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Gaseous States
1. INTRODUCTION
The various kinds of substance that make up matter can be divided roughly into three categories,
namely, gases, liquids and solids. These are called as three states of matter. These states can be considered to
arise as a result of competition between two opposing molecular forces, namely, the force of attraction
which tends to hold the molecules together, and the disruptive force due to the thermal energy of molecules.
If the disruptive forces due to thermal energy are much greater than the forces of attraction, then we have
matter in its gaseous state. Molecules in the gaseous state move with very large speeds and the forces of
attraction amongst them are not sufficient to bind the molecules at one place, with the result that the
molecules move practically independent of one another. Because of this feature, gases are characterized by
marked sensitivity of volume change with change of temperature and pressure. There exists no boundary
surface and, therefore, gases tend to fill completely any available space, i.e. they do not possess a fixed
volume. If the forces of attraction are greater than the disruptive forces due to thermal energy, we have
matter in the liquid state. Molecules in the liquid state too have kinetic energy but they cannot go very far
away because of the larger forces of attraction amongst them. Due to this feature, liquids have definite
volume, but they do not have definite shape. They take the shape of the vessel in which they are placed. In
general, liquids are denser and less compressible than gases. If the forces of attraction between molecules
are much greater than the disruptive forces due to thermal energy, the positions of the molecules remain
fixed and we have the solid state of matter. The molecules in the solid state, therefore, do not possess any
translational energy, but have only vibrational energy since they can vibrate about their mean positions.
Extremely large forces of attraction exist amongst them. That is why solids differ markedly from liquids and
gases in respect of size, shape and volume. Solids, in general, have definite size, shape and volume.
Gaseous state is the simplest state of matter. Throughout our life we remain immersed in the ocean of
air which is a mixture of gases. We spend our life in the lowermost layer of the atmosphere called
troposphere, which is held to the surface of the earth by gravitational force. The thin layer of atmosphere is
vital to our life. It shields us from harmful radiations and contains substances like dioxygen, dinitrogen,
carbon dioxide, water vapour, etc. Let us now focus our attention on the behavior of substances which exist
in the gaseous state under normal conditions of temperature and pressure.
Gases have much lower density than the solids and liquids.
The volume and the shape of gases are not fixed. These assume volume and shape of the container.
Gases mix evenly and completely in all proportions without any mechanical aid.
(i) Pressure:- It is exerted by gas due to collision of randomly moving gas molecules with the walls of the
container. Pressure can be measured in following units:
Pascal: - It is SI unit for pressure; Pascal is very small amount of pressure
2
o (10mg weight on 1cm area)
o 1 Pa = 1 N/m2
Atm: - atm is pressure exerted by mass of the atmosphere on the earth’s surface
Various units of pressure can be interrelated as follows
1 atm = 76 cm of Hg = 760 torr = 101325 Pa = 1.01325 bar
(ii) Volume :- It represents free volume available for motion of gas particles
Various units of volume are interrelated as follows
1 L = 1000 ml = 10-3 m3 = 1000 cc
Simplicity of gases is due to the fact that the forces of interaction between their molecules are
negligible. Their behavior is governed by same general laws, which were discovered as a result of their
experimental studies. These laws are relationships between measurable properties of gases. Some of
these properties like pressure, volume, temperature and mass are very important because relationships
between these variables describe state of the gas. Inter-dependence of these variables leads to the
formulation of gas laws.
Temperature-constant Temperature-constant
T = constant
Mass = constant
Mass-constant Mass-constant
P V PV
V 1/P P
T1 T1
T2 T2
(T1 > T2 > T3)
T3 log P
P T3
(T1 > T2 > T3) P T1 PV
T2 (T1 >T2 > T3)
T3 log V
1/V
V P
Charles made measurements of the volume of a fixed mass of a gas at various temperatures under the
condition of constant pressure and found that the volume of the gas is a linear function of the temperature.
Experiments have shown that when 273 ml sample of a gas at 0oC is heated to 1oC, its volume
increases by 1 ml, i.e., it becomes 274 ml. At 10oC, the volume increases to 283 ml if the pressure remains
constant in both cases. Similarly, when 273 ml sample of gas at 0oC is cooled to −1oC, its volume decreases
to 272 ml while at −10oC the volume decreases to 263 ml if the pressure remains constant.
Thus, all gases expand or contract by the same fraction of their volumes at 0oC per degree change of
temperature, i.e., for each degree change of temperature, the volume of a sample of a gas changes by the
1
fraction of its volume at 0oC.
273
Let the volume of a given amount of a gas be Vo at 0oC. The temperature is increased by toC and the new
volume becomes Vt.
V0 t
Thus, Vt V0 t = V0 1 +
273 273
273 + t
or Vt = V0 (since K = oC + 273) … Eq(i)
273
by substituting T for 273 + t and To for 273 in Eq. (i),
V T Vt V0 V
Vt 0 or or = constant (if pressure is kept constant)
T0 T T0 T
This is Charles law. It can be stated as follows:
The volume of a given amount of a gas at constant pressure varies directly as its absolute
temperature.
V T (if pressure is kept constant)
P1
P2 > P1
P2
V
Since volume is directly proportional to Kelvin temperature, the volume of a gas should theoretically
be zero at Kelvin zero. However, gases liquefy and then solidify before this low temperature is reached. In
fact, no substance exists as a gas at a temperature near Kelvin zero, through the straight-line plots can be
extrapolated to zero volume. The temperature that corresponds to zero volume is −273.15oC.
Can you guess how the graph of volume vs Temperature (0C) will look like
Example 2: A flask is of a capacity of 1 liter. What volume of air will escape from the flask if it is heated
from 270C to 370C? Assume pressure is constant.
At constant volume, the pressure of a given amount of a gas is directly proportional to its absolute
temperature.
Example 3: A certain amount of ethane is confined in a bulb of 1 liter capacity. The bulb is so weak that it
will burst if pressure exceeds 10 atm. Initially gas exerts 8 atm pressure at 270 C.
Find temperature at which the bulb will burst?
Solution: Considering limiting condition
P1 P
Since volume remain constant = 2
T1 T2
Thus 8/300=10/T2
T2 = 375 K
Suppose the gas is in the initial state with volume, V1, pressure p1and temperature T1. We then
change the state of the gas to a volume V2, pressure p2 and temperature T2. Let us carry out this
change in two steps.
(i) First we change the pressure from p1 to p2 keeping the temperature T1 constant.The resultant
pV
volume Vr as given by Boyle’s law is Vr = 1 1
p2
(ii) Next, temperature is changed from T1 to T2, keeping the pressure p2 constant. The
final volume V2 as given by Charles law is
Vr T2 p V / p T p1V1 pV
V2 = = 1 1 2 2 or = 2 2
T1 T1 T1 T2
It follows that no matter how we change the state of the given amount of a gas, the ratio pV/T
pV
always remains constant, i.e. =K
T
The value of K depends on the amount of gas in the system. Since V is an extensive property
(which is mass dependent), its value at constant p and T is proportional to the amount of the gas
present in the system. Then K must also be proportional to the amount of gas because p and T are
intensive properties (which have no mass dependence). We can express this by writing K = nR, in
which n is the amount of gas in a given volume of gas and R is independent of all variables and is,
therefore, a universal constant. We thus have the general gas law
pV = nRT
The universal gas constant R = pV/nT. Thus, it has the unit of (pressure volume) divided by (amount
of gas temperature). Now the dimensions of pressure and volume are,
Pressure = (force/area) = (force/length2) = force length−2
Volume = length3
(force length ) (length 3 ) (force length) work (or energy)
Thus R=
(amount of gas) (kelvin) (amount of gas) (kelvin) (amount of gas) (kelvin)
Thus, the dimensions of R are energy per mole per kelvin and hence it represents the amount of
work (or energy) that can be obtained from one mole of a gas when its temperature is raised by one
kelvin.
