BGIS-Y201920-HY

Chemistry
MM: 70 GRADE-11(SCI) TIME: 3 hr
All questions are compulsory
Question 1 is of 20 marks having four sub parts, all of which are compulsory.
Question numbers 2 to 8 carry 2 marks each, with any two questions having
internal choice.
Question numbers 9 to 15 carry 3 marks each, with any two questions
having an internal choice.
Question numbers 16 to 18 carry 5 marks each, with an internal choice.
All working, including rough work, should be done on the same sheet as, and
adjacent to the rest of the answer.
Balanced equations must be given wherever possible and diagrams where
they are helpful.
When solving numerical problems, all essential working must be shown.
In working out problems, use the following data:

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Gas constant R = 1.987 cal deg-1 mol-1 = 8.314 JK-1 mol-1 = 0.0821 dm3 atm K-
1
mol-1. 1 l atm = 1 dm3 atm = 101.3 J. 1 Faraday = 96500 coulombs.
Avogadro’s number = 6.023 x1023.
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Question 1

(a) Fill in the blanks by choosing the appropriate word/words from those
given in the brackets: [4]

(Lattice enthalpy, greater, Trigonal planar, same, lower, bond

enthalpy, Pyramidal, linear)

(i) Shape of BCl3 molecule is __________

(ii) The amount of energy required to break one mole of bonds of a
particular type between the atoms in the gaseous state is called as
_________
(iii) Bond pair – bond pair repulsion is __________ than lone pair –
lone pair repulsion.
(iv) Bonding Molecular orbital possesses _________ energy than anti-
bonding Molecular orbital.

(b) Complete the following statements by selecting the correct

alternative from the choices given: [4]
1
 (i) The electronic configuration of outer most shell of the most
electronegative element is:
(1) ns2np3 (2) ns2np4 (3) ns2np5 (4) ns2np6

(ii) Which of the following species is diamagnetic in nature?

  
(1) He2 (2) H 2 (3) H 2 (4) H 2

(iii) Which of the following radius value is highest, for a same element?
(1) Metallic radius (2) Vander Waal radius
(3) Covalent radius (4) All are same

(iv) In which of the following elements, diagonal relationship does not

exist?
(1) Mg (2) Si (4) B (4) C

(c) Match the following: [4]

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(i) n (a) designates the orientation of orbital
(ii) l (b) orientation of the spin of the electron
(iii) ml (c) has values corresponding to ‘n’
(iv) ms (d) defines the shell

(d) Answer the following questions: [4 x 2]

(i) Write Finklestein reaction and Swart reaction for the preparation of
alkyl halides, along with equations.

(ii) Write any two tests for finding aniline, along with equations.

B2 H 6 / H 2O2 OH Cl2 / h
(iii)
CH 3C  CH   A 
NH 2 NH 2 / KOH

 B  C  D
Find A, B, C & D.

(iv) If A= CH 3  C  C  CH 3 ,
A O3
Zn / H 2O
B and A 
O3 / H 2O2
 C . Find B & C.

Question 2 [2]

2
(a) Calculate the energy associated with the first orbit of He+. What is the
radius of this orbit?
OR
(b) When light of wavelength 470 nm falls on the surface of potassium
metal, electrons are emitted with a velocity of 6.4 x 10 4 ms-1. What is
the minimum energy required to remove an electron from potassium
metal?

Question 3 [2]

An electron having mass 9.1 x 10-31 kg has a speed of 500 ms-1 with
uncertainty of 0.02%. What is the uncertainty in locating its position?

Question 4 [2]

(a) How can we distinguish between saturated and unsaturated

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hydrocarbons using Bromine water test. Write the equations.
OR
(b) Consider the following species: N3-, O2-, F-, Na+, Mg2+ and Al3+
(i) What is common in them?
(ii) Arrange them in the order of increasing ionic radii.

Question 5 [2]

What is Lucas reagent? How to distinguish between 1o, 2o and 3o

alcohols using this reagent?

Question 6 [2]


(i) Draw the Resonance structures of NO 3

(ii) State the differences between ionic and covalent compounds.

