Fiitjee: Review Test - 07

3 REVIEW TEST-07-PCM-JEE(Advanced)
FIITJEE REVIEW TEST - 07

PHYSICS, CHEMISTRY & MATHEMATICS
Time Allotted: 3 Hours Maximum Marks: 225
 Pleas e read the instructions carefully. You are allotted 5 minutes specific ally for this purpose.
 You are not allowed to leave the Examination Hall before the end of the test.
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR
sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Parts.
3. SECTION–I is Physics, SECTION–II is Chemistry and SECTION–III is Mathematics.
4. Each part is further divided into three parts: Part – A, B & C
REVIEW TEST
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
B. Filling of OMR Sheet
1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on
OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your
Enrolment No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Two Parts.
(i) Part–A (01-05) contains 05 Multiple Choice Questions which have Only One Correct answer. Each
question will be evaluated according to the following marking scheme.
Full Marks : +3 If only (all) the correct option(s) is (are) chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases.
(ii) Part–A (06 – 10) contains 06 multiple choice questions which have one or more than
one correct answer. Each question will be evaluated according to the following marking scheme.
Full Marks : +4 If only (all) the correct option(s) is (are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen and both
of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases.
(iii) Part–B (01 – 02) contains 02 questions you will be awarded 2 marks for each row corresponding to
the correct answer. Thus, each question in this section carries a maximum of 8 marks. There is no
negative marking for incorrect answer(s) for this section.
(iv) PART–C (13 – 18) contains 06 Numerical based questions, the answer of which maybe positive or
negative numbers or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each question carries
+4 marks for correct answer. There is no negative marking.
Name of the Candidate :______________________________________________________

Batch :______________________________ Date of Examination :___________________
Enrolment Number :_________________________________________________________
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
REVIEW TEST-07-PCM-JEE(Advanced)
4
SECTION – I : PHYSICS
PART – A: (Single Correct Answer Type)
This section contains 5 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONLY ONE is correct.
1. Consider a region in space filled with spherically symmetrical mass y

aer
density (r)  2 centred around the origin O. Here ‘a’ is a constant
r
and r is the distance from origin. The gravitational filed due to this
density at r = 1 is: r
4aG 4aG O x
(A) (B)
e (e  1)
4aG(e  1)
(C) 4aG(e  1) (D) z
e
2. Figure shows an object O placed in front of an equi-convex 47 cm

3
lens (refractive index = ) behind which is a medium of
2 Air
4 3/2 4/3
refractive index = and a plane mirror at a distance 47 cm
3
from the lens. Find the distance x of the object placed in air if
the final image formed coincides with the object itself. Given Medium A
that radius of curvature of lens surface is 30 cm. x
Plane mirror
(A) 94 cm (B) 45 cm
(C) 54 cm (D) 49 cm
Space for Rough work
3. Figure shows a massless semicircular ring that is hinged at O. A and B O

are two small and equal masses, A is welded to the ring while B can slide
on the smooth ring. The system is released from the position shown,
oscillation are allowed to die out due to small viscous friction between the
ring and B. The system then settles into an equilibrium state. If the ring’s
radius is R, then, the vertical separation between the hinge and ring’s A C
centre in equilibrium state is
R
(A) (B) R
2
R 2R B
(C) (D)
5 5 Figure
4. Figure shows a cube of side length ‘a’ placed on a horizontal

surface. A particle projected from A with speed u, at an angle  =
u a
tan1 5 with horizontal, just misses the cube at two vertices as a
shown. Find projection speed u. 
A
27
(A) ag (B) 2ag
8
8
(C) 3ag (D) ag
3
5. Capacitor (1) is connected to point A at t = 0. The switch is L B + 

A

flipped to position B at t1  LC . Capacitor (2) was C(2) C(3)
3
uncharged while capacitor (3) was charged to potential  C (1) L
difference , in the polarity shown, before flipping the switch to
53 LC
B. Find the charge on capacitor (3) at time t2 = t1  .
180 3
2 14
(A) C (B) C
5 15
C 3
(C) (D) C
15 5
6
PART – A: (Multi Correct Answer Type)

This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE or MORE THAN ONE are correct.
6. A disc of mass m, radius R is hinged at its periphery and P

suspended in a vertical plane. A particle of same mass m
strikes the disc with an initial velocity u in the horizontal
direction. It is given that the particle rebounds in a vertical Disc (m, R)
C
direction, there is no friction between the particle and the
m u
disc, coefficient of restitution is e. The angular velocity of 60
disc just after collision is . Pick correct option(s). A
u 2u
(A)   (B)  
3R 3R
1
(C) e  (D) e = 1
2
7. Figure shows a cyclic process for a monoatomic ideal P

