Professional Documents
Culture Documents
Classification of Nucleus
Bohr atom model with explanation and Atomic orbital and energy
equation
Nuclear size and binding energy
Radioactivity
Radioactive decay law
Half life and Mean life
Mass energy relation
Momentum energy relation
Compton effect
Photoelectric effect
De Broglie matter wave
Nuclear reaction (fission & fusion) introduction to nuclear reactor.
Classification of Nucleus
Nucleus is consisting of the elementary particles, protons and nucleons which are known as
nucleons.
Proton is +ve charged of the same magnitude of electron and its rest mass is about 1836 times
the mass of the electron.
The charge of electron/proton is 1.602 x 10 -19 Coulomb mass of electron is 9.1x 10 -31 Kg.
A neutron is electrically neutral whose mass is almost equal to the mass of proton. Basing on
number of protons a nucleus is classified as:
Isotopes. Isotopes are atoms of same element having the same atomic number Z (number
of proton) but different mass number A ( sum of proton and neutron) ZXA.
Isobars. Isobars are atoms of different element having the same mass number A (number
of proton & neutron) but different atomic number Z ( number of proton) .
Isotones. Isotones are atoms of different element having the same umber of neutrons.
Mirror Nucleus: Nuclei having the same mass number but the proton and neutron number
are interchanged are called mirror nucleus.
Wn2 – Wn1 = hv
Calculation of Radius, Energy and Frequency
---------------------------- (2)
Calculation of Radius, Energy and Frequency
From equation (1) and (2 ) we get
K. E = mv2
= ( Using equation 3) ------------------------------------------- (7)
hυ = En2-En1
hυ = - ( )
hυ = +
hυ = ( - )
So, υ = ( - ) -------------------- ----------------- (10) ( Where
Z=1 for Hydrogen atom)
= ( - )
F E
E
EE e
r E
Nucleus dx
or = R( - ) where R = is Rydberg constant = 1.096 x 107 per m
Lyman Series. When an electron jumps from the outer orbits to the first orbit, the
spectral lines are in the ultra-violet region . Here n 1=1 and n2 = 2, 3, 4, 5-----
So the wave number for Lyman Series will be:
υ1 = R ( - ) = R ( - )= R
υ2 = R ( - ) = R ( - )= R
and so on
Balmer Series. When an electron jumps
from the outer orbits to the second orbit,
the spectral lines are in the visible region.
Here n1=2 and n2 = 3, 4, 5-----
Spectral Series of H2 Atom
So the wave number for Balmer Series will be:
υ1 = R ( - ) = R ( - )= R
and so on
Paschen Series. When an electron jumps
from the outer orbits to the third orbit, the
spectral lines are in the near Infrared
region. Here n1=3 and n2 = 4, 5, 6-----
υ1 = R ( - ) = R ( - )= R
And so on---
Brackett Series. When an electron jumps Pfund Series. When an electron jumps
from the outer orbits to the fourth orbit, the from the outer orbits to the fifth orbit, the
spectral lines are in the far Infrared region spectral lines are in the far Infrared
(electromagnetic radiation). Here n1=4 and (electromagnetic radiation) region. Here
n1=5 and n2 = 6, 7-----
n2 = 5, 6-----
Balmer Series
Paschen Series
Bracket Series
n1
n2
Pfund Series n3
n4 Lyman Series
n5
n6
Mathematical Problem
Problem: Calculate the radius of the first Bohr orbit for H 2 and He atoms.
We know,
Here,
Problem: How much energy is required to remove an electron from n=3 or n=2 state in
Hydrogen atom.
It is found that the mass of a nucleus is less than the sum of the masses of the constituent particles in the
free state.
According to Einstien the decrease in mass is due to the release of energy when the particle combine to
form a nucleus.
This energy can be expressed by the relation E=mc 2 where m is the decrease in mass and c is the velocity of
light.
Fe56
Mass no
Binding energy
If a nucleus is to be broken into its constituent particles an energy equal to or
more than the binding energy must be supplied to the nucleus.
It is convenient to calculate energy in Joule or electron volt (ev).
The energy equivalent of the mass defect in a nucleus is called binding energy
and is a measure of the stability of the nucleus.
The greater the B.E per nucleon, the more stable the nucleus is. F 56 is the most
stable nucleus in the nature.
Fe56
Mass no
Mass Deffect and Binding Relation
Mass defect: Neutrons and protons together create a nucleus. So, the mass of a nucleus
should be equal to the mass of the protons and neutrons added together. But actually, the
mass of a nucleus is little less than the mass of the protons and neutrons added together.
The difference in mass is known as mass defect. It is denoted by M.
