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CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 19 – 22) Questions with Single Correct Choice 3 -1 4 12
Questions with Multiple Correct
Sec – II(Q.N : 23 – 30) 4 -1 8 32
Choice +1 partial marks
Questions with Numerical Value
Sec – III(Q.N : 31 – 36) 3 0 6 18
Answer Type
Total 18 62
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 37 – 40) Questions with Single Correct Choice 3 -1 4 12
Questions with Multiple Correct
Sec – II(Q.N : 41 – 48) 4 -1 8 32
Choice +1 partial marks
Questions with Numerical Value
Sec – III(Q.N : 49 – 54) 3 0 6 18
Answer Type
Total 18 62
73 146 39 146
A) B) C) D)
24 25 16 37
3. A semicircular wire of radius R carrying current I is placed in a magnetic field as shown
in the figure. On right hand side of y y’ the magnetic field is 2B0 outward and on the left
hand side it is B0 inward as shown. The magnetic force experience by the wire is
2
A) Extension in AB is m
3
2
B) Extension in BC is
3 3
C) Extension in AB is equal to extension in BC
D) Mass of each particle is 5kg
7. A series R-C circuit is connected to AC voltage source. Consider two cases : (A) when C
is without a dielectric medium and (B) when C is filled with dielectric of constant 4. The
current I R through the resistor and voltage VC across the capacitor are compared in the
two cases. Which of the following is/are true?
A) IA B
R IR B) IA B
R IR C) VCA VCB D) VCA VCB
8. A small source of light is mounted inside a cylindrical container of height h. The bottom
of the container is covered with a mirror. Initially, the container is empty. Then a clear
liquid with the index of refraction n is slowly poured into the container. The level of
liquid H rises steadily, reaching the top of the container in time T. Let h1 be the distance
of source of the light from the bottom of the container. Consider paraxial ray
approximation.
3
A) The speed V2.f in terms of V1.0 is v
2 1.0
3
B) The speed V2.f in terms of V1.0 is v
2 1.0
7
C) Final mechanical energy of system is m v2
8 1 1.0
1 2
D) Final mechanical energy of system is m1v1.0
8
1 1 5 2 3
A) A1 ,A 2 0 and A3 B) A1 ,A 2 and A3
3 3 13 13 13
100 50 100
C) V1 ,V3 0 D) V2 ,V4
3 3 3
11. A parallel beam of light rays are incident on the flat surface of half cylinder made of
glass as shown in the figure. The refractive index of the material of glass is 2 . The
angle of incidence is 450 . ‘R’ and ‘L’ are the radius and length of cylinder respectively.
Choose the correct option(s)
A) Laws of refraction are valid for plane surface and spherical surface only
B) Surface area of cylinder from which the rays emerging out is RL
2
C) Surface area of cylinder from which the rays emerging out is RL
6
D) Let A1 is the area of portion PS from which rays are emerging out and A 2 is from QS.
A1 1
Then
A2 5
drum with mass m 2 and radius r2 r2 r1 is mounted on same axle and is at rest although
it is free to rotate. A thin layer of sand with mass m is distributed on inner surface of
smaller drum. At t = 0, small perforations in the inner drum are opened. The sand starts to
fly out at a constant rate kg / sec and sticks to the outer drum. Ignore the transit time of
the sand. Choose the correct alternatives.
2
t 0 r1
A) Angular speed of outer drum at time is
m 2 t r2
14. Four identical massless springs, two massless pulleys and a block of mass m are
connected as shown and system is kept in vertical plane. Initially the system is in
equilibrium. Now the block is slightly displaced from equilibrium position along a
vertical line and then released. Find the time period (in sec) of small oscillation of the
block if m = 6.6 kg and k = 70 N/m. (take 3.14 )
15. and pk
Two small dipoles 2pk are located at (0, 5, 0) and (1, 5, 2) respectively. The
magnitude of resultant electric field due to the two dipoles at the point (1, 5, 0) is given as
kp
n . Find value of n.