gas. Process AB is such that PV2 = constant. B
BC is an adiabatic process and CA is isochoric. Pick the C
correct option(s).
(A) Work done by gas on AB is W 1 = 2P0V0 P0 A
(B) Work done by gas on AB is W 1 = P0V0.
(C) Work done by gas in the cycle is
W = P0V0  4  3  21/3  V0 2V0 V
(D) Work done by gas in the cycle is W = P0V0
8. A square wire loop (non-conducting) with uniformly distributed

charge q distribution and mass m is placed in a certain region. Now,
a uniform time-varying magnetic field, B perpendicular to the square
loop’s plane is switched on in a cylindrically symmetrical manner
(centred at the circum-center of the square loop). The radius of the r
circum-circle is r. Pick the correct option(s) for situation just after
switching on the magnetic field.
qB
(A) Angular speed of the square loop is .
2m
2qB
(B) Angular speed of the square loop is .
m
q2B2r 2
(C) Kinetic energy of square loop will be .
24m
q2B2r 2
(D) Kinetic energy of square loop will be .
48m
9. An electron, initially at rest, is released far away from a proton (fixed in space). The de-broglie
wavelength of the electron when it is at distance r from proton is . The ratio of its Kinetic energy at
this distance with the kinetic energy of the electron in ground state of hydrogen atom (Bohr model)
with the radius of its orbit being r, is k. Pick the correct option(s).
1
(A)   r (B)  
r
1
(C) k  (D) k = 2
2
10. An asteroid orbiting around a planet in circular orbit suddenly explodes into two fragments. Ratio of
masses of the fragments is 1 : 4. If immediately after the explosion, the smaller fragment starts
orbiting the planet in reverse direction in the same orbit, what had happened with the heavier
fragment?
(A) It had fallen on the planet
(B) It had started orbiting the planet in a larger orbit.
(C) It had started orbiting the planet in a smaller orbit
(D) It had escaped from the gravitational interaction with the planet.
8
PART – B: (Matrix Match)
This section contains 2 multiple choice questions. Each question has matching Column(s). The codes for
the Column(s) have choices (A), (B), (C) and (D) out of which only ONE OR MORE is/are correct
11. The physical situation in Column-I with graphs of the variation of total energy (E), potential energy (U)
and kinetic energy (K) with time in Column-II are given. Match the statements from Column-I with
those in Column-II and select the correct answer using the code given below the lists.
Column-I Column-II
(A) A mass attached to an (p)
unstretched ideal spring,
released from position O
in vertical plane from rest K E
until it reaches its
maximum extension. O
Assume that the U
m Natural length
gravitational P.E.
position K
reference is at the
equilibrium position of m.
(B) An object of mass m is A (q)
released from tower AB
undergoes free fall E
H
U
K
B
(C) An object of mass m is m F (r)

being pulled by a constant
force in horizontal E
direction on a horizontal
frictionless surface. U
K
(D) A particle of mass m is v0 (s)

given velocity v 0
downward on a rough H
inclined surface whose  E
coefficient of friction is  =
tan 
K U
12. A thin but very large plank of mass 2m is placed on a horizontal smooth surface. A solid cylinder of
mass m and radius r is given only translation velocity v 0 and gently placed on the plank as shown in
the figure. The coefficient of kinetic friction between the plank and the cylinder is .
m V0
2m
Match the statements from Column-I with those in Column-II and select the correct answer using the
code given below the lists.
Column-I Column-II
(A) Final kinetic energy of the plank (p) 14mv02
98
(B) Final kinetic energy of the cylinder (q) mv 2 0
49
(C) Negative work done by kinetic friction till (r) 24mv 20
the cylinder starts rolling
98
(D) Final kinetic energy of the cylinder with (s) 33
respect to plank. mv 20
98
10
PART – C: (Numerical Based Type)

This section contains 06 questions. Numerical based questions, the answer of which maybe positive or
negative numbers or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each question carries +3
marks for correct answer and there will be no negative marking.
13. A liquid column of height h is in equilibrium inside a

capillary tube of radius r = 2 mm as shown in figure. Due
to difference in the material of the tube; the contact angles 37
are different at the two curved surfaces. If h = 1 cm,
density of fluid  = 700 kg/m3, surface tension of fluid will
be T = n N/m, find n. (meniscus effects may be ignored)
h
53
14. Figure shows a typical simple pendulum with the O

modification that a tangential force mg acts in addition to
its weight. If the pendulum is given an initial angular
2 
displacement    1 and released, time taken for the
3
 
string to become vertical is , find the integer value n.
n g
mg
mg
15. Figure shows three spherical objects which may be considered as ideal black bodies. If TA = TB;
r1 r 48 n
 3, 2  , then, TC = nTA in steady state, where n is an integer. Find . (size of B is very
R1 R2 11 10
small)
A C
R1
R2
r1 r2
16. Circuit-1 shows a potentiometer setup with length of potentiometer being 100 cm (given that
potentiometer wire’s resistance is 8 ). Balance points are obtained with switch S opened and then
closed, they are found at 50 cm and 25 cm respectively. Then, the unknown battery from circuit-1 is
used in circuit-2 in order to deliver maximum possible power, to resistor R. The value of this
maximum power will be x watt, find the integer value 10x.
2 10 Volts , r
R
A
G Circuit-2
, r S
2
Circuit-1
12
17. A frustum of a cone with mass m = 14  kg, r