Numerical Values of R
i) In liter atmosphere = 0.0821 litre atm deg–1 mole–1 ii) In ergs = 8.314 107 erg deg–1 mole–1
iii) In calories = 1.987 cal deg–1 mole–1 iv) In Joules = 8.314 J deg–1 mole–1
Use the value of R depending on the units in which value of pressure and volume has been used in
ideal gas equation.
Example 4 : What mass of ammonia will exert same pressure as 12 g of H2S(g) in the same container
under the similar conditions of temperature?
Solution: Under identical conditions of T and V, p n
equal moles of ammonia as that of H2S(g) will exert same pressure, when confined in
the same container
Moles of H2S = 12/34 = moles of ammonia
Mass of ammonia = (12/34) 17 = 6g
Example 5: 4 g of an ideal gas was confined in a 1.0 L flask at 1.0 atm. Increasing temperature of
flask by 30oC increases gas pressure by 8%. Determine molar mass of gas.
Solution: Let the initial temperature be, TK.
1 T
Since, n and V are constants P1/T1= P2/T2 T 375 K
1.08 T 30
Ashwani Tyagi Sir 7 Code: ATJEE / ATNEET
Chemistry Gaseous States
nRT w dRT d
P= RT M= RT
V M V M P
Vapour Density
For gases another term which is often used is vapour-density. Vapour density of a gas is
defined as the ratio of the mass of the gas occupying a certain volume at a certain temperature and
pressure to the mass of hydrogen occupying the same volume at the same temperature and pressure
i.e.
PVM
W(gas) = and
RT
PV 2
WH 2 ( mol. wt.of Hydrogen is 2)
RT
Wgas M
= Vapour density of gas
WH2 2
Example 6: Determine the density of carbon dioxide gas at the sublimation temperature of 78oC
and 1.0 atm, assuming ideal behaviour of the gas.
pM 1 44
Solution: 2.75 g L1
RT 0.082 195
Example 7: Determine payload of a 1000,000 L balloon filled with He gas at 27oC and 1.0 atm.
Composition of air can be considered to be 79% N2 and 21% O2 by volume and balloon is
massless.
Solution: Moles of gas present in balloon
pV 1000,000
40650.4
RT 0.082 300
Payload = Wair Wgas = 40650.4 (Mair MHe) g
40650.4
= (28.84 4) kg 1009.75 kg
1000
The statement of Dalton’s Law is “The total pressure of a mixture of non-reacting gases is equal to the
sum of their partial pressures”.
Let a mixture of gases have amount n1 of the first gas, n2 of the second gas, and so on. Let the corresponding
partial pressures be p1, p2, …… The total pressure is given by
ptotal = p1 + p2 + ….
If the gases present in the mixture behave ideally, then, it is possible to write separately for each gas,
p1V = n1 RT (a)
p2V = n2RT (b)
Hence (p1 + p2 + …) V = (n1 + n2 + …) RT
i.e., ptotal V = ntotalRT (c)
where ntotal is the total moles of gases in the mixture. Dividing Eqs (a) and (b) by Eq. (c), We get
n
p1 = 1 p total = x1p total
n total
n2
p2 = p total = x 2 p total
n total
x1 , x2, and so on are the mole fraction of each gas respectively
Partial Pressure of a gas = Mole fraction of the gas × Total Pressure of the gaseous mixture
Dalton’s Law of Partial pressure is applicable only for non – reacting gases.
Example 8: Calculate partial pressure of nitrogen and oxygen in air assuming it to be composed of mostly
nitrogen and oxygen. Volume percentage of oxygen and nitrogen in air are 20 and 80
respectively, and atmospheric pressure to be 1.0.
Solution: Mole fraction of N2(g) = 0.8 and Mole fraction of O2(g) = 0.2
Partial pressure of N2(g) = 0.8 1 = 0.8 atm
Partial pressure of O2(g) = 0.2 1 = 0.2 atm
Ashwani Tyagi Sir 9 Code: ATJEE / ATNEET
Chemistry Gaseous States
Example 9: 0.1 mol of ethane gas and 0.3 mol of oxygen gas are taken in a flask at 27oC and 1.0 atm
pressure and sealed. Now the flask is heated to 1000 K where the following reaction
occurs quantitatively:
5
C2H6 + O2 2CO + 3H2O
2
Calculate partial pressure of each component at the end of reaction.
Solution: The balanced chemical reaction (with states specified) is
5
C2H6(g) + O2(g) 2CO(g) + 3H2O(g) at 1000 K
2
Moles at start: 0.10 0.3 0 0
Moles at end: 0 0.05 0.2 0.3
Total moles ng = 0.55
Now, applying gas laws at constant volume
p1 nT n T 0.55 1000
11 p p 2 2 1.0
2 1 nT 4.58 atm
p2 n2T2 11 0.4 300
0.05
p 4.58 0.416 atm
O 0.55
2
0.2
p CO 2 4.58 1.664 atm and
0.55
0.30
p 4.58 2.5 atm
H O 0.55
2
Dalton’s law is used to calculate the pressure of a dry gas when it is (Gas + Water vapour)
collected over water at atmospheric pressure. By Dalton’s law.
If a tiny hole is made in the wall of a vessel containing a gas, then the rate at which gas
molecules leak out of vessel will be proportional to the number of molecules that collide with unit
area of the wall in unit time.
Diffusion is the tendency of any substance to spread throughout the space available to it.
Diffusion will take place in all direction and even against gravity. So gases diffuse through firm
substances and through small holes. The streaming of gas molecules through a small hole is called
effusion
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Chemistry Gaseous States
Schottish physical chemist, Thomas Graham’s research on the diffusion of gases was triggered
by his reading about the observation of Germen chemist Johan Dobereiner that Hydrogen gas effused out of
a small crack in a glass bottle faster than the surrounding air diffused in to replace it. Graham measured the
rate of effusion of different gases experimentally through very fine tube. In this way he slowed down the
process, so that it could be studied quantitatively.
He plotted the following graph for complete effusion of 100 ml of different gases at 25oC.
According to Graham the rate of diffusion (effusion) of a gas at constant P&T is inversely proportional
to square root of its molecular mass.
1 r M
r at constant P & T 1 = 2 at constant P & T
M r
2
M
1
The above Equation is applicable only if two said gases are at same temperature
and pressure, effusing through openings of identical geometry. The two gases
may be in the combined system if they are non-reacting and at the same partial
pressure.
If a gaseous mixture consists of several components of different molar masses and at different partial
pressure as well, initial rate of effusion of a component will depend on both molar mass and their partial
pressure as
1
ri pi and r
i M
i
p
r i , if rate of effusion is linearly related to its partial pressure.
i M
i
r1 p M2
Under the above conditions, 1
r2 p2 M1
Example 10: Rate of effusion of ethane is 1.53 times faster than rate of a hydrocarbon containing 14.27%
hydrogen by weight, under identical conditions. Deduce the molecular formula of
hydrocarbon.
r (ethane) M
Solution: 1.53 M 70.23
r (hydrocarbon) 30
Empirical formula C H
Wt.% 85.73 14.27
Mol % 85.73 / 12 14.27
SR 1 2
Empirical formula = CH2 ;
Example 11: Ammonia gas and HCl gas from the two flasks, at same temperature and pressure were
injected simultaneously through pinholes of similar geometry, attached at the two ends of a
1.0 m long glass tube. At what distance from the ammonia end, the first flash of white fume
would be observed?
