INORGANIC CHEMISTRY : V.K.

JAISWAL(VKJ SIR)

ASSIGNMENT-1
1. d-orbitals are having
(A) Two lobes and two nodal planes
(B) Four lobes and one nodal plane
(C) Opposite lobes are having same sign of wave function ()
(D) Opposite lobes are having opposite sign of wave function ()

2. The half filled and completey filled subshell are _______ stable than partially filled subshell :
(A) Less (B) More (C) Equal (D) Cannot be said

3. The energy of an electron of 2py orbital is :

(A) Greater than that of 2px orbital (B) Less than that of 2px orbital
(C) Equal to that of 2s orbital (D) Same as that of 2pz orbital

4. An electron has magnetic quantum number as –3, what is its principal quantum number.
(A) 1 (B) 2 (C) 3 (D) 4

VIBRANT ACADEMY
5. Which of the following has minimum number of unpaired d-electrons :
(A) Fe3+ (B) Co3+ (C) Co2+ (D) Mn2+

6. Which of the following statements is correct ?

(A) An orbital describes the path of an electron in an atom
(B) An orbital is a region in space in which the electron is located
(C) An orbital is a function which gives the probability of finding an electron in a given region
(D) None is correct

7. The quantum numbers of the last electron which enters an element are :

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 = 3, m = –2 and s = +½. In which block of the periodic table is this element present?
(A) s-Block (B) p-Block (C) d-Block (D) f-Block

8. When the 3d orbital is complete, the new electron will enter in ?

(A) 4p orbital (B) 4f orbital (C) 4s orbital (D) 4d orbital

9. The four quantum numbers for the electron in the outermost orbital of potassium are :
(A) n = 4,  = 1, m = 0, s = +1/2 (B) n = 4,  = 1, m = 0, s = –1/2
(C) n = 4,  = 0, m = 0, s = –1/2 (D) n = 4,  = 0, m = +1, s = –1/2

10. The total number of electrons present in all the p orbitals of bromine are
(A) Five (B) Eighteen (C) Seventeen (D) Thirty five

11. Which of the following electronic configuration is not possible

(A) 1s22s22p6 (B) 1s22s22p7 (C) 1s22s2 (D) 1s22s22p5

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12. The d-orbital with the orientation along X and Y axes is called

(A) d xy (B) dzx (C) dyz (D) d

x 2 y 2

13. d-orbital has lobes

(A) 6 (B) 8 (C) 4 (D) 2

14. What is the number of subshells in principal quantum number 3 :

(A) 3 (B) 5 (C) 9 (D) 14

15. How many electrons with  = 2 will be there in an atom having atomic number 23
(A) 2 (B) 3 (C) 4 (D) 5

16. Hund’s rule deals with the distribution of electrons in

(A) Shell (B) Sub-shell
(C) an orbital (D) degenerate orbitals

17. Match the Column (each entry of column-I is uniquely matched with entry of column-II) :
Column-I Column-II
(A) The d-orbital which has two nodal plane (P) 3d
x2 y 2

VIBRANT ACADEMY
(B) The d-orbital with two nodal surfaces formed cones
(C) The orbital without angular node
(Q) 3dz 2
(R) 4f
(D) The orbital which has three angular nodes (S) 3s

Comprehension (Q.18 to Q.20)

Bohr’s model could not explain fine structure of hydrogen spectrum. To explain this, it was suggested that
each level consists of a number of sublevels, the transitions between which gave rise to closely spaced lines.

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The numbers representing the main energy levels are called Principal Quantum Numbers (n) while those
representing sublevels are called Azimuthal Quantum numbers () and these determine the angular momentum
of the electron. The orbital angular momentum may have different quantized space orientations represented
by Magnetic Quantum Numbers (m) which is just like a further split of a sublevel into finer sublevels. Lastly,
the electron may rotate or spin about its own axis giving rise to Spin Quantum Number (s) which determines
the spin angular momentum of the electron.
18. The quantum number not obtained from the solution of Schrodinger wave equation is
(A) Principal Quantum number (B) Azimuthal Quantum number
(C) Magnetic Quantum number (D) Spin Quantum number

19. The maximum number of electrons in a subshell having the same value of spin quantum number is given by

(A)  + 2 (B) 2 + 1 (C) ( + 1) (D) (   1)

20. The two electrons have the following sets of quantum numbers
X : 3, 2, –2 + 1/2 Y : 3, 0, 0, + 1/2
Which of the following is true?
(A) X and Y have same energy (B) X has greater energy than Y
(C) X has less energy than Y (D) X and Y represent same electron

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 INORGANIC CHEMISTRY : V.K. JAISWAL(VKJ SIR)

