CONTENT

S.No Pages

1. DPP-1 04 – 6

2. DPP-2 07 – 9

3. DPP-3 10 – 11

4. DPP-4 12 – 14

5. DPP-5 15 – 17

6. DPP-6 18 – 19

7. DPP-7 20 – 22

8. DPP-8 23 – 25

9. DPP-9 26 – 28

10. DPP-10 29 – 32

Let's Crack it !

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 ORGANIC CHEMISTRY
Daily Practice Problems Target IIT-JEE

Class : XII Time : 30 min. DPP # 1

CH2 Cl


KSH
1. Major product :
(SN2)
Br
SH Cl

(A) (B)

SH SH
SH SH

(C) (D)

Br Cl

2. Consider the reaction of (R)-2-iodooctane to react with radioactive iodide ion (*T-).
Rate constant Ks = The rate of substitution determined by measuring the rate of incorporation of
radioactivity into the alkyl halide

Rate constant K  The rate of loss of optical activity from the alkyl halide under the same condition.
For which of the following stereochemical scenerio K°/Ks=1 ?
(A) Retention (B) Inversion
(C) Equal amounts retention and inversion (D) For all scenerio K / Ks  1


KCN H3O 
C2H4Cl 2 (B) (C) (D)
3. (A)
The compound D has the characteristics
(A) It is succinic anhydride if (A) is vicinal-dihalide.
(B) It is popionic anhydride if (A) is gem dihalide.
(C) It is succinic anhydride if (A) is gem dihalide.
(D) If is propionic anhydride if (A) is vicinal-di-halide.

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4. The best sequence of reactions to prepare 2 -heptanone is
NaNH NC C Br H O, Hg2
(A) propyne 
2
 X 
4 9
Y 
2
H SO 2 4

NaNH2 nC 5H11Br H2O, Hg2

 X 
(B) ethyne   Y  H2SO4
NaNH CH Br H O,Hg2
(C) 1-hexye 
2
 X 
3
 Y 
2
H SO 2 4

NaNH2 C2H6Br H2O, Hg2

 X 
(D) 1-pentyne   Y  H2SO4

O Cl

x PCl5 yNaNH2 CH3I

5.      

O C C CH3

Sum of x + y ?
(A) 4 (B) 5 (C) 3 (D) 2

6. Total number of moles of HI consumed by all of the reactants will be

(i) CH3 O O CH3 (ii) CH3 O O Ph

OCH3
OCH3
(iii) Ph O O Ph (iv)
OCH3
CH2 OH
(v) Et-O-Et (vi)

OH
(A) 10 (B) 11 (C) 12 (D) 13

CH3
H Br NaI/acetone
7. (SN2) condition
H Cl
CH3
CH3 CH3 CH3
H I H I I H
(A) (B) (C) (D)
H Cl Cl H H Cl
CH3 CH3 CH3

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 I
NBS KSH
8.   A   B 
CH3
Product (B) is
SH I
(A) (B)
Br
SH
I SH
(C) (D)
CH2 SH Br

CH3

1 NaNH2
1mole ColdKMnO
9. 
 2 CH3I   A   4
 B 
CH2OH 1mole
OH
Identify final product (B) ?
O
OH

(A) (B)
CH2OH
OH O COOH
O O

(C) (D)
COOH CHO
OH OH

O
(i) LDA
(A)
(ii) CH3I
10. (i) C2H5ONa
(B)
(ii) CH3I
What is relation between A & B
(A) Tautomer (B) Chain (C) Position (D) Geometrical

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 ORGANIC CHEMISTRY
Daily Practice Problems Target IIT-JEE

Class : XII Time : 30 min. DPP # 2

1. Compare the reactivity towards KI/Acetone of and CH3CH2CH2-Cl and CH3CCH2Cl

(A) CH3COCH2 Cl  CH3CH2 CH2Cl (B) CH3CH2CH2 Cl  CH3 COCH2Cl
(C) CH3CH2CH2 Cl  CH3 COCH2Cl (D) Can’t compare

2. The first demonstration of the stereochemistry of the SN2 reaction was carried out in 1935 by prof.E.D.
Hughes and his colleagues at the University of London. They allowed (R)-2-iodooctane to react with
radioactive iodide ion (*I–).
* - -
CH3CH(CH 2)5 + I CH3CH(CH 2)5 + I

