FIITJEE Review Test-06 Answers

Review Test-06_PCM(000000.
1)-17
FIITJEE REVIEW TEST

PHYSICS, CHEMISTRY & MATHEMATICS
ANSWERS
PHYSICS (SECTION –I)
PART – A
1. A, C, D 2. A, B, C, D 3. C 4. A, D
5. A, D 6. B, D
PART – C
7. 5 8. 6 9. 6 10. 3
11. 4 12. 7 13. 9.00 14. 3.00
15. 3.00 16. 4.00 17. 5.00 18. 2200.00
CHEMISTRY (SECTION –II)

PART – A
1. A, B, C 2. C, D 3. C, D 4. C
5. A, B, D 6. A, B, C
PART – C
7. 5 8. 4 9. 6 10. 2
11. 5 12. 8 13. 60.25 14. 61.83
15. 1.53 16. 23.00 17. 1.15 18. 1.33
MATHEMATICS (SECTION –III)

PART – A
1. A, B, C, D 2. A, C 3. A, C, D 4. C, D
5. A, C, D 6. A, B
PART – C
7. 9 8. 2 9. 8 10. 4
11. 5 12. 6 13. 3.50 14. 1.25
15. 0.50 16. 1.41 17. 6.25 18. 0.50
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website: www.fiitjee.com.
Review Test-06_PCM(000000.1)-18
HINTS & SOLUTIONS

PHYSICS (SECTION –I)
50 R1
1.  i1 0   2 amp
L
25 i1
50
(i2 )0   0.01 amp R2
5000
1 = 0.125 sec I2 C
2 = 0.125 sec
i1 = 200 i2
 t   t 
2  1  e 0.125    0.01 e 0.125  200 V
   
   
n2
t
8
q di
4   L 1
C dt
 t  t

4  50  1  e 0.125   50e 0.125
 
 
1 5
t  n  
8 4
2. All are based on true facts.
3. T and v are perpendicular so speed is constant. v0

x

R
d dx
 
dt Rdt 
R v0
v0 dx 
 
x Rdt
 xdx = Rv0dt
2
 t
2Rv 0
Now check the options.
4. Use horizontal & vertical velocity components for comparison.
5. Kinetic energy can never be negative.
6. Net B at distance x from O along x-axis A

 I
= 0 2cos 
2 r 
 I
  dF   I 0 2cos dx O
x 
2 r  P
  L2  
 0 I2 n  1  2 
2   
B
7. Stress are zero at free ends and maximum at middle so rod will rupture at middle.
By Newton’s second law 
2
F   F  dF   dmx dx F+dF
  dF   A2  dx F
x
Where  is the speed of rotation
x
F  x2 
 F0  A 2  
 z   /2
A 2    2 2

F       x 
z  2  
A2  2
At x  0 F 
8
F 2 2
 
A 8
F 2 2
For rupture   
A 8
1 8
 n
2 2
2V VC(t)
8. Start with VC  ; By discharging
3
V
2
formula VC  t   Ve t1 /R 2C
3 2V/3
V
For VC  t   we get t1  R2 Cln2 V/3
3
V t
After the switch opens voltage is ;
3 T
increasing towards V with time constant
R1  R2  C so
2
V e 2  1 2 
 t / R R C
VC  t   V 
3
 t 2   R1  R2  C ln 2
9. The current through E2 is given by the solid line, while that through E1 is given by the dotted line. We
can choose points on the graph, apply KVL and KCL to the circuit and substitute these values to
determine the unknowns. This gives E1  6 V.
F
10. Acceleration of system =
Mm
Tension at distance x from A at t = t
Fmx
T  ma 
 M  m 
 Speed of pulse at x distance from A is
Fmx  Fx
v 
 M  m m Mm
F
 a
2 M  m 
h
11. In Region 1 K  2a  1 
4ma
h
In Region 2 K  3a   2 
6ma
1 6
 