Mathematically,
Where, Z = Number of protons, (A-Z) = Number of neutrons , Mp = Mass of protons, Mn =
Mass of neutrons and M = Mass of nucleus.
Relation:
The relation between the binding energy and mass defect is given by
Electron Volt (EV) is the unit of work and energy in nuclear physics.
It is defined as the work done in taking an electron through a difference of potential
of one volt.
Problem
Calculate of the Binding Energy in case of Lithium of A =7 and Z=3
Practice
Radioactivity
The phenomenon of spontaneous emission of powerful
radiations exhibited by heavy elements is called radioactivity.
So, N= N
0e ---------- --------------- (2)
Radioactive Decay Law Cont-----
N= N
0 e -
From the above equation it is evident that the number of radioactive atoms decreases exponentially with time.
𝑵𝟎
𝟐
N
t
𝑵) 𝟎
The half life period of a radioactive atoms are defined as the time requires for one half of the radioactive (initial
𝟐
atoms to disintegrate. Suppose half life period =T and as per definition N=
Therefore, from equation
N= N
0 e- N=
=e -
Or e =2
Or Loge 2= Loge e
= Loge 2
So, T=
t
N =N
0 e-
Or, e - (differenting)
Or, dNt= e - dt ---------------- ----- (1) it means dNt atoms
4. Consider an atomdisintegrate
of lifetime =tat short interval of time dt.
So, lifetime for dNt atom = t dNt
T
5. he Meantolife
According τ==
definition, =
=
= (
τ=
When a force F displaces a body ds then the increase in kinetic energy E k is given by
Or dEk = v [ ] dv
Or dEk = m0 v [ ] dv
Mass energy relation
Or dEk = m0 v [ ] dv
After differentiation we shall get
dEk = [ ( 1/2 + . ] dv
= [ ] dv (series expansion)
dEk = = -------- ----- (3)
Now consider that the mass of a body at rest is m0 and when it is moving with a velocity
ʃ dEk= ʃ m0
m
dm= (m- m0)
E2 = + C2P2
Momentum energy relation
If a body of mass m is moving with a velocity v its momentum
P= mv --------------------- (1)
Again, we know E = mc2
Or E2 = m2C4 (squaring both sides) --------------- -------------- (2)
and m = ------------------------ (3)
From (1) we can write
P 2 = m2 v 2
C2P2 = m2v2C2--------------------- (4)
Now (2) – (4) E2 - C2P2 = m2C4 - m2v2C2
= C4 - v2C2 (Using 3)
= = =
So, E2 = + C2P2
This is the desired relation between momentum and energy
What is Compton Effect?
Consequently, the scattered photon has less energy than the incident photon.
Therefore, the frequency of the scattered photon is shorter than that of incident
photon.
Let an energetic (X-ray) photon of energy and momentum hν/c strikes a free electron at rest.
The energy of incident photon will be divided into energy of scattered photon = hν/ and energy
of electron = K.E.
Compton Effect
For the conservation of energy, we can write
Momentum is a vector quantity that incorporates direction as well as magnitude and in a collision
momentum must be conserved in each of two mutually perpendicular directions. The directions we
choose here are that of the original photon and one perpendicular to it in the plane containing the
electron and the scattered photon (fig.).
The initial photon momentum is hν/c and the scattered photon momentum is hν//c, and the
initial and final electron momenta are respectively 0 and p.
In the original photon direction (x direction)
The angle θ is that between the directions of the initial and scattered photons and, is
that between the directions of initial photon and recoil electron.
Multiplying equations (4) and (5) by c we can write
Compton Effect
Since
We have
Since
Compton Effect
We can write
Equation (11) is the expression for the change in wavelength when an incident radiation
of wavelength l is scattered by a free electron by an angle .
The quantity is called Compton wavelength of scattering particle.
Then equation (11) becomes
Compton Effect
Special Cases:
1. When , then
2. When , then
3. When , then
Here,
h=6.63×10-34JS
m0=9.1×10-31kg
c=3×108 ms-1
λ=0.124 A0
=0.124×10-10m
φ=1800
λ/ = ?
Compton Effect
Problem-2: X-ray of l= 1 A0 are scattered from a graphite block and the scattered radiation
is viewed at 900 to the incident beam. What is Compton shift? Calculate the kinetic energy
imparted to the recoiling electron.
Compton Effect
Here,
Practice
At maximum
The maximum Kinetic energy of recoil electrons
U=
= h( c/ - c/ ’)
Photoelectric Effect
• For a given metallic surface, there is a minimum frequency for which the
incident light can eject the photo-electrons out of the metal. Light of
frequency smaller than the particular value cannot eject electrons, no matter
how long it falls on the surface.
