Review Test 24 p1 PCM Sol. - Jee Adv.

FIITJEE REVIEW TEST-24-P1-(JEE ADV.
)PCM
ANSWERS, HINTS & SOLUTIONS
PAPER-1
ANSWERS KEY
REVIEW TEST-24 –P1-JEE ADV.
Q. No. PHYSICS CHEMISTRY MATHEMATICS

1. C B A
2. C A A
3. D C B
4. B C C
5. B D B
6. A, B, C A, C A, B, C
7. A, C A, B, C A, B
8. B, C A, B, C A, B, C, D
9. B, C A, B A, B, D
10. A, D A, B, C, D A, B, C
11. B, C, D B, D A, C
12. A, C B, D A, D
13. A, C, D A, B, C A, D
1. 9 4 1
2. 2 7 2
3. 5 3 1
4. 3 4 9
5. 3 6 8
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3
3 REVIEW TEST-24-P1-PCM-JEE ADV.-2020
Physics PART – I
SECTION – A
2 2
1. E = mc =  9.11 10 kg   2.998  108   8.1881 10 14 J
31
Since value of m has only three significant figure so we must round this to
–14
E = 8.19×10 J
Topic : Error Analysis sub topic : significant figure

Rank range : <20000 (Easy)
2. A spherical non-conducting sphere with uniform charge density , behaves as a conductor.
4. N  m2R  mgsin  fS
A
fs  mgcos 
As we know that N 1 2
1
f S  N  mg

g
 R2  (cos    sin ) B  C

g 
 2  (sin(  )( 1  2 )
R  
The equation should be valid for all value of , hence for maximum value of sin ( + ).
2 g 10  3  4 5
min  1  2    50
R 3 4
min  5 2 rad/s
5. Consider a thin plane layer of water, which

is located near the opening, whose
thickness in the direction of normal to the
plane of growing is a h 
h/2
a
In equilibrium
gh
 a  acos   ha
2
g h 2 a
a 1  cos   
2
2 1  cos   0.07  3
 h   4.6  103 = 4.6 mm
g 103  10
4
6. Where a is positive constant P Monoatomic one moles

PB VB2  Pc Vc2
A
V 
2
V   2V 
2 2 8P0
 PB  PC  C   PC  B   P0  0   4P0 PV = constant
 VB   VC   V0 
PA V0  4P0  2V0  PA  8P0 4P0 B
Process – CA  Isochoric
WCA  0  UCA  QCA  nCV T 2
P = aV
P0
3R  3P0 V0  P0 V0  21 C
 1    P0 V0
2  R  2
Process AB  Isothermal V
O V0 2V0
8P0 V0  VB 
UAB  0  WAB  Q AB  1 R  n   8P0 V0  n  2 
R  VA 
Process BC – Polytropic process: PV 2  a
3R R 3R R 9R  2R 11R
C     
2 1 m 2 3 6 6
11R  P0 V0  8P0 V0  77P0 V0
QBC  nCT  1  
6  R  6
3R  7P0 V0  21 63
UBC  nC V T  1     P0 V0  P0 V0
2  R  2 6
77P0 V0 63P0 V0 14P0 V0 7P V
WBC  QBC  UBC     0 0
6 6 6 3
7. N2
N3 Wedge-B
fk 2

N2
A
F fk 2
mg
fk1
fk1
mg
N1
sin  = (3/5), cos  = (4/5), 1 = (14/23), 2 = (1/3), 3 = (1/2)

N3 = N2 sin  + 2N2 cos  = N2(sin  + 2 cos )
 3 1 4  13
= N2      N2
 5 3 5  15
N2 cos   fk3  fk 2 sin   mg  3N3   2N2 sin   mg
 2N2 (sin    2 cos )  2N2 sin   mg
 N2  cos  1   2 3   sin    2   3    mg
mg mg
 N2  
cos (1   2 3 )  sin(  2   3 ) 4  1 3 1 1
 1     
5  6 53 2
5
mg

4 3

6 6
 N2 = 6 mg
26
 N3 = mg
5
From FBD of wedge –A
4 1 3 23
N1 = mg + n2 cos   fk 2 sin   mg  6mg   6mg   mg
5 3 5 5
F  fk1  N2 sin   fk2 cos   fk1  N3
14 23 26
  mg  mg  8mg
23 5 5
2GM 2  (6.67  1011 )(3  2  1030 )

