GUIDED REVISION ENTHUSIAST & LEADER

Target : JEE(Main + Advanced) - 2019 COURSE

ORGANIC CHEMISTRY
GUIDED REVISION PLAN-SCORE ADVANCED
Question Bank # 04
Only one correct :
1. Phenol and ethanol are distinguished by the reaction with
(A) Red litmus (B) NaHCO3 (C) FeCl3 (D) Na

2. Chloral + Cl Conc
 
. H 2SO 4
 product. The product is:

(A) Lindane (B) DDT (C) Teflon (D) Ethaneperchlorate

3. In the following carbocation, H/CH3 that is most likely to migrate to the positively charged carbon
is :

H H
1 2 + 4 5
H3C — C ——3C —— C —— CH3

HO H CH3

(A) CH3 at C - 4 (B) H at C - 4 (C) CH3 at C - 2 (D) H at C - 2

4. Among the following compounds, the most acidic is :
(A) p-nitrophenol (B) p-hydroxybenzoic acid
(C) o-hydroxybenzoic acid (D) p-toluic acid
Mg–Hg Conc.H2SO4
5. 2Ph—C—CH3 H2 O
Product
O

The main product is :

(A) Ph—C—C—Ph (B) CH 3—C—C—CH3

O O O O

Ph Ph
(C) Ph—C — C—CH3 (D) Ph—C —C—CH3
CH3 O O CH3

6. Which of the following reactions would give the best yield of t-butyl methyl ether ?
H2SO4
(A) (CH3 )3C–OH 140ºC
(B) (CH3)3C–Br + CH3OH 

E 1
 GUIDED REVISION ENTHUSIAST & LEADER
Target : JEE(Main + Advanced) - 2019 COURSE

– –+
(C) (CH3)3 C–Br + CH3 ONa+ (D) (CH3)3C—OK + CH3Br

7. Decide the correct order of reactivity of following compounds towards halogenation with (Cl2 + AlCl3).

COOPh CH3 Et

I II III IV

(A) I > II > III > IV (B) II > III > IV > I (C) III > II > IV > I (D) II > III > I > IV
AgCN H ,Ni
8. Br   A   B 2

The final product (B) is :

H

(A) NH2 (B) (C) N (D)

N NH2
H
9. Which of the following method(s) is/are not used to prepare p-bromo aniline as major product :

NH 2 NH2 NH 2 NH2
Br2 CH3COCl Br2 NaOH/H2O
(A) H2O
(B) FeBr3 

Br Br

NH 2 NH2 NH 2 NH2

H2SO4 Br2 KCN LiAlH4 Br2

(C) FeBr3 (D) NaNO2/HCl CuCN FeBr3
0-5°C 

Br Br

O O
|| ||
10. Of the species PhSR, PhSR , PhSR and Ph  S  OR the meta-substituted product is obtained from
|| || ||
O O O

O O
|| ||
(A) PhSR (B) PhSR (C) PhSR (D) Ph  S  OR
|| || ||
O O O
11. Which of the following statements is incorrect for electrophilic substitution.
(A) Ortho-and para-directing groups increase electron density at ortho-and para-positions
(B) Meta-directing groups increase electron density at meta-position

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 GUIDED REVISION ENTHUSIAST & LEADER
Target : JEE(Main + Advanced) - 2019 COURSE

(C) Meta-directing groups decrease electron density only at meta-position

(D) Ortho-and para-directing groups decrease electron density at meta-position

Paragraph Type :

Comprehension (Q.12 to Q.14)

G
The monomer (G = Me or Cl) when treated with Zieglar - Natta catalyst undergo polymerisation

in the manner given below -

Zieglar-Natta
n
Catalyst n
cis-poly-1,3-butadiene

12. The Zieglar-Natta catalyst is

(A) TiCl4 (B) R3Al (C) R3 Al / TiCl4 (D) R3 B/TiCl4

Cl
13. The polymer obtained when monomeric unit used is CH2=C–CH=CH2

(A) Neoprene (B) Stilbene (C) Styrene (D) Chloropicrin

14. Which of the following statement is not true considering the process given above.

(A) The general class of polymer formed is known as homopolymer

(B) The polymer obtained is stereoregular

(C) Buna–N can be prepared using above process

(D) Synthetic rubber can be formed by above process using 1,3- butadiene.

Matrix Match Type :

15. Match the column :

Column - I Column - II

(A) HCHO + NaOD (conc.) (P) DCOO– + CDH2OH

(B) DCHO + NaOH (conc.) (Q) DCOO– + CD2OH

(C) DCDO + NaOH (conc.) (R) DCOO– + CDH2OD

E (D) DCHO + NaOD (conc.) (S) HCOO– + CH3OD 3

 GUIDED REVISION ENTHUSIAST & LEADER
Target : JEE(Main + Advanced) - 2019 COURSE

ANSWERS
ORGANIC CHEMISTRY
Guided Revision Plan-Score Advance-Question Bank (04)
Only one correct :
1. Ans. (C) 2. Ans. (B) 3. Ans. (D) 4. Ans. (C) 5. Ans. (C)
6. Ans. (D) 7. Ans. (A) 8. Ans. (B) 9. Ans. (A,C,D) 10. Ans. (C,D)
11. Ans. (B,C,D)
Paragraph Type :
12. Ans. (C) 13. Ans. (A) 14. Ans. (C)
Matrix Match Type :
15. Ans. (A)S ; (B)P ; (C)Q ; (D)R

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