Region-I Region-II
30
= 1 mm, h = cm, crosses a boundary and
7 r
enters region-II from region –I. Pressure in
region-I is p0 and 2p0 in region-II. If the u
velocity of the frustum in region-I normal to h
the boundary is u = 2 m/s and v = 1 m/s in
region-II, p0 = n  10n Pa. Find integer n.
2r
P0 2P0
18. An organ pipe of length L is open at one end and closed at the other end. The air column in the pipe
is vibrating in second overtone. The minimum distance from the open end where the pressure
L
amplitude is half of the maximum value is . Find the value of .

SECTION – II : CHEMISTRY
of which ONLY ONE is correct.
1. The change in enthalpy when one mole of ideal gas is expanded from 4 atm to 1 atm at constant
temperature against a constant external pressure of 1 atm is:
(A) 0.0 Kcal
(B) is equal to the heat absorbed as change in internal energy is zero
(C) is equal to the work done
P
(D) can be calculated as H  2.303 nRT log 1
P2
2. The number of stages of effusions required to be enriched from initial molar ratio of H2 and He
2 : 1 to 32 : 1 by means of diffusion process are
(A) 16 (B) 8
(C) 32 (D) 1
3. SO2Cl2 is added to water to make 25 ml of 0.2 M solution. What volume of 0.2 M Ba(OH)2 is needed
to completely neutralize 25 ml of 0.2 M SO2Cl2 solution?
(A) 25 mL (B) 50 mL
(C) 100 mL (D) 200 mL
14
4. Which will show greater degree of retention on hydrolysis?

Cl Cl
(A) Et S (B) Et O
CH3 CH3
H 3C CH3 CH3
(C) (D) H3C Cl
Cl CH3
5. O
1. NaOH, H O
2
H3C O   A, A is
2. HCl, H2O
H3C OH
O
OH OH OH
(A) (B) HO
OH
OH OH OH
O
H3C HO O OH
H3C O
OH
(C) (D)
H3 C
O OH
OH OH
of which ONE OR MORE may be correct.
6. For the reaction:
FeBr3
 Br2  Na / Ether
 A   Product P 
The correct statement about product is/are:
(A) (B)
P= P=
(C) P = optically active (D) P = optically inactive
7. Which of the following statement(s) is/are true?

(A) The van der Waal’s constant ‘b’ is characteristic of each gas.
(B) The value of ‘b’ is 1 for ideal gases.
(C) The compressibility factor (Z) is more than one due to the excluded volume ‘b’ of the gas and ‘a’
is neglected.
(D) At Boyle’s temperature, the effects caused by the van der Waal’s constants ‘a’ and ‘b’
compensate each other causing the gas to behave ideally over a wide range of pressure.
16
8. The properties which are common to both groups 1 and 17 elements in the periodic table are:
(A) Electropositive character increases down the group.
(B) Reactivity decreases from top to bottom in these groups.
(C) Atomic radii increases as the atomic number increases.
(D) Electronegativity decreases on moving down a group.
9. Z LiH
B X Y LiBF 4
Heat
Which of the statement(s) is/are true for the above sequence of reactions?
(A) Z is hydrogen gas (B) X is B2H6
(C) Z and Y are F2 and B2H6 respectively (D) Z is KOH
10. In which of the following reactions carbocation is the intermediate?

HOCl Oxymercuration
(A) MeCH  CH2   (B) Me3 C  CH  CH2 
Demercuration

Cl2 / CCl4 Alc.KOH
(C) MeCH  CHMe   (D) Me2 CH  CH2Br  
11. Match the following:

Column – I Column – II
(A) Mulliken test (p) To distinguish primary, secondary
and tertiary amines
(B) Hinsberg test (q) To detect nitro groups
(C) Hofmann – Mustard oil (r) To detect primary amines
(D) Sodium extract (s) To detect nitrogen in an organic
compound
12. Match the relations of column – I with their names in column – II:
Column – I (Reactions) Column – II (Products)
(A) CaC  N   Product-1  H3 O
 Product-2 (p) NH3
2 2
(B) NaNH2  N2 O  H3 O
 Product-1   Product-2