8. Rs =   8.9km
C2 (3  108 )2
M 3  6  1030
=   2  1018 kg / m3
4R2s 4  3.14  (8.9  103 )3
1
9. E = 0  U0  m2 A 2
2
1
  0.5 + (m 2 )(0.1)2  0
2
2 0.5  2
 m   100
0.1 0.1
1
U0  0.5  k(x 0 )2  mgx 0
2
1 
0.5   kx0  mg  (0.1)
2 
mg
 5  m = 1 kg
2
mg 10 2
 k   100 N/m
x0 0.1
10. For maximum intensity

nc nc n  3  108
x  n  dsin    sin   
f fd 1.5  106  400
n
 sin      0,  30,  90
2
2   x  2  dsin   2  df 
I  I0 cos    I0 cos2    I0 sin     I0 cos  c sin  
2
        
 I0  0.02 w/m 2
If   4 & d  10m, c  3  10 8 m/s f = 60 × 106 HZ
   10  60  10 6 
I0  0.02  cos2  8
sin 4 
 3  10 
2 2
= 0.02 × cos (2 sin 4)  0.016 w/m
6
I 5  2
11.    103  104 rad/s
40 
VC = 20 sin t  XCI0 = 20
VR = 30 cos t  RI0 = 30
VL = 60 sin t  XLI0 = 60
XL I 0 40
V0
RI0
I0

XC I 0
I0 30
4
V0  50 Volt   tan1    53
3
 53 
V  50cos  t     50cos  10000t  
 180 
50 1 1
I0   0.1 A  x C  200  C    0.5F
500 x C  200  104
30 600
R  300 , xL  600  L  4  60mH
0.1 10
  1 ˆ 1 ˆ  y
12. FCD  I  k j  2a   B(i)ˆ
  2 2  
C
 IaB (k  j)  i   BaI  j  kˆ 
 ˆ ˆ ˆ   ˆ
As we know that net magnetic force on the loop in uniform 45
magnetic field is zero so
 
Fabcdef  Faf   Ia( k)  Biˆ   BIa( ˆj)  BIa( ˆj)
Where, I = 6A, a = 0.75 m, B = 0.8 T
O
7
1
13. Pa  gh2  2L2  gh3  Pa 
2
1
g(h3  h2 )  2L2 …(i)
2
1
Pa  gh2  2L2  gh1  p ….(ii)
2
L
Pa A  (L  h1 )A h1 = 5L/8 h2 h3
2
4P
P a …(iii)
3
3L L
h1  h2  h3  …(iv) L
2
1 4P
From (ii) Pa  gh2  2L2  gh,  a
2 3
Pa 2L2
 h2  h1   …(v)
3g 2g
2L2 P
From (i) h3  h2   h1  a
2g 3g
2L2 2P 3L
 3h1  a 
2g 3g 2
Putting h2 and h3 in …(iv)
2 2
Pa L P 3L
h1  h1    h1  a 
3g 2g 3g 2
21
  rad/sec
4
4P 4  105
P a  N/m2
3 3
5L 105 35
h2   3
 0
8 3  10  10 3
SECTION – C
1. Consider any cross-section of thickness

dx and at a distance of x from end A, So T T + dT
 S dx  a  T  dT  T  dT  d S
d
xa   tan 
dx
 tan 1 3/4 9
 1   
2 tan 2 4/3 16
8
2. The Snell’s law applied to two neighbouring layers of B

radiuses R1 and R2 gives 

n1 sin  = n2 sin  . . .(1)
R2
In the triangle CAB we have, 
sin  R1

sin  R2 n2
R n1
 sin   sin   2 . . . (2)
R1 R1
where we accounted for sin ( - ) = sin . By C
substituting (1) into (2) one obtain
R1 n1 sin  = R2 n2 sin  . . . (3)
In general R n(R) sin (R) = constant

Along beam, where (R) is the angle of incidence of the beam on the spherical layer of radius R.
Using he expression for n(R) we obtain
n0 2
R sin   cons tan t. . . . (4)
R0
At the minimal distance from the symmetry center the angle between the radius and the beam is
 = /2. Therefore,
n0 2 n 2
R1 sin300  0 Rmin .. . (5)
R0 R0
1
The minimum distance = sin300 = m.
2
vy
 3v 
3. 
Ndt  mg  m  
 8 
vx
3mv

