(1001CJA101021230035) Test Pattern

CLASSROOM CONTACT PROGRAMME JEE (Main)

PART TEST
(Academic Session : 2023 - 2024)
06-01-2024

JEE(Main+Advanced) : ENTHUSIAST COURSE [PHASE : S, TRAS, I(A) & I] (SCORE-I)

ANSWER KEY PAPER-1 (OPTIONAL)
PART-1 : PHYSICS
Q. 1 2 3 4 5 6 7 8 9 10
A. C D D D D A A A B A
SECTION-I
Q. 11 12 13 14 15 16 17 18 19 20
A. C D A A D C D B D A
Q. 1 2 3 4 5 6 7 8 9 10
SECTION-II
A. 1200 20 10 6 90 6 4 17 50 2

PART-2 : CHEMISTRY
Q. 1 2 3 4 5 6 7 8 9 10
A. C B B D C B C C C B
SECTION-I
Q. 11 12 13 14 15 16 17 18 19 20
A. A D B B C C A A A B
Q. 1 2 3 4 5 6 7 8 9 10
SECTION-II
A. 7 4 6 56 100 1 257 5 27 3

PART-3 : MATHEMATICS
Q. 1 2 3 4 5 6 7 8 9 10
A. C C A B A C B C A C
SECTION-I
Q. 11 12 13 14 15 16 17 18 19 20
A. A B C C D C A B C A
Q. 1 2 3 4 5 6 7 8 9 10
SECTION-II
A. 60 8 1 9 1 2 11 1 38 4

HINT – SHEET
PART-1 : PHYSICS 5. Ans ( D )
SECTION-I I=
V
, R1 = ρ4L20 , R2 = ρL02 ,, R3 = ρ2L20
R 2L0 8L0 4L0
1. Ans ( C )
I1 : I2 : I3 = 1 : 16 : 4
heg
F = Pavg ⋅ Area = (P0 + )A
2
6. Ans ( A )
= (1105 + 6 × 103 + ×10) × 120 × 12
= 2.3 × 108 N F = ΔP × A

2. Ans ( D ) 1 2 2
= {(V
2 − V1 ) A
Mg kx 2
= 1
A1 A2 = × 1.29 × (251)2 − 2252 ) × 24
40 × 10 × 15 2
1
x= = m = 6.25 cm
1600 × 16 16 = 1.92 × 105 N
4. Ans ( D )
mg = A × 0.1 × eg
(m + Ahe)g = A × 0.3 × eg
h = 0.2 m = 20 cm
1001CJA101021230035 HS-1/10
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7. Ans ( A ) 10. Ans ( A )
p 1mm Force of attraction between the plates
LC = = = 0.01 mm
N 100 Q2 CV 2 ε0 AV 2
The instrument has a positive zero error, = = =
2ε0 A 2d 2d 2
e = +n(LC) = + (6 × 0.01) = +0.06 mm at eql.
ε0 AV 2
Linear scale reading = 2 × (1mm) = 2mm kx =
2d 2
2
Circular scale readings 62 × (0.01 mm) = 0.62 mm ε0 AV 2 8.85 × 10−12 × 8.85
× 1002
⇒x= =
2d 2 k 2
2 × (10−3 ) × 1
∴ Measured reading = 2 + 0.62 = 2.62 mm
⇒ x = 0.01m = 1cm
True reading = 2.62 – 0.06 = 2.56mm.
12. Ans ( D )
8. Ans ( A ) L2 k1 ε0
C1 =
D2 d
V olume = 4π = πD2
4 πL2 ε0 2
C2 = k
4 d
= 3.00 × (20.0 ± 0.1)2 C1 = C2
0.1
2 πk2
= 3.00 × (20.0)2 [1 + k2 =
20.0
]
4
4 12
0.2 k2 = ( k1 ) = ( )
= 1200 (1 ± )
π π
20.0
13. Ans ( A )
0.2
= 1200 ± 1200 × Let VP = 0 and VQ = V
20.0
Using KCL at Q
= 1200 ± 12 mm2 −3 − V 6−V −9 − V
+ + =0
2 4 8
9. Ans ( B ) – 12 – 4V + 12 – 2V – 9 – V = 0
−EC1 + EC2 + OC2 7V = – 9
EMN =
C1 + C2 + C2 V = ( – 9/7)
E (1 − C1 /C2 ) 6 − (−9/7)
E (C2 − C1 ) ∴I= = 1.82A
= = 4
C1 + 2C2 C1 /C2 + 2
14. Ans ( A )
( 1 − C1 /C2 )
EMN = E = 9.s
2 + C1 /C2 ) = 0.4
(
9+s
1−2 9s – 0.45 = 3.6, s = 0.42
(P) EMN = 100 × = 25 × −1 = −25V
2+2 3 × 0.42 = (I – 3) 9
1−1 I = 3.14 A
(Q) EMN = 200 × =0
2+1
16. Ans ( C )
1−3 τ1 = RCeq = R. C
(R) EMN = 100 × = −40V
2+3 C
⎛ 2C × 2 ⎞

1−4 −3 τ2 = R
(S) EMN = 200 × = 200 × = −100V ⎝ 2C + C /2 ⎠
2+4 6
2 2
= R ( C ) = × 0.72 = 0.29 sec
5 5

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 Enthusiast Course/Phase-S, TRAS, I(A) & I/Score-I/06-01-2024/Paper-1
17. Ans ( D ) 8. Ans ( 17 )
Resistance of heater
(RH) = V2 = 100 × 100 = 10Ω
P 1000
Current in the circuit is
100
I=
10R
10 + (10+R)

∴ Current in heater is
R 100 R
IH = I × = ×
(10 + R) [ 10 + 10R
]
(10 + R)
(10+R)
10R 5R
= =
[ 1+ R
] (10 + R) (5 + R)
(10+R)