(q) N3H
(C) 
Na2B 4 O7  NH4 Cl  H3 O
 Product-1 

 Product-2 (r) H2O
(D) COCl2  NH3  H3 O
 Product-1 

 Product-2 (s) BN
18
SECTION –C
(Numerical Based Answer Type)
This section contains 06 questions. Numerical based questions, the answer of which maybe positive or
negative numbers or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each question carries +4
marks for correct answer and there will be no negative marking.
13. A container initially has one mole gas of A2. A2 dissociate at temperature 300 K according to the
following equation:
A2 2A
Total pressure of equilibrium mixture, at T = 300 K is 1 atm pressure.
The equilibrium mixture diffuses 2 times as fast as Cl2 diffuses under the same condition.
Calculate the equilibrium constant (Kp) in atmosphere of reaction at T = 300 K. [Mol. Wt. of A = 15.00
g/mole].
o o
14. Two moles of an ideal gas is expanded from 2 atm at 0 C to 1 atm at 27 C against a constant
pressure of 1 atm. If for the gas Cp = 5 cal mole-1.deg-1, calculate heat change ‘q’ (in joule) for the
process.
15. Find number of species which produce elemental sulphur when treated with H2S:
Fe3  ,Fe2  ,SO2 ,H2 O2 ,O 3 ,HNO 3
16. Out of Be, Mg, Ca, Sr and Ba, total number of metals whose nitrates are decomposed according to
following reaction

2M  NO3 2   2MO  4NO2  O2
H /Ni
17. C2FClBrI  2
X  excluding stereoisomers 
 All isomers
H /Ni
C4H8  alkene  
2
Y  excluding stereoisomers 
 All isomers 
Find the value of X + Y.
18. How many isomers ‘X’ of C8H10 give only aromatic dicarboxylic acid when react with hot alkaline
KMnO4.
How many isomers ‘Y’ of C4H8 give CO2 when reacts with hot alkaline KMnO4. Find the value of
X + Y?
SECTION – III : MATHEMATICS

of which ONLY ONE is correct.
1. In ABC, D, E and F are mid-points of BC, AC and AB respectively. If P, Q, R are the points on AD,
AP BQ CR area of PQR
BE and CF such that  ,   and   , then is
AG BG CG area of ABC
(where , ,   (0, 1) and G is centroid of ABC)
(A)
 1   1    (B)
 – 1
3 3
(C)
 
(D) none of these
3
 1
2. If g(x) is non-negative continuous function such that g(x) + g  x    2 , then the value of
 2
1
 sin 4x  g  x  dx is
0
(A) 0 (B) 1
1
(C) (D) none of these
2
3. Let a, b, c, d be four integers (not necessarily distinct) in set of {1, 2, 3, 4, 5}. The number of
4 3 2
polynomials x + ax + bx + cx + d which is divisible by x + 1 is
(A) between 55 and 65 (B) between 66 and 85
(C) between 85 and 105 (D) more than 105
4. The equation of directrix of the parabola which touches x-axis and y-axis at points (4, 0) and (0, 2)
respectively, is
(A) y + 3x = 0 (B) y + 2x = 0
(C) y + 4x = 0 (D) none of these
2 2 2 3
5. If x sin A + y sin B + z sin C = 0 and x sin 2A + y sin 2B + z sin 2C = 0, then the value of x sin 3A
3 3
+ y sin 3B + z sin 3C is equal to (where x, y, z, A, B, C  R and A + B + C = )
(A) 0 (B) depend on A, B, C
(C) depend on x, y, z (D) none of these
Space for rough work
20
of which ONE OR MORE may be correct.
          
6.  
Let a and b be two non-collinear unit vectors. If   a  a  b b and   a  b , then  is
   
(A)  (B)     a
      
(C)     b (D)     a  b  
+ 1 1 
7. Let f: R  R be a function which satisfy f(x)f(y) = f(xy) + 2    1 for x, y > 0, then value of
x y 
1
 
f   is
 2
(A) 4 (B) 5
8
(C)  (D) –5
3
2 5 1
8. Considering the equation   where x, y  N the number of solution of the equation, is
x y 6
(A) 6, if both x and y are multiple of 4
(B) 6, if both x and y are of the type 4n + 2, n  0
(C) 0, if x is a multiple of 4, whereas y is of the form 4n + 2, n  0
(D) 0, if x is of the p type 4n + 2, n  0 where y is a multiple of 4
2 1 10 a b 
9. Let A    be a matrix if A    , then
0 3  c d
(A) a + d is a multiple of 13 (B) b is an even integer
(C) number of factors of d – b is 11 (D) number of factors of a + b + c + d is 22
10. Identify the correct statements

 x   1  3
(A) the number of solution of the equation tan1  2 
 tan1  3   belonging to the interval
 1 x  x  4
(0, 1) is two
 1  1  1   1 
(B) tan1    tan1    tan1    ..... n terms is  tan1  
2 8  18  4  2n  1 
 
(C) if 0  x  1 and  = sin–1 x + cos–1 x – tan–1 x, then   
4 2
 4   7  
(D) the value of sin1  sin   cos1 cos   is
 3  6
  2
11. Match the following Column-I with Column-II

