Professional Documents
Culture Documents
A.P T.S KARNATAKA TAMILNADU MAHARASTRA DELHI RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec: Sr.S60_NUCLEUS & STERLING-BT 2021_P1 Date: 02-10-22
Time: 09.00Am to 12.00Noon PTA-04 Max. Marks: 180
02-10-2022_Sr.S60_NUCLEUS & STERLING-BT_Jee-Adv(2021-P1)_PTA-04_Syllabus
PHYSICS : Kinematics, NLM & Friction: Kinematics in one and two dimensions
(Cartesian coordinates only), projectiles; Relative velocity. Newton’s laws of
motion; Inertial and uniformly accelerated frames of reference; Static and
dynamic friction;
CHEMISTRY : Alcohol-Phenol , Ether & Amines: Alcohols: Physical properties;
Reactions: esterification, dehydration (formation of alkenes and ethers);
Reactions with: sodium, phosphorus halides, ZnCl2/concentrated HCl, thionyl
chloride; Conversion of alcohols into aldehydes, ketones and carboxylic acids
Phenols: Physical properties; Preparation, Electrophilic substitution reactions
of phenol (halogenation, nitration, sulphonation); Reimer-Tiemann reaction,
Kolbe reaction; Esterification; Etherification; Aspirin synthesis; Oxidation and
reduction reactions of phenol. Ethers : Preparation, Properties &Reactions
Amines: Amines: basicityofsubstituted anilines and aliphaticamines,
Preparation from nitro compounds, nitriles and amides; Reactions: Hoffmann
bromamide degradation, Gabriel phthalimide synthesis; Reaction with nitrous
acid, Azo coupling reaction of diazonium salts of aromatic amines; Sandmeyer
and related reactions of diazonium salts; Carbylamine reaction, Hinsberg test,
Alkylation and acylation reactions
MATHEMATICS : STRAIGHT LINES AND CIRCLES
CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 20 – 23) Questions with Single Correct Choice +3 -1 4 12
Paragraph Questions with Numerical
Sec – II(Q.N : 24 – 29) +2 0 6 12
Value Answer Type
Questions with Multiple Correct
Sec – III(Q.N : 30 – 35) +4 -2 6 24
Choice with partial mark
Questions with Non-negative Integer
Sec – IV(Q.N : 36– 38) +4 0 3 12
Value Type
Total 19 60
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 39 – 42) Questions with Single Correct Choice +3 -1 4 12
Paragraph Questions with Numerical
Sec – II(Q.N : 43 – 48) +2 0 6 12
Value Answer Type
Questions with Multiple Correct
Sec – III(Q.N : 49 – 54) +4 -2 6 24
Choice with partial mark
Questions with Non-negative Integer
Sec – IV(Q.N : 55 – 57) +4 0 3 12
Value Type
Total 19 60
A
q
Av 2 sin
A) B) tan
mg Av 2 cos
Av 2 Av 2
C) tan D)
mg mg Av 2 cos
2. If coefficient of friction between all surfaces is 0.4, then the minimum horizontal force F
(as shown in figure) to have the equilibrium of the system will be, ( g 10m / s 2 )
3. A top view of a stream whose one of the banks is inclined at 300 to the other is shown in
the figure. Velocity of the stream is 3 kmph parallel to bank 2. velocity of a man in still
water is 4 kmph. The man is supposed to start at P and reach bank 2 in shortest possible
time. PQ and PR are directions perpendicular to Bank 2 and Bank 1 respectively. Then
velocity of man w.r.t. stream is
A) 5 kmph along PR
B) 4 kmph along PQ
C) 37 kmph between PR and direction of stream velocity
D) 4 kmph along PR
1 u 2v 2 m u 2v 2 1 u 2v 2 m u 2v 2
A) m B) C) m D)
2 u 2 v 2 4 (u 2 v 2 ) 2 u 2 v 2 4 (u 2 v 2 )
SECTION 2
This section contains THREE (03) questions stems.