 Ndt  
8
 mv
5vm

 Ndt 
8
3vm

Ndt 
8
min = 5/3
L m
5. t   3 sec.
v0 2k
9
Chemistry PART – II
SECTION – A
1. From first law of thermodynamics E  q  W

The work done W may be expansion work or non-expansion work. So,
E  q  Wexp ansion  Wnon  exp ansion
or E  q  PV  Wnon  exp ansion
 W exp ansion  PV 
or q  E  PV  Wnon  exp ansion
or q  H  Wnon  exp ansion
qrev.
Further S 
T
or qrev.  TS
TS  H  Wnon  exp ansion
or Wnon  exp ansion  H  TS
or W non-expansion = G
The non-expansion work is also called non-PV work or useful work.
Thus, the maximum non-PV work that a system can perform at constant P is G .
2.   CST
w ST

M V
w ST

V M
w ST
 versus curve will have slope equal to
V M
Thus, slope will increase on increasing temperature and on decreasing molar mass of solute.
3. H2  2H
Dissociation energy = energy possessed by two H-atom – energy possessed by H2 molecule.
= 2 × (- 13.6) – (- 31.7)
= - 27.2 + 31. 7
= + 4.5 eV
4. Complementary colour of blue is orange.
HBr Mg/ ether

7. (A) HC CH   H2 C CH Br 
CO
H2 C CH COOH
2
H
H2 / Pd
H3 C CH2 COOH
10
(B)
H3C I
NaNH2 +
HC CH   HC CNa HC C CH3
i R2BH
ii H2 O2 / OH
KMnO 4
CH3  CH2  COOH   H 3C CH2 CHO
(C) 2NaNH2
+ +
2CH3I
HC CH   Na C CNa  H3C C C CH3
HgSO 4 / H2 SO 4
I2 /OH 
CHI3  CH3  CH2  COOH  H
 H 3C C CH 2CH3
O
8. (A) Average kinetic energy is a function of temperature, not of molar mass.

(B) At constant T and P
dM
 Density of gas P will be four times of gas Q.
(C) Equal volumes of P and Q will have equal moles at constant T and P therefore, mole fraction
of each component in mixture will be 0.5.
 PA  x A  PT
PA  0.5  1 atm  0.5 atm .
y z
9. C xHyNz  O2 
 xCO 2  H2 O  N2
10 cm3 10 x cm3 2 2
z
10  cm3
2
z
10x cm3 = 20 cm3 5 10 
2
x=2 z=1
Any reasonable value of y is not possible as more information is missing.
 A, B options may be correct on the basis of value of x and z.
10. a a a
a b b a a a
M M M
c b c b c b
a a b
SECTION – C
1. 4 stereoisomers (only optical)

Two optical isomers due to chiral carbon and two due to restricted rotation of two phenyl rings.
2. (i) 4AgNO3  2H2 O  H3PO2 

 4Ag  H3PO4  4HNO3

(ii) 2NaN3   2Na  3N2
11
Electrolysis
(iii) NaCl  aq    H2  Cl2  NaOH  aq

(iv) ZnO  C   Zn  CO

(v) 2Cu2O  Cu2 S   6Cu  SO2

(vi) HgS  O2 
600o C
 Hg  SO 2
(vii) Tollen’s reagent test (metallic silver is formed)
 1
(viii) 2LiNO3   Li2O  2NO2  O2
2
 1
(ix) 2AgNO3   Ag2 O  2NO2  O2
2
 1
Ag2 O   2Ag  O2
2
3. (iv) Ionic product

(v) Dielectric constant
(vi) Solubility of NaCl in 100 g H2O/D2O
4. Cubic, tetragonal, orthorhombic and rhombohedral.
5. [KCl, KMnO4, [Co(NH3)4Cl2]Cl, AgNO3, KHF2, LiAlH4]

Above all have n-factor = 1
12
Mathematics PART – III
SECTION – A
9 x 25
1. 4  4  4 : (where  = 4 + x ; 0  x < )
17  43
43x 17x
So, 
25 9
Clearly, for x = 4,  = 7
 min = 7  4 + 4 = 32
32
C1  28C2
2.  16  26
3
3. x3 + x + 1 = 0; roots are , , 
 +  +  = 0,  +  +  = 1
 = –1
2 2  4
Let required root be y, so; y              4   2 
 