Solution: Since, the two gases are injected at same pressure, their rate of effusion will depend only on
molar mass and ammonia being the lighter than HCl, will move at faster rate as illustrated
in the following diagrams:
100 cm
NH3 HCl
x cm
r NH 3 x 36.5
x 59.43 cm
r HCl 100 x 17
Example12 : Diffusion of a certain volume of N2(g) at 1.0 atm and 300 K, takes 25s, while same volume of
an unknown gas of Xenon and Fluorine at 2.0 atm and 300 K takes 34 s for diffusion through
the same pinhole. Deduce the molecular formula of the unknown gas.
1
Solution: Rate
time
r N 2 34 PN 2 M 1 M
M = 207.15
r gas 25 Pgas 28 2 28
Since atomic mass of Xe = 131, the gas cannot contain more than one Xe atom per
molecule.Hence, the molecular formula of unknown gas could be XeFn.
207.15 = 131 + 19 n x = 4 and gas is XeF4.
Ashwani Tyagi Sir 12 Code: ATJEE / ATNEET
Chemistry Gaseous States
Instantaneous rate of effusion will depend on the instantaneous partial pressure of that
component, which decreases continuously with progress of effusion. Considering, instantaneous rate of
decrease of partial pressure (−dp/dt) to be directly proportional to instantaneous gas pressure and inversely
proportional to square root of molar mass, instantaneous pressure at any time can be solved as
dp Kp
where K is constant of proportionality,
dt M
p2 t
dp K p Kt Kt
= dt ln 1 = or p2 = p1 exp
p1
p M 0 p2 M M
p ln p
t t
Example13: Pressure of nitrogen gas falls from 4000 mm to 2000 mm in 30 min, when allowed to effuse
through a pinhole in the cylinder. If the same cylinder is filled with an equimolar mixture of
N2 and He gas at 4000 mm of Hg, what would be the molar ratio of gases (N2 / He) in the
cylinder after 1.0 hour? Assume rate of decrease of pressure as linear function of gas
pressure.
Solution: Since, initially equal moles of gases are present, initial partial pressure of both N2 and He is
2000 mm of Hg. Also
dP KP p1 K1t
ln
dt M p2 M
4000 30K
For N2(g): ln … (i)
2000 28
In mixture: For N2 :
2000 60 K
ln … (ii)
p N 28
2
2000 60 K
For He: ln … (iii)
pHg 4
Solving Eqs. (i), (ii) and (iii), pN2 = 500 mm : pHe = 51 mm of Hg
Molar ratio after 1.0 hour (N2 : He) = p N 2 : pHe = 500 : 51
A polyatomic gas may remain in either pure form or it may remain in partially dissociated or associated
form. Dissociation or association alter the average molar mass of gas mixture compared to its pure form and
hence, their rates of effusion. To illustrate, let us consider one mole of PCl5(g) confined in a flask. If it is
considered to be 100% pure, its mass will be 208.5 g. In actual practice, PCl5(g) always remains in
equilibrium with some of its dissociation products
Due to the above dissociation, moles have changed from 1.0 to (1 + α), but the mass remains same,
208.5 g.
Hence, in case of dissociation, average molar mass of mixture decreases compared to molar mass of pure
gas, therefore, rate of effusion of partially decomposed gas mixture is always greater than the rate of
effusion of a pure gas.
In case of association, number of moles decreases and hence, molar mass of partially associated gaseous
mixture is always greater than molar mass of pure gas as
2NO 2 N 2 O4
α
Total mole = = 1 1 Mmix > M NO2
2
1 /2
Thus, if a gas undergoes partial association, its rate of effusion will be less than the rate of effusion of pure
gas (without considering any association).
Example 14: Rate of effusion of ethane gas is 1.9 times, the rate of effusion of a partially decomposed
Cl2O7 (g) mixture. Determine the degree of dissociation of Cl2O7 (g).
rC2 H 6 M mix M Cl2O7 183
Solution: 1.9 M mix 108.3 = 0.197
rmix 30 1 3.5 1 3.5
When a gaseous mixture containing lighter and heavier components is allowed to pass through several
diffusion chambers connected in series, there occur enrichment of lighter component in each successive
step. By carrying out diffusion of a gaseous mixture for a specific number of steps in succession, a specified
enrichment of lighter component can be achieved as follows:
1 2 3 4 n
A, B
rA n A MB n
From the 1st chamber: = = A
rB 1 n B 1 M A n B 2
2/ 2
nd rA nA MB n M n
From the 2 chamber: = = A B = A
rB 2 n B 2 M A n B 1 M A n B 3
3/ 2
rd rA nA MB n M n
From the 3 chamber: = = A B = A
rB 3 n B 3 M A n B 1 M A n B 4
n1
r n MB n M 2 n
Similarly, from (n1)th chamber: A = A = A B = A
rB n 1 n B n 1 M A n B 1 M A n B n
n1
r n M 2 n
A = A B = A
rB n 1 n B 1 M A n B n
This Equation indicates that after (n 1)th step of diffusion a specific enrichment (nA/nB)n can be achieved in
the nth chamber.
Example 15: A sample of Ne is originally 10% by mole in Ne20 isotope and remaining are Ne22
isotope. In how many steps of effusion, 25% enrichment of Ne20 can be achieved?
Ne 20 10 1
Solution: Initially 22
Ne 90 9
Ne 20 25 1
Desired ratio : 22
Ne 75 3
n 1
1 22 2 1 n 1 22
Applying equation : log log 3 n 24
9 20 3 2 20
2.8 Eudiometry
Eudiometry or “gas analysis” involves calculations based on gaseous reactions in which at least two
components are gases & their amount is given in terms of volumes measured at same pressure &
Temperature. The relationship amongst gases, when they react with one another, is governed by two laws,
namely Gay-Lussac law and Avogadro’s law.
Avogadro’s Law
In 1812, Amedeo Avogadro stated that samples of different gases which contain the same
number of molecules (any complexity, size, shape) occupy the same volume at the same temperature
and pressure. It follows from Avogadro’s hypothesis that V n (when T and P are constant).
Gaseous reactions for investigation purposes are studied in a closed graduated tube open at one end
and the other closed end of which is provided with platinum terminals for the passage of electricity
through the mixture of gases. Such a tube is known as Eudiometer tube and hence the name
Eudiometry also used for Gas analysis.
During Gas analysis, the Eudiometer tube filled with mercury is inverted over a trough
containing mercury. A known volume of the gas or gaseous mixture to be studied is next introduced,
which displaces an equivalent amount of mercury. Next a known excess of oxygen is introduced and
the electric spark is passed, whereby the combustible material gets oxidised. The volumes of carbon
dioxide, water vapour or other gaseous products of combustion are next determined by absorbing
them in suitable reagents. For example, the volume of CO2 is determined by absorption in KOH
solution and that of excess of oxygen in an alkaline solution of pyrogallol. Water vapour produced
during the reaction can be determined by noting contraction in volume caused due to cooling, as by
cooling the steam formed during combustion forms liquid (water) which occupies a negligible
volume as compared to the volumes of the gases considered. The excess of oxygen left after the
combustion is also determined by difference if other gases formed during combustion have already
been determined. From the data thus collected a number of useful conclusions regarding reactions
amongst gases can be drawn.
General Assumptions: In all problems, it is assumed that the sparking occurs at room temperature. This
implies that water formed would be in liquid state and that nitrogen gas is inert towards oxidation. Also,
if a gas is added externally, it will be assumed to be in excess unless otherwise stated.