There are TWO (02) questions corresponding to each question stem.
The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value corresponding to the answer in the designated place using the mouse and the on-screen
virtual numeric keypad.
If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +2 If ONLY the correct numerical value is entered at the designated place;
Zero Marks:0 in all other cases
7. The magnitude of velocity (in m/s) of the point B on the rod at this instant is
a 2t m / s 2 as shown in the figure where t is the time in seconds
9. The difference in normal reaction (in N) exerted by AC and AB on the ring at t = 2 sec is
_____
10. The ring starts to rise up the wire AC at a time (in seconds) t = ________
v (parabola)
B A
t
O t0
A) Relative speed between the cars first increases for some time, and then decreases for
accelaration
due to
gravity is g
C
B m
A M
5g
A) Acceleration of point C is upwards
2
B) Acceleration of block B is 2g upwards
C) Acceleration of block A is g downwards
D) Acceleration of point C is g downwards.
13. The figure shows a smooth fixed wedge on which a block of mass m is kept and released
then which of the following are true. Give your answers in given coordinate system
where a = acceleration of block and N is the contact force between the block and the
wedge
Sec: Sr.S60_NUCLEUS & STERLING-BT Space for rough work Page 8
Sri Chaitanya IIT Academy 02-10-2022_Sr.S60_NUCLEUS & STERLING-BT_ Jee-Adv(2021-P1)_PTA-04_Q.P
A) N cos mg B) N mg cos
N sin N cos mg ˆ
C) a iˆ j D) a g sin cos iˆ g sin 2 ˆj
m m
14. In the arrangement shown, the string is light, pulley is smooth, the total mass on left hand
side of the pulley is m1 , on right hand side is m2 , the coefficient of friction between
1
block B and the wedge is and the inclination angle 300 . Select the incorrect
2
option(s)
/////////////////////////
B
1
A) acceleration of block D is m / s 2 upwards
2
B) end A is pulled with force of 22N
1
C) mass of block B is kg
2
D) acceleration of block B is 7m / s 2 upwards
16. A gun is aimed at a fruit and fires a bullet as shown. The fruit is dropped simultaneously.
The initial speed of bullet is ‘u’ from the surface of earth. Choose the correct statement(s)
fruit
H
u
X ground
C) If u
g H2 X2 and meanwhile the earth loses its attraction, then also the bullet
H
can hit the fruit
D) If u gH , the bullet cannot hit the fruit
Sec: Sr.S60_NUCLEUS & STERLING-BT Space for rough work Page 10
Sri Chaitanya IIT Academy 02-10-2022_Sr.S60_NUCLEUS & STERLING-BT_ Jee-Adv(2021-P1)_PTA-04_Q.P
SECTION 4
This section contains THREE (03) question.
The answer to each question is a NON-NEGATIVE INTEGER.
For each question, enter the correct integer corresponding to the answer the using the mouse and the on-screen virtual numeric keypad in the
place designated to enter the answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct integer is entered;
Zero Marks : 0 In all other cases.
17. Two plates AB and CD are rigidly attached perpendicular to base of a massive box is
released on a smooth incline plane having angle of inclination 37 . With what minimum
speed (in m/s) with respect to box a particle is projected so as to graze top points A and C
of plates AB and CD. Given separation between top of plates is 3m. take AB = 2m, CD =
3m and g 10 m / s 2 .
18. A mouse can scrawl with a velocity 2 m/s on a stationary truck of rectangular shape. The
top view of the truck is shown in the diagram. The truck is moving with constant speed 5
m/s along a straight road. The points P, Q, B and C are the corners of the truck and A is
midpoint of PQ. Now the mouse starts moving from point A and following the cyclic
path A B C A along the triangular mark shown. The displacement of mouse (in
meters) with respect to ground when it returns to point A is 8x. Find the value of x.