4
17. A long coaxial cable carries I Current flows down the surface of the inner cylinder, of
radius a and back along the surface of outer cylinder of radius 2a as shown. The self-
0 ln
inductance per unit length of the coaxial cable is . The value of is __________
8
18. Radiation from hydrogen gas excited to first excited state is used for illuminating certain
metallic plate. When the same plate is exposed to the radiation from some unknown
hydrogen like gas excited to the same level it is found that de-Broglie wavelength of
fastest photoelectron has decreased by 2.3 times. It is given that energy corresponding to
longest wavelength of Lyman series of the unknown gas is 3 times the ionization energy
of hydrogen gas (13.6 eV). The work function (in eV) of the metallic plate is [Take
2
2.3 5.25 ]
A) B)
Which of the following statement(s) is/are correct regarding the above reaction?
A) Reaction is endothermic
B) Reaction is exothermic
C) Reaction is spontaneous at low temperature when each gas being ideal at 1 bar
D) Increase in rate of backward reaction is more than that of forward reaction with
increase of temperature
24. There are three elements P, Q and R which belong to p-block of the periodic table.
They all form trifluorides with F2 , such that PF3 is Lewis’s acid but QF3 is a weaker
Lewis base (dipole moment =0.23 D). These two compounds react with each other in
F
presence of 2 to produce QF4 PF4 . The compound RF3 is inter halogen molecule. Which
A) B)
C) D)
26. The correct reaction(s) among the following is/are
A) 3B2O3 P2O5 2P BO 2 O 2 3
B) B2 O 3 CoO Co BO 2 2
28.
Select the correct statements w.r.t. the final product of the given reaction.
A) It is the monomer of Nylon-6.
B) Degree of unsaturation is 2
C) It contains two distinct functional groups.
D) It can be reduced to primary amine by LiAlH 4 .
Sec: Sr.Super60&All Space for rough work Page 14
Sri Chaitanya IIT Academy 03-08-2022_Sr.Super-60&All_ Jee-Adv(2019-P1)_GTA-26_Q.P
29. Which of the following carbides gives methyl acetylene on treatment with water?
A) CaC2 B) Al4C3 C) Be2C D) Mg2C3
30.
(i) Hg(OAc)2, H2O
A 2,3-dimethylpentan-3-ol
(ii) NaBH4, OH-
A) B) C) D)
SECTION – III
(NUMERICAL VALUE TYPE)
This section contains 6 questions. Each question is numerical value type. For each question, enter the correct numerical value (in decimal notation,
truncated/rounded-off to second decimal place. (e.g. 003.2343, 6.250023, 7.000000, ‐0.33, ‐.30, 30.27000, ‐127.0030).
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases. Section 3 (Max Marks: 18)
This Section contains Six (06) Questions. The answer to each question is a Numerical Value
The Marking scheme to evaluate Answer to each question will be :
Full Marks: +3 (If ONLY the correct numerical value is entered)
Zero Marks: 0 (In all other cases)
31. Suppose an orbital of hydrogen like atom is represented, whose radial wave function as
1
below and angular function is .
2
r
r k1.e
k2
r 2
5k 3r 6k32
Find the value of (A + B + C + D + E + F) where
A = Value of n where “n” is principal quantum number
B = Number of angular nodes
C = Azimuthal quantum number of subshell to which orbital belongs
D = maximum number of subshells having energy more than (n + 5) s and less than
(n + 5)p, where n is principal quantum number
E = Orbital angular momentum of given orbital
F = Radial distance of the spherical node ( A ) which is farthest from the nucleus
(Assuming: k3 = 1 Unit) and ‘r’ values are measured in A .
32. Following represents variation of t1/ 2 (in sec) with log a 0 for the decomposition of
reactant X. t1/ 2 = half-life period of the reaction, a0=initial molar concentration of X
What is the value of 250 K?
33. One mole of an ideal gas is taken reversibly from state A to C through path ABC as
shown below. If the gas is brought back to state A through the path CDBEA as shown in
the figure. What is the magnitude of net heat (in Joule) per complete cycle?