I *I
2-iodooctane 2-iodooctane
(radioactive)
The rate of substitution (rate constant k s ) was determined by measuring the rate of incorporation of

radioactivity into the alkyl halide. The rate of loss of optical activity from the alkyl halide (rate constant k )
was also determined under the same conditions.
(a) What is the value of k%k s for equal amount of inversion and retention?
(A) less than 1 (B) More than 1
(C) equal to 1 (D) Can not predict

3. Which of the following will not undergo SN2 reaction

Cl

(A) (B) (C) (D) All

Br

4. The correct order of nucleophilicity among the following

-
CH3 C O

(I) O (II) CH3O-

O
-
(III) CN- (IV) H3C S O
O
(A) I > II > III > IV (B) IV > III > II > I
(C) II > III > I > IV (D) III > II > I > IV

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5. Correct statement
(A) F  Cl  Br   I Nucleophilicity in polar-protic solvent
(B) F  Cl  Br   I Nucleophilicity in polar-aprotic solvent
(C) I  Br   Cl  F Leaving group order
(D) R-I > R-Br > R-Cl > R-F Rate of SN1 and SN2 reaction

6. In which of reactions final product is ketone :

NaNH2 CH0 I HaSO4
(A) CH3-CC–H   (a)   (b) 
H SO
c 2 4

NaNH2 CH3  CH2 I Hg  OAc 2 , H2O

(B) H-CC–H   (d) 
 (c)  NaBH ,HO
 (e)
4

O
NaOH CH3 I
(C) R C OH   (a)   (b)
1  CH3 1HF
NaNH 2 2 2 CH I H O /HO
(D) 1-butyne 
2
 (a) 
3
 (b)  


7. Which of the following is an SN2 reaction ?

NaOH
Cl  OH + NaCl
(A)  H2O

H Cl HO H

aq. NaOH (S)

(B) (R)  + NaCl
Cl OH
NaOH
(C) 
H2O
 + NaCl

Cl HO OH
+ H Cl
(S) H2O (R) (S)
(D)  +

Passage (Q.8 to Q.10)

CH
C

1. NaNH2  2 eq.
2. CH3CH2 
 x 
3. CH3 
Scheme-I
4. H2 /Pd BaSO4

OH
CH
C

1. NaNH2  2 eq.
2. Ch3 CH2 

3. H O mild
 (y) Scheme-II
3
4. Na/NH3   

CH2 OH

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8. The product (y) is
CH3CH2
CH2CH3

(A) (B)

CH2 OH CH2 OH
CH2
CH

(C) (D) Both B and C

CH2 OCH 2CH3

9. The correct statement regrding product (x) is

(A) It gives a Positive Tollen's test and is a functional isomer of (y)
(B) It gives a Negative Tollen's test and is a geometrical isomer of (x)
(C) It gives a Positive lodoform test and is a functional isomer of (x)
(D) It gives a Negative lodoform test and is a functional isomer of (x)

10. The product (x) is

CH CH2 CH3 CH CH3
(A) (B)
CH OCH3 CH OCH3CH3

CH3CH2 CH
(C) (D)
CH OCH3
w

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 ORGANIC CHEMISTRY
Daily Practice Problems Target IIT-JEE

Class : XII Time : 30 min. DPP # 3

CH3 CH3

H2O
1. 
SN1


Cl
Total number of plane of symmetry present in carbocation formed (of given compound) in rate determining
step will be?
(A) 1 (B) 3 (C) 2 (D) 4

2. How many Dichloro products of (I) are possible (including stereoisomers and neglecting rotational isomers)
Cl2

hv
?
Cl
(A) 5 (B) 6 (C) 7 (D) 4

3. t-butyl methyl ether on heating with conc. HI gives a mixture of

(A) t-butyl iodide & methyl alcohol. (B) t-butyl alcohol & methyl iodide
(C) Methyl iodide & Probutylene. (D) Methyl alcohol & isobutylene.

CH3
SN1
4. C6H 5 Br Maximum racemisation takes place when :
H
(A) 100% H2O (B) 100% Acetone
(C) 80% H2O + 20% acetone (D) 80% acetone + 20% H2O

5. The major product obtained in the reaction below is

HCl
 
CH2

(A) (B) Cl
Cl

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 (C) (D)
Cl
Cl

6. Which chemical test will distinguish the compounds shown below?

Br CH3 CH2 Br

(A) Fehlings test (B) Ethanolic silver nitrate test

(C) Beilstein's rlathe lest (D) SudiurI rusiun extract

7. What is the maximum number of products possible when (2R, 3R) 2-chloro-3-phenylbutane is undergone
through hydrolysis  SN1 
(A) 2 (B) 3 (C) 4 (D) 5

8. Observe the reaction given below-

Br2  
CH OH aq

hv
 
3
 solution ‘A’

Br2  
CH OH aq

Fe
 
3
 solution ‘B’

Which of the above solution are acidic ?