[Assume that the mouse moves with 2 m/s w.r.t. truck throughout the motion]
4m
5 m/s
A Q
P
6m
19. Two particles are thrown simultaneously from points A and B with velocities u1 2ms 1
and u2 14ms 1 respectively, as shown in Fig. Find the minimum separation (in meters)
between two particles during their journey
O O
H3C O C H3C C O
A) B)
O
H3C C OH OH
O CH3
O
C) D)
21. What will be the major product of the following reaction?
D
O
H
H
Product
CH3
OD D OH OH
H OH D H
CH3 CH3
18 CH3 CH3
HO CH2 C CH3 18 HO CH2 C CH3
HO CH2 C CH3 HO CH2 C CH3
OH OH
A) 18 B) OH C) 18 D) OH
HI(excess)
NC O
OH I OH I
A) NC OH B) NC OH C) NC I D) NC I
SECTION 2
This section contains THREE (03) questions stems.
There are TWO (02) questions corresponding to each question stem.
The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value corresponding to the answer in the designated place using the mouse and the on-screen
virtual numeric keypad.
If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +2 If ONLY the correct numerical value is entered at the designated place;
Zero Marks : 0 In all other cases.
1) LiAlH 4 excess
O NCH 3 2) H O
product
3
O O
NaNO 2 ,HCl
E F
H 2 ,Pd/C in ethanol
90% yield
Cu,HBr
80% yield
G 0 5 C
100% yield
m.f .C6H 7 N
x g and y g are mass of D and G
(i) N K
CH3
H3C
O
S
CH 2Br (ii)(aq) KOH,
(iii) H3O
CH3 CH3
H3C H3C
A) CH2NH 2 B) CH2NH 2
CH2NH 2 CH2NH 2
H3C H3C
C) CH3 D) CH3
31.
G
N2.Cl N N G
i NaNO2 / HCl
ii H 2O(Warming)
B)
i Oleum
ii NaOH, Heating
C) iii H
Cl
O O
CH3 O H CH3 O H
A) B)
Sec: Sr.S60_NUCLEUS & STERLING-BT Space for rough work Page 17
Sri Chaitanya IIT Academy 02-10-2022_Sr.S60_NUCLEUS & STERLING-BT_ Jee-Adv(2021-P1)_PTA-04_Q.P
NO 2 OCH3
O O
C) CH3 O H D) CH3 O H
A) OH B) O C) OH D) OH
35.
O
O
C NH2 15
C NH2
and
KOH / Br2
P Q
CH3
CH3
P Q
A) B)
15
NH2 NH2
P Q
C) CH3 D) CH3
SECTION 4
This section contains THREE (03) question.
The answer to each question is a NON-NEGATIVE INTEGER.
For each question, enter the correct integer corresponding to the answer the using the mouse and the on-screen virtual numeric keypad in the
place designated to enter the answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct integer is entered;
Zero Marks : 0 In all other cases.
O
O CH3
(i) (ii) O (iii)
OCH 3
O
O
(iv) (v) CH 3 O CH 3 (vi) (vii)
O
O
O
(vii) (ix) (x)
37. Find the number of compounds which are more basic than Ph NH 2
H3C CH3
NH2 CH 2NH 2 N
CH3
, Et 3 N , (CH3 )2 N H , , NH 3 ,
OH OMe
CH 3 N H 2 , , ,
OH
38. Two moles of H 2CrO4 can oxidized how many moles of secondary alcohols in the
following reaction.
OH O
2 4 H CrO
R R
R R
Secondary alcohol Ketone
39. Tangents are drawn from P(1,8) to the circle x 2 y 2 6 x 4 y 11 0 touch the circle
at points A and B, respectively. The radius of the circle which passes through the points
73 71
A) B) C) 3 D) 2
4 2
40. From points on the line 3 x 4 y 12 0 , tangents are drawn to circle x 2 y 2 4 . Then
the chords of contact pass through a fixed point. The slope of the chord of the circle
having this fixed point as its midpoint is
4 1 1 3
A) B) C) D)
3 2 3 4
41. let L = 0, be a line passing through (1, 2) and the point of intersection of this line with
6
x y 4 is at a distance of units from (1, 2). Then the square of distance of the
3
point (1, 0) from the line x y 1 0 , measured in the direction of L = 0.