Question 7 [2]

At what temperature on Celsius scale will the volume of a given mass

of a gas at 0oC become half of its volume at constant pressure?

Question 8 [2]

3
 (a) Calculate the DU of following compounds:
(i) C6H6ClBrO (ii) C5H9N
(b) How many isomeric alkynes on hydrogenation gives
3,3-Dimethylhexane.

Question 9 [3]

How would you explain the fact that first ionization enthalpy of Na is
lower than that of Mg but its 2nd ionization enthalpy is higher than that
of Mg?

Question 10 [3]

0.16g of a dibasic organic acid requires 25cm3 of 0.1M NaOH for

complete neutralization. Find the molecular mass of acid?

Question 11 [3]

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(a) Write two differences between hydrogen and covalent bonds.
(b) Draw the geometry of XeF4 and write the shape.
OR
In following molecules, show the ground and excited states of central
atom and write the geometry and hybridization of the molecule.
(a) CH2=CH2 (b) PCl5

Question 12 [3]

(a) The average velocity of gas molecules is 400m/s. Calculate its r.m.s.
velocity at the same temperature.
OR
(b) What are the reagents used to form cis and trans alkenes from
alkynes? Write both reactions.

Question 13 [3]

4
 A gaseous mixture containing 50g of nitrogen and 10g of oxygen were
enclosed in a vessel of 10L capacity at 27oC. Calculate
(a) the number of moles of each gas.
(b) the partial pressure of each gas.
(c) the total pressure of gaseous mixture.

Question 14 [3]

Write the equations for following reactions.

(a) Nitration of benzene
(b) Sulphonation of methylbenzene
(c) Friedal-Craft’s alkylation of benzene.

Question 15 [3]
 

(a) A   B , A    C .

H 2O / H ( BH 3 )2 H 2O2 / OH

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If ‘A’ is
CH 3CH  CH 2 , find B and C.

(b)
CH 3 C  CH 
Tollen ' s Re agent
A
CH 3CH  O 
Tollen ' s Re agent
B 
Write the color of Precipitates A and B.

Question 16

(a) (i) Write the molecular orbital configuration of N 2. Calculate the

bond order and predict its magnetic behavior. [3]
(ii) What are the products obtained when 2-Chloropropane reacts
with
following reagents. [2]
(1) KCN (2) AgCN (3) KNO2 (4) AgNO2

OR

(b) (i) An electron is moving with a kinetic energy of 2.275x10 -25J.

Calculate its de-Broglie wavelength. [2]

(ii) Write the complete electronic configuration and no. of unpaired

electrons in Cr (Z=24), Si (Z=14) and Kr (Z=36) [3]
5
Question 17

(a) (i) Which of the elements Na, Mg, Si and P would have the greater
difference between the 1st and 2nd ionization enthalpies? Briefly
explain your answer. [2]
(ii) Arrange the elements in the order w.r.to mentioned property.
 
(1) Ionic size: I , I , I
   
(2) Ionic size: F , Li , Na , Cl
(3) Chemical reactivity: F, Cl, Br, I [3]

OR

(b) (i) A straight glass tube has two inlets X and Y at the two ends.
The
length of the tube is 200 cm. HCl gas through inlet X and NH 3

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gas through inlet Y are allowed to enter the tube at the same
time. White fumes first appear at a point P inside the tube. Find
the distance of P from X. [3]

(ii) 2.9 g of a gas at 95oC occupied the same volume as 0.184 g of

hydrogen at 17oC at the same pressure. What is the molar
mass of the gas?
[2]

Question 18

CH 3CH 2OH 

Conc. H 2 SO4
t oC
B
(a) (a) , Write the product B, when
t=80, 140 and 170. Write all 3 products. [3]

(b) Write along with equations

(i) HVZ reaction (ii) Hunsdiecker reaction [2]

OR

(a) Write along with equations (i) Wurtz reaction [2]

(ii) Williamson ether synthesis

6
 CH 3  MgCl  (i ) A
( ii ) H O 
B
(b) 3 . Find the product ‘B’, if ‘A’ is: [3]
(i) HCHO (ii) CH3CHO (iii) CH3COCH3

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