∴ Q = IH2 × 10
25R2
Or × 10 = 62.5 (given) q q
(5 + R)2 20 − − 10 − = 0
3 7
Which gives R = 5 Ω . 10
q× = 10
Hence the correct choice is (D) 21
PART-1 : PHYSICS q = 21µC
SECTION-II 21
Va − − 10 = Vb
3
4. Ans ( 6 )
U1 = U2 va – vb = 17 V
1 1
CV 2 = (kC) V ′2 9. Ans ( 50 )
2 2
V 12 20 division of vernier scale = 39 mm
V′=( ) = = 6V
√
k √4 1 division of vernier scale = 39 = 1.95mm
20
5. Ans ( 90 ) LC of main scale = 1mm
Q CV ∴ LC of instrument = 2 – 1.95 = 0.05 mm
(i0 )lebaze = =
ρKε0 ρKε0
−12
2 × 10 × 400 10. Ans ( 2 )
=
200 × 50 × 8.85 × 10−12 πD2 4V 2ΔD Δv
V = × v; = +
4 V D v
= 903 µA = 9 mA
4V ΔV ΔD Δv
u= ; =2 + × πD2
6. Ans ( 6 ) πD2 V D 4V
3Rx 2V ΔD 2V πD2
+ 2R + 2R = x ΔV = +
3R + x 4
D
⇒ x = 6R
dΔV −2V ΔD ΔV πD
7. Ans ( 4 ) =0= +
dD D 2 4
ε
I1 = 1/3
8V ΔD
R1 3
D = ; D = 2( V ΔD )
I1 R + R3 πΔv πΔv
= 1 =4
I2 R1 1/3
ε 10π × 5 × 10−3
I2 = = 2( ) = 2 cm
R1 + R3 π × 0.05
1001CJA101021230035 HS-3/10
 Target : JEE (Main + Advanced) 2024/06-01-2024/Paper-1
PART-2 : CHEMISTRY 11. Ans ( A )
SECTION-I The balanced equation is:
3CH3CH2OH + 2K2Cr2O7 + 8H2SO4 →
2. Ans ( B )
3CH3COOH + 2Cr2(SO4)3 + 2K2SO4 + 11H2O
i = 1 + α (2 – 1)
∧M ∧M From the amount of K2Cr2O7 required to react
α= ∞ ∴i−1= ∞
∧M ∧M with the blood sample, we can calculate the mass
∞
log ∧M − log ∧M = log(i − 1) of ethanol
8. Ans ( C ) (CH3CH2OH) in the 10.0 g sample of blood.
n = 2 for this reaction (lead goes from First, calculate the moles of K2Cr2O7 reacted.
0.07654 mol K2 Cr2 O7
Pb → Pb2+ in PbSO4) × 4.23 mL
100 mL soln
E = Eo −
0.0591
log
1 = 3.238 × 10 – 4 mol K2Cr2O7
2 [H + ]2 [HSO−4 ]
2
Next, using the mole ratio from the balanced
0.0591 1
= 2.04V − log equation, we can calculate the mass of ethanol
2 (4.5) (4.5)2
2
that reacted.
E = 2.04 V + 0.077 V = 2.11 V
3.238 × 10 – 4 mol K2Cr2O7 ×
9. Ans ( C ) 3 mol ethanol 46.068 g ethanol
×
Δ Hr = 2( Δ Hf)SO2 + ( Δ Hf)CO2 – ( Δ Hf)CS2 2 mol K2 Cr2 O7 1 mol ethanol
– 275 = 2 × ( – 75) + x – 25, x = – 100 = 0.02238 g ethanol
10. Ans ( B ) The percent ethanol by mass is:
Calculation of van’t Hoff Factor % by mass ethanol
0.02238g
Normal molecules weight calculated from = × 100% = 0.224%
10.0g
formula = 6 × 12 + 5 + 16 + 1 = 94 This is well above the legal limit of 0.1 percent
Observed molecular mass by mass ethanol in the blood. The individual
1000Kf w 1000 × 1.85 × 0.658
= = = 161.84 should be prosecuted for drunk driving.
ΔT W 0.215 × 35
mormal mol. mass 17. Ans ( A )
van’t Hoff factor (i) =
observed mol. mass ΔrG = ΔrGº + RT ln Qp
94
=
161.84 ΔrGº = ΔrHº – T . ΔrSº
Calculation of Degree of association
300(2 × 210 − 205 − 190)
Number of particles after association ⇒ 2 × 90.5 – 1000
= 183.5kJ/mol
i=
Number of particles for no association −5 2
5750 (10 )
If x be the degree of association, we have ΔrG = 173.5 + log
1000 (10−4 )(10−2 )
2C6 H51 OH ⇌ (C6 H5 OH )
1−x
ΔrG = 150.5 kJ/mol
x/2
2
∴ Number of particles on association PART-2 : CHEMISTRY
= 1 – x + x/2 = 1 – x/2 SECTION-II
Number of particles for no association =1
1. Ans ( 7 )
94 1 − x/2
∴i=
161.84
=
1 w = – 1 × 5 – 10 × 1 ℓ n2 + 1 × 10
2
Hence x = 0.838 or Phenol is 83.8% associated = – 10 ℓ n2 = – 10 × 0.7 = – 7 atm – ℓ .
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2. Ans ( 4 ) 7. Ans ( 257 )
Percentage carbon In the electrolysis of aqueous sodium chloride,
144
= × 100 = 40 H2O is reduced in preference to Na+, and Cl – is
144 + m + 35.5 (10 − m)
∴m=4 oxidized in preference to H2O. The anode
3. Ans ( 6 ) reaction is 2 Cl – → Cl2 + 2 e – , and the cathode
V2 reaction is
Δ S = nR ln
V1
2 H2O + 2 e – → H2 + 2 OH – .
= 1 × 8.314 × ln 2 = 8.314 × 0.7
The overall reaction is:
= 5.82 JK – 1 = 6 (nearest integer)
2 H2O(l) + 2 Cl – (aq) →
4. Ans ( 56 ) Cl2(g) + H2(g) + 2 OH – (aq)
CaCO3 → CaO + CO2
From the 1 : 1 mol ratio between Cl2 and H2 in
4 mol 4 mol the overall balanced reaction, if 257 L of Cl2(g)
n 50 50
CO2 = 2 × × = 0.5 mol is produced, then 257 L of H2(g) will also be
100 100
2KOH + CO2 → K2CO3 + H2O produced because moles and volume of gas are
1 mol 0.5 mol directly proportional at constant T and P
wKOH = 1 × 56 = 56 g 8. Ans ( 5 )
10HI + 2KMnO4 + 3H2SO4 → 5I2 + 2MnSO4 +
5. Ans ( 100 )
specific conductance K2SO4 + 8H2O
cell constant =
observed conductance 9. Ans ( 27 )
Given conductance of KCl = 2 × 10–3 1 mole of molybdenum(III) compound loses 3 moles
1
Observed conductance of KCl = mho of electrons on oxidation while 1 mole of
165
2 × 10−3 permanganate accept 5 moles of electrons in acidic
∴ cell constant = = 0.33 cm−1
1/165
medium.
specific conductance of NaCl = cell constant x obs.
Amount of MnO4 – in 27.50 cm3
conductance
= 27.5 × 10 – 3 × 0.02 = 5.50 x 10 – 4 mol
= 0.33 × 1/330 = 10–3 ohm–1 cm–1 Amount of Mo = 5/3 × 5.50 × 10 – 4
∴ Eqvt conductance of NaCl = 9.17 × 104 mol
= sp. conductance × 100 Mass of Mo = 95.9 × 9.17 × 10 – 4
N
10−3 × 1000 = 8.80 × 10 – 2 g
= = 100
0.01 % Mo = (8.80 × 10 – 2/0.330) × 100
= 26.7 %
1001CJA101021230035 HS-5/10
 Target : JEE (Main + Advanced) 2024/06-01-2024/Paper-1
PART-3 : MATHEMATICS 6. Ans ( C )
SECTION-I
1. Ans ( C )
lim f(x) ⩾ f(1)
x→1−

