in which electrons are progressive filled in 4f orbital [1]
are called
a) Actinoids b) Transition elements
c) Lanthanoids d) Halogens
Q.9 Which molecule/ion out of the following does not contain [1]
unpaired electrons.
a) N2+ b) O2 c) O22- d) B2
Q.10 Species having bond order 3 is- [1]

a) N2 b) N2- c) F2+ d) O2--

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 In the following questions, a statements of Assertion is followed
by a corresponding statement of Reason of the following
statements, choose the correct one.
(i) Both Assertion and Reason are correct statements, and
Reason is correct explanation of these Assertion.
(ii) Both Assertion and Reason are correct statements, and
Reason is not the correct explanation of these Assertion.
(iii) Assertion is true, but Reason is incorrect statement.
(iv) Assertion is incorrect, but Reason is correct statement.
Q.11 Assertion :- 30 Carbocation is more stable than 20 Carbocation. [1]
Reason: Greater the number of hyperconjugative structures
more will stability of carbocation
Q.12 Assertion: Isobutane has higher boiling point than n-Butane. [1]
Reason : Isobutane has lower surface area than n-Butane
Q.13 Assertion :- Rutherford bombarded alpha particles on gold foil. [1]
Reason :- Platinum metal was not discovered by that time.
Q.14 Assertion- Molality depends on temperature [1]
Reason- Molality is better concentration expressing unit than
molarity
Q.15 Which of the following species has tetrahedral geometry [1]
a) BH4- b) NH2- c) CO32- d) H3O+
Q.16 In which of the following substances will hydrogen bond be [1]
strongest
a) HCl b) H2O c) HI d) H2S
Q.17 Write the conjugate acid and conjugate base of HSO4- [2]

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 Q.18 Balance the following redox reactions : [2]
MnO4– +I – → MnO2 + I2 (Basic medium )
Q.19 Explain vanderwaal equation. [2]
OR
What will be the pressure exerted by a mixture of 3.2 g of methane
and 4.4 g of carbon di oxide contained in a 9 dm3 flask at 27o c
Q.20 Write IUPAC name of the following organic compounds- [2]
(i) CH3-CH2-CH=CH-CHO
(ii) CH3-CH2-CH(CH3)-C(CH3)3
Q.21 Explain: [2]
a) Nitration b) Isomerization
Q.22 Draw the structure of following compound accoding to VSEPR- [2]
a) XeF4 b) H2O
Q.23 Calculate the wavelength of an electron moving with a velocity [2]
of 3.05 × 106 m s–1.
(Mass of electron = 9.1 x 10-31 Kg, h = 6.62 x 10-34 JS)
Q.24 a) State Modern periodic Law. [2]
b) Write IUPAC name and symbol of the element having Z=124.
OR
What do you mean by isoelectronic species? Explain giving
one example
Q.25 Explain Conformation of Ethane. [2]
OR

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 What happens when-
a) Conc. Sulphuric acid is added to ethyl alcohol.
b) Ethyne is passed through red hot iron tube.
Q.26 Draw the MOT diagram for N2 [3]
Q.27 The reaction of cynamide , NH2CN (s) with oxygen was affected [3]
in a bomb caloriemeter and internal energy was found to be – 742.5
KJ/mol of cynamide at 298 K. Calculate the enthalpy change for
the reaction at 298 K.
NH2CN (s) + 3/2 O2(g) → N2(g) + CO2 (g) + H2O
Q.28 a) State Pauli’s exclusion principle. [3]
b) Write value of ‘n’ & ‘l’ for 5d orbital.
c) Draw shape of dxy and dz2 orbitals
Q.29 A compound contains 4.07% Hydrogen , 24.27% Carbon and [3]
71.65% Chlorine. Its molar mass is 98.96 g. What are its
empirical and molecular formula?
OR
3 g of H2 react with 29 g of O2 to form H2O.
a) Which is the limiting reagent?
b) Calculate the maximum amount of H2O formed.
c) Calculate the amount of the reactant left unreacted.
Q.30 (i) State Le-Chatelier’s principle. [3]
(ii) Explain buffer solution giving two examples?

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 Q.31 a) Explain the conformation of ethane molecule with the help of [5]
sawhorse and newmann projections ?
b) Explain Anti Markovnikov rule with one limitation.
OR
Conversion :-
a) Benzene to Toluene b) Ethyne to Benzene
c) Bromo butane to Octane d) Chloro ethane to ethene
e) Benzene to Benzene hexa chloride
Q.32 a) Draw the structure of the following compounds :- [5]
i) 3 Methyl 2,2 di ethyl Hexane
ii) 3 ethyl 1,1 di methyl cyclo hexane
b) Define the following terms :-
i) Hess law
ii) Ozonolysis
iii) Enthalpy of combustion
OR
a) Explain Homolytic and Heterolytic cleavage.
b) Give the IUPAC name of the following compounds :-

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 Q.33 a) Calculate the molecular mass of glucose [5]
b) Define molarity
c) Calculate the amount of water (g) produced by the
combustion of 16 g of methane
OR
A welding fuel gas contains carbon and hydrogen only. Burning a
small sample of it in oxygen gives 3.38 g carbon di oxide,0.690 g
of water and no other products. A volume of 10 L of this welding
gas is found to weigh 11.6 g . Calculate empirical formula,
Molecular formula and molar mass of the gas.

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