A known amount of hydrocarbon is taken into an Eudiometry tube. O2 gas is then inserted to cause complete
combustion of hydrocarbon & the reaction mixture is cooled back to the original room temperature. This
gives 1st volume contraction VIC. The resultant gaseous mixture is then passed through alc.. KOH which
gives second volume contraction VII c. These data can help to calculate the molecular formula of the
hydrocarbon as explained below.
y y
C x H y x O 2 xCO 2 H 2O
4 2
Example 16: A gaseous hydrocarbon requires 6 times its own volume of O2 for complete oxidation
and produces 4 times its volume of CO2. What is its formula?
du, for a gas of molar mass (M) depends only on temperature. Hence, for a
given temperature, this fraction is constant. A plot of fraction of molecules Speed
1 dNu
in the speed range u and u + du, N du vs u is described in the
graph.
The peaks in the curve correspond to a speed, which is possessed by maximum fraction of molecules, called
“most probable speed”.
(ii) The total area under the curve in Figure is a measure of total number of molecules in collection
X
(iv) Distribution of molecular speed also depends upon the Fraction
Y
of the
mass of gas molecule. At similar temperature, a heavier Molecule
gas molecule has a narrow distribution of speeds than a
lighter gas molecule as shown in the following diagram
Speed
(MX>MY): For a given number of mole and temperature but diffrent gas
As per kinetic theory of gases, each molecule is moving with altogether different velocity. Let ‘n’
molecules be present in a given mass of gas, in which n1 molecules have a speed of v1, n2 molecules
have a speed of v2, ,nn molecules have a speed of vn.
The average velocity or Uav = average of all such velocity terms.
n u n2u2 n3u3 ........ nnun
Average velocity = 1 1
n
8RT
Using Maxwell distribution average velocity is determined as Uav =
πM
Another mean velocity proposed by Maxwell was Urms as the square root of means of square of all
such
velocities.
3RT
Using Maxwell distribution rms velocity is determined as Urms =
M
2RT
Most probable speed is the velocity which is possessed by maximum no. of molecules. Vmp =
M
2RT 8RT 3RT 8
Furthermore Ump : Uav : Urms : : : : = 2 : : 3 =1 : 1.128 : 1.224
M πM M π
Also Uav = Urms 0.9213
For calculating Vrms, Vmp, or Vav by above relations the value of M should be used in kg/mole
and R should be taken as 8.314 J/K mole to get velocity in m/s.
Example 17: Derive an expression relating to increase in Urms of a gas for a relatively small
temperature rise and calculate increase in urms for a sample of Ne(g) as the temperature is
increased from 100 K to 101 K?
3RT durms 3R 1 3R 1 3R
Solution: urms
M dT M 2 T 2M 3RT 2 Murms
M
3R 3R
du rms dT u rms T
2Mu rms 2Mu rms
3RT 3 8.314 100
urms 353 ms1
M 20 10 3
3 8.134
urms 3
(101 100) 1.766 ms1
2 20 10 353
Imagine a cube of edge-length l, containing N molecules, each having a mass of m. Molecules are moving at
random in all directions, with speed covering a considerable range of
values. G C
The velocity u1 of any molecule may be resolved into three-component
H
velocities designated as ux, uy and uz.. These are in the three directions at D
right angles to each other and parallel to the sides of the cube as shown in
uz
figure. The component velocities are related by the expression u
2 2 2 2 ux
u1 = u x u y + u z … (1) uy
F B
Considering the x-component motion of a molecule, we will have
Momentum of molecule before collision with the side ABCD = mux.
E
Momentum of the molecule after collision with the side ABCD = − mux. l A
Change of momentum of the molecule in a single collision with the side ABCD = |2mux|.
Since l is the edge length of the cube, the molecule has to travel a distance 2l to arrive back at the wall
ABCD. The number of collisions per unit time with the wall ABCD will be equal to ux /2l.
2
u x mu x
The total change of momentum per unit time due to such impacts is 2mu x
2l l
Example 18: Calculate the pressure exerted by 1025 gas molecules each of mass 1022 g in a container of
volume 1.0 dm3. The root mean square speed is 105 cm s1.
1 1 1 1
Solution: pV mN u 2 p 10 25 kg 10 25 (103 ms 1 ) 2 3 3 109 Pa
3 3 10 m 3
Example 19: A two litre bulb contains 3 1023 gas molecules and exert 106 Pa pressure. Calculate
translational energy per molecule and total translational energy.
pV 106 2 103 6.022 1023
Solution: pV = nRT T 483K
nR 3 1023 8.314
3 3
E trans k b T 1.38 1023 483 1020 J / moleule
2 2
3
Etrans (Total ) kb TN 3000.25 J
2
4. REAL GASES
The ideal gas laws are derived from the kinetic theory of gases which is based on the following two
important assumptions:
(i) The volume occupied by the molecules is negligible in comparison to the total volume of the gas.
(ii) The molecules exert no forces of attraction upon one another.
It is because neither of these assumptions can be regarded as applicable to real gases that the real
gases show departure from the ideal behaviour.
Volume Correction
the centre of the vessel. This results in decreasing the velocity of the molecule, and hence its
momentum. Thus, the molecule does not contribute as much force as it would have, had there been no
force of attraction. Thus, the pressure of a real gas would be smaller than the corresponding pressure of
an ideal gas, i.e. pi = pr + correction term
For example, size of He, CH4, CF4, C4H10 are in order of He < CH4 < CF4 < C4H10 and same will be
the order of b.
n 2a
vi) Pressure correction factor ( ) depends on intermolecular force of attraction. Hence, larger the
V2
intermolecular force of attraction larger the value of ‘a’, for same n and V. For example,
intermolecular force of attraction among the molecules H2, CO2, NH3 are in order of
H2 < CO2 < NH3 (H-bonding) thus same is the order of a.
For an ideal gas Z=1 and is independent of pressure and temperature. For a real gas,
Z = (T, p), is a function of both temperature and pressure.
i) At low pressures: ‘V’ is large and ‘b’ is negligible in comparison with V. The Vander Waals
equation reduces to:
a a
P+ 2 V=RT ; PV + = RT
V V
a
PV = RT - or PV RT
V
iv) Hydrogen and Helium: These are two lightest gases known. Their molecules have very small masses.
a
The attractive forces between such molecules will be extensively small. So 2 is negligible even at
V
ordinary temperatures. Thus PV RT.
0°C
2 CO2 50° C
100°C
N2
100°C
H2 Z
He 1.0
Z 1 Ideal gas
50°C
0°C
0 P
P (atm)
(Deviation of gases from ideal The plot of Z vs P for N2 gas at different temperature is
behaviour with pressure.) shown here.
Example20: The density of steam at 100oC and 1.0 atm pressure is 0.5974 kg m3. Determine
compressibility factor for steam in the given condition.
horizontal line increases at lower temperatures. At critical point horizontal portion of the isotherm merges
into one point.
P 2P
So at point E = 0 and 2 =0
V TC V TC
Critical temperature Tc is the maximum temperature at which a gas can be liquefied, i.e. the temperature
above which a liquid cannot exist.
Critical pressure pc is the minimum pressure required to cause liquefaction at the temperature Tc.
Critical volume Vc is the volume occupied by one mole of a gas at critical temperature Tc and critical
pressure pc. The point E in Fig represents the gas in its critical state. At this point the temperature, pressure
and volume have critical values. These three are known as critical constants. The isotherm corresponding to
the temperature Tc is known as critical isotherm. To the left of the point E on this isotherm, we have the
liquid state whereas to the right, we have the gaseous state. Thus, at point E transition from liquid to gaseous
state (or vice versa) takes place and thus it is not possible to state whether the substance is in the gaseous
form or in the liquid form. In fact, both the states become indistinguishable at the critical point. The surface
of separation between liquid and gas disappears. At this point the various physical properties such as
density, refractive index, etc., have identical values for both the states.
p p
V = 0 and the condition that this slope has a maximum value of V V = 0
T T T
RT a
From the van der Waals equation p = 2 we get
Vm b Vm
p RT 2a
2
3
Vm T Vm b Vm
2p 2RT 6a
2 = 3
4 .
