Chemistry

Biomolecules & Polymers

JEE Advanced
Exercise -2
Problem Solving
Course
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1. Which of the following pairs give positive Tollen’s
test ? [IIT 2004] (A) Glucose,
sucrose
(B) Glucose, fructose
(C) Hexanal, acetophenone
(D) Fructose, sucrose
2. The two forms of D–glucopyranose obtained from
the solution of D–glucose are called :
[IIT 2005]
(A) isomer (B) anomer
(C) epimer (D) enantomer
3. Column – I Column – II
[IIT 2007]
(A) Cellulose (P) natural polymer
(B) nylon – 6, 6 (Q) synthetic polymer
(C) protein (R) amide linkage
(D) sucrose (S) glycoside linkage
4. Cellulose upon acetylation with excess acetic
anhydride/H2SO4 (catalytic) gives cellulose
triacetate whose structure is [IIT 2008]
5. Among cellulose, poly (vinyl chloride), nylon and
natural rubber, the polymer in which the
intermolecular form of attraction is weakest is :
[IIT 2009] (A) nylon
(B) poly (vinyl chloride) (C) cellulose (D)
natural rubber
6. The correct statement(s) about the following
sugars X and Y is (are) [IIT 2009]
(A)X is a reducing sugar and Y is a non–reducing
sugar
(B)X is a non–reducing sugar and Y is a reducing
sugar
(C)The glucosidic linkages in X and Y are a and
b, respectively
(D)The glucosidic linkages in X and Y are b and
a, respectively
7. The correct statement about the following
disaccharide is [IIT 2010]

(A) Ring (a) is pyranose with a–glacosidic link

(B) Ring (a) is furanose with a–glycosidic link
(C) Ring (b) is furanoswe with a–glycosidic link
(D) Ring (b) is pyranose with b–glycosidic link
8. The following carbohydrate is [IIT 2011]

(A) a ketohexose (B) an aldohexose

(C) an a – furanose (D) an a–pyranose
9. The correct functional group X and the
reagent/reaction conditions Y in the following
scheme are [IIT 2011]

(A) X = COOCH3, Y = H2/Ni/heat

(B) X = CONH2, Y = H2/Ni/heat
(C) X = COHN2, Y = Br2/Naoh
(D) X = CN, Y = H2/Ni/heat
10. A tetrapeptide has – COOH group on alanine.
This produces glycine (Gly), valine (Val), phenyl
alanine (Phe) and alanine (Ala), on complete
hydrolysis. For this tetrapeptide, the number of
possible sequences (primary structures) with –
NH2 group attached to a chiral centre is
[JEE Advance 2013]
ONE OR MORE THAN ONE
11. The structure of D – (+) – glucose is
[JEE Advance 2015]

The structure of L–(–)–glucose is

SINGLE CHOICE QUESTIONS
12. On complete hydrogenation, natural rubber
produces [JEE Advance 2016]
(A) Ethylene–propylene copolyer
(B) Vulcanised rubber
(C) Polyproplene
(D) Polybutylene