PROF.

RAKESH RATHI’S CHEMISTRY TUTORIALS 24-01-23

[70 MARKS] FULL PORTION CHEMISTRY THEORY TEST PAPER [HSC XII] [3 HR.]
PRELIM PAPER – I
 For each MCQ, the correct answer must be written along with its alphabet;
e.g., (a) ……/ (b) ……/ (c) ….. / (d) ……
 Evaluation of each MCQ would be done for the first attempt only.
 Draw neat, labelled diagrams and write balanced chemical equations wherever necessary
 Use log table if necessary. Use of calculator is not allowed.

SECTION (A)
Q.1) Select and Write the Correct Answer: [10]
1) The correct sequence of the atomic layers in cubic close packing is
1) ABABA 2) ABACABAC 3) ABCABC 4) AABBAABB
2) If equimolar solution is of urea, NaCl, sucrose and BaCl2 have boiling points A, B, C and D, then
1) A = C < B < D 2) A = D < B < C 3) A > B > C > D 4) A < B < C < D
3) The degree of dissociation of 0.1 M weak acid solution is 0.001. the ionisation constant of weak acid
will be _____
1) 10−5 2) 10−6 3) 10−7 4) 10−8
4) A mixture used for respiration by the sea divers is
1) He + O2 2) Ne + O2 3) Ar + O2 4) Kr + O2
5) The rate law for the reaction aA + bB ⎯→ P is rate = [A][B]. The rate of reaction doubles if:
1) Concentration of [A] and [B] both doubles 2) [A] is doubled and [B] is kept constant
3) [B] is doubled and [C] is halved 4) [A] is kept constant and [B] is halved
6) When an excess of AgNO3 is added to the complex one mole of AgCl is precipitated. The formula of
the complex is
1) [CoCl2(NH3)4]Cl 2) [CoCl(NH3)4]Cl2 3) [CoCl3(NH3)3] 4) [Co(NH3)4]Cl3
7) Which of the following compounds of chlorine is used as refrigerant?
1) CCl3NO2 2) CCl2F2 3) COCl2 4) CCl4
8) The general electronic configuration of Lanthanoids is
1) [Xe] 4f1−145d0-16s2 2) [Xe] 4f2−145d0-16s2 3) [Xe] 4f1−135d0-16s2 4) [Xe] 4f0−145d0-16s1
9) It is difficult to break C – Cl bond in CH2 = CH – Cl due to
1) Hyper conjugation 2) Resonance 3) Electromeric effect 4) Inductive effect
10) The monomer used to prepare orlon is
1) CH2 = CH – CN 2) CH2 = CHCl 3) CH2 = CH – F 4) CH2 = CF2
Q.2) Answer the Following [08]
I) The gas phase reaction between NO and Br2 is represented by the equation
2NO(g) + Br2(g) ⎯→ 2NOBr(g). Write the expression for the overall reaction in terms of rate of
consumption of reactant and formation of product.
II) Define “electrolysis”
III) Draw the structure of pyrosulphuric acid
IV) Zinc shows only one oxidation state. Explain.
(V) Draw enantiomers of the [Pt(en)3]4+ complexes.
(VI) Write the reaction for the preparation of Nylon-6

(VII) Write the IUPAC name of Cl C2H5

(VIII) Give cell representation for following reaction: Mg(s) + Br2(l) ⎯→ Mg(aq)2+ + 2Br−(aq)

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 PROF. RAKESH RATHI’S CHEMISTRY TUTORIALS 24-01-23
SECTION (B)
Attempt any EIGHT: [16]
3) Obtain the relationship between freezing point depression of a solution containing non-volatile
non-electrolyte and its molar mass.
4) Why is KCl solution neutral to litmus?
5) Write mathematical expression for the first law of thermodynamics in (a) adiabatic and (b) isobaric
process.
6) State and explain Kohlrausch’s law of independent migration of ions
7) Write the oxidation – reduction involved in the Nickel – cadmium storage cell.
8) Give the balance equation
(i) Chlorobenzene with CH3Cl and anhydrous AlCl3 (ii) Aniline with Bromine water
9) What is the action of hot and concentrated H2SO4 on (i) CaF2 and (ii) HI?
10) Distinguish between Lanthanoid
11) Define Flux. Give two uses of neon and actinoid
12) What is the difference between a double salt and a complex? Give an example.
13) Write preparation reaction of Buna-S. Give structure and IUPAC name of monomer of natural
rubber.
14) Write a note on Cannizaro’s reaction.

SECTION (C)
Attempt any EIGHT: [24]

15) What is unit cell? Calculate the packing efficiency of metal crystal that has simple cubic structure.
16) What are colligative properties? State and explain Henry’s law.
17) How phenol is obtained form chlorobenzene in Dow’s process. Give colouration test to distinguish
between Phenol and Ethanol
18) Write four salient feature of SN2 mechanism. Give Wurtz Fitting reaction.
19) Explain the geometry of [CoF6]3− on the basis of valence bond theory.
20) The vapour pressure of water at 20oC is 17 mm Hg. What is the vapour pressure of solution
containing 2.8 g urea in 50 g of water? [Mol. Wt. of Urea = 60 g mol−1]
21) Lithium crystallises in body centred cubic structure with edge length 350 pm. Determine the density
of lithium. (Atomic mass of lithium is 6.95 u)
22) Derive the relationship between degree of dissociation and dissociation constant for a weak acid.
23) Draw neat labelled diagram of S.H.E. Give its drawbacks.

24) Write preparation reaction of XeF2. What is action of following on XeF2 (i) H2O ii) PF5

25) What are d-block element. Give two uses of KMnO4. Give chemical formula of siderite.

26) Define bond enthalpy and obtain the relationship between H and U for gas phase reaction.

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 PROF. RAKESH RATHI’S CHEMISTRY TUTORIALS 24-01-23
SECTION (D)
Attempt any THREE: [12]
27) I) Write the type of defect present in AgBr.
II) Give reaction for preparation of ethanoic acid from dry ice.
III) How much heat is evolved when 14 g of CO reacts with NO2? The reaction is:
4CO(g) + 2NO2(g) → 4CO2(g) + N2(g), rH0 = -1200 kJ

28) (I) What is action of chlorine on excess of NH3?

(II) Give reaction for preparation of propanone using acetonitrile
(III) What are zero order reaction. Explain with suitable example

29) (I) What is action of following on propanone: a) NaHSO3 b) Phenyl hydrazine

(II) Explain lanthanoid contraction effect on decrease in basicity of post-lanthanoid

30) (I) What is action of following on glucose [Balance reaction only]

a) Bromine water b) Acetic anhydride
(II) How ethyl amine is prepared using a) Nitro ethane b) Acetaldoxime

31) (I) Identify the compounds ‘A’ and ‘B’ in the following equation:

C2H5N+(CH3)3I− 𝐀𝐠𝟐𝐎/𝐇𝟐𝐎 A B + (CH3)3N + H2O.

(II) a) Name the chemical which leachs out of plastic packaging materials.
b) Name the nanoparticles used in sunscreen.
(III) What is green chemistry?