(A) A only (B) B only (C) A & B (D) None

9. Decreasing order of rate of SN1 reaction is

CH3
O
(I) CH3 CH Br (II) CH3 C CH2 Cl (III) CH3-O-CH2-Br
(A) III > II > I (B) I > III > II (C) III > I > II (D) II > III > I

10. Correct graphical representation of rate of SN1 will concentration of nucleophile and alkyl halide

Rate Rate Rate

(SN1)
(A) (B) (SN1) (C) (SN1) (D) (B) & (C) Both
-
[Nu ] -
[Nu ] [R-Br]

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 ORGANIC CHEMISTRY
Daily Practice Problems Target IIT-JEE

Class : XII Time : 30 min. DPP # 4

1. The major product of the following sequence is

CN Br
C2 H5 O  Br 
C2 H5 O
CH2   A B   C (?)
CN

CN CN CN CN CN

CN CN
(A) (B) (C) (D)

CN

2. Solvolysis of the optically active compound X gives, mainly gives :

MeO
Me

OTs
Me AcOK
 
AcOK
?

MeO MeO
Me Me

(A) OAc (B) OAc

Me Me

(Optically active) (Optically active)

MeO MeO
Me Me

OAc OAc
(C) Me
(D) Me
Racemic Racemic
(optically inactive) (optically inactive)

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 Passage Q.3 to Q.4
The reaction sequence shown below gives products Q,R,S,T respectively.

OH

2 PCl5 4NaNH2 Cl H2 /Pd-BaSO 4

  (Q)   (R) (S) (T)
(SN 2)

CH2
CH O

3. The product (S) is :

C C C C
(A) C (B) C (C) (D)
C C

4. Identify the starting material I in the given reaction :

H3C O
OH H3C
(I)
CH3
Br Br

H3C H3C
(A) H C OH (B) H C OH
3 3
CH3 CH3
OH OH

H3C H3C
(C) H C Br (D) H C Br
3 3
CH3 CH3

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 Multiple Choice Questions
5. The hydrolysis of ether (x) shown below –

OR acid
OH + ROH

Correct statement for the above hydrolysis is :

(A) Not possible when pH is more than 7
(B) Slower when one phenyl replaces by p-nitro phenyl.
(C) Not possible when R replaced by phenyl group.
(D) faster when one phenyl replaced by p-methoxy phenyl group.

Matrix Type Questions

6. List-I List-II
CH3
Conc. HI
(P) CH3 O C CH3   (1) SN1
CH3
OH

SOCl2
(Q)   (2) SN2

OH

PCl5 /Pyridine
(R)  
(3) SN1

OH

Aq. KOH
(S)   (4) SN NGP

CH2 CH2 OTs

Codes :
P Q R S
(A) 3 2 1 4
(B) 1 3 2 4
(C) 2 1 4 3
(D) 1 2 3 4

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 ORGANIC CHEMISTRY
Daily Practice Problems Target IIT-JEE

Class : XII Time : 30 min. DPP # 5

1. The rate of order or SN-Ar (Nucleophilic aromatic substitution) is :

Cl Cl Cl Cl
NO2 O 2N NO 2

NO2 NO 2 NO 2

(i) (ii) (iii) (iv)

(A) (i) > (ii) > (iii) > (iv) (B) (iv) > (iii) > (ii) > (i)
(C) (ii) > (iii) > (iv) > (i) (D) (iv) > (iii) > (i) > (i)
2. What is the major product of the following reaction ?
H
N O
Br2 / FeBr3

H
H
N O O
N

(A) Br (B)

Br
Br
H H
Br N O N O

(C) (D)

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 NO 2

 1 NaOH
3. F 
 2 H3O
Br
Product (A) is
NO 2
NO 2 OH
NO 2
OH
(A) (B) (C) (D)
OH
F F
F
Br
OH Br
Br

4. Most reactive towards SN-Ar (Nucleophilic aromatic substitution)

Br Br Br Br
NO 2
(A) (B) (C) (D)
NO 2 NO 2

NO 2 NO 2 NO 2

5. Which of the following reacts fastest via SN Ar mechanism ?

F Cl Br

(A) (B) (C) (D)

6. Choose the one compound within each set that meets the indicated criterion :
List –I List-II
F

(P) The compound that reacts with alcoholic (1)

O2N
CH3

(Q) The compound that cannot be prepared by a (2) OC2H5

Williamsor ether synthesis.

