important questions

chapter 1 to 9 11th science Chemistry Date : /04/24

Full syllabus
Section A
//X
• Write the answer of the following questions. [Each carries 2 Marks] [56]
1. Classify matter according to physical state.
2. Match the following prefixes with their multiples :
Prefixes Multiples
(i) micro 106
(ii) deca 109
(iii) mega 10–6
(iv) giga 10–15
(v) femto 10
3. Write about Dalton’s Atomic Theory.
4. Explain Dalton’s atomic theory.
5. Write down Rutherford’s atomic model.
6. Explain the “Law of Triads” with examples ?
7. Explain Law of Octaves given by Newland.
8. What is chemical bonding ? How it is formed and give its types.
9. ) Use Lewis symbols to show electron transfer between the following atoms to form cations and
anions Ca and O.
10. Define octet rule. Write its significance and limitation.
11. Calculate the formation heat for propen from given equations.
(i) C(s) + O2(g) ® CO2(g) ; DH1 = –94.05 k.cal/mole
1
(ii) H2(g) + O 2(g) ® H2O(l) ; DH2 = –68.32 k.cal/mole
2
(iii) C3H8(g) + 5O2(g) ® 3CO2(g) + 4H2O(l) ; DH3 = –530.61 k.cal/mole

12. Explain solid-vapour equilibrium by example.

13. What is homogeneous equilibrium ? Give examples.
14. Predict if the solutions of the following salts are neutral, acidic or basic :
NaCl, KBr, NaCN, NH4NO3, NaNO2 and KF

15. The concentration of H2 , I2 and HI at 731 K respectively 0.92 ´ 10–2, 0.20 ´ 10–2 and 2.96 ´ 10–2 mol L–1,
calculate equilibrium constant. H2(g) + I2(g) ƒ 2HI(g)

16. What is redox reaction ? Explain its uses.

17. What is oxidation reaction ? Explain it with example.
18. Explain balancing of redox reaction by oxidation number method.
19. PbO and PbO2 react with HCl according to following chemical equations
(i) 2PbO + 4HCl ¾® 2PbCl2 + 2H2O
(ii) PbO2 + 4HCl ¾® PbCl2 + Cl2 + 2H2O
Why do these compounds differ in their reactivity ?

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20. Explain characteristic of p bonds.
21. Give classification of organic compounds.
22. What is isomerism ? Which are the types of isomerism ?
8.1)
23. How many s and p bonds are present in each of the following molecules ?
(a) HC º CCH = CHCH3
(b) CH2 = C = CHCH3
24. ) For each of the following compounds, write a condensed formula and also their bond-line formula.
(a) HO CH2 CH2 CH2 CH (CH3) CH (CH3) CH3
OH
(b) |
N º C – CH – C º N
25. Importance of hydrocarbons.
26. Give classification of hydrocarbon.
27. Give physical properties of alkane ?
28. Write the preparation of methane from methyl chloride and acetic acid.

Section B
//X
• Write the answer of the following questions. [Each carries 3 Marks] [99]
29. Describe the characteristics due to different physical state of mater.
30. Explain classification of matter based on chemical properties. (Macroscopic)
31. Define mixture and its types.
32. R) Explain a, b and g-rays.

33. Explain Rutherford’s nuclear model of atom.

34. Explain Covalent radius and ionic radius with an examples.
35. What is the basic difference between the terms electron gain enthalpy and electronegativity ?
36. Explain periodicity of valence or oxidation states and explain Na2O and OF2.

37. Which elements of group shows anamolous behaviour. Explain with examples.
38. State number of covalent bond in H2O and CCl4 and give bond structure and Lewis structure in H2O
& CCl4.
39. Which multiple bond present in CO2, C2H4, N2 and C2H2 ? Draw Lewis and simple bond structure
of these molecules.
40. Explain the difference between the system and surrounding.
41. Explain Heat Capacity.
42. Prove Hess’s law of constant heat summation.
43. R) Lattice Enthalpy.

44. Write Hess’s rule of integral heat and explain it with one example.
45. How many types of equilibrium based on proportion of reactant and product ?
46. Explain effect of temperature change on chemical equilibrium by example.
47. Explain pH scale and pH.
48. ) Explain relation of solubility (S) and Ksp.