b ⩾ 81

2. Ans ( C )
Rolle's theorem is applicable in [ – 1, 1]
f '(c) = 0
∴c=0

3. Ans ( A )
Statement-II is obviously true.
2 −2 x1
= ax1 + 1 and 2 = a =
x1 x1 x 1−0
Also, for f(x) = 2cosx + 3sinx
−2 2 − x1 −1
−1 2 ⇒ 2
= ⇒ x1 = 4 ⇒ a =
= √ 13 sin(x + tan ), x1 x21 8
3
x 2 −1
g (x) = sin−1 − tan−1 . a∈( , 0) ∪ (0, ∞)
√13 3 8

Hence, Statement-I is true. 7. Ans ( B )

4. Ans ( B )
π 3π
A = {−1, 1, √ 2, √ 3, 2} , B = { , }
4 4
Total number of onto functions are
25 – 2C1 = 30
5. Ans ( A )
2 1 1
8. Ans ( C )
2
y − 2xy + 1 = 0 ⇒ y = x ±
3 3 3 √
x −1 1 dy −1
xy = 1 ⇒ y = ⇒ =
x dx x2
ln y = 3 ln(x ± √x2 − 1)
P (x1 , y1 ), x1 ≠ 0
y1 ±3
= ⇒ (x2 − 1)y12 = 9y 2 MN = x21 > 0
y √ x2 −1

⇒ xy1 + (x2 − 1)y2 = 9y log2 (1 + 5a − a2 ) > 0 ⇒ 1 + 5a − a2 > 1

x2 − 1 x ⇒ a ∈ (0, 5)
⇒ ⋅ y2 + ⋅ y1 = 9
y y

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9. Ans ( A ) Part-4 :

Part-1 :

x2 + y2 = 5
a √
Let PQ = x then, = 5 cos θ; b = √5 sin θ
2
4−x 4−x Let f(q) be perimeter f(θ) = 2a + 2b
BP = ; PS − tan 60∘
2 2 f(θ) = 2√5(2 cos θ + sin θ)
√3(4 − x)
= f ′ (θ) = 2√5(−2 sin θ + cos θ)
2
Area A of rectangle = 3 (4 − x)x
√
f ′′ (θ) = 2√5(−2 cos θ − sin θ)
2 1
dA √3 f ′ (θ) = 0 tan θ =
= (4 − 2x) = 0; x = 2 2
dx 2 f"(θ) < 0 f(θ) is greatest
d2A
= −√ 3 < 0 a=4 b=1
dx2
A is maximum, when x = 2 a3 + b3 = 65
√3 10. Ans ( C )
Maximum area − 2.2 = 2√3
2
y = sin(x + y)
Square of maximum area = 12
y ′ = cos(x + y) (1 + y ′ )
Part-2 :
cos(x + y)
Dimension of box is x, 2x, h y′ =
1 − cos(x + y)
72 = x.2x.h; x2h = 36 Given
Surface area = 4x2 + 6xh cos(x + y)
=
1
6 × 36 1 − cos(x + y) √ 2−1
S = 4x2 + 1
x ⇒ cos(x + y) =
dS 216 8(x3 − 33 ) √ 2
= 8x − =
dx x2 x pair of (x, y) ≡
for least S, x = 3
π 1 1 π 1 1
6 × 36 ( − , ) , ( 2π + − , )

Surface area = 4 × 32 + = 108 4 √2 √ 2 4 √2 √ 2

3
π 1 1 π 1 1
Part-3 : ( 2π − + , − ), ( 4π − + , − )
4 √2 √2 4 √2 √2

x + y = 60 x3y is maximum (
−π
+
1
, −
1
), ( −2π −
π
+
1
, −
1
)
4 √2 √2 4 √2 √2

f(x) = x3y = x3(60 – x) 1 1 1 1

π π
( −2π + − , ) , ( −4π + − , )