      2    3    4 
(A) If tan  tan     tan     tan  15  5   tan  15  5  =
15  15 5   15 5      (p) 3
k 3 , then the value of k is
n 1
nr 55
(B) If  r  1 r  2  r  3  is
3k
for n = 10, then the value of k is (q) 4
r 0
(C) If the maximum area of ellipse with centre (0, 0) and axis parallel to
coordinate axis and tangent to it with slope 2 is normal to the circle x 2 + (r) 8
y2 + 4x + 1 = 0 is k, then the value of k is
(D) If the angle between asymptotes of 5x 2 – 2 7 xy – y2 – 2x + 1 = 0 is , (s)
1
then the value of tan2  is 3
(t) 5
  5ln 1  t   10t  tan t  16 sint  dt

2 1
12. Considering the function f  x   use ( > 3)
0
(A) f(x) is (p) positive for all x  (0, 1)
(B) f(x) is (q) negative for all x  (0, 1)
x
(C)  f  t  dt is (r) increasing for all x  (0, 1)
0
(D) f(x) is (s) decreasing for all x  (0, 1)
(t) has a point of local maxima is (0, 1)
22
PART – C: (Numerical Based Type)
This section contains 06 Numerical based questions, the answer of which maybe positive or negative
numbers or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30).
13. Let f be a double differentiable function and satisfy the condition f(0) = 0, f(1) = 0 and
d2
dx 2 
e x f  x   x 2 > 0  x  (0, 1). Then the number of values of x such that
2 x
f(x) – 3 = (x – x)e , which belongs to (0, 1) is/are _____
30 30 30 30 30 29
14. If the value of C0  C1  C2  C3  ......  C10 is Ck then the sum of digits of least value of
k is _____
15. There are 4 bowlers, 4 batsmen, 1 all rounder (who is bowler as well as batsman). Randomly a team
of four players consisting of atleast two bowlers and atleast two batsmen is formed. If the probability
4
that all rounder has been selected in the team is , then the value of p is _____
p
6
 5 
16. The remainder when   20 C2k 1  is divided by 11 is _____
 k 1 
17. Let G be the centroid of the ABC whose sides are of lengths a, b, c if P be a point in the plane of
a2  b2  c 2
ABC such that PA = 1, PB = 3, PC = 4 and PG = 2, then the value of is _____
6
1
61x  80x2 
18.  
If f  x   x   xy 2  x2 y f  y  dy and f  x   x 

, then the value of
17
is equal to _____
0
ANSWERS
PHYSICS (SECTION –I)
1. D 2. B 3. D 4. C
5. B 6. B, D 7. A, C 8. A, D
9. A, D 10. D
11. (A)  (q) (B)  (r) (C)  (p) (D)  (s)
12. (A)  (q) (B)  (s) (C)  (p) (D)  (r)
13. 0.05 14. 3.00 15. 0.20 16. 20.00
17. 7.00 18. 15.00
CHEMISTRY (SECTION –II)

1. A 2. B 3. B 4. A
5. A 6. A, C 7. A, C, D 8. A, C, D
9. C 10. A, B, C
11. A  q, B  p, C  r, D  s
12. (A  p) (B  q, r) (C  p, r, s) (D  p)
13. 3.6 14. 3396 15. 5 16. 5
17. 5 18. 5
MATHEMATICS (SECTION –III)

1. A 2. A 3. B 4. B
5. A 6. A, C 7. A, C 8. A, B, C, D
9. A, C, D 10. B, C, D
11. (A)  (t); (B)  (r); (C)  (q); (D)  (p)
12. (A)  (p, r); (B)  (p, r); (C)  (p, r); (D)  (p, s)
13. 0 14. 1 15. 7 16. 3
17. 7 18. 7
24
HINTS & SOLUTIONS

PHYSICS (SECTION –I)
1. E  4r2 = 4Gmenc
r
aer
= 4G 4r 2 

0
r2
dr
4Ga(1  er )
 E
r2
At r = 1,
4aG(e  1)
E
e
3 4 3
1 
4/3 1
2.   2 3 2
 (  x) 30 30
1 1 1
  
x 60 180
x = 45 cm
3. 2x = R cos  O
x 1
So, tan   
R cos  2  R cos 
2R C
 h = R cos  =
5
A 
COM
B
X X
4. v cos   ucos  v
2v 2 sin  cos  
a
g u
2 2 2 2 
v sin  u sin 
a 
2g 2g A
By equation (1), (2) and (3)
4  2
u sin2   2ag [u2 cos2 ]  a2
g2  
a2 g2
 u4 sin2  cos2   (2agcos2 )u2  0
4
2agcos2   4a2 g2 cos4   a2 g2 sin2  cos2 
 u2 
2sin2  cos2 
 2  4  tan2  
 ag  
 2sin2  
 u  3ag
  t   C
5. q1  C 1  cos  1    /2
  LC   2
L
   C/3
  t 2  t1   C
C 
q2  1  cos   
6   LC   15
  
 3  
Required charge on capacitor (3)
14
q  C  q2  C
15
6. u sin 30 = v sin 60 P


u
 v
3 30
3R 3R 3 C
mu   mv   mR2  u 60
2 2 2
A
2u
 3R  3u  v 
3
2u v
 
3R
Coefficient of restitution,
v 3
 R
v  3 R
e 2 2 
3 3u
u
2
Or, e = 1
P0 (2V0 )  4P0 (V0 )