Vm T Vm b Vm
RTc 2a
Hence at the critical point, 2
+ =0
Vc b Vc3
2RTc 6a
and 3
+ = 0.
Vc b Vc4
8a
Solving Eqs. for Vc and Tc, we get Vc = 3b, Tc =
27Rb
Substituting the values of Vc and Tc in the van der Waals equation, we have
RTc a R(8a/27Rb) a 4a a a
pc = 2 = 2
2
2
=
Vc b Vc (3b b) (3b) 27b 9b 27b 2
pVm 1 1 1
Z= =1+ B + C 2 + D 3 +....
RT Vm Vm Vm
where B, C, …. are temperature dependent constants known as second, third, etc., virial coefficients. These
coefficients must be evaluated experimentally at each different temperature.
The van der Waals equation of state for 1mole of a gas is
a RT a
p + 2 (Vm b) = RT or p= 2
Vm Vm b Vm
1
pVm Vm a b a
Multiplying both sides by Vm/RT, we get RT = V b V RT or Z = 1 V
m m m Vm RT
In the low pressure region, Vm is large and b/Vm << 1. Thus, the expression(1 – b/Vm)-1 can be expanded
into a power series in b/Vm:
1 2 2
b b b b
1 =1 + + + + ...
Vm Vm V
m V
m
2
a 1 b
Substituting this in the expression for Z, we get Z = 1 + b RT V + V + ...
m m
a
Thus for the second virial coefficient, we have B = b RT
Third virial coefficient C = b2, and so on.
An alternate form of the virial equation of state involves the expression of Z in terms of a power series in p,
i.e. Z = 1 + A1p + A2p2 + …
BOYLE’S TEMPERATURE
1 a b2
Also the expansion series Z = 1 + b + + ... is a decreasing
Vm RT V 2 m
1 a
series and can be approximated as: Z =1+ b RT
Vm
1 a
Imposing the condition of ideality: Z = 1
Vm b RT = 0
a
T= =Boyle’s temperature (TB)
Rb
Boyle temperature is that temperature at which a real gas behaves like an ideal gas for a range of pressure.
Example 21: Calculate the pressure exerted by a mole of CO2 gas confined in a 0.095 L container at
100oC. The 1st and 2nd coefficients Bv RT and Cv RT are -2.26 (l2 atm mol1) and 0.161 (L3
atm mol1) respectively.
RT RT C RT
p Bv 2 v 3
Vm Vm Vm
0.0821 373 2.26 0.161
= 2
= 259.32 atm
0.095 (0.095) (0.095)3
V log V
(C) P (D) P
1
V V
C 1
Solution: P= Where C is a constant. We can see that (c) is true as the graph of P vs would be a
V V
straight line.
(B) is true because log P = log C – log V.
dP C
(A) is true because 2
dV V
which means that as V increases the slope decreases and is always negative (D)
Example 3 A commercial gas cylinder contains 75 L of He at 15 bar (Gauge pressure). Assuming ideal
gas behavior for the isothermal expansion, how many 3.0 L balloons at 1.1 bar pressure can
be filled by the gas in the cylinder?
(A) 338 (B) 430 (C) 403 (D) 304
Ashwani Tyagi Sir 28 Code: ATJEE / ATNEET
Chemistry Gaseous States
Solution: Assuming atmospheric pressure to be one bar, initial pressure and final pressure
of He gas present in cylinder will be:
pi = 15 + 1 = 16 bar and pf = 1.1 bar
16 75
Volume of He gas when expanded isothermally to 1.1 bar = 1090.9L
1. 1
Out of 1090.9L, 75 L of gas will remain in cylinder since this point pressure
equilibrium will be established.
1090.9 75
Numbers of balloons = 338 Thus (A)
3
Example 4 A vessel has N2 gas saturated with water vapor at a total pressure of 1 atm. The partial
pressure of water vapour is 0.3 atm. The contents of this vessel are transferred to another
vessel having one third of the capacity of original volume, at the same temperature the total
pressure of this system in the new vessel is
(A) 3.0 atm (B) 1 atm (C) 3.33 atm (D) 2.4 atm
Solution: PN' 2 PH' 2O 1atm PH' 2O 0.3 atm PN' 2 0.7 atm
Now new pressure of N2 in another vessel of volume V/3 at same temperature T is given by
V1
PN" 2 0 .7 V PN" 2 2.1 atm
3
since aqueous tension remains constant, and thus total pressure in new vessel
PN" 2 PH' 2O = 2.1 + 0.3 = 2.4 atm (D)
Example 5 X ml of H2 gas effuses through a hole in a container in 5 seconds. The time taken for the
effusion of the same volume of the gas specified below under identical conditions is :
(A) 10 seconds : He (B) 20 seconds : O2
(C) 25 seconds : CO (D) 35 seconds : CO2
rH 2 4 rH 2 32
Solution: 2 (A) is incorrect ; 4 (B) is correct
rHe 2 rO2 2
rH 2 28 rH 2 2 1
14 (C) is incorrect ; = (D)is incorrect (B)
rCO 2 rCO2 44 12
Example 6 In what molar ratio He and CH4 should be mixed so that when the mixture is allowed to
effuse through a pinhole, initially both gases come out at equal rate?
(A) 2:1 (B) 1:1
(C) 2:3 (D) 4:1
n
Solution: Since, rate of effusion (r ) from a mixture.
M
r ( He) n( He) 16
1. 0 n CH4 : n He 2 :1 (A)
r (CH 4 ) n(CH 4 ) 4
Example 7 Dalton’s law of partial pressure is not applicable to, at normal conditions
(A) H2 and N2 mixture (B) H2 and Cl2 mixture
(C) H2 and CO2 mixture (D) H2 and O2 mixture
Solution: H2 and Cl2 reacts to form HCl; Dalton’s law of partial pressure is valid only for the gases
which don’t react at ordinary conditions (B)
Example 8 For two gases A and B with molecular weights MA and MB, it is observed that at a certain
temperature T1 the mean velocity of A is equal to the root mean square velocity of B. thus the
mean velocity of A can be made equal to the mean velocity of B if
(A) A is at temperature T and B at T, T > T
(B) A is lowered to a temperature T2 , T2 < T while B is at T
(C) Both A and B are raised to a higher temperature
(D) Both A and B are placed at lower temperature
8RT 3RT 8 M
Solution: (UAV)A = and (Urms)B = A
MA MB 3 MB
8RT2 8RT T2 MA 8 8
for A (UAV) = for B (UAV) = T2 = T or
MA M B T MB 3 3
T2 < T (B)
Example 9 The K.E. of N molecule of O2 is x Joules at –123°C. Another sample of O2 at 27°C has a KE
of 2x Joules. The latter sample contains.
(A) N molecules of O2 (B) 2N molecules of O2
(C) N/2 molecules of O2 (D) N/4 molecule of O2
3 3
Solution: Total KE = nRT ; T = – 123 + 273 = + 150 K ; nR 150 xJ
2 2
=> 225 8.314 n = x
At 27°C = 27+ 273 = 300K
3
Total KE = 2x Joule = n1 8.314 300 n1 n (A)
2
Example 10 If for two gases of molecular weights MA and MB at temperature TA and TB,
TAMB = TBMA, then which property has the same magnitude for both the gases.
(A) density (B) pressure (C) KE per mol (D) Vrms
PM
Solution: i) density of a gas () =
RT
MB MA
Since , at the same pressure A = B . But if pressure is different
TB TA
then A B .
ii) Pressure of the gases would be equal if their densities are equal otherwise not.
3
iii) KE per mol = RT
2
It will be different for the two gases.
