EXCEL 2022

GENERAL ORGANIC CHEMISTRY

ACID AND BASES 03G

Marking Scheme : Single Correct (+3,-1) M M: 84 Time : 1hr

1. The acidity of the protons H in each of the following is:

(i) (ii) (iii)

(a) (i) > (ii) > (iii) (b) (iii) > (ii) > (i) (c) (i) > (iii) > (ii) (d) (iii) > (i) > (ii)
2. Identify correct acidic strength order in the following compounds

(i) (ii) (iii)

(a) (i) > (ii) > (iii) (b) (ii) > (iii) > (i) (c) (ii) > (i) > (iii) (d) (iii) > (i) > (ii)
3. Identify correct acidic strength order in the following compounds

(i) (ii) (iii)

(a) (i) > (ii) > (iii) (b) (iii) > (ii) > (i) (c) (i) > (iii) > (ii) (d) (iii) > (i) > (ii)
4. Identify correct acidic strength order in the following compounds

(i) (ii) (iii)

(a) (i) > (ii) > (iii) (b) (ii) > (iii) > (i) (c) (i) > (iii) > (ii) (d) (iii) > (i) > (ii)
5. Identify correct acidic strength order in the following compounds

(i) (ii) (iii)

(a) (ii) > (i) > (iii) (b) (ii) > (iii) > (i) (c) (i) > (iii) > (ii) (d) (iii) > (i) > (ii)

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6. Identify correct acidic strength order in the following compounds

(i) (ii) (iii)

(a) (i) > (ii) > (iii) (b) (ii) > (iii) > (i) (c) (i) > (iii) > (ii) (d) (iii) > (i) > (ii)
7. Identify correct acidic strength order in the following compounds

(a) (i) > (ii) > (iii)

(b) (ii) > (iii) > (i)
(c) (i) > (iii) > (ii)
(d) (iii) > (i) > (ii)

8. Identify correct acidic strength order in the following compounds

(a) (i) > (ii) > (iii) (b) (ii) > (iii) > (i)
(c) (i) > (iii) > (ii) (d) (iii) > (i) > (ii)

9. Identify correct acidic strength order in the following compounds

(a) (i) > (ii) > (iii) (b) (ii) > (iii) > (i)
(c) (i) > (iii) > (ii) (d) (iii) > (i) > (ii)

10. The acidity of the protons H in each of the following is

(i) (ii) (iii)

(a) (i) > (ii) > (iii) (b) (ii) > (iii) > (i) (c) (ii) > (i) > (iii) (d) (iii) > (i) > (ii)
11. The acidity of the protons H in each of the following is

(i) (ii) (iii)

(a) (i) > (ii) > (iii) (b) (ii) > (iii) > (i) (c) (i) > (iii) > (ii) (d) (iii) > (i) > (ii)
12. Identify correct acidic strength order in the following compounds

(i) (ii) (iii)

(a) (iii) > (ii) > (i) (b) (ii) > (iii) > (i) (c) (i) > (iii) > (ii) (d) (iii) > (i) > (ii)

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13. Identify correct acidic strength order in the following compounds

(i) (ii) (iii)

(a) (i) > (ii) > (iii) (b) (iii) > (ii) > (i) (c) (i) > (iii) > (ii) (d) (iii) > (i) > (ii)
14. Identify correct acidic strength order in the following compounds

(i) (ii) (iii)

(a) (i) > (ii) > (iii) (b) (ii) > (iii) > (i) (c) (i) > (iii) > (ii) (d) (iii) > (i) > (ii)
15. Identify correct acidic strength order in the following compounds

(i) (ii) (iii)

(a) (iii) > (ii) > (i) (b) (ii) > (iii) > (i) (c) (i) > (iii) > (ii) (d) (iii) > (i) > (ii)
16. Identify correct acidic strength order in the following compounds

(i) (ii) (iii)

(a) (i) > (ii) > (iii) (b) (ii) > (iii) > (i) (c) (i) > (iii) > (ii) (d) (iii) > (i) > (ii)
17. Identify correct acidic strength order in the following compounds

(i) (ii) (iii)

(a) (i) > (ii) > (iii) (b) (ii) > (iii) > (i) (c) (i) > (iii) > (ii) (d) (iii) > (i) > (ii)
18. Identify correct acidic strength order in the following compounds

(i) (ii) (iii)

(a) (i) > (ii) > (iii) (b) (ii) > (iii) > (i) (c) (i) > (iii) > (ii) (d) (iii) > (i) > (ii)
19. Identify correct acidic strength order in the following compounds

(i) (ii) (iii)

(a) (i) > (ii) > (iii) (b) (ii) > (iii) > (i) (c) (i) > (iii) > (ii) (d) (iii) > (i) > (ii)
20. Identify correct acidic strength order in the following compounds

(i) (ii) (iii)

(a) (i) > (ii) > (iii) (b) (ii) > (iii) > (i) (c) (i) > (iii) > (ii) (d) (iii) > (i) > (ii)

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21. Which nitrogen in LSD is most basic?
(a) 1 (b) 2
(c) 3 (d) All are equally basic

22. The decreasing order of basic strength is:

(a) (i) > (v) > (iii) > (iv) > (ii)
(b) (iv) > (i) > (v) > (iii) > (ii)
(c) (v) > (iv) > (i) > (ii) > (iii)
(d) (iv) > (v) > (iii) > (i) > (ii)

23. Arrange the following in the decreasing order of their acidic strength

(i) (ii) (iii) (iv)

(a) (i) > (ii) > (iii) > (iv) (b) (iv) > (iii) > (ii) > (i) (c) (ii) > (i) > (iv) > (iii) (d) (i) > (ii) > (iv) > (iii)
24. Arrange the following hydrogens in the order of their acidic behaviour

(a) (i) > (iii) > (ii) (b) (ii) > (iii) > (i)
(c) (i) > (ii) > (iii) (d) (iii) > (ii) > (i)

25. Which of the following acid gives evolution of CO2 with NaHCO3?

(i) (ii) (iii) (iv) (v)

(a) (i), (iii), (iv), (v) (b) (iii), (iv), (v) (c) (i), (ii), (iii), (iv), (v) (d) (i), (iii), (v)
26. Select the correct statement

(a) is more basic than (b) is more basic than

(c) is more basic than (d) All of them

27. Which of the following is most basic?

(a) (b) (c) (d)

28. Which of the following is most basic?

(a) (b) (c) (d)

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All students are advised to solve DPPs within allowed time only.
All discussions are scheduled in every 4th doubt discussion class
–MKA Sir (Guruji)

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