7. WAB  W1   2P0 V0
2 1
5
 1 3
PC  4P0   = 21/3 P0
2
4P0 V0  24/3 P0 V0
Work done in BC, W2 
5
1
3
= 6P0V0  3  2 1/3 P0V0
So, work done in the cycle, W = W 1 + W 2
Or W  P0 V0  4  3  21/3 
8. ar 2 E
a tan 
y=
2 d
a y
dy = sec2  d 
2 z a
a
z = sec 
2
26
a
d = dq  E  sec 
2
  
 q dB 4 
 a2  sec 4 d   4
  
 64 dt 
 
 
4

qa2 dB ma2 d
   
6 dt 3 dt
1 qB
  
2 m
1 ke2
9. mu2  0
2 r
2k
 u e
mr
h 1
   r
mu u
1 ke2
KE1 = mu2 
2 r
1 ke2
For Bohr model, mv 2   KE2
2 2r
KE1
 k 2
KE2
11. (P) forces are conservative so E is constant K will increase upto equilibrium and then decreases
(Q) Gravitational force is conservative, so E is constant U decreases and K increases.
1 1 F2 2
(R) U = mgh  constant, K  mv 2  ma2 t 2  t
2 2 2m
F2 2
E = U + K = mgh + t
2m
(S) U0 =mgH A v0
AB = v0t h
B
h C
 sin   h = v0 sin  t
v0t 
U = U0  mg v0 sin  t
1
K  mv 20
2
1
E = K + U = (U0 + mv 20 )  mgv 0 sin t
2
12. COLM mv 0 = mv1 – 2mv2

mr 2
COAM mv0r = mv1r + W
2
For no slipping
r – v 1 = v2
v  v2
v0 = v1 + 1
2
 2v0 = 3v1 + v2
15 v
After solving v1 = 5v0/7, v2 = 2v0 - v 0 = 0
7 7
1  5v 0 v 0  4v0
W=    =
r 7 7  r
2
1 25v 0 1 mr 2 16v 20
KEcylinder = m 
2 49 2 2 49r 2
25mv02 8mv 02 33
  mv 20
98 98 98
1 v 2 mv 20
KEplane = 2m 0 
2 49 49
1 33mv 20 mv 20  14mv 20
W friction =   mv 20    = 
2 98 49  98

2 2 2
1 16v 0 1 mv 2 16v0 24mv 0
K.E. of cylinder w.r.t plank = m   =
2 49 2 2 49 98
13.   r 2h  g  T cos 1  2r  Tcos 2  2r

ghr
T
(cos 1  cos 2 )  2
Or T = 0.05 N/m
14. At angle , we may write

d2   g
2
    (   1)
dt 
d2   g
      , where  =  +1
2
dt 
2
Now  varies from to 1;
3

2
g
So, time taken =
6
 
Or time 
3 g
15. In steady state,

  4R12  TA4  a2   4R22  TC4  a2
    4a2  TB4
4r12 4r22
 2   r 2
 R  
 TC4   4TB4   1  TA4   2 
 r
 1    R2 
 TC4  16TA4
Or TC  2TA
16.  = 4 volts, r = 2 
28
2
 Pmax   2W
4r
1 1
17.
2

m(u2  v 2 )  (2p0  p0 )  8r 2h  r 2h 3
3m(u2  v 2 )
 p0 
14r 2h
14  3
=
3
14   106     10 1
7
 p0  7  107 Pa
5 4L 5 L
18. L    k .
4 5 2L
Equation of wave from open end:
P0 sin kx cos t
O
5 x
P  P0 sin  cos t
2L
P 1 5x
At t  0 P  0   sin
2 2 2L
 2L L
 x  
6 5 15
CHEMISTRY (SECTION –II)
PART – A:
3. SO2Cl2 + 2H2O   H2SO4 + 2HCl
25 ml of 0.2 M
moles of SO2Cl2 = 25  0.2  103 = 5  103
moles of H2SO4 produced = 5  103
moles of HCl produced = 10  103
H2SO4 + Ba(OH)2 BaSO4 + 2H2O
2HCl + Ba(OH)2   BaCl2 + H2O
moles of Ba(OH)2 needed to neutralize H2SO4 = 5  103
10  103
moles of Ba(OH)2 needed to neutralize HCl =  5  10 3
2
Total moles = 10  103
103  V  0.02 = 10  103 = 50 ml
4. CH3
Cl OH
 Et S
 H2O
 
Et S CH3 Et S CH3
5.
O OH OH
H3C O NaOH H3C O

 HCl
H3C H3C  A
O HO O HO
6.
Br
FeBr3
 Br2  Na / Ether
 
10. (A) HOCl OH

 
MeCH  CH2   Me  CH  CH2 Cl   Me CH CH2
intermediate  OH Cl
(B) Hg OAc  2 / H
Me3 C  CH  CH2  Me3C HC CH2 H2 O
Me 3 C  CH  CH3   Me 3 C CH CH 3

