ORGANIC CHEMISTRY

ENTHUSE
DPP # 17

1. Match the following reaction with their corresponding pattern of graph :

Column-I Column-II

Potential energy
Product 1
(A) 
Conc.H 2SO 4
(P) Product 2
OH 

Reaction coordinates

Potential energy
Product 1
Product 2

(B) OH Conc.H 2SO 4


(Q)

Reaction coordinates
Potential energy

Product

conc H2SO4
(C) Product(s) (R)

OH
Reaction coordinates
Potential energy

Product 1
Product 2
conc. H2SO4
(D) OH (S)


Reaction coordinates
Potential energy

Product

(T)

Reaction coordinates

H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, 0744-2423333 1
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 ORGANIC CHEMISTRY
ENTHUSE
2. When the boiling points of the first ten normal alkanes are plotted the graph looks like:

(A) (B) (C) (D)

3. Major product obtained in following reaction is :

HCl

peroxide

(A) (B) (C) (D)

4. Possible products formed during the reaction is/are :

CH2 –Cl
Na (Dry ether)
CH2 –Cl
CH3

(A) (B)

(C) (D)

5. Statement-1 : Wurtz reaction is not a good method to prepare R–R from R–X in which R is a
3° alkyl group. ( X ++ –F)
Statement-2 : 3° carbocation is formed during this reaction which preferably give alkene.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.

6. In the given reaction, structure of X can be :

14
CH3
H
(X) Alcohol  
CH3
OH OH OH
14
CH3 CH3 CH3 CH3
(A) (B) (C) (D)
14
CH3 CH3 CH2–OH CH3
14 14

H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, 0744-2423333 2
www. nucleuseducation.in
 ORGANIC CHEMISTRY
ENTHUSE
7. Major product obtained in following reaction is :
OH
OH 

H


O
OH
(A) (B) (C) (D)
O
O

8. Compare the rate of hydration of following alkenes -

MeO
Ph Ph Ph

(I) (II) (III) (IV) (V) (VI)

(A) IV > V > VI > II > II > I (B) VI > IV > V > III > I > II
(C) VI > V > IV > III > I > II (D) VI > IV >V > III > II > I

9. How many structures of 1,4-disubstituted benzene is/are possible with molecular formula C8H8O3 in
which one –COOH (carboxylic) group must be present :

10.(a) Propane reacts with chlorine in sunlight to give two products. 1-chloropropane is obtained in 44% yield
and 2-chloropropane is obtained in 56% yield of the total product. 2-Methylpropane reacts with chlorine
under same conditions to produce 1-chloro-2-methylpropane 66% and 2-chloro-2-methylpropane 33%
What will be the percent yield (X) of the major monochloro product obtained when 3-ethylpentane is
treated with Cl2 in similar conditions. (Round answer to nearest integer)
(Ignore stereoisomers)

(b) What will be the percent yield (Y) of the monochloro product obtained in minimum amount.
(Round answer to nearest integer)

H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, 0744-2423333 3
www. nucleuseducation.in