[Given: 1 L atm = 100J, ln2 = 0.7]
34. Total number of compounds in which central atom (underlined) have only two lone pair
is X then what is
x ? CF ,SeF , XeO ,CF ,SNF , I ,SOC ,SO2
2 4 2 3 2 3 3 2 3
35. (+)-Tartaric acid has a specific rotation of + 12.00 . Calculate the specific rotation of a
mixture of 50% (+)-tartaric acid, 32% (-)-tartaric acid and remaining meso tartaric acid.
36. Molecular mass of the final product of the given reaction sequence is
(Bn = Benzyl)
(Molecular Mass H=1, C=12, N=14, O=16, S=32, Cl=35.5)
Sec: Sr.Super60&All Space for rough work Page 16
Sri Chaitanya IIT Academy 03-08-2022_Sr.Super-60&All_ Jee-Adv(2019-P1)_GTA-26_Q.P
MATHEMATICS Max Marks: 62
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 4 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer, out of which ONLY ONE option can be
correct. Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases. Section 1 (Max Marks: 12)
Section 1 contains Four questions
Each Question has Four Options and Only One of these four will be the correct answer.
For each question, choose the option corresponding to the correct answer
The Marking scheme to evaluate Answer to each question will be :
Full Marks: +3 (If the answer is correct)
Zero Marks: 0 (If the question is unanswered)
Negative Marks: -1 (In all other cases)
/2
37. Consider a real valued continuous function f such that f x sin x sin x t f t dt . If
/2
maximum value of the function is equal to k 1 ,k N , then the value of k is :
A)1 B)2 C)3 D)4
38. If p, q r R satisfy 4p + 3p + r = 7, then the least value of 2p2 q 2 r 2 is equal to
7 49 7
A) 7 B) C) D)
2 2 18
39. 4 3 2
Let a, b, c, d are roots of polynomial x 5x 4x 6 0 then the value of
1 1 1 1
is :
a 2 5a 6 b 2 5b 6 c2 5c 6 d 2 5d 6
76 219 677
A) B) C) 0 D)
46 186 1426
224
15 n
40. n 1 equals
224
15 n
n 1
A) 2 B) 2 -1 C) 2 +1 D) 3 -1
SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer, out of which ONE OR MORE than ONE
option can be correct. Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -1 in all wrong cases
Section 2 (Max Marks: 32)
Section two contains Eight (8) questions
Each Question has Four Options and One Or More Than One of these four will be the correct answer.
For each question, choose the option(s) corresponding to all the correct answer(s)
The Marking scheme to evaluate Answer to each question will be :
Full Marks: +4 (If the answer is correct)
Partial Marks: +3 (If all the four options are correct but only 3 are chosen)
Partial Marks: +2 (If THREE or More options are correct but only 2 correct answers are chosen)
Partial Marks: +1 (If TWO or More options are correct but only 1 correct answer is chosen)
Zero Marks: 0 (If the question is unanswered)
Negative Marks: -1 (In all other cases)
Sec: Sr.Super60&All Space for rough work Page 17
Sri Chaitanya IIT Academy 03-08-2022_Sr.Super-60&All_ Jee-Adv(2019-P1)_GTA-26_Q.P
41. Let R be the region bounded by yx 4 1 y 0, y 0 and 0 x 1 . If SR be the area of
region R, then which of the following is/are TRUE?
1 3 1 5 3 3
A) SR B) SR
8 5 2 8 8 5
13 3 3
C) SR D) SR
16 5 4
42. Let E denote the parabola y 2 8x . Let P 2, 4 , and let Q and Q ' be two distinct
points on E such that the lines PQ and PQ ' are tangents to E. Let F be the focus of E.
Then which of the following statements is (are) TRUE?
A) The triangle PFQ is a right-angled triangle
B) The triangle QPQ ' is a right-angled triangle
43. If z is non-real complex number satisfying z 2 , then which of the following is(are)
correct?
z 2 z 1 i 3
A) arg (where z 2 ) B) arg
z 2 2 z 1 i 3 6
C) z 2 1 3 D) z 2 1 5
1 1
B) 0 f x dx x f x dx where f x 0x 0,1
0
1 dt 1/ x dt
C) x 1 t 2 x 0
1 1 t2
x2 e x
D) 0
e dx
0 x
dx