f '(x) = 4x2 (45 – x) 4 √2 √ 2 4 √2 √ 2

n n
8
f(x) is maximum at x = 45 ∑ |αk | = 16π ∑ |βk | =
k=1 k=1 √ 2
1001CJA101021230035 HS-7/10
 Target : JEE (Main + Advanced) 2024/06-01-2024/Paper-1
11. Ans ( A ) 14. Ans ( C )
⎧
⎪ xk sin( 1x ) x≠0 h(x) = x f(x) + g(x)
⎨ differentiable if k > 1.
⎩
⎪ 1 1
0 x=0 h′ (x) = f(x) + f ′ (x) + ( g ′ (x) = )
f ′ (g(x)) f ′ (g(x))
12. Ans ( B ) 1
h′ (1) = f(1) + f ′ (1) +
⎡
1−cos(1−tan( π4 −x)) f ′ (g(1))
,x > 0
f (x) = ⎢
⎢
x2 = 2 + 2 + 1 = 5.
⎢
λ sin 4x
⎣
x
, −1 < x < 0 15. Ans ( D )
R.H.L. p(x) has 2024 zeroes in ( – ∞ , 1)
1 − cos(1 − tan( π4 − x))
∴ Using Rolle's theorem p'(x) also has all zeros
lim+ f (x) = =2
x→o x2
in ( – ∞ , 1)
L.H.L.
Now, f'(x) = p(ex)
λ sin 4x
lim = 4λ
x→o− x f"(x) = p'(ex) ex
if continuous,
But ex > 1 ∀ x > 0
4λ = 2 So, f'(x) and f"(x) have no zeroes in (0, ∞ )
1
λ= 16. Ans ( C )
2
1 1
f (0) = 2 y = g(x) is not differentiable at x = ,
2 3

2 (f (0) + λ) = 5 and y = f(x)· g(x) is differentiable

1 1
13. Ans ( C ) ⇒ f( ) = f ( ) = 0
2 3
f(x) = a0 + a1x + a2x2 + a3x3 + a4x4 + a5x5 + a6x6 17. Ans ( A )
f (x) tan−1 x
Lim(1 + ) =1 Put =θ
x→0 x3 n

⇒ a0 = a1 = a2 = a3 = 0 x = tan nθ

1/x θ→0
f (x)
Lim (1 + ) = e2
x→0 x3 tan nθ − n tan θ
lim
Lim e ( a4 +a5 x+a6 x2 )
= e2 ⇒ a4 = 2
θ→0 n sin θ − tan nθ
x→0
use series expansion,
4 5 6
f (x) = 2x + a5 x + a6 x 6n2
2− 2n2 2 − f (n) 1+2n2
f (n) = ; =
f ′ (x) = x3 (8 + 5a5 x + 6a6 x2 ) f ′ (1) = 0, 1 + 2n2 1 + f (n) 3
1+2n2
5
2 × 5 × 6 × 11
f ′ (2) = 0 ∑ 2n2 = = 110
n=1
6
12 2 12 5 2 6
a5 = − , a6 = f (x) = 2x4 − x + x
5 3 5 3
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18. Ans ( B ) 2. Ans ( 8 )
2
k
f (k) = (x − (1 + cos t))2 + ( − (1 + sin t))
x
∴ f (k) is square of distance between two points

on each curve (x – 1)2 + (y – 1)2 = 1 and xy = k

For k > 0, min. value of f(k) will be square of

min. distance of from (x – 1)2 + (y – 1)2 = 1

2
= −(√2k − 1 − √2)

3. Ans ( 1 )
2 1
f ′ (x) + f ′ (x) ⋅ f((x)) =
x

Point of discontinuity = 0 = p ∴ f ′ (x) > 0 ∴ f (x) is increasing

Point of non-diff. = 1 = q
∴ (2x2 − 2) < (x2 + 2x + 1)
19. Ans ( C )
x+1 x ⇒ x2 − 2x − 3 < 0
lim (x3 ℓn ( ) + − x2 )
x→∞ x 2
1 ⇒ x ∈ (−1, 3)
x=
t
2 ln(1 + t) + t2 − 2t 1 Here, x ≠ 0, x ≠ 1
= lim =
t→0 2t3 3
∴ x=2
(Using expansion)
20. Ans ( A ) 4. Ans ( 9 )
a = 1, b = 4 Graph of y = 2f(x)
PART-3 : MATHEMATICS
SECTION-II
1. Ans ( 60 )
f (6) − f (2)
For some x ∈ (2, 6), f ′ (x) = ∴ There are total 8 roots of sin (2 f(x)) = 0 in (a, b)
6−2
100 − f (2) Also there are two roots of one in ( α , β ) and one
Now −10 ⩽ − 20 ⩽ 10
4
in ( β , γ ).
∴ 40 ⩽ 100 − f (2) ⩽ 120
∴ Total 10 roots of sin(2f (x)) ⋅ f ′ (x) = 0
⇒ f (2) ∈ [−20, 60] ∴ There are at least 9 roots of
d ′
(sin(2f (x)) ⋅ f (x)) = 0 in (a, b).
dx

1001CJA101021230035 HS-9/10
 Target : JEE (Main + Advanced) 2024/06-01-2024/Paper-1
5. Ans ( 1 ) 8. Ans ( 1 )
x3 + y 3 − 3xy = 3 … (1) f ′ (x) = x2 − 2 sec 2x

3x2 − 3y −9 Total one point of maxima in [0, 2 π ]

y′ = − ⇒ m= =3
3y 2 − 3x −3
9. Ans ( 38 )
Equation of tangent
For Lim− f (x) to exist k = 2, then
x→0
2
y = 3x – 5 ......(2) e x (ℓn(1+x)) − e2
Lim− f (x) = = e2
x→0 tan 2x − sin 3x
To find (a, b),we have to solve (1) and (2) ∴ a = e2
x3 + (3x − 5)3 − 3x(3x − 5) − 3 = 0 −b
Lim+ f (x) = = e2 ∴ b = −4e2
x→0 4
128 32
Product of roots = 2 × 2 × a = = ∴ k + a − b = 2 + e2 + 4e2 = 2 + 5e2
28 7
8 −11
⇒ a= ⇒ b= ∴ [k + a − b] = [2 + 5e2 ] = 38
7 7
6. Ans ( 2 ) 10. Ans ( 4 )
(2x + 1) (2x − k) − (x2 − kx + 2) (2)
f (x) = 2, ∀ x ∈ R f ′ (x) =
(2x + 1)2
(sin x)2 − (tan x)2 2x2 + 2x − k − 4
f ′ (x) =
Lim =L (2x + 1)
2
x→0 1 − cos(x2 )
(sin x − tan x) × (sin x + tan x) D of 2x2 + 2x – k – 4 is (+ve)
Lim 2
=L
x→0 x2
2(sin( 2 )) ⇒ 8 + 8k + 32 > 0
x3 x3
( x− −x− ) × (2x) 9
6 3 ⇒k>−
= Lim = −2 2
x→0 x4
2× 4 ∴ m = −4, |m| = 4
7. Ans ( 11 )
Solution P(a, b) is point of inflextion.
4
f ′′ (x) = 6x − 8 = 0 ⇒ x =
3
4 −281 317
∴a= ,b = ∴a−b=
3 27 27