ASSIGNMENT-2
Single Choice Questions :
1. The d-orbital which has maximum electron density of two p-orbitals

(A) d x 2 – y 2 (B) dxy (C) d z2 (D) dzx

2. The number of unpaired electrons present in Cr2+, Fe2+, Co2+ and Ni2+ cations are respectively
(A) 4, 2, 1 and 0 (B) 2, 4, 1 and 0 (C) 4, 4, 3 and 2 (D) 4, 2, 0 and 1

3. The correct set of quantum numbers for the unpaired electron of Cl-atom is

(A) 2, 0, 0, +1/2 (B) 2, 1, –1, +1/2 (C) 3, 1, 1, 1/2 (D) 3, 0, 0, ±1/2

4. Which of the following sets of quantum numbers is not allowed ?

(A) n = 3,  = 2, m = 0, s = – 1/2 (B) n = 3, = 2, m = – 2, s = – 1/2
(C) n = 3, = 3, m = – 3, s = – 1/2 (D) n = 3, = 0, m = 0, s = –1/2

VIBRANT ACADEMY
5. The lowest energy level for which g sub-shell is possible is
(A) fourth (B) fifth (C) sixth (D) third

6. The energy of electron in Li2+ species depends on

(A) principal quantum number
(B) principal and azimuthal quantum numbers
(C) principal, azimuthal and magnetic quantum numbers

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(D) principal, azimuthal, magnetic and spin quantum numbers

7. Which of the following configuration has highest magnetic moment?

(A) d4 (B) d2 (C) d5 (D) d7

8. The multiplicity of 3d7 electron in an atom is

(A) 1/2 (B) 3/2 (C) 5/2 (D) 7/2

9. In the presence of magnetic field, d-sub-shell is

(A) 5-fold non degenerate (B) 3-fold non degenerate
(C) 7-fold non degenerate (D) degenerate

10. The number of d-electrons in Fe2+ (Z = 26) is not equal to

(A) p-electrons in Ne(Z = 10) (B) s-electrons in Mg (Z = 12)
(C) d-electrons in Fe(Z = 26) (D) p-electrons in Cl (Z = 17)

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11. Which of the following arrangement of electrons is most likely to be unstable ?

(A) (B)

3d 4s 3d 4s

(C) (D)

3d 4s 4s
3d

12. If Hund’s rule is not followed, (maximum paired electron) magnetic moment of Fe2+, Mn+, and Cr, all having 24
electrons will be in the order of

(A) Fe2+ < Mn+ < Cr (B) Fe2+ = Cr < Mn+ (C) Fe2+ = Mn+ < Cr (D) Mn+ = Cr < Fe2+

13. If there are three possible values (–1/2, 0, +1/2) for the spin quantum number ‘s’, then electronic configuration
of K (19) will be

(A) 1s3 2s3 2p9 3s3 3p1 (B) 1s2 2s2 2p6 3s2 3p6 4s1

(C) 1s2 2s2 2p9 3p4 (D) none is correct

14.
VIBRANT ACADEMY
Which of the following pair of atomic numbers of elements, is showing same magnetic behaviour
(A) 33, 36 (B) 10, 12 (C) 28, 30 (D) 17, 18

15. Total number of orbitals in a shell having principle quantum number n is

(A) 2n (B) n2 (C) 2n2 (D) (n + 1)

16. The maximum number of electrons having same value of spin quantum number in any subshell is

(A)  + 1
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(B) 2 + 1 (C) 2(2 + 1) (D) (   1)

17. Match the Column :

Column-I Column-II

(A) No. of orbitals in the nth shell (P) 2(2 + 1)

(B) Max. no. of electrons in a subshell (Q) n

(C) No. of subshells in nth shell (R) 2 + 1

(D) No. of orbitals in a subshell (S) n2

Subjective :

18. Consider the following orbitals (i) 3px (ii) 4d (iii) 3d (iv) 3dyz
z2 x2 – y2

Then calculate value of “x – y + z” here x is total number of gerade orbital and y is total number of ungerade
orbitals and z is total number of axial orbital in given above orbitals.

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 ASSIGNMENT-1
1. C 2. B 3. D 4. D 5. C 6. C 7. D
8. A 9. C 10. C 11. B 12. D 13. C 14. A
15. B 16. D
17. A – P ; B – Q ; C – S ; D – R 18. D 19. B 20. B

ASSIGNMENT-2
1. A 2. C 3. C 4. C 5. B 6. A 7. C
8. B 9. A 10. D 11. B 12. B 13. A 14. B
15. B 16. B 17. A–S ; B–P ;C–Q ;D–R 18. 5

VIBRANT ACADEMY

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