3RT T T
iv) Vrms = , since A B ; Vrms of A = Vrms of B (D)
M MA MB
Example 11 Helium atom is two times heavier than a hydrogen molecule. At 298 K, the average kinetic
energy of a Helium atom is
(A) two times that of hydrogen molecule (B) same as that of a hydrogen molecule
(C) four times that of a hydrogen molecule (D) half that of a hydrogen molecule
3
Solution: The average kinetic energy of an atom is given as kT.
2
It does not depend on mass of the atom. (B)
Example 12 The ratio between the rms velocity of H2 at 50 K and that of O2 at 800 K is
(A) 4 (B) 2 (C) 1 (D) 1/4 [IIT–JEE ’96]
3R 50 3R 800
Solution: Vrms (H2 at 50 K) = ; Vrms (O2 at 800K) =
2 103 32 103
3R 50
Vrms (H2 ) 2 10 3 25 10 3
1 (C)
Vrms (O 2 ) 3R 800 25 10 3
32 10 3
Example 13 The temperature of an ideal gas is increased from 140 K to 560 K. If at 140 K the root mean
square velocity of the gas molecule is V, at 560 K it becomes
(A) 5V (B) 2V (C) V/2 (D) V/4
Example 14 At 100oC and 1 atm, if the density of liquid water is 1.0 g/cc and that of water vapour is
0.0006 g/cc, then the volume occupied by water molecule in one litre of steam at that
temperature is
(A) 6 cc (B) 60 cc (C) 0.6 cc (D) 0.06 cc
Solution: A gas can be liquefied only if its temperature is lower than its critical temperature
(B)
Ashwani Tyagi Sir 31 Code: ATJEE / ATNEET
Chemistry Gaseous States
Example 16 The behavior of a real gas is usually depicted by plotting compressibility factor Z versus P at
a constant temperature. At high temperature and high pressure, Z is usually more than one.
This fact can be explained by van der Waals equation when
(A) the constant ‘a’ is negligible and not ‘b’
(B) the constant ‘b’ is negligible and not ‘a’
(C) both constants ‘a’ & ‘b’ are negligible
(D)both the constants ‘a’&‘b’ are not negligible.
n 2a
Solution: P 2 (V – nb) = nRT
V
At high pressures, ‘b’ cannot be ignored as the volume of the gas is very low. At high
temperatures ‘a’ can be ignored
P (V–b) = RT ; PV - Pb = RT
PV Pb
PV = RT + Pb ; Z 1 (A)
RT RT
Example 17 The compressibility factor for a given gas is 0.927 at 273 K and 100 atm.
Calculate the amount of gas required to fill a gas cylinder of 100 liter capacity
under given conditions. (Molecular wt of gas is 30
(A) 16.4 Kg (B) 14.44 Kg (C) 4 Kg (D) 10.5 Kg
Example 18 Using van der waal’s equation, calculate the constant, ‘a’ (atm Ltr2 mole-2)when
two moles of a gas confined in a four litre flask exerts a pressure of 11 atm at a
temperature of 300 K. The value of ‘b’ is 0.05 Litre mole-1
(A) 6.5 (B) 2.23 (C) 23.2 (D) .85
Example 2 A flask containing some He gas at 1.5 atm and 300 K is connected to another flask, four
times larger in volume containing nitrogen gas at same temperature and pressure by means of
a narrow tube of negligible volume. The bigger flask was then kept in a thermostat bath
maintained at 500 K, while other flask was maintained at constant 300 K. Determine the final
pressures.
Solution: Since, initially gases are at same temperature and pressure, if there is x mol of He gas, mole
of N2(g) = 4x (Avogadro’s law)
V 4V
He N2
Final conditions:
n1, 300 K, p n2, 500 K, p
Applying ideal gas laws
V V V 4V
nT I nT II n1 300 I n2 500 II
12n1 17 n1 25 x
Also, n1 + n2 = x + 4x = 5x = n1 + n1
5 5 17
Now, applying ideal gas law on flask I, before and after heating.
1.5 x x 17 1.5 25
pn 17 p 2. 2
p n1 25 x 25 17
Thus p =2.2 atm
Example 3 Two flasks of equal volume, connected by a narrow tube of negligible volume contain 1.0
mol of H2 gas at 300 K and 0.5 atmosphere. Now one of the flasks is immersed into a
thermostat maintained at 400 K and other was maintained at constant 300 K temperature.
Determine final pressure and amount of H2 gas in each flask.
Solution: Initially, both the flasks contained Initial conditions: 0.5 mol. 0.5 atm 0.5 mol. 0.5 atm
300 K 300 K
equal moles of H2(g) i.e., 0.5 mol each
(Avogadro’s law). A B
Y cm
8 cm
Hg
Air
x cm
Air
8 cm
Hg
(a) pair = patm + pHg (b) pair = patm pHg
Hg
h
Air
α = 45o
Example 5 A vertical hollow cylinder of height 1.52m is fitted with a movable piston of negligible mass
and thickness. The lower half of the cylinder contains an ideal gas and the upper half is filled
with mercury. The cylinder is initially at 300 K. When the temperature is raised half of the
mercury comes out of the cylinder. Find the temperature assuming the thermal expansion of
mercury to be negligible?
Example 6 A spherical glass bulb of radius 1.0 m contains a concentric rubber balloon that contains
some N2 gas and the remaining space in the flask contains 50 g H2. In the given conditions,
radius of the rubber balloon was found to be 40 cm. Now the seal of glass bulb was opened
and 25 g H2(g) was further added and resealed. Determine radius of the rubber balloon in the
new conditions. Assume constant temperature throughout.
Solution:
50 g H2(g) 75 g H2(g)
p p
40 cm +25 g H2(g) r cm
100- rcm
N2 N2
60 cm
p p
I II
From the above illustration, it is obvious that pressure inside and outside the balloon is same
in both the cases. Applying the gas law on I to N2(g) and H2(g); p and T are same:
4 4
V( H 2 ) V( N 2 ) 3
1003 40 3 3
403
n( H 2 ) n( N 2 ) 25 n( N 2 )
25 (40) 3
n( N 2 ) 1.7 mol
[(100)3 (40) 3 ]
Applying the gas law on II to N2(g):
4 3
3 3 r 3
4 [(100) r ] 3 37.5 (100) 3 r 3 100
1
3 37.5 1.7 1.7 r3 r
3
100 37.5 392
1 r = 35.13 cm
r 1. 7 17
Example 7 A 100 mL flask containing oxygen gas at 1.2 atm and 300 K is connected to a 250 mL flask
containing NO(g) at 0.6 atm and 300 K, by means of a narrow tube of negligible volume,
where they combine quantitatively to form NO2. Finally NO2(g) dimerized partially into
N2O4 and pressure inside the flask was found to be 0.41 atm at the same temperature.
Determine the percentage dimerization of NO2 as
2NO2(g) N2O4(g)
Solution: Before reaction Partial pressure of O2 in the combined system
100
= 1. 2 0.3428 atm
350
Partial pressure of NO in the combined system
250
0.6 0.4285 atm
350
250 mL (T)
100 mL (T)
O2(g)
NO(g)
1.2 atm 0.6 atm
Also, in the combined system P1 n1; partial pressure can directly be used to
solve the stoichiometry of reaction as
l
2NO + O2
2NO2 N2O4
Initial partial p: 0.4285 0.3428 0 0
Example 8 A 50.00 ft long classroom has twenty rows of seats and the adjacent rows are separated by
2.5 ft each. A N2O cylinder on the front door and a CH4 cylinder on the rear door were
opened simultaneously, so that gases start diffusing into the classroom. Student of which row
will first experience both tears and laughing? Assume both the cylinders have gases at same
temperature and pressure and valves have similar dimensions.