∴ [a − b] = 11

HS-10/10 1001CJA101021230035
(1001CJA101021230036) Test Pattern

CLASSROOM CONTACT PROGRAMME JEE (Advanced)

PART TEST
(Academic Session : 2023 - 2024)
06-01-2024

JEE(Main + Advanced) : ENTHUSIAST COURSE (PHASE : S, TRAS, I(A) & I) (SCORE-I)

ANSWER KEY PAPER-2 (OPTIONAL)
PART-1 : PHYSICS
Q. 1 2 3 4 5 6
SECTION-I(i)
A. B,C A,C A,B,C B,D B,C A,B
Q. 7 8 9 10
SECTION-I(ii)
A. D D C A
Q. 1 2 3 4 5 6 7 8
SECTION-II
A. 1.00 10.00 2.37 to 2.38 0.65 to 0.68 0.20 to 0.21 9.00 6.00 3.00

PART-2 : CHEMISTRY
Q. 1 2 3 4 5 6
SECTION-I (i)
A. B,C,D A,B,C,D C,D B,C,D A,B,D A,B,C
Q. 7 8 9 10
SECTION-I (ii)
A. B A A C
Q. 1 2 3 4 5 6 7 8
SECTION-II
A. 0.00 7.00 8.00 9.00 15.55 to 15.60 6.25 4.35 20.00

PART-3 : MATHEMATICS
Q. 1 2 3 4 5 6
SECTION-I (i)
A. A,B,C,D C,D A,B,D A,C,D B,D A,B,C
Q. 7 8 9 10
SECTION-I (ii)
A. D A D A
Q. 1 2 3 4 5 6 7 8
SECTION-II
A. 0.00 5.00 20.00 6.00 6.00 2.66 to 2.67 0.00 3.00

HINT – SHEET
PART-1 : PHYSICS 2. Ans ( A,C )
SECTION-I(i) (a) At equilibrium, we have
1. Ans ( B,C )

P1 + ρ gh = P2
Area of circular shape = π x2 = 2 π y P1 = Patm + ρ wg(a – x)
Volume of liquid flowing out in dt time
P2 = Patm + ρ 0(a + h – x)
= √2gy (10 × 10−4 ) m3
⇒ ρ w(a – x) + ρ h = ρ 0(a + h – x)
So, −2πy dy = 10−3 √ 2gy dt
0 t ⇒ ( ρ 0 – ρ w)x = – ρ h = ρ 0 (a + h) – ρ wa
3
1
√2g dt, t =
20
∫ −2π × 10 y dy = ∫
2 hrs. (ρ − ρ0 )h + (ρw − ρ0 )a
27 ⇒x=
2 0 ρw − ρ0
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Fraction of the cylinder in the water 5. Ans ( B,C )

x (ρ − ρ0 ) + (ρw − ρ0 ) ha −190 + 210 × 30

21
Percentage errors in calculation of a, b and M
= =
ρw − ρ0
=
210
h
19 30 11 are
=− + =
21 21 21
(b) If x → Δ x ( Δ x > 0), the water level will Δa 0.01
× 100% = × 100% = 0.25%
a 4
rise and the oil level will drop. Δb 0.01
× 100% = × 100% = 0.5%
b 2
The rise of the water level is
ΔM 0.003
× 100% = × 100% = 1%
πR21 (a + Δaw ) − πr2 (x + Δx) = πR21 a + πr2 x M 0.3
r2
⇒ Δaw = Δx Moment of inertia about the given axis
R21
Similarly, 1
I= M ( a2 + b 2 )
2
r2
π(R22 − R21 )Δa0 = πr2 Δx ⇒ Δx0 = Δx ΔI ΔM 2aΔa + 2bΔb
R22 − R21 = +
I M a2 + b 2
The net force acting on the cylinder is
2 (4) (0.01) + 2 (2) (0.01)
= 0.01 +
Fnet = (P1 + ρ gh – P2 ) π r2 20
ΔI
× 100% = 1 + 5 {0.08 + 0.04} = 1.6%
P1 = Patm + ρ wg(a + Δ aw – x – Δ x) I

P2 = Patm + ρ 0g(a – Δ a0 – h – x – Δ x) 6. Ans ( A,B )

⇒ Fnet = ρ wg(a + Δ aw – x – Δ x) + ρ gh – ρ 0g

(a – Δ a0 + h – x – Δ x)

= ρ wg( Δ aw – Δ x) + ρ 0g( Δ a0 + Δ x)
r2 r2 Common voltage = 450
= ρw g ( − 1) Δx + ρ0 g ( + 1) Δx
R21 R22 − R21
r2 r2 ⇒k=2
= (ρw ( − 1 ) + ρ0 ( + 1)) gΔx
R21 R22 − R21
also q2 = 18 × 10 – 3 = (2C) 450)
The force will push the cylinder into the
⇒ C = 20 μ F
equilibrium position if Fnet > 0
r2 r2 initial change = (20 μ F) (1350) = 27mC
⇒ ρw ( − 1 ) + ρ0 ( + 1) > 0
R21 R22 − R21
and q1 = (20 μ F) (450) = 9mC
R21 − r2 R22 − R21 + r2
⇒ ρw ( ) < ρ0 ( )
R21 R22 − R21

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PART-1 : PHYSICS 3. Ans ( 2.37 to 2.38 )
SECTION-I(ii)