4
 y  2  ….. (1)

Also, 3 +  + 1 = 0 ….. (2)
Solve equation (1) and (2)
4. Locus of P(a2, a – 2) is x = (y + 2)2

1 : x  y  2  0 and  2 : x  y  4  0
So, on analyzing the figure
a  (–4, –1)  (0, 2)
R(4, 0)
(0, –2) 2
1
P(1, –3)
Q(16, – 6)
5. P(3R, 2W) + P(4R, 1W) + P(5R, 0W)

5
C3  4 C2 5
C4  4 C1 5
C5
= 9
+ 9
+ 9
C5 C5 C5
a cb
1  a  2 b 1  35
So; required probability =    c 0 =
abc 4 4  81
13
4 3
6. f(x) = x + 4x + 26

  

f f f  f  x    26
z (0, 26)
f(z) = 26 so, z = 0, –4

i.e. f f  f  x    4
 

t1
f(t1) = –4 has no real solution
–4 –3 –2
Also, when z = 0

 

f f  f  x   0
(–3, –1)
z
1
 f(z1) = 0  2  (–4, –3)  2  (–3, –2)
Again no solution
7. For the function f(x) = {sin x}·{cos x}

 3
Doubtful points of non-differentiability are x = 0, , ,
2 2

Since f(x) = {sin x}·{cos x} is discontinuous at x = 0, 2,
2

So, not differentiable at x = 2n, 2n 
2
8.  f(x) > 0; f(x) is an increasing function

Let b – a = t
4t 4t
So, a  , b
2 2
4 t 4 t
a b 2 2
Let Q  t    f  x  dx   f  x  dx   f  x    f  x  dx
0 0 0 0
Now find Q(t)
3
9. Put tan x  t 2
1
3 tdt
So, I1 
2 0 t 3  1
t
Now draw the graph of f(t) = 3
and use estimation
t 1
1
2
Also draw the graph of y   tan x  3 and y   tan x 
Clearly I1 > I2
14
10. Required area = area of square – area of the ellipse (3, 8)

2
=  72   2 3
(3, 3)
(–3, 2) (3, 2) (9, 2)
(3, 1)
(3, –4)
11. (MP)max = (CG)max = a – b = 4 M

(CM)min = b = 1 P
C
G
f   x  f x
12. 1 
f x f x
x
So, f  x   ee 1
 
13.  5a  b  3
5 cos   3
3
cos  =
5
   
Now c  4a  b  2b  
 2  2
c  2b  4a  b
2 2   2 2
 c  4 b  4b  c  16 a b sin2 
10
Hence, cos   
356
SECTION – C
x 1
1. I dx
4 2
 x  1  2  x  1  1
2
Let (x – 1) = t
2(x – 1)dx = dt
1 dt 1 dt 1
So, I     = ln  t  1  c = ln   x  12  1   c
2 2 2
t  2t  1 2 2 2  
 t  1
8 5
2. Let f(x) = x
sin
 x and g(x) = x
  cos
 x

even function even function
Draw the graph of f(x) and g(x) clearly they intersect at 2 points
15
3. Doubtful points of non-differentiability are x = –1, 0, 1

 2x 
Clearly y  sin1   is not differentiable at x = –1
 1  x2 
Reason being there is a vertical tangent at x = –1
3  2x  + –
and y  x  1 sin1   is differentiable at x = 1 and f(0 ) = f(0 ) = 2
 1  x2 
4. If two co-axial conics intersect orthogonally then they are confocal

P4 5
So, 
P 9
P=9
5. f(x) = x3 – 2x2 + 4x + 1 y=4

f(x) = 3x2 – 4x + 4 > 0  x  R
0 1
A   f  x    23   dx    4  f  x   dx –2 (0, 1)
2 0
0 1
59
= 37 
12
385
= y = –23
12

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FIITJEE REVIEW TEST-24-P1-(JEE ADV.

Q. No. PHYSICS CHEMISTRY MATHEMATICS

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2. A spherical non-conducting sphere with uniform charge density , behaves as a conductor.

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11. (MP)max = (CG)max = a – b = 4 M

3. Doubtful points of non-differentiability are x = –1, 0, 1

4. If two co-axial conics intersect orthogonally then they are confocal

5. f(x) = x3 – 2x2 + 4x + 1 y=4

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