(0999DJM262103230002) Test Pattern

DISTANCE LEARNING PROGRAMME JEE (Main)

UNIT TEST # 02
(Academic Session : 2023 - 2024)
23-07-2023

JEE(Main) : LEADER TEST SERIES / JOINT PACKAGE COURSE

ANSWER KEY
PART-1 : PHYSICS
Q. 1 2 3 4 5 6 7 8 9 10
A. A B B D B C D D C A
SECTION-I
Q. 11 12 13 14 15 16 17 18 19 20
A. A B A C B B B B B A
Q. 1 2 3 4 5 6 7 8 9 10
SECTION-II
A. 1 -48 198 1 17 5 53 40 3 260

PART-2 : CHEMISTRY
Q. 1 2 3 4 5 6 7 8 9 10
A. C D C B A C D C A A
SECTION-I
Q. 11 12 13 14 15 16 17 18 19 20
A. D A A C C D D A B C
Q. 1 2 3 4 5 6 7 8 9 10
SECTION-II
A. 500 2 150 1 16 6 4 1 10 50

PART-3 : MATHEMATICS
Q. 1 2 3 4 5 6 7 8 9 10
A. A C A A A C B A B B
SECTION-I
Q. 11 12 13 14 15 16 17 18 19 20
A. A D A D D C A A C A
Q. 1 2 3 4 5 6 7 8 9 10
SECTION-II
A. 2 80 2 7 6 1 6 -3 6 5

HINT – SHEET
PART-1 : PHYSICS 2. Ans ( B )
SECTION-I Potential at center of conducting sphere

1. Ans ( A ) VC = Vdue to induce charge + Vdue to dipole

V  =  KQ kP
3a VC = 0 +

KQ x2
VB =  = 3V

a
where cos ϕ =  r  x = r

KA + UA = KB + UB
x cos ϕ
kpcos2 ϕ
1 2
mv + qv = 0 + q(3V)

VC =         

2 A r2
1 2 Potential at center and at surface is same for
mv = 2 qv

2 A
             = 2q KQ
conducting sphere

a
kpcos2 ϕ
vA = √ 4KQq VA = VC =
ma r2

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3. Ans ( B ) 7. Ans ( D )
σ σ σ
W2→1 = q(V1 – V2)
E= + = ,

2∈0 2∈0 ∈0

P = qd

Fnet = 0,

Kq(Q1 − Q2 ) 1
( 1− )
R √ 2 τ = PEsin θ

4. Ans ( D )
U = – PEcos θ

8. Ans ( D )
→
∮
→ ⋅ ds = qin

E
∈0
q
2 × (200)102 =  in

∈0
–
qin = 8.85 × 10 12 × 4 × 104

= 3.540 × 10 – 7 Nm2/C
5. Ans ( B ) K(−q − q + 2q)
V = = 0

→ a
∮
→ ds = qin  ;

E.
∈0 ∴ E2 = E3

Q × 43 π (x3 − r31 ) K2q

E . 4 π x2  =  /∈0
∴ Enet = E1 = 

4
π (r32 − r31 ) a2
3
At 2q,

Q x3 − r31
E =  ( )
4π∈0 x2 r32 − r31 Fnet =  √
F 2 + F 2  

6. Ans ( C ) √ 2K2q 2
kqR/2
        =  √ 2F  = 

kqr kq 2
E1 = = =
(a√2)
R3 R3 2R2 √ 2Kq 2
kq         =
E2 =
a2
R2
9. Ans ( C )
E1 1
=
KQtotal
E2 2 V =

r
2
kq 2 R 11 kq
V1 = [3R − ( ) ] =
V ∝ Qtotal 
2R 3 2 8 R
kq
V2 =
10. Ans ( A )
R
V1 11 No. of lines ∝ q
=
V2 8

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11. Ans ( A ) 15. Ans ( B )
During upward journey a1 = g + a

2h
t1 = √

g+a

During Downward journey  a2 = g – a

2h
t2 =  √

g−a
t1 √ g − a √ 10 − 2 √ 8
t2
= =
10 + 2
=
12
 = √ 2
g+a 3
12. Ans ( B )
17. Ans ( B )

13. Ans ( A )
→ → →
V BA = V B − V A

18. Ans ( B )

= 10j^ − (−10i^)

= 10j^ + 10i^

VBA = 10√2 km/h

19. Ans ( B )

dis tan ce
Time = 

speed
50√2
=  = 5h
10√2
14. Ans ( C )
1
6 = 4t –    × 12 × t2

t = 2.3 s 20. Ans ( A )

– 36 = 3t – 5t2 ⇒ t = 3s
Range = 4 × 3 = 12 m
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PART-1 : PHYSICS 5. Ans ( 17 )
SECTION-II k × 5 × 0.3 × 10−12
F1 =

9 × 10−4
1. Ans ( 1 )
9 × 109 × 5 × 0.3 × 10−12
=

9 × 10−4

= 1.5×10 = 15 N

λ 1 = λ 2 9 × 109 × 5 × 0.16 × 10−12

F2 =  = 8N

2. Ans ( -48 ) 9 × 10−4

∵ Ex, Ey are parallel to face ABCD force experienced by charge at

so ϕI = 0
A = √ F1 2 + F2 2

At face BCGF, only Ex are perpendicular to surface.