7. Ans ( D )
Time constant

T = Req × C

T = 1 sec

Charge on capacitor will be max on steady state

At steady state current through battery of 10V

FA1 x = ρV1 ω2 R, FA1 y = ρV1 g
emf
5
= μA FA2 x = ρV2 ω2 .3R, FA2 y = ρV2 g
3
5
VA + 5 − × 6 = VB
3
FA1 x − T1 sin α = ρ1 V1 ω2 R
VA – VB = 5V

qmax = 1 µc FA1 y − ρ1 V1 g − T1 cos α = 0

Charge at any time t FA2 x + T1 sin α + T2 cos α = ρ2 V2 ω2 .3R

q = (1μc) (1 − e−t/T )
FA2 y − ρ2 V2 + T1 cos α − T2 sin α = 0
Current in the branch of capacitor
dq 1
i= ⇒ i = (1μc) (e−t/T × )
( ρ – ρ 1)V1 ω 2R = T1sin α ,
dt T
PART-1 : PHYSICS
SECTION-II ( ρ – ρ 1)V1g = T1cos α ,
1. Ans ( 1.00 )
10 ( ρ 2 – ρ )V2 ω 2.3R = T1sin α + T2cos α ,
0.4 × K0 = 10 ⇒ K0 = = 25
0.4
Now, (3K0 ) × Δℓ = 30 ( ρ 2 – ρ )V2g = T1cos α – T2sin α
10
Δℓ =
25 x sin α + cos α T1
3tgα = ,x=
x cos α − sin α T2
Δℓ = 0.4 mm
T1 19
x = 1.00 x= =
T2 8

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4. Ans ( 0.65 to 0.68 ) 5. Ans ( 0.20 to 0.21 )
Since the thread is weightless and the force of ma = mg – Fb
surface tension is everywhere perpendicular to Density of ball of larger radius ρ 1 = 2 ρ
the thread, the tension force of the thread is 4ρ
Density of ball of larger radius ρ 2 =
3
constant T = const. If we take a section of After a long time, ball will acquire terminal
thread of length dl and neglect the effect of speed
gravity, then only the tension forces of the 2 2 (ρ − ρL )
V = R g
thread and the surface tension force dF act on 9 η
it. Let us approximate a section of the thread 6. Ans ( 9.00 )
with an arc of a circle of a certain radius R. In By wheatstone bridge principle, we have
the radial projection we have the equilibrium P R
=
Q X
condition R = T/20, and thus R = const, that is, RQ
or X =
the entire thread has the shape of a circular arc. P
Rmax Qmax
Since AB and CD are equal, the minimum Now Xmax =
Pmin
distance between the threads is reached at the 9000 × 1000
Xmax = = 9 × 105
middle of the height. C From the figure for 10
distances: AC = h, EF (L-d)/2. 7. Ans ( 6.00 )

V S VS
ig = × =
GS
+r G+S GS + rS + rG
G+S
2 × 50 100
= 1000
=
2000 + (90) 12000
9
div 50
Sensitivity = = = 6000 div/A = 6div/mA
ig 1
2 2 120
h L−d
R2 = ( ) + (R − ) , PART-2 : CHEMISTRY
2 2
2 2
(L − d) + h SECTION-I (i)
R=
4(L − d)
h
5. Ans ( A,B,D )
sin α = At equilibrium concentration in all three
2R
2Tcos α + 2 σ L = mg compartment = 0.2 M
mg(L − d) ∴ VA = 250 ml, VB = 500 ml, VC = 750 ml
σ=
h2 + L2 − d 2 π = 0.2 × 0.0821 × 500 = 8.21 atm
20 × 10−3 × 10 × 0.05 After adding 1 L solvent it will distribute in the
=
[(8.7)2 + 102 − 52 ] × 10−4 ratio 1 : 2 : 3 in A, B and C respectively
10−2 1
= = = 0.66 ∴ VB = 500 + 333.33 = 833.33 ml
150.69 × 10−4 1.50
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PART-2 : CHEMISTRY 2. Ans ( 7.00 )
SECTION-I (ii)
i = 1.5

9. Ans ( A ) xi = 1
x
Final mole fraction of solute
1 1.5
=
(A) Container-I reacts with Container-II 5 1.5 + (n − 1)
1.5 + (n – 1) = 7.5
n-factor of CuS = 6
n=7
KMnO4 K2Cr2O7 3. Ans ( 8.00 )
Consider it as concentration cell
1×5=x×6 1×6=x×6
0.0591 0.08
0.591 = log
5 1 Ksp /0.75
x= x=1 0.08 × 0.75
6 10 = log
Ksp
(B) n-factor of Cu2S = 8 – 12
ksp = 6 × 10
KMnO4 K2Cr2O7 6 × 10 – 12 = [Ag+] 0.75
Ag+ = 8 × 10 – 12
1×5=x×8 1×6=x×8 ∴ Ans 8
5 6 3 4. Ans ( 9.00 )
x= x= =
8 8 4 In layer M nA = x nB = y
(C) n-factor of NH4SCN = 6 x
= 0.2 ⇒ y = 4x
x+y
KMnO4 K2Cr2O7 3−y 1
In layer N +1=
1−x 0.6
5 x = 0.7, y = 2.8
x= x=1
6 WM = 0.7 × 20 + 0.7 × 4 × 40 = 126
(D) n-factor of K2C2O4.3H2C2O4.3H2O = 6 WN = 0.3 × 20 + 20.2 × 40 = 14
WM
KMnO4 K2Cr2O7 =9
WN
5 3 5. Ans ( 15.55 to 15.60 )
x= x=
8 4 RT
VA = = 20.5 lit
PART-2 : CHEMISTRY PA
∴ VB = 10.25 lit
SECTION-II
Now B → C is adiabatic
γ
1. Ans ( 0.00 ) PB V
=( C)
RT PC VB
Ecell = Ecell − |nQ 5
nF 4 V 3
=( C)
0.06 C 2 VB
=0− log( 2 ) VC
n C1 = 23/5 = 1.52
13 VB
0.06 400 VC = 1.52 × 10.25
=− log 3.25
= 0v
n VC = 15.58 lit
100