(R) The compound that gives an acidic solution (3) O

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 when allowed to stand in aqueous ethanol.
Br
(S) The ether that cleaves more rapidly in HI. (4) C CH3
CH3
Codes :
P Q R S
(A) 3 2 1 4
(B) 1 3 4 2
(C) 2 1 4 3
(D) 1 2 3 4

7. List-I List-II
Cl

NaOCH3
(P)   (1) Electrophilic aromatic substitution reaction
NO2
Br
NO 2

(Q) (2) Biomolecular nucleophilic substitution reaction  SN2 

F
Cl
Cl

(3) Unimolecular nucleophilic substitution reaction  SN1 

HNO3
(R) 



CH3

O CH3


H3O
(S)   (4) SIV-Ar reaction

CH3
Codes :
P Q R S
(A) 1 2 3 4
(B) 4 3 1 2
(C) 2 4 1 3
(D) 3 2 1 4

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 ORGANIC CHEMISTRY
Daily Practice Problems Target IIT-JEE

Class : XII Time : 30 min. DPP # 6

1. The product which results from antiperiplanar elimination on pyrolysis of following sulfonate ester of
menthol is
O
O
Heat
N S O ?
H O

(A) (B) H (C) (D)

2. Predict the relationship between major products (P) and (Q) ?


EtO
(P)
Br EtOH


t-BuO
Br  (Q)
t-BuOH

(A) Positional isomers (B) Enantiomers (C) Enantiomers (D) Chain isomers

Br
Br
alc KOH alc KOH
3. (I) (II)
O

Br
(III) alc KOH
N
H
The rate constant of which of the above reaction is highest
(A) (I) (B) (II) (C) (III) (D) (II) & (III) have same rate constant

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 Cl

t-but O
(A)
t-but O
4.

O
“(A)” is
t-but O O
 Cl O t-but

(A) (B) (C) (D)

O O O
OH

5. SOCl 2
A

C2H5ONa/C2H5OH
A   X (Alkene)
Total number of alkenes formed are
(A) 3 (B) 6 (C) 5 (D) 4

6. How many isomer of C4H9Br when reacts with NaNH2. Diastereomers will form ? (excluding stereoisomer)
(A) 0 (B) 1 (C) 2 (D) 3

ElONa/EtOH
7. A (Major), A is
Cl

(A) (B) (C) (D)

OEt OEt

8. Give the order of reaction rate with alc-KOH

Br
(i) (B) Br (C) Br

(A) (i) > (ii) > (iii) (B) (ii) > (i) > (iii) (C) (iii) > (ii) > (i) (D) (iii) > (i) > (ii)

9. Which of the following could not be used to synthesize propyne ?

t  but O / 
(A) CH3-CH=CH-Br (B) CH  CNa  CH3  I 

t  but OH
1 NaNH  excess 
(C) HC  CH  CH3Na 
 (D) CH3  CHBrCHBr 2
 2 H

10. Which of the following compounds undergo E2 reactions with the fastest rate ?
(A) CH3 CH CH3 (B) CH3CH2CH2I (C) CH3 CH CH3 (D) CH3CH2CH2-Br
Cl I

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 ORGANIC CHEMISTRY
Daily Practice Problems Target IIT-JEE

Class : XII Time : 30 min. DPP # 7

1. Number of diastereomeric pair formed in product B.

OH

H  HBr
(A) (B)
CCl 4
(major)
(A) 2 (B) 3 (C) 4 (D) 6

2. Conc. H2SO 4
A + H 2O

(major)

OH
Which of the following is product “A” in the above reaction ?

(A) (B)

(C) (D)

3. In which of the following reaction product formation takes place by saytzeff rule ?
OAc Br
 CH3ONa/ 
(A) H3C (B) H3C
CH3 CH3

H3C
 Br (CH3)3COOK/ 
(C) OH (D) H3C
+
N CH3
H3C CH3

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4. Which one of the following will be the major product when OH is treated with H SO ?
2 4

CH 2

(A) OH (B) (C) OH (D) OH

O

CH3 CH3
OH CH3 OH CH3

CH3
N
OH
5.
(B)

(A) (C)
Compound (A) do not decolories bromine and dissolve in HCl. On treatment with con H2SO4 gives B. Now
count the number of Hoffmann exhaustive methylation of B to C is
(A) 1 (B) 2 (C) 3 (D) no reaction

 
TsCl/Py EtO K
6. (A) (B) + (C)
EtOH/ 
OH
KSH
(D)
DMSO
Comment on stereo chemistry of product :
(A) B, C = Position, D=Single (B) B, C = Racemic, D = Position
(C) B, C = Racemic, D = Racemic (D) B, C Racemic, D = Single
7. Which of the following carbocations donot undergo rearrangement to give a major product.