√
152 + 82

ϕ II = ExS = (4 × 3) × 22 = 48 N-m2/C

= √289 = 17 N
ϕ I – ϕ II = 0 – 48 = – 48
6. Ans ( 5 )
3. Ans ( 198 )
q → nq

7. Ans ( 53 )

4. Ans ( 1 )

8. Ans ( 40 )

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PART-2 : CHEMISTRY 6. Ans ( C )
SECTION-I Rate = k [A] α [B] β     .....(i)

1. Ans ( C )
a     2 × rate = k[2A] α [B] β     .....(ii)

For zero order, t1/2  and T = 2 × t1/2  

2k

t1/2 = 1
 = 500 sec and T = 1000 sec      3 × rate = k[A] α [9B] β     .....(iii)

2 × 0.001
2. Ans ( D )     From eqs. (i) and (ii), 2 α = 2, α = 1

For all reactions,

1
    From eqs. (i) and (iii),  9 β = 3, β = 
    K ⇒ independent of conc. 2

    (Only depends on temperature, catalyst)     order = a + b = 1 + 1  =  3

2 2
3. Ans ( C ) 8. Ans ( C )
                  A2B3     →    A2    +     3  B2

2 AB5 → AB + 4B

      t = 0        P0               0             0

rAB5
    eq.           P0 –  x          x            
3x

    =  =  rB

1 4
2
    75 = P0 +  3 x = 60 +  3x
k[AB5 ] k1 [AB5 ]
2 2     =  =   ⇒ k1 = 4k
1 4
    x = 10 

Δp
11. Ans ( D )
∣ ∣ ∣ 50 − 60 ∣
    Rate  = ∣ ∣ =∣ ∣

∣ Δt ∣ ∣ 2.5 ∣
(a) 
            = 4 torr min – 1  Mg = 1s2 2s2 2p6 3s2
ℓ = 0 0 1 0
for m = 0
4. Ans ( B ) m = 0 0 1 0
No. of e− − = 8
Rate is parallel to time axis, i.e., it is constant,
dx
Rate = = k = k × [conc. ]∘
                    

dt
Hence, it will be zero order reaction.
(b) One orbital occupied maximum 2e –

Rate = k
5. Ans ( A ) (c) M shell n = 3, no. of e – = 2n2 = 2 × 32 = 18

(t1/2 )I 1−n
a1 (d) P = 1s22s22p63s23p3

=( )

(t1/2 )II a2
1−n      l = 0 for s orbital, so 6e – , in s, so for 3e, s = + 1

=  300 = ( 1 )   ⇒ 1 – n = 1 
2
600 2
     and for 3e, s = − 1
2
= n = 0        
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12. Ans ( A ) PART-2 : CHEMISTRY
Orbital with lower value of (n + ℓ ) will have SECTION-II
1. Ans ( 500 )
less energy. If (n + ℓ ) values are same then the
2.303
orbital with lower value of ‘n’ will have less tx% =  log  100

K 100 − x

energy.
2.303 t1/2 100
13. Ans ( A ) =  log

ln2 (100 − 99.999)

h h
Orbital angular momentum  =  √
ℓ(ℓ + 1)
2π
= √3
π

2.303 × t1/2 100

=   log 

ℓ = 3 = F
2.303 log 2 10−3

nh
mvr =    4f, 5f, 6f ............ Possible
30 30 × 5
2π log 105  =   = 500
0.3 0.3
For F-subshell n =3 not possible.
2. Ans ( 2 )
15. Ans ( C )

F – and Na+ are isoelectronic but F belongs to

2nd period while Na belongs to 3rd period. n−1

440 182
=( )

880 364
16. Ans ( D )
n−1
All statements are correct 1 1
=( )

2 2
18. Ans ( A )
Correct order of electron affinity is n–1=1
S > Se > Te > O

20. Ans ( C ) n=2

Among these four elements, oxygen has highest
3. Ans ( 150 )
electronegativity t75% = t3/4 =2t1/2 = 100 min t1/2 = 50 min

t87.5% = t7/8 = 3t1/2 = 3 × 50 = 150 min

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4. Ans ( 1 ) PART-3 : MATHEMATICS
SECTION-I
t 1 ∝ [A]1−n
0