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49. 0) Calculate the pH of 0.08 M solution of hypochlorous acid, HOCl. The ionization constant of the acid
is 2.5 × 10–5. Determine the percent dissociation of HOCl.
50. Give reaction when Zn rod kept in copper nitrate solution ?
51. R) Fe+2 in acidic medium is convert Cr2O–72 ion into Cr+3 ion by reduction Fe+3 is obtained balance
these redox reaction with equation.
.10) Permanganate(VII) ion, MnO–4 in basic solution oxidises iodide ion, I– to produce molecular iodine (I2)
52.
and manganese (IV) oxide (MnO2). Write a balanced ionic equation to represent this redox reaction.

53. Explain by examples : (a) Complete (b) Conde-nsed and (c) Bond-line structural formulas
54. What is Fission of a covalent bond ? Explain its type with example and main difference.
55. What is inductive effect ? Which electron displacement effect can explain order of acidity of following
carboxylic acid ?
(a) F3C COOH > F2CH COOH > F CH2 COOH
(b) CH3 COOH > CH3 CH2 COOH > (CH3)2 CH COOH
56. Write in detail about hydrogenation of unsaturates hydrocarbon.
57. ) Give the preparation of alkane from the unsaturated hydrocarbons.

58. Give the formation of alkane by Kolbe’s electrolysis method with its examples.
59. ) Give the preparation of alkane from carboxylic acid by the electrolysis.

60. ) Write the polymerisation of alkene ?

61. Explain polymerisation of alkyne.

Section C
//X
• Write the answer of the following questions. [Each carries 5 Marks] [90]
62. Express the following in the scientific notation:
(i) 0.0048
(ii) 234,000
(iii) 8008
(iv) 500.0
(v) 6.0012
63. How many significant figures are present in the following ?
(i) 0.0025
(ii) 208
(iii) 5005
(iv) 126.000
(v) 500.0
(vi) 2.0034
64. R) Explain according to Bohr’s model of hydrogen.
(i) Principal quantum number (ii) Radius of stationary orbit (r) (iii) Energy of stationary state (iv)
Isoelectronic ion of H. (v) Velocity of electron.
65. Among the second period elements the actual ionization enthalpies are in the order
Li < B < Be < C < O < N < F < Ne.
Explain why
(i) Be has higher DiH than B
(ii) O has lower DiH than N and F ?

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66. Discuss the shape of the following molecules using the VSEPR model.
BeCl2 , BCl3 , SiCl4 , AsF5 , H2S , PH3
67. What is system ? Explain types of system.
68. Explain liquid-vapour equilibrium.
69. What is meant by the conjugate acid-base pair ? Find the conjugate acid/base for the following species
: HNO2, CN–, HClO4, F–, OH–, CO32– and S2–

70. R) Derive the equation for calculation of pH of acidic buffer solution.

71. Assign oxidation number to the underlined elements in each of the following species :
(a) NaH2PO4 (b) NaHSO4 (c) H4P2O7
(d) K2MnO4 (e) CaO2 (f) NaBH4
(g) H2S2O7 (h) KAl(SO4)2 · 12H2O

72. What are the oxidation number of the underlined elements in each of the following and how do you
rationalize your results ?
(a) KI3 (b) H2S4O6 (c) Fe3O4
(d) CH3CH2OH (e) CH3COOH
73. Discuss the types of redox reactions in detail ?
74. What is functional group ? Give example.
75. Explain heterolytic cleavage of organic compound (b) Carbanions by examples.
76. Write about Inductive effect.
77. What is the hybridisation of carbon ?
(a) CH3C º N
(b) CH2 = C = CH2
(c) C2H6
(d) CH2 = CH – CH2 – C º CH
(e) CH3COOH

78. Complete the below reaction :

Ni,
(i) CH º CH + 2H2 ¾¾¾¾¾¾ ®
523 _ 573 K
Pd or Pt
(ii) CH3C º CH + 2H2 ¾¾¾¾¾¾¾¾¾ ®
or Raney nickel, D
Zn,H+
(iii) 1-chlorobutane + H2 ¾¾¾¾ ®
Anhy, Al Cl 3
(vi) CH3 CH2 CH2 CH3 ®
HCl, D
79. Write about ozonolysis of alkene.

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