A) 6 B) 8 C) 3 D) 2
42. Given A 1,1 and AB is any line through it cutting x-axis in B. If AC is perpendicular
to AB and meet the y-axis in C, then the locus of mid point P of BC satisfies the
equation ________
A) x y 1 B) x y 4 C) x y 2 xy D) 2 x 3 y xy
Sec: Sr.S60_NUCLEUS & STERLING-BT Space for rough work Page 20
Sri Chaitanya IIT Academy 02-10-2022_Sr.S60_NUCLEUS & STERLING-BT_ Jee-Adv(2021-P1)_PTA-04_Q.P
SECTION 2
This section contains THREE (03) questions stems.
There are TWO (02) questions corresponding to each question stem.
The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value corresponding to the answer in the designated place using the mouse and the on-screen
virtual numeric keypad.
If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +2 If ONLY the correct numerical value is entered at the designated place;
Zero Marks: 0 In all other cases.
Question Stem
Let L1 : 4 x 3 y 13 0 , L2 : 4 x 3 y 37 , L3 : 3x 4 y 34 are three lines in xy plane
x 2 y 2 2 x 2 y 1 0 , x 2 y 2 2 x 2 y 1 0 , x 2 y 2 2 x 2 y 1 0 and
27 36
A) Centre of S1 0 is ,
7 7
275
B) Length of tangent from origin to S1 0 is
7
27 16
C) Centre of S1 0 is ,
7 7
375
D) Length of tangent from origin to S1 0 is .
7
53. Consider two circles S1 0 and S2 0 each of radius 1 unit touching internally the sides
of OAB and ABC respectively where O (0,0) ; A (0,4) and B, C are points on
positive x – axis such that OB OC , then which of the following is/are CORRECT
Sec: Sr.S60_NUCLEUS & STERLING-BT Space for rough work Page 23
Sri Chaitanya IIT Academy 02-10-2022_Sr.S60_NUCLEUS & STERLING-BT_ Jee-Adv(2021-P1)_PTA-04_Q.P
A) If the angle subtended by S1 0 at the point A is then cos is equal to 4/5
B) Length of tangent front A to the circle S2 0 is 9/2
3
C) If one of the diameter of S2 0 is chord of the circle S3 0 whose centre is ,3
2
3
and radius of S3 0 is r then r is 9/4
4
D) Radius of the smallest circle that contains both the circles S1 0 and S2 0 is 9/4
54.
Let E ( x, y ) : x 2 y 2 2 y 39 0 (2,7),(2, 5),(6,3),(6,3) .
Let F be the set of all straight line segments joining a pair of distinct points of E and
passing through R (1,1) . E ' be set of midpoints of the line segments in the set F. Then,
which of the following is/are INCORRECT?
1 1
A) , doesnot lies in E '
2 2
B) atleast one line segment of set of F which lies on 6 x y 7
C) atleast one line segment of set of F which lies on 2 x 5 y 3
D) (1,1) does not lie in E ' .
SECTION 4
This section contains THREE (03) question.
The answer to each question is a NON-NEGATIVE INTEGER.
For each question, enter the correct integer corresponding to the answer the using the mouse and the on-screen virtual numeric keypad in the
place designated to enter the answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct integer is entered;
Zero Marks : 0 In all other cases.
OA at points C and D respectively. The least value of CD 2 for which line L divides the
b
area of OAB into two regions of equal area is a 41 b where a, b N , then is
a
equal to
57. In a right angled triangle BC = 5, AB = 4, AC = 3, Let S be the circum circle. Let S1 be
the circle touching both sides AB and AC and circle S internally. Let S2 be the circle
touching the sides AB and AC(extended sides) of triangle ABC, and touching the circle S
externally if r1, r2 are radii of circle S1 and S2 respectively, then 1 r1r2 is