Example 9 Rate of effusion of a sample of ozonized oxygen is 0.95 times the rate of effusion of pure
oxygen. Determine mass percentage of ozone in the ozonized sample.
Solution: 2O3
For ozonisation: 3O2
1 2/3
Total mole at equilibrium 1
3
32 r (ozonised mix) 32
M mix 0.95 1
r (oxygen) 32 3
1
3
= 0.2925
Weight of ozone in the mixture = Weight of oxygen ozonised
= 32 0.2925 g.
0.2975 32
Weight percentage of O3 in mixture 100 29.75 %
32
Example 10 Root mean square speed of N2(g) in air is 515 ms1. What is the average speed of He gas in
the same air?
3RT 8 RT
Solution: u rms and uavg
M N2 M He
Both are at same temperature:
uHe 8M N2 8 28 103
2.4375
urms ( N2 ) 3 M He 3 4 103
uHe 2.4375 515 1255.3ms1
Example 11 Density of a sample of air was found to be 1.17 g/L at 1.0 atm. Determine average speed of
gas molecules present in air in the given conditions.
8RT 8P 8 101325 Nm 2
Solution: u and PM = RT ; u 3
469.6ms1
M 1.17 kg m
Example 12 Using van der Waals’ equation of state, find the minimum in pVp curve for one
mole of O2(g) at 0oC.
Given: a = 1.362 L2 atm mol2, b = 0.032 L mol1.
Solution: The minimum in curve will occur at
( pV )
0
p
RT a
p 2 … (i)
Vm b Vm
( pVm ) V p
Also, Vm p m Vm …(ii)
p p P / Vm
p RT 2a
From (i) 2
3
Vm (Vm b) Vm
RT a
2
( pVm ) (V b) Vm
Vm m 0 at minima
p RT 2a
(Vm b) 2 Vm3
(bRT a) Vm2 2abVm ab 2 0 …(iii)
Substituting values of ‘a’ and ‘b’ gives
0.647 Vm2 0.0869Vm 0.001386 0
Vm 0.0185 and 0.1158
The first solution yields negative p and discarded, while second solution yields, p = 166 atm.
B
Example 13: One way of writing the equation of state for a real gas is PV RT 1 Where B
V
is a constant. Derive an approximate expression for B in terms of Vander waal’s constant ‘a’
and ‘b’
a RT a
Solution: P V 2 V b RT or P= 2
V b V
RTV a V V a
Multiply by [V] then, PV = or PV = RT
V b V2 V b VRT
1
b a
or PV = RT 1
V VRT
1 2 3 2
b b b b b a b
Now 1 1 PV =RT 1
V V V V V VRT V
2
a 1 b a
Or PV = RT 1 b B=b –
RT V V RT
Example 14: 10 ml of a gaseous hydrocarbon were burnt completely in 80 ml of O2 at N.T.P. The
remaining gas occupied 70 ml at N.T.P. This volume becomes 50 ml on treatment with KOH
solution. What is the empirical formula of hydrocarbon?
Solution: Let the molecular formula of hydrocarbon be CxHy.
CxHy + (x + y/4)O2 xCO2 + y/2 H2O.
Volume reacted 10 ml 10(x + y/4)
Volume produced 10x negligible
10x = 20 x = 2.
Since, the remaining gas occupied 70 ml,
Total volume left = 70 = VO 2 + VCO 2
where VO 2 = volume of oxygen left and VCO 2 = Volume of CO2 produced.
VO 2 = 70 20 = 50 ml.
80 10(x + y/4)= 50
x + y/4 = 3
y/4 =1 y = 4.
So, formula is C2H4.
Thus, empirical formula of the hydrocarbon is CH2.
Example : 15 A mixture of ethane (C2H6) and ethene (C2H4) occupies 40 litre at 1.00 atm and at 400 K. The
mixture reacts completely with 130 g of O2 to produce CO2 and H2O. Assuming ideal gas
behaviour, calculate the mole fractions of C2H4 and C2H6 in the mixture.
1 40
Solution: Number of moles of C2H6 and C2H4 = 1.218
0.0821 400
Let the number of moles of C2H6 in the mixture be x
7
C2H6 + O2 2CO2 + 3H2O
2
7x
x
2
C2H4 + 3O2 2CO2 + 2H2O
1.218-x 3(1.218-x)
7x 130
Number of moles of O 2 3 (1.218 x )
2 32
On solving, x = 0.817
0.817
Moles fraction of C2H6 = 0.67
1.218
Mole fraction of C2H6 = 0.33
1. I, II, III are three iso-therm respectively at T1, T2 & T3 temperatures will be in order
(A) T1 = T2 = T3 (B) T1 T2 T3 P
(C) T1 T2 T3 (D) T1 T2 = T3 II
I
III
V
2. The volume of a large irregularly shaped tank is determined as follows. The tank is
first evacuated, and then it is connected to a 50 L cylinder of compressed helium gas. The gas
pressure in the cylinder, originally at 21atm, falls to 7.0atm without a change in temperature. What is
the volume of the tank?
(A) 100L (B) 150L (C) 200L (D) 300L
3. At a constant temperature what should be the percentage increase in pressure for a 5% decrease in
the volume of gas:
(A) 5% (B) 10% (C) 5.26% (D) 4.26%
4. At a constant pressure, what should be the percentage increase in the temperature in Kelvin for a
10% increase in volume
(A) 10% (B) 20% (C) 5% (D) 50%
6. The volume of gas is 100ml at 100oC. If pressure remains same then at what temperature it will be
200ml?
(A) 200oC (B) 473oC (C) 746oC (D) 50oC
7. A gas cylinder containing cooking gas can withstand a pressure of 14.9 atm. The pressure gauge of
cylinder indicates 12 atm at 27°C. Due to sudden fire in building the temperature starts rising. The
temperature at which the cylinder will explode is.
(A) 42.5°C (B) 67.8°C (C) 99.5°C (D) 25.7°C
8. Flasks A and B of equal size contain 2 gm of H2 and 2 gm of N2 respectively at the same temperature.
The number of molecules in flask A is
(A) Same as those in flask B (B) Less than those in flask B
(C) Greater than those in flask B (D) Exactly half of those in flask B
9. 3.2g S on heating if occupy a volume of 780 ml at 450°C and 723 mm pressure. Formula of sulphur
is:
(A) S2 (B) S (C) S4 (D) S8
10. The volume of balloon filled with 4.0g He at 22oC and 720 mm of Hg is
(A)25.565 L (B) 20 L (C) 15 L (D) 30 L
11. Two containers A and B contain the same gas. If the pressure, volume and absolute temperature of
the gas in A are twice as compared to that of gas in B, and if the mass of the gas B is x g, the mass of
gas in A is
(A) x g (B) 4x g (C) 2/x g (D) 2x g
12. What is the final temperature if a sample of ammonia gas, initially at a pressure of 3.00 atm, a
temperature of 500K, and a volume of 275L is changed to a volume of 200L and a pressure of
2.50atm?