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6. Ans ( 6.25 ) 2. Ans ( C,D )
1 1
50
× 1 r must be an even integer because two
∧M = × 1000 = 100
0.2
100 1 decreasing functions are required to make it
α= =
400 4
1
∴ i = 1 + (2 − 1) = 1.25 increasing function.
4
1
π = iCRT = 1.25 × 0.2 × × 300 = 6.25 n2 n 2
12 Let y = r (n – r) = − (r − )
4 2
7. Ans ( 4.35 )
600 × 0.1 When n is odd, r = n − 1 or n+1
for
m. mol of P OP = 2 2
2
∴ mass of P OP = 145 × 30 × 10−3 = 4.35 g maximum values of y.
8. Ans ( 20.00 ) n
when n is even, r = for maximum value of y.
2
KMnO4 oxidises only C2O42– ion
3. Ans ( A,B,D )
5C2O42–(aq) + 2KMnO4(aq) + H+(aq) →
1
2Mn2+(aq) + 5CO2(g) f(x) = (x – 1)tan – 1x – ℓ n(1 + x2)
2
5
No of millimoles of C2 O2−
4 = × 20 × 0.02 = 1
f'(x) = tan – 1x –
1
2
1 + x2
Now, Cu2+(aq) + KI(aq) → Cu2I2 + I2
2Na2S2O3 + I2 → 2NaI + Na2S4O6 f'(x) > 0 ∀ x ≥ 1
No of moles of Cu2+ = 10 × 0.05 = 0.5
⇒ f(x) is increasing function
nC2 O2− 1
X= 4
= =2
nCu2+ 0.5 f''(x) > 0
PART-3 : MATHEMATICS
SECTION-I (i) ⇒ f'(x) is increasing function ∀ x ≥ 1

1. Ans ( A,B,C,D ) π π
lim f ′ (x) →
x→∞
⇒ f ′ (x) < ∀ x≥1
Differentiate w.r.t x we get 2 2

2f(x) f'(x) + 0 + 2y = 2f'(x + y) f(x + y) Using LMVT in [x, x + 4], x ≥ 1

But y = –x we get f(x) f'(x) = x + f'(0) f(0) ...(1) f(x + 4) − f(x)
= f ′ (c) for c ∈ (x, x + 4)
Put x = 0 ; y = 0 in functional equation we get x+4−x
f(0) = √ 2
∴ f(x + 4) – f(x) < 2 π ∀ x ∈ [1, ∞ )
Now f(x) f'(x) = x + f'(0) √ 2
f 2 (x) x2
4. Ans ( A,C,D )
⇒ = + √ 2 f'(0) x + c
2 2 1
f(0) = lim cos(2x cos ) = 1
Put x = 0, f(0) = √ 2 c we get c = 1 x→0 x
⇒ f2(x) = x2 + 2 + 2 √ 2 f'(0)x ℓn(1 + sin2 x) sin2 x 1
g(0) = lim .( ) . x2 =
Put x = √ 2 , f(√2) = 2 we get f'(0) = 0
x→0
2(
tan2 x
) x2 . sin2 x x2 2
x2

⇒ f(x) = √
x2 + 2

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5. Ans ( B,D ) PART-3 : MATHEMATICS
x −x
e −e 1
f(x) = + SECTION-I (ii)
2 x
′ ex + e−x 1 7. Ans ( D )
⇒ f (x) = −
2 x2 (I) We have
⇒ f'(x) = 0 ⇒ e + e = 22
x –x
x (ex + e – x) = e – y ...(1)
⇒ x = ±x1 (critical points)
Differentiate both sides w.r.t x, we get
dy
(ex – e – x) = – e – y. ...(2)
dx
Again differentiate both sides
ex − e−x 2 w.r.t x, we get
⇒ f ′′ (x) = + which is negative in
2 x3 2
d2y dy
(–∞, 0) and positive in (0, ∞) x
− (e + e −y
) =e −y −y
−e ( ) ...(3)
dx 2 dx
⇒ concave downwards in (–∞, 0) and concave
upwards in (0, ∞) ⇒ y'' – (y')2 + 1 = 0
But f(0) is not defined so no inflection point at ∴ c = 1.
x = 0.
(II) f(x) = x2 + 4 cosx + 5, x ∈ R
6. Ans ( A,B,C )
x2 x3 x4 x5
f'(x) = 2x – 4 cosx + 0 = 2(x – 2sinx)
f(x) = x + + + +
2 3 4 5 Also, f''(x) = 2(1 – 2cosx)
f(0) = 0, f'(0) = 1, f''(0) = 1, f'''(0) = 2
Now, put f'(x) = 0, we get
g(x) = f – 1(x) π π
x = α ∈ (−π, = − ), x = 0 & x = β ∈ ( , π)
Now g[f(x)] = x 2 2
g'[f(x)]. f'(x) = 1 ...(1) (using graphically or IVT)
1 ∴ x = 0 (point of local maximum)
put x = 0, g'(0) = =1
f ′ (0)
Again differentiate equation (1) and x = α , β (point of local minimum)
g''[f(x)].(f'(x))2 + g'[f(x)].f''(x) = 0 ...(2) ⇒ Total number of extremum points = 3
put x = 0 x3
(III) y =
g''(0). (f'(0))2 + g'(0).f''(0) = 0 (x − α)(x − β)(x − γ)
8 8
∴ y(x = 2) = = =2
we get g''(0) = – 1 (2 − α)(2 − β)(2 − γ) 4
Again differentiate equation (2) (IV) Put IxI = t
g'''[f(x)].(f'(x))3 + g''[f(x)]. 2f'(x) f''(x) + g''[f(x)] As x ∈ [ – 1,2] ⇒ t ∈ [0, 2]
f'(x) f''(x) + g'[f(x)].f'''(x) = 0
let g(t) = 2t3 + 3t2 – 12t + 1
put x = 0
∴ g'(t) = 6(t + 2) (t – 1)
g'''[f(0)].(f'(0))3 + g''[f(0)]. 2f'(0) f''(0) + g''[f(0)]
f'(0) + g'[f(0)].f'''(0) = 0 ∴ g(0) = 1

g'''(0) – 2 – 1 + 2 = 0 g(1) = – 6
g'''(0) = 1 and g(2) = 5, is the greatest value.