Hg2
intermediate  OH
(C) Cl

 Cl
Cl2 / CCl4
MeCH  CHMe   MeHC CHMe Me  CH  CH  Me   Me CH CH Me

 intermediate  Cl Cl
Cl
(D) Alc.KOH
Me2 CH  CH2Br 
E2 mechanism
 no intermediate formed
PART – B:

H2 O  CO 2 H3 O
12. (A) CaC2  N2  CaCN2  C   CO NH2 2  CaCO 3   2NH3  CO 2

H3 O
(B) NaNH2  N2 O 
 NaN3  H2O   N3H

 H3 O
(C) Na2B 4 O7  NH4 Cl   BN+NaCl+B 2 O3  4H2 O   B 2 O3  2NH3

H3 O
(D) COCl2  NH3 
 NH2 CONH2   2NH3  CO2
SECTION –C
A2 2A
13.
1  2
rmix 71

rCl2 Mmix of A2 &A
71
2
Mmix
Mmix = 17.75
1    MA 2  2MA
Mmix 
1    2
1     15  2
=
1   
30
17.75 
1 
  0.69
30
For Kp
A2 2A
1 0
1  2
 1 atm  1 atm
1  1 
2
 2 
 
1  
Kp  
 1  
 
 1  
4 2
Kp  atm
1  2
4  .4761
 atm
0.5239
Kp = 3.6 atm
14. E  q - w
nCV T  q - Pext (V2 – V1)
 nRT2 nRT1 
nCV T  q - Pext   
 P2 P1 
E= nC V T
= 2 × 3 × 27 × 4.18 J
= 677.16 J
w = Pext (V2 – V1)
 2  R  300 2R  273 
= 1  
 1 2 
= 2718.6 J
E  q  w
q = E  w
= 677.16 + 2718.6
= 3395.76 J
15. Fe3   H2 S  S  Fe2 
SO2  2H2 S 
 3S  2H2 O
H2 O2  H2 S  2H2O  S
H2 S  O3  H2 O  S  O2
2HNO3  H2S   2NO2  S  2H2 O
16. All nitrates of alkali earth metal decompose like this.
17. Br F Br F
H2 /Ni
C C  HC CH
I Cl I Cl
E (or) z give same product.
Cl F Cl F
H /Ni
C C 2
 HC CH
I Br I Br
Cl F Cl F
H /Ni
C C 2
 HC CH
Br I Br I
So, x = 3
or or H /Ni
2
 n  butane
H /Ni

2
iso butane C C C
C
Y=2
X Y 5
18. CH3 CH3 CH3
CH3
or or hot alkaline
  Aromatic dicarboxylic acid
KMnO 4
CH3
CH3
So X = 3
hot alkaline
C C C C or C C C 
KMnO  CO 2
4
C
Y=2
X+Y=5
MATHEMATICS (SECTION –III)

PART – A
1. A
area of PQR Ar  GPR  GQR  GQP 
Ratio of =
area of ABC Ar  ABC 
2. A
1 1/2 1
1
 sin 4x  g  x  dx =  sin 4x  g  x  dx +  sin 4x  g  x  dx For I2 put x =
2
t
0 0 1/2
(I1) (I2 )
3. B
a+c=b+d+1
The number of polynomial will be 2(1  2 + 3  2 + 4  3 + 5  4)
4. B
1
Slope of axis is and origin lies at directrix
2
5. A
6. A, C
32
 
Let  be the angle between a and b
 
a  b = cos 
2 2
  sin2   
   
    and   b  0
   
    b  
7. A, C
Put x = 1, y = 1
2
f (1) – f(1) – 6 = 0
 f(1) = 3 or f(1) = –2
Now, put y = 1
2  2x  1
f x 
x  f 1  1
2x  1  1
For f(1) = 3, f  x   ,f   4
x  2
2  2x  1  1  8
For f(1) = –2, f  x   , f   
3x  2 3
8. A, B, C, D
In all the cases x and y both are even, let x = 2p, y = 2q
2 5 1
So,    6q + 15p – pq = 0
p q 3
 (p – 6)(q – 15) = 2  32  5
(A) When both p and q are even (p – 6) and (q – 15) are even and odd respectively
So, number of solution 1  3  2 = 6
(B) Number of solution = 6
(C) p = even, q = odd, (p – 6)(q – 15) is a multiple of four which is not true
(D) p = odd, q = even  LHS = odd, not true
9. A, C, D
2n 3n  2n 
As A n   
 0 3n 
10 10 5 5
Solution a + d = 2 + 3 = 4 + 9 multiple of 13
Also, d – b = 2 , a + b + c + d = 2  310
10
10. B, C, D
 x  1  1
(A)  2  3 
  1  0 < x < 1 a is false
 1 x   x  
1 x2 x2 
 1 
(B) un  tan1  2  n = 1, 2, 3, …..
 2n 
 2 
= tan1  2 
 4n  1  1 
 1   1 
= tan1    tan1  
 2n  1   2n  1 
 (B) option is true