2 1. Ans ( A )
1 log55(x2 + 1) > log5 (ax2 + 4x + a)

t1 ∝  Given n = 3

[A]n−1
0
2 ⇒     5(x2 + 1) > ax2 + 4x + a > 0 ∀ x ∈ R

2
1 1 ⇒     ax2 + 4x + a > 0 ∀ x ∈ R &     

t1 ∝ =t1 ∝

3/2−1
[A]0 [A]0
1/2 5x2 + 5 > ax2 + 4x + a > 0 ∀ x ∈ R

2 2
It is possible if 

1
m= a > 0 & 16 – 4a2 < 0

2
(a2 – 4) > 0

5. Ans ( 16 )
a > 0 ∩ ( – ∞ , – 2) ∪ (2, ∞ )

2SO2 + O2 → 2SO3

a ∈ (2, ∞ )

and ......................................................................

1 d [SO3 ] −d [O2 ]
+ =   = R·O·R
(5 – a)x2 – 4x + (5 – a) > 0 ∀ x ∈ R

2 dt dt
1 0.8  d [O2 ] 5 – a > 0 & 16 – 4 (5 – a)2 < 0

( mol. lit−1 sec−1 ) =  

2 80 dt a < 5

1 d [O2 ] and

mol . lit−1 sec−1 =

200 dt (a – 3) (a – 7) > 0

d [O2 ] 1 (a ∈ ( – ∞ ,3) ∪ (7, ∞ )

Now    =  × 32 g.lit – 1 sec – 1

dt 200 Now  a ∈ (2, 3)

⇒ 0.16 g.lit – 1 sec – 1 2. Ans ( C )
f(x) = √ log2 (4sin2 x − 2√3 sin x − 2 sin x + √3 + 1)
7. Ans ( 4 )
Correct Order are :
is defined if

Order of EN : Zn < Cd < Hg

log2(4 sin2x – 2( 3sinx+sinx) + ( 3+1) ≥ 0

√ √

Order of IE : B > Tl > Ga > Al > In

or 4 sin2x – 2sinx ( 3+1) + √ √ 3 +1 ≥ 1

Order of EA : S > Se > Te > O

or  sin2x – sinx (
√
3 1
+ )+
√
3
  ≥ 0

Order of atomic radius : Ni < Cu < Zn 2 2 4

3 1
8. Ans ( 1 ) or ( sin x −
√

2
) (sin x −
2
)   ≥ 0

Due to inert pair effect the most stable 3

 i.e., – 1 ≤ sinx ≤ 1  or
√
 ≤ sinx ≤ 1

oxidation state of T ℓ is +1. 2 2

π π 2π 5π
10. Ans ( 50 ) or x ∈   [ −π, ] ∪ [ , ] ∪ [ , π] 

6 3 3 6
% change in mass =  18 − 12 × 100 = 50%   Number of integral solutions = 4 + 1 + 1 = 6
12

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3. Ans ( A ) 7. Ans ( B )
log3 x
Remainder = 0

3log10 x = 3 log310 = xlog10 3

x + b/a

∴ Equations is

xlog10 3 = 54 − xlog10 3

2xlog10 3 = 54

xlog10 3 = 27

x = (27) log103 = 27log3 10 = 3log3 10 = 1000

x = 1000
ad = bc

4. Ans ( A )
a, b, c, d → GP
(2n + 1) 6 1 1
Tn =  = 6[ − ]
8. Ans ( A )
n(n + 1) (2n + 1) n n+1
1.3 + 3.5 + 5.7 + 7.9 + … … . + (2n – 1) (2n + 1)

S50 = 6 [ 1 − 1 + 1 − 1 +. . . . . . . . + 1 − 1 ] 1
1 2 2 3 50 51 {(2n − 1)(2n + 1)(2n + 3) + 3}
(2 + 1).2

100 9. Ans ( B )
=     
17 2x – 1)2 = 2(2x + 3)

22x – 2.2x = 2.2x + 6 

5. Ans ( A )
22x – 4.2x + 5 = 0 

2011
1 1 1 1 1
t1
+
t2
+ +. . . . . . . . . . +
t3 t2011
 =  ∑
(2x – 5) (2x + 1) = 0

n=1
tn
2x = – 1  ; 2x = 5
2011
4
2011
1 1 10. Ans ( B )
⇒  ∑ = 4∑ [ − ]

n=1 (n + 2) (n + 3) n=1 n+2 n+3

A.M > G.M

1 1 1 1 1 1
1 + x + x2 +. . . . . . . +x100
= 4  − + − +. . . . . + − ]

⇒ 

[
3 4 4 5 2013 2014 101
                           > (1.x.x2 ........x100)1/101

1 1 4022
= 4  − ] =  1 + x + x2 +. . . . . . . +x100
[
3 2014 3021 ⇒   

101
100×101 1
× 101
6. Ans ( C )                           >  x 2

Given → a, b, c, d  → A.P.
1 + x + x2 +. . . . . . . +x100
⇒    ⩾ x50

101
divide by  a b c d
1 x50
1 1 1 1 ⇒    ⩾

, , ,  → A.P.
101 1 + x + x2 +. . . . . . . +x100
bcd acd abd abc
⇒     abc,  abd,  acd,  bcd → H.P. Greatest value =  1
101