O




(A) CH2 (B)



 O
(C) CH3 (D)

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8. Compound X, C7H13Cl is reacted with sodium ethoxide and gives a elimination product Y, C7H12. Treatment of
ozone followed by zinc and water gives the compound below. X and Y are respectively :
O O
O3, Zn
X Y
H2 O H

Cl Cl
(A) X = Y= (B) X = Y=

Cl

Cl
(C) X = Y= (D) X = Y=

Conc.H2SO4
9.   Products are

OH
(A) Mirror image stereoisomers (B) Geometrical isomers
(C) Identicle (D) Diastereomers

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 ORGANIC CHEMISTRY
Daily Practice Problems Target IIT-JEE

Class : XII Time : 30 min. DPP # 8

Br

alc. KOH
1.   No. of products including stereoisomers are

(A) 1 (B) 2 (C) 4 (D) 6

2. Major product (X) & (Y) of the below reaction are respectively ?
CH3 CH3
CHCH3
CHCH3
 
EtO EtO

EtOH  X ; 
EtOH Y
H3C H3C Cl
Cl
(Methyl chloride) (Neomenthyl chloride)
CH3 CH3
CHCH3 CHCH3

(A) (X) , (Y)

H3C H3C
CH3 CH3

CHCH3 CHCH3

(B) (X) , (Y)

H3C H3C
CH3
CHCH3

(C) (X) and (Y) both equals

H3C
CH3
CHCH3
(D) (X) and (Y) both equals
H3C

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 OH

conc. H2 SO4 O3 /H2O2

3.  
 A   B , Final product B is

(A) Dicarboxylic acid (B) Dicarbonyl compound

(C) Olifines (D) Cyolio oster

Passage (Q.4 to Q.6)

(i) 1% dil. KMnO 4
(B) + (C)
(ii) HIO 4

(A)
C6H12
Terninal
Alkene
O
(i) H-Br (ii) KOH (alcoholic) (iii) O 3
(D) (E)
followed by
(F)
Zn/H2O

4. What are the products (B) and (C), respectively

O
+ HCHO + HCHO
(A) (B)
O
CH3

(C) CHO (D) CHO + HCHO

+ HCHO

5. What is the relationship between (A) and (E)

(A) Chain isomers (B) position isomers
(C) Geometrical isomers (D) Different molecular formula

6. Red Brown colour of bromine water disappears when it reacts with alkene (A) Identify the product.
Br OH

(A) (B)
OH Br
Br OH

(C) (D)
OH Br

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 Passage (Q.7 to Q.9)
Elimination is reaction is important to synthesize alkene. Generally more stable product (Saytzeff's alkene) is
major but in certain cases less stable product (Hoffman's alkene) can also be major.

+
N

OH Major product
7.

(A) (B) (C) (D) Ethylene

Et-O
Major product
8. Et-OH/ 
Br

(A) (B) (C) (D)

OEt

9. In which of the following reaction but-2-ene obtained as major product

Br Br
NaNH 2 t+-Butoxide
(A)  (B) 
F
Et O
 
(C) (D)

O N CH3

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 ORGANIC CHEMISTRY
Daily Practice Problems Target IIT-JEE

Class : XII Time : 30 min. DPP # 9

CH3 I
alc. KOH
1. C C CH2
CH3 CH CH3

CH3
X = Number of chiral products (including stereoisomer).
(A) 2 (B) 4 (C) 6 (D) 8

NH2

(1) CH 3 I (excess)
(2) Ag 2O
2. (3) 
Identify major product
CH2

(A) (B) (C) (D)

OH

H ,
3.  X

Possible structure of X formed is :

(A) 1 (B) 2 (C) 3 (D) 4

4. + H


 (P) Major

N
H
Major Product (P) is :

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 N
N
(A) (B)