(C) sin1 x  cos1 x  tan1 x   tan1 x
2
Since x  [0, 1]
 

4 2
 (C) option is true
 3  3 
(D) sin1   1
  cos    
 2   2  2
 (D) option is true
11. (A)  (t); (B)  (r); (C)  (q); (D)  (p)

n 1
nr n  n  1
 r  1 r  2  r  3  = 4 n  2
r 0
12. (A)  (p, r); (B)  (p, r); (C)  (p, r); (D)  (p, s)
f(x) = 5 ln(1 + x2) – 10x tan–1x + 16 sin x
f(x) = 2(8 cos x – 5 tan–1 x)
 5 
f(x) = 2  8 sin x    0 ,  x  (0, 1)
 1  x2 
So f(x) is decreasing  x  (0, 1)
For x < 1, f(x) > f(1)
 5    5 
 2  8 cos1   2  8 cos  0
 4   3 4 
So, f(x) is increasing for x > 0, f(x) > f(0) = 0
x
So,  f  t  dt is positive and increasing
0
13. 0
f(x) < (x2 – x)ex  x  (0, 1)
14. 1
Coefficient of x10 in (1 – x)29
15. 7
4
C2  4C1  4 C2  4C1
Probability = 4
C2  4 C1  4C2  4 C1  4 C2  4C2
16. 3
6 6 21 21
 20
C1  20
C3  20
C5  .....  20
C9   2 
18
 8   32   8  33  1
So, it leaves remainder 3
17. 7
9(PG)2 + (AB)2 + (BC)2 + (CA)2 = 3((PA)2 + (PB)2 + (PC)2)
= 9  22 + (a2 + b2 + c2) = 3(12 + 32 + 42)
a2 + b2 + c2 = 42
a2  b2  c 2
7
6
18. 7
1 1
f  x   x  x  y 2 f  y  dy  x 2  y f  y  dy
0 0
34
1 1
2
Let  y f  y  dy  A ,  y f  y  dy  B
0 0
2 1 A B 1 A B
f(x) = x + Ax + Bx  A    , B  
4 4 5 3 3 4
61 80 61x  80 x 2
A , B , f x  x 
119 119 119
  = 119

 7
17

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3 REVIEW TEST-07-PCM-JEE(Advanced)

FIITJEE REVIEW TEST - 07

Name of the Candidate :______________________________________________________

1. Consider a region in space filled with spherically symmetrical mass y

2. Figure shows an object O placed in front of an equi-convex 47 cm

Space for Rough work

3. Figure shows a massless semicircular ring that is hinged at O. A and B O

4. Figure shows a cube of side length ‘a’ placed on a horizontal

5. Capacitor (1) is connected to point A at t = 0. The switch is L B + 

Space for Rough work

PART – A: (Multi Correct Answer Type)

6. A disc of mass m, radius R is hinged at its periphery and P

7. Figure shows a cyclic process for a monoatomic ideal P

(D) Work done by gas in the cycle is W = P0V0

Space for Rough work

8. A square wire loop (non-conducting) with uniformly distributed

Space for Rough work

PART – B: (Matrix Match)

(C) An object of mass m is m F (r)

(D) A particle of mass m is v0 (s)

Space for Rough work

Space for Rough work

PART – C: (Numerical Based Type)

13. A liquid column of height h is in equilibrium inside a

14. Figure shows a typical simple pendulum with the O

Space for Rough work

Space for Rough work

17. A frustum of a cone with mass m = 14  kg, r

Space for Rough work

Space for Rough work

4. Which will show greater degree of retention on hydrolysis?

Space for Rough work

PART – A: (Multi Correct Answer Type)

6. For the reaction:

The correct statement about product is/are:

(C) P = optically active (D) P = optically inactive

7. Which of the following statement(s) is/are true?

Space for Rough work

10. In which of the following reactions carbocation is the intermediate?

Space for Rough work

PART – B: (Matrix Match)

11. Match the following:

Space for Rough work

Space for Rough work

SECTION – III : MATHEMATICS

Space for rough work

PART – A: (Multi Correct Answer Type)

10. Identify the correct statements

Space for rough work

PART – B: (Matrix Match)

11. Match the following Column-I with Column-II

  5ln 1  t   10t  tan t  16 sint  dt

Space for rough work

PART – C: (Numerical Based Type)

Space for rough work

CHEMISTRY (SECTION –II)

MATHEMATICS (SECTION –III)

HINTS & SOLUTIONS

6. u sin 30 = v sin 60 P

P0 (2V0 )  4P0 (V0 )

12. COLM mv 0 = mv1 – 2mv2

13.   r 2h  g  T cos 1  2r  Tcos 2  2r