2 4
12. According to given condition

9   1 1  5   1 1  1
 5  1  R  R    4  1   R     20
     
8 1 1
  
5R 4R 20
27 1
   R  27 cm
20R 20
 9  1 1  1 1 1
and   1        1     
 5  R R   R   40
8  1 1
  
5R R 40
13  5  1
 
5R 40
27
 13  5 
8
77 77
 5    ;
8 40
y
1 gsin  2
13. h   tan  
2 v 20 cos2  v0
gsin 2 g sin 

v0  2 h=1m
2cos ( tan   h) 
x
4  = 8m
10   8  8
= 5  9 m/s
4 4 3 
2    8   1
5 5 4 
9 3 a a
14.  
15 5 g 15 
5
12 3
3 53 37
a g
5 9 2 4
I
15. T  2
mgd
1 mgd
f
2 I
1 (2m)(g)(3 / 4) 1 18g
f0  
2  m 2  2 13
  m 2 
 3 
When disc is removed
1 1 6g
f 
mg( / 2) 2 
2
m 2 / 12
f 6g 13 13
 
f0  18g 3
1
16. K mv 2
2
dK 1 2 dm 1 dv
 v  m  2v
dt 2 dt 2 dt
1 2 1
= 9t  18   54  2  3t  3
2 2
dK
 9  2  18  54  18
dt t  2
= 1296 J/s
dm
17. F= u and P = Fv
dt
18. T = T Extension …(i)

mg F 
 Y e
S S 
mg
  e   compression …(ii)
SY
If there is no change in length, it means extension due to temperature raise must be equal to the
elastic compression due to weight. So
mg
T 
SY
SYT 1.1 10 5  10  10 4  10  2.0  1011
 m   2.2  103 kg
g 10
CHEMISTRY (SECTION –II)
2. It is an example of benzil-benzilic acid rearrangement.
3. In acid hydrolysis will give a compound which forms a yellow ppt. with KOH/I2.
  dE  
4. H  nF E  T   
  dt P 
 dE 
S  nF  
 dt P
5.  o  P high spin complex.
Cl
Cl
en Co d& 
NH3
NH3
Cl
NH3
en Co optically inactive
NH3
Cl
NH3
Cl
en Co optically inactive
Cl
NH3
6. (A) Pex = 0
W  Pex V  0
(B) W  Pex  V2  V1 
 nRT nRT 
Pex   
 P2 P1 
 1 1
Pex nRT   
 P2 P1 
1 1 
0.850  0.0821 300  1  
 1 15 
19.54 L atm
(C) For an isothermal reversible expansion
P
W  2.303nRT log 1
P2
15
 2.303  0.850  8.314  300log
1
= - 5.742 × 103 J
(D) W > 0
Numerical Based Integer
7.
A 

H
Dibromide
2 1 2
8. Molar mass Ni(CO)x = 59 + x(12 + 16)

= (59 + 28x) g/mole
-1
Molar mass CH4 = 16 g mole
rCH4 MNiCO x

rNi CO x MCH4
59  28x
3.3 
16
59  28x
  10.89
16
59 + 28x = 174.24
x = 4.11  4
9. H
OH OH
N N O
O  NH2  OH  N Conc. H SO
2 4
O  
O N
H


2Cl  g 
 Cl2  g 
10.
nCl  nCl2 at eq.
1 1
XCl   PCl  PT XCl 
2 2
1 1
XCl2  ; PCl2  PT X Cl2 
2 2
1
PCl2
KP  2
 2 2 2
 Cl   1 
P
 2
 
11. Oxygen combined with 1.25 gm Ga

= 1.68 – 1.25 = 0.43 g
1.25
Moles of Ga = x =
70
0.43
Moles of O2 = y =
16
x 1.25 / 70 0.0179 1 2
   
y 0.43 / 16 0.0268 1.50 3
Thus, x + y = 5
12. For acidic buffer,
pH  pK a  log
Conjugate base
 Acid
= pKa + 0.9
 log
Conjugate base  0.9
 Acid
Conjugate base  8 [log8 = 0.9031]
 Acid
Numerical Based Solution