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8. Ans ( A ) PART-3 : MATHEMATICS
f(x) = cos 2x and g(x) = ex. SECTION-II
1
x2
(I) Lim (f (x)) = e−2 1. Ans ( 0.00 )
x→0
g(x) − f(x) 1
(II) Lim = f(2x) = f(3x) ∀ x ∈ R ⇒ f(x)
x→0 2x 2
(III) h(x) = ex + 1 2√ 4
for x ∈ ( – ∞ , 0], h(x) ∈ (1, 2] ⇒ f( √ 3) = f ( 3) = f ( √3) = ...
3 9
1
(IV) cos2x = in [0, 3] has 2 solutions
2 = f(0+) ⇒ 1 = f(0+)
9. Ans ( D )
2x 4
The critical points are x = – 2, 0, 2 , 2, 6 ⇒ f(x) = f (
3
) = f (
9
x) = ... f(0±) = 1
3
2 1
fmin = f ( ) = . Also the graph is horizontal
3 3 ⇒ f(x) = 1 as f(x) is continuous
in the interval (2, 6)
tan 1 − tan 1
10. Ans ( A ) ⇒ lim =0
x→0 tan2 x
ds
(I) = t3 – 6t2 + 8t
dt 2. Ans ( 5.00 )
d2s 8 4
= 3 (t2 − 4t + ) = 3 ((t − 2)2 − )
dt 2 3 3
d2s
( ) at t = 2
dt2 min

(II)

V = 1 π(1 – x)2x Let the charges for railway line be k Rs/km.

3
dv π
= (x – 1)(3x – 1) Now, total freight charges,
dx 3

T = kx + 2k √ (20 − x)2 + 75
5
ℓ = √x2 + (1 − x)2 = √
9 dT 2(x − 20)
(III) k = |x|e–x Let = 0 or k + 2k =0
dx 2
2√(x − 20) + 75

or 4(x – 20)2 = 75 + (x – 20)2

or (x – 20)2 = 25 or x = 25, 15
(IV)
or x = 15 (as AP < AB)
π π+
f( ) < f ( )
2 2 or PB = AB – AP = 20 – 15 = 5 km
a+b–2<b+2
⇒0<a<4
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3. Ans ( 20.00 ) 5. Ans ( 6.00 )
f(–x) = f(x) ⇒ f(x) is even fn Let P(x) = a0xn + a1xn – 1 + a2xn – 2 + a3xn – 3 + .... + an
–f'(–x) = f'(x) ⇒ f'(x) + f'(–x) = 0
At x = 0 2f'(0) = 0 ⇒ f(0) = 0 P(2x) = a02nxn + a12n – 1xn – 1 + .... + an
f(2 + x) = f(2 – x) P(x) + P(2x) = 5x2 – 18
⇒ function is symmetric about x = 2
f'(2 + x) = –f'(2 – x), so at x = 0, ⇒ (a0 + a02n)xn + ... + 2an = 5x2 – 18

f'(2) = –f'(2) ⇒ 2f'(2) = 0 ⇒ f'(2) = 0 ∴n=2

and also f'(2 + x) = –f'(2 – x)
replace x by 2 – x (a0 + 4a0)x2 + 2a2 = 5x2 – 18
f(4 + x) = –f'(–x) = f'(x)
5a0 = 5 and a2 = – 9
it means f'(x) = f'(4 + x)
hence f'(0) = f'(4) = f'(–4) = f'(8) = f'(–8) = 0 ∴ P(x) = x2 – 9
and f'(2) = f'(6) = f'(–2) = f'(–6) x2 − 9
lim = lim (x + 3) = 6
= f'(–10) = f'(10) x→3 x−3 x→3

hence minimum 11 roots of in f'(x) 6. Ans ( 2.66 to 2.67 )

x
= 0 in x ∈ [–10, 10] −1
⎛
2
( 1 − cos n ) ⎞
f(x) = lim tan 4x = tan−1 2x2
n→∞ x 2
Hence there are atleast 10 roots of ⎝
(
n)
⎠

2x
f''(x) = 0 in x ∈ (–10, 10) 4x2
ℓn (1 + (cos n
− 1)) 1 − cos 2x
n
g(x) = n→∞
lim − × = −x2
2 2
now consider g(x) = f'(x) f''(x) ( cos( 2x
n
) − 1) (
2x
n
)

g'(x) = (f''(x))2 + f'(x) f'''(x)

g(x) has atleast 21 roots in x ∈ [–10, 10]
Hence g'(x) has atleast 20 roots in x ∈ (–10, 10) e−2g(x) − ef(x)
2
e2x − etan
−1
2x2
lim = lim
x→0 x6 x→0 x6
4. Ans ( 6.00 )
2 −1
Continuous at x = 1 e2x ( 1 − etan 2x2 −2x2 )

= lim
∴ cos2 θ ( α 2 + 4) = 1 – 4 β 2 x→0 x6
⇒ α 2 cos2 θ + 4 β 2 + 4cos2 θ ...(i) 2x2 − tan−1 2x2
= lim 8 ( )
Continuous at x = 3 x→0 (2x2 )3
∴ 3 – 4β2 = α β – β2 – 3β2 + 2
Put 2x2 = h we get required
⇒ αβ = 1 ...(ii)
1
Use A.M. ≥ G.M. 8 (1 − )
h − tan−1 h 1+h2
= lim 8 ( ) = lim
α2 cos2 θ + 4β 2 h→0 h3 h→0 3h2
⩾ 2αβ |cos θ|
2
8 1 8
1 – 4cos2 θ ≥ 4|cos θ | = lim ( ) =
h→0 3 1 + h2 3
√ 2−1
⇒ Maximum value of cos θ =
2
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7. Ans ( 0.00 ) 8. Ans ( 3.00 )
ℓn f(x) = ℓn (x + 1) + ℓn(x + 2) ... ℓn (x + 100) f'(1) = A f''(2) = B f'''(3) = C
f ′ (x) 1 1 1 f(x) = x3 + Ax2 + Bx + C
= + ....
f(x) x+1 x+2 x + 100
f'(x) = 3x2 + 2Ax + B
Differentiating with respect to x
f''(x) = 6x + 2A
f(x)f ′′ (x) − (f ′ (x))2
(f(x))2
f'''(x) = 6
1 1 1
=( + .... )
2 2
(x + 1) (x + 2) (x + 100)2
Given g(x) = f(x) f'(x) – (f'(x))2
1 1 1
= + .... >0
2 2
(x + 1) (x + 2) (x + 100)2
So g(x) = 0 has no solution

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