(A) 303K (B) 436K (C) 573K (D) 825K
13. 5.40 gm of an unknown gas at 27C occupies the same volume as 0.14 gm of hydrogen at 17C and
same pressure. The molecular weight of unknown gas is
(A) 79.8 (B) 81 (C) 79.2 (D) 83
14. Which of the following gases would have the largest density at 25C and 1.00 atm pressure?
(A) Methane, CH4 (B) Acetylene, C2H2 (C) Ethylene, C2H4 (D) Propane, C3H8
15. To expel half the mass of air from a large flask at 27oC, it must be heated to:
(A) 54oC (B) 177oC (C) 277oC (D) 327oC
16. An open vessel containing air is heated from 300 K to 400 K. The fraction of air originally present
which goes out of it is:
(A) 3/4 (B) 1/4 (C) 2/3 (D) 1/8
17. 0.2 mole sample of hydrocarbon CxHy yields after complete combustion with excess O2 gas, 0.8
mole of CO2, 1.0 mole of H2O. Hence hydrocarbon is
(A) C4H10 (B) C4H8 (C) C4H5 (D) C8H16
18. If the pressure of a given mass of gas is reduced to half and temperature is doubled simultaneously
then the volume will be
(A) Same as before (B) Twice as before (C) ¼ the as before (D) None
19. The 1 mol of an Ideal gas A with 300 mm of Hg is separated by 2 mol of another ideal gas B with
300 mm of Hg in closed container at the same temperature. If the separation is removed than total
pressure is
(A) 200 mm of Hg (B) 300 mm of Hg (C) 500 mm of Hg (D) 600 mm of Hg
20. Assume centre of sun to consist of gases whose average molecular weight is 2. The density and
pressure of the gas are 1.3 g cc–1 and 1.12 109 atm respectively. The temperature of sun is
(A) 2 103 K (B) 2 105 K (C) 2 107 K (D) 2 109 K
21. 6 g each of the following gases at 87oC and 750 mm pressure are taken. Which of them will have the
least volume
(A) HF (B) HCl (C) HBr (D) HI
22. The density of O2 gas at 25oC is 1.458 mg/lt at one atm pressure. At what pressure will O2 have the
density twice the value?
(A) 0.5 atm/250C (B) 2atm/25oC (C) 4atm/25oC (D) none
24. Figure shows graphs of pressure versus density for an ideal gas at two temperatures T1 and T2.
Which is correct?
T1
T2
Pressure
Density
(A) T1 > T2 (B) T1 = T2 (C) T1 < T2 (D) none of these
25. Equal masses of three ideal gases X, Y and Z are mixed in a sealed rigid container. If the
temperature of the system remains constant, which of the following statements about the partial
pressure of gas X is correct?
(A) It is equal to 1/3 the total pressure
(B) It depends on the intermolecular forces of attraction between molecule of X, Y and Z.
(C) It depends on the relative molecular masses of X, Y and Z.
(D) It depends on the average distance travelled between molecular collisions.
26. When 2g gas A is introduced into an evacuated flask kept at 25°C, the pressure is found to be 1 atm.
If 3g of another gas B is further added to same flask, the total pressure becomes 1.5 atm. The ratio of
molecular weights is
(A) 1:1 (B) 1:2 (C) 1:3 (D) 1:4
27. Air contains 79 % N2 and 21 % O2 by volume. If the barometric pressure is 750 mm Hg. The partial
pressure of oxygen is
(A) 157.5 mmHg (B) 175.5 mmHg (C) 315.0 mmHg (D) none
28. A gaseous mixture contains 1g of H2, 4g of He, 7g of N2 and 8g of O2. The gas having the highest
partial pressure is
(A) H2 (B) O2 (C) He (D) N2
29. A mixture consisting of 0.10 moles of N2, 0.05 moles of O2 and 0.20 moles of CH4 and an unknown
amount of CO2 occupied a volume of 9.6 L at 27C and 1.0 atm pressure. How many moles of CO2
are there in this sample ?
(A) 0.04 mol (B) 0.39 mol (C) 0.05 mol (D) 0.10 mol
Graham’s Law
30. X ml of H2 gas effuses through a hole in a container in 5 secs. The time taken for effusion of same
volume of gas specified below under identical condition is
(A) 10 secs : He (B) 20 secs : O2 (C) 25 secs : CO (D) 55 secs : CO2
31. Which of the following pair will diffuse at the same rate?
(A) CO2 and N2O (B) CO2 and NO (C) CO2 and CO (D) N2O and NO
32. A mixture of H2 and O2 in 2:1 volume is allowed to diffuse through a porous partition what is the
composition of gas coming out initially
(A) 1:2 (B) 4:1 (C) 8:1 (D) 1:4
34. The pair of gases which can be most easily separated from effusion technique
(A) D2 and H2 (B) CH4 and CD4 (C) C12H4 and C14H4 (D) U235F6 and U238F6
35. The rate of diffusion of methane at a given temperature is twice that of gas X. The molecular weight
of X is:
(A) 64.0 (B) 32.0 (C) 4.0 (D) 8.0
36. The mole fraction He is 0.4 in gaseous mixture He and CH4. If both the gaseous are effusing through
the constant area of the orifice of the container, then what will be % composition by volume of CH4
gas effusing out initially?
(A) 50% (B) 40% (C) 43% (D) 75%
37. Bromine vapour at a given temperature is roughly 5 times denser than oxygen gas. Calculate the
relative rates at which Br2(g) and O2(g) diffuse.
(A) O2 should diffuse roughly 2.2 times faster.
(B) Br2 should diffuse roughly 2.2times faster.
(C) O2 should diffuse roughly 5.0 times faster.
(D) Br2 should diffuse roughly 5 times faster.
38. A balloon filled with moist air has developed a pinhole. It is quickly plunged into a tank of dry air at
the same pressure. In a short while
(A) It will collapse (B) It will enlarge
(C) No change will take place (D) can’t be predicted
39. Some moles of SO2 diffuse through a small opening in 20 seconds. Same number of moles of an
unknown gas diffuses through the same opening in 60 seconds. Molecular mass of the unknown gas
is
2 60 2 20
(A) 64 X (B) 64 X
20 60
2 2
60 20
(C) 64 X (D) 64 X
20 60
40. Vegetables are canned, while they are steaming hot because
(A) the heat inside will seal the jars
(B) the heat increases the atmospheric pressure
(C) the heat creates more pressure inside the jars
(D) when the jars cool, a vacuum inside will help to seal the jars
Eudiometry
41. 200 ml of a gaseous mixture containing CO, CO2 and N2 on complete combustion in just sufficient
amount of O2 showed contraction of 40 ml when the resulting gases were passed through KOH
solution it reduces by 50% then calculate the volume ratio of VCO2 : VCO : VN 2 in original mixture.
(A) 4: 1: 5 (B) 2: 3: 5 (C) 1 : 4 : 5 (D) 1 : 3: 5
42. 10 ml of a compound containing ‘N’ and ‘O’ is mixed with 30 ml of H2 to produce H2O (l) and 10 ml
of N2 (g). Molecular formula of compound if both reactants reacts completely, is
(A) N2O (B) NO2 (C) N2O3 (D) N2O5
43. One mole mixture of CH4 & air (containing 80% N2 20% O2 by volume) of a composition such that
when underwent combustion gave maximum heat (assume combustion of only CH4). Then which of
the statements are correct, regarding composition of initial mixture.(X presents mole fraction)
1 2 8 3 1 1
X CH 4 , X O2 , X N 2 X CH 4 , X O2 , X N 2
(A) 11 11 11 (B) 8 8 2
1 1 2
X CH 4 , X O2 , X N 2
(C) 6 6 3 (D) Data insufficient
44. A mixture of C2H2 and C3H8 occupied a certain volume at 80 mm Hg. The mixture was completely
burnt to CO2 and H2O(l). When the pressure of CO2 was found to be 230 mm Hg at the same
temperature and volume, the fraction of C2H2 in mixture is
(A) 0.125 (B) 0.5 (C) 0.85 (D) 0.25
45. In the quantitative determination of nitrogen, N2 gas liberated from 0.42 gm of a sample of organic
100
compound was collected over water. If the volume of N2 gas collected was ml at total pressure
11
860 mm Hg at 250 K, % by mass of nitrogen in the organic compound is
[Aq. tension at 250 K is 24 mm Hg and R = 0.08 L atm mol-1 K-1]
10 5 20 100
(A) % (B) % (C) % (D) %
3 3 3 3
46. A definite amount of gaseous hydrocarbon having (carbon atoms less than