• The number of photo-electrons ejected depends upon the intensity of the
incident light. Thus, the photo-electric current depends upon the intensity of
the incident light.
We have , h𝛎 = mv2
Again K. E= mv2 = eV0
So eV0= h𝛎
= h(𝛎 )
Here,
Or
∴ 𝒗 𝒎𝒂𝒙 =𝟐 . 𝟐𝟒 × 𝟏 𝟎𝟓 𝒎𝒔 −𝟏 ( 𝑨𝒏𝒔 )
Problems : Photo-electric Equation
Problem-3: The wavelength of light falling on the surface of a metal of work function 2.3 eV
is 4300 A0 with what velocity the electron will be emitted?
( )
𝟏 𝒄 Here,
𝒎 𝒗𝟐
𝒎𝒂𝒙 = 𝒉 − 𝒘𝟎
𝟐 𝝀
√ { ( ) }
𝒄
𝟐 𝒉 − 𝒘𝟎
𝝀
𝒗 𝒎𝒂𝒙 =
√
𝒎
{ ( ) }
𝟖
−𝟑𝟒𝟑×𝟏𝟎 −𝟏𝟗
𝟐 𝟔.𝟔𝟑×𝟏𝟎 × −𝟕
−𝟑.𝟔𝟖×𝟏𝟎
𝟒.𝟑×𝟏𝟎
𝒗 𝒎𝒂𝒙 =
𝟗.𝟏×𝟏𝟎−𝟑𝟏
𝟓 −𝟏
𝒗 𝒎𝒂𝒙 =𝟒 . 𝟓𝟓 ×𝟏 𝟎 𝒎𝒔 ( 𝑨𝒏𝒔 )
Problems : Photo-electric Equation
𝐀𝐧𝐬 : 𝟔𝟎𝟎𝟎 𝑨
𝟎
Problem: The stopping potential for electrons emitted from a metal due to photoelectric
effect is found to be 1V for a light of 2500 A0. Calculate the work function of the metal in eV.
𝐀𝐧𝐬 : 𝟑 . 𝟗𝟕 𝒆𝑽
Assignment
In 1924 Luis de-Broglie proposed that matter possesses wave as
well as particle properties. This wave is called de-Broglie wave.
de- Broglie matter wave
Thus, the greater the particle’s momentum, the shorter its wavelength.
We know,
de- Broglie matter wave
Again, we know
Here is called the angular frequency of the wave and k is called the wave vector.
Here is called the phase/wave velocity. In other words, is the velocity with which a plane progressive
wavefront travel forward. It has a constant phase
Wave velocity and group velocity
The phase/wave velocity of a wave is the rate at which the phase of the wave propagates in
space. This is the velocity at which the phase of any one frequency component of the wave
travels.
Or, equivalently, in terms of the wave’s angular frequency ω, which specifies the number of
oscillations per unit of time, and wave number k, which specifies the number of oscillations
per unit of space, by
Wave velocity and group velocity
The group velocity of a wave is the velocity with which the overall shape of the waves'
amplitudes-known as the modulation or envelope of the wave-propagates through space.
The group velocity vg is defined by the equation:
where ω is the wave's angular frequency (usually expressed in radians per second ),
and k is the angular wave number (usually expressed in radians per meter).
Relation Between Wave velocity and Group velocity
Here,
Nuclear Reaction (fission & fusion)
When a nucleus gets in close contact with another nucleus, the incident particle and the
target nucleus form a composite system which is an excited state and after a short while
a reaction is produced in which the incident particle itself or some other particle or
gamma ray is emitted with excess energy and a resulting nucleus is obtained. This
phenomenon is called a nuclear reaction.
A nuclear reaction can be written as
Nuclear fission: If neutrons or gamma rays of definite speed strike a heavy nucleus (A>230)
and breaks the nucleus into two main parts, then a vast nuclear energy is released. This
kind of breakup of nucleus is called nuclear fission.
Let us consider the capture of neutron by a heavy nucleus. The reaction can be represented
as
Nuclear Reaction (fission & fusion)
Nuclear fusion: More than one light nuclei are fused (or combined) together to
form a single heavy nucleus and produce enormous nuclear energy. This process
is called nuclear fusion.
The reaction can be represented as
Atomic Bomb
As of early 2019, the IAEA reports there are 454 nuclear power
reactors and 226 nuclear research reactors in operation around the
world.
Introduction to Nuclear Reactor
Reactor Criticality
In nuclear reactors, reactor criticality is the state in which a reactor is
stable and self-sufficient to continue a nuclear chain reaction. This
condition is also known as the critical state. The reactor criticality is
measured by effective multiplication factor (keff).
Date of Deposition :