13. KH = PA/YA
Partial pressure of O2 = 0.21 atm = 21278.2 Pa.
PN2  0.79 atm  80046.8 Pa
21278.2
XO2 in dissolved water  8
 10.4819  105
2.03  10
80046.8
XN2 dissolved in water   15.7883  10 5
5.07  108
X O2
 0.6639  0.66
XN2
0.66
% of O2   100  39.75
1.66
% of N2 = 60.25
14. Mass of dissolved naphthalene = 0.624 gm

Mass of solvent (CCl4) = 0.060 kg
0.624 / 128.2
Molality =   0.08
0.060
Tb  K bm
0.42
 Kb   5.25
0.08
For unknown solution
0.53
0.75  5.25 
M  0.06
M  61.8333  61.83
 2  28    3  4 
15. Mmix   13.6
5
rmix 5 32
  1.5339  1.53
rO2 5 13.6
P1V1 1 10
16. V2    10 m3
P2 1
P1V1 10  1 103
n   445.9186
RT  0.0821 273.15 
 445.92
P1
W = - 2.303 nRTlog
P2
= - 2.303 × (445.82) (0.0821) (273.15)log10
= - 23002.018 J = - 23.00 kJ
17. 

LiCl.3NH3  s  
 LiCl.NH3  s   2NH3  g
1


LiCl.NH3  s   2NH3  g 
 LiCl.3NH3  s  , KP  atm2
16
Initially 0.2 a 
Finally 0 a  0.4 0.2
1 1
K P  2

PNH3
16
 PNH3  4 atm at equilibrium
PV = nRT
4 × 5 = n × 0.0821 × 323
n = 0.75419  0.75 moles at equilibrium.
 Initial moles of NH3 = 0.75 + 0.4 = 1.15.
O
18.
O C
O
1.33
MATHEMATICS (SECTION –III)

PART – A
1. A, B, C, D
n/2
n  n  n n n
 n!    1  2  .....      
 2  2   2 2 2
1/2
n
 n!1/n    which tends to 
 2
2. A, C
a2 + b2 + c2 =1
1
  ab  bc  c a  1
2
3. A, C, D
When f(x) is continuous at x = 2, f(x) don’t exist at x = 2 and f(x) changes sign from positive to
negative
2
k 3  k  1
 f(x) attains max at x = 2, if 0
k2  k  2
 k = 0, 1
When f(x) is discontinuous at x = 2, f(x) changes its sign from positive to negative f(x) will attain
maximum if lim f  x   f  2  as lim f  x   f  2
x 2 x 2
i.e., if k  (–, –1)  (0, 1)  (1, 2)
4. C, D
 ABC  BPC   APC C
1 1 2
 ar  br  r 
2 2 ab
A B C s s  a s s  b s s  c 
cos cos cos 
2 2 2 bc ac ab A B
P
s
=
abc
5. A, C, D
We have p(exactly one of m and n occurs)
 p(m  n) = p((m – n)  (n – m)) = p(m – n) + p(n – m) = p(m) – p(m  n) + p(n) – p(m  n)
 p(m) + n(n) – 2p(m  n)
6. A, B
We have 2xy dy = (x 2 + 1)dx + y2 dx
2xydy  y 2 dx  1 
 2
 1  2  dx
x  x 
2
y   1
 d   d x  
 x   x
2
y 1
  x c
x x
 y2 = x 2 – 1
 x0 = 2
PART – C
7. 9
x
dy
Let  f  t  dt  y , f  x   dx
0
y 2
dy f 0  1 f 0  x
2
 f 0  c  y 
x dx y x cx  1
dy f 0 
f  x   put x = 1  (c + 1)2 = 4
dx  cx  12
 1
c can not be negative as f    is not defined but domain is [0, )
 c
8. 2

 f  x  sin x dx  0  f(x) has one root in (0, )