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14. Ans ( D ) PART-3 : MATHEMATICS
Let
SECTION-II

1. Ans ( 2 )
1 2 3

1 2 4 .2 8 .2 16 . . . ∞

P ut = x

n 2 3
1 8 + 16
+

⇒  2 4 +. . . . ∞ → A.G.P = 2'=2

2. Ans ( 80 )
1 1 1
+ + +...∞ a, ar, ar2, ....

(1 − cos x) 2 2 2
2 3
= lim

x→0 x2

a(1 + r + r2) = 70          ... (i)

(1 − cos x) (1 + cos x)
= lim 4a, 5ar, 4ar2 are in A.P.

x→0 x2 (1 + cos x)

2 ⇒    10ar = 4a + 4ar2

sin x 1 1 1
= lim ( ) lim = (1)2 × =
x→0 x x→0 (1 + cos x) 1+1 2

18. Ans ( A ) ⇒    2r2  – 5r + 2 = 0    ⇒   r = 2, 1/2

(r = 2 is impossible)

putting r = 1/2 in (i)   ⇒   a = 40

a 40
so S = = = 80 
1 − r 1 − 1/2
19. Ans ( C )
3. Ans ( 2 )
ℓn (1 + h2 ) ℓn (1 + h2 )
f (0+ ) = lim = lim =2
h→0 1 − cosh h→0
h2 . (
1−cosh x x 1 1
h2
)
+ + ⩾√
3

2 2 x2 4

2
ℓn(1 − h) ℓn1
f (0− ) = lim = =0
h→0 1 − cos(1 − h) 1 − cos 1
for min.  x =
1
⇒ x3 = 2
2 x2
20. Ans ( A )
2 + cos x − 1
K = lim

x→π
(π − x)2 (√2 + cos x + 1)

1 − cos(π − x) 1
= x→π
lim 2
×
(π − x) ( √
2 + cos x + 1)

1 1 1
= ×
2 2 4

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4. Ans ( 7 ) 7. Ans ( 6 )
Let Numbers are p,q,r,s
∵ y2  – 4y + 11 = (y – 2)2 + 7

Using A ≥ G

min = (y2  – 4y + 11) = 7 (at y = 2)

1
p+q+r+s
⩾ (pqrs) 4
∵   lim [min (y 2 − 4y + 11)
sin x
]

4 x→0 x
⇒ (p + q + r + s)4 ≥ 256 pqrs               … . (1)
7 sin x
lim [ ]

x→0 x
but given (p + q + r + s) ≤ 256 pqrs     … . (2)
7 sin x
Now, Let f(x) =  [ ]

x
So, A = G ⇒ Numbers are equal ⇒ p = q = r = s

For x > 0

So 3P + 2q + 5r + 4s = 14

sin x < x

14P = 14 ⇒ P = 1 = q = r = s

sin x
  < 1

x
So, β 2 + 2q3 + 3r4 + s5 = 1 + 2 + 3 + 1 = 7
7 sin x
 < 7

5. Ans ( 6 ) x
7 sin x
[ ]  = 6

A ≥ H
x

RHL =  lim   + f(x) = 6

x→0
a+b+c a+b+c a+b+c
+ +
a b c 3
≥ 
x < 0

3 a+b+c
a+b+c

b+c c+a a+b sinx > x

+1+ +1+ + 1 ⩾ 9

a b c
sin x
  < 1

x
c+a
So ,  b + c + +
a+b
  ⩾  6 7 sin x
a b c   < 7

x
6. Ans ( 1 ) 7 sin x
[ ]  = 6

tan2 2x x
2
x( ) 4x2
xtan 2x 4x2
lim = lim =1 LHL = x→0
lim   f(x) = 6
x→0 tan 4xsin2 x x→0 tan 4x sin2 x 2
( ) 4x ( )x
4x x2

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8. Ans ( -3 ) 10. Ans ( 5 )
ℓn(1 + 3x) ℓn(1 − 2x)
ƒ(x) is continuous  A + B = A + 3 – B
k =  lim ( − )

x→0 x x

3 k=3+2=5
⇒  B =

ƒ(x) is differentiable 2B = 6 + A 

⇒  A = – 3

9. Ans ( 6 )
0
The given limit has form.

Using L' Hospital's rule, we have

2f ′ (x) − 6f ′ (2x) + 4f ′ (4x) 0

Limit=  lim   ( form)

x→0 2x 0

(Using L' Hospital's rule)

6f ′′ (0)
= =6
2

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