N N

(C) (D) OH

 1 O3 H2 Conc. H3PO4
5. 
 2  Zn/H2O 
Ni
  


Identify all the possible product(s) formed in the above reaction is/are :
CH2

(A) (B) (C) (D)

TsCl/py H2SO 4
(x) (a)
OH OH HgSO 4

CH3 CH3
6.
CH3 H Conc. H2SO 4 B2H6 (THF)
(y) (b)
H2O 2, NaOH
Find the relationship in between (x) and (y), (a) and (b)
(A) Identical, (x) and (y) (B) Position isomer, (x) and (y)
(C) Identical, (a) and (b) (D) Position isomer, (a) and (b)

OCH3 O

7. NaOH,  Br2,CCl 4
A Solution (B)
(major)
Correct statement(s) about the solution B is/are : -
(A) It has 2 products (B) It has 1 product
(B) It is optically inactive mixture (D) It is optically active mixture

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 Br
8. Base
(P)

COOH

Br
Base
(Q)

COOH

Identify product P and Q are

=P =P
(A) COOH (B) COOH

=P =Q
(C) (D)

 
Br2 Et3CO K NBS Alo. KOH 1 H 1 mole
9. 
hv
 P  
Q   R   S Ni
 T
Major major 
X = difference in molecular weight in reactant and product T than X = ?

Alc. KOH
10.   Number of alkene obtained by E2.
Br
CH3

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 ORGANIC CHEMISTRY
Daily Practice Problems Target IIT-JEE

Class : XII Time : 30 min. DPP # 10

1. Ph CH2 CH CH3  SN1  E1  Product  s   'X'

Cl
Considering products including stereoisomerism find the value of (X) :
(A) 7 (B) 8 (C) 9 (D) 10
Et

2. total SN1 + E1 product

Cl
(A) 6 (B) 7 (C) 8 (D) 9

3. List-I List-II

H2O
(P) Ph Cl (1) SN1


Cl Ph S Na
(Q) (2) SN2
F
KOH
(R)  (3) Carbocation is intermediate
NO 2
Br2
(S) 
CCl4
 (4) Carbanion is intermediate

Codes :
P Q R S
(A) 1 2 4 3
(B) 1 2 3 4
(C) 2 1 4 3
(D) 2 1 3 4

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4. List-I List-II
CH 2 Cl

(P) (1) Benzyne mechanism

NO 2
F
NO 2
(Q) (2) Sterically inhibited resonance

NO 2
F

(R) (3) SN-Ar

NO 2
CH 3
Cl

(S) (4) SN2

Codes :
P Q R S
(A) 3 2 1 4
(B) 4 3 2 1
(C) 2 1 4 3
(D) 1 2 3 4

5. Column-I Column-II
(1) Hg(OAc)2, H2O
 (I)
(2) NaBH4, HO

(A) CH3 C CH (P) I and II are functional isomers

(1) BH3 : THF
 (II)
(2) H2O 2, HO
HBr
(I)
CCl 4

(B) CH3 CH CH2 (Q) I and II are positional isomers

HBr
Peroxide (II)

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 
(C) CH CH Cl NaC CH (R) I and II are formed by addition
3 2 (I)
Br
(i) alc. KOH
CH3 C CH2 CH3 (II)
(ii) NaNH2
Br Reaction

H2O
(D) Major (I)(S) I and II are enantiomers
SN1
I
CH3 OCH3
CH3 OCH3
I
H2O
Major (II)
SN1

(T) I and II are diastereomers

6. List-I List-II
(Reaction sequence) (Reagent required)

(P) O OEt (1) EtO

(Q) Br (2) EtBr

OEt
(R) (3) EtOH/H

Codes :
P Q R S
(A) 1 2 4 3
(B) 2 1 4 3
(C) 2 1 3 4
(D) 3 2 1 4

CH3
CH3OH
?
7.

Br
X = Total number of substitution & elimination product(s). Find the value of X ?

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8. How many of the following reactions will prefer following a path way which gives 1st order kinetics.
Cl
OH + NaNH2
H
(a) (b)

Cl
CH CH2
CH2 CH2 F
-
EtO /EtOH
(c) NO2
NO2
SH

Cl Cl
NaI
KOH S
(d)  (e) (Acetone)

Cl

H2O
(f) (g) Base, 
Cl OH 
N

O
(1) PhMgBr
(h) +
(2) H

9. x = number of compound undergo nucleophilic substitution reaction

Cl
O O

CH3 Cl , Cl , ,
O Et , OH ,CH3 CH CH2 , Cl , CH3 C N

NO2

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