0
  
Let that be x1 then cos x1  f  x  sin x dx  sin x1  f  x  cos x dx =  f  x  sin  x  x1  dx  0
0 0 0
 f(x) must have another root. Take f(x) = sin 3x to confirm two roots are possible
9. 8
(MN)2 = 9MN
Also (NM)3 = N(MN)2M = N(9MN)M = 9(NM)2
 NM = 9I
10. 4
 /2
n n 1
Let In   sin xdx then In  In 2
0
n

Where I0  , I1 = 1
2
Since, I2n – 1 > I2n > I2n + 1
I 2n  1 I
1  2n   lim 2n  1
I2n 1 2n n  I2n1
2
2 4  2 4 6  
Hence,      .....      .....  
1 3  3 5 7  2
11. 5
Product of roots  (0, 1)  b = 1, 2, 3, ….. n – 1
Also, f(1) > 0
and –a < b + n  –a  b + n – 1
2 2
a > 4bn  a  4bn + 1
2 2
Hence, (b + n – 1)  a  4bn + 1
b = 1, n  5, b = 2, n  6 ….. etc.
Also, for n = 5, 5x2 – 5x + 1 has distinct roots
12. 6
1
Put x 
2
 1 1 1   1 2 
lim  2 ln 2  2  2 lnsin   , lim   2 ln 2  2  ln sin   
0      0    
 2 2    lnsin   ln   
lim   ln   2 lnsin   , lim  2  
0  2   0   2 
 1  3 
cot         ..... 
   L.H. Rule, lim   tan   lim  3  1
lim   2
0
   0  tan  0  tan   3
3  
    
13. 3.50
e2x 2  x  1 e2x
Let f  x   , f   x  
x2 x3
2
Graph of f(x)  0 < k < e , kmax = 3.5 O 1
14. 1.25
Let l, m, n be the directions of the line lying in the three planes, then the line is perpendicular to the
normals to these planes, so we have
l – cm – bn = 0
–cl + m – an = 0
–bl – am + n = 0
1 c b
2 2 2
Elimination l, m, n from these equation, we get c 1 a  0  a + b + c + 2abc = 1
b a 1
15. 0.50
1 m1 n1 1 m1 n1 1 0 0
   2 m2 n2  2 m2 n2  0 1 0  1
3 m3 n3  3 m3 n3 0 0 1
 || = 1
16. 1.41
x2 y 2
  1 , whose director circle x 2 + y2 = 12
9 3
So, required condition (2, ) should lie inside the circle and outside the ellipse i.e.
9 12
  2 
7 5
17. 6.25
2
Write x  e x xln x  x ln x 
 1  x ln x  .....
2!
1 1
n m m m 1
Now  x ln x  dx    xn  ln x  dx
0
n  10
1
n n n!
   xln x  dx   1
n  1n1
0
1
x 1 1 1
 x dx  1 
22
 3  4  .....
3 4
0
18. 0.50
Let side of length 2 subtends 2 at the center and side of length 3
subtends 2  R

Then 2  2 
2
1

 
4

FIITJEE Review Test-06 Answers

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FIITJEE REVIEW TEST

CHEMISTRY (SECTION –II)

MATHEMATICS (SECTION –III)

HINTS & SOLUTIONS

2. All are based on true facts.

3. T and v are perpendicular so speed is constant. v0

4. Use horizontal & vertical velocity components for comparison.

5. Kinetic energy can never be negative.

6. Net B at distance x from O along x-axis A

12. According to given condition

gsin 2 g sin 

18. T = T Extension …(i)

CHEMISTRY (SECTION –II)

2. It is an example of benzil-benzilic acid rearrangement.

5.  o  P high spin complex.

8. Molar mass Ni(CO)x = 59 + x(12 + 16)

11. Oxygen combined with 1.25 gm Ga

12. For acidic buffer,

Numerical Based Solution

14. Mass of dissolved naphthalene = 0.624 gm

MATHEMATICS (SECTION –III)

 f  x  sin x dx  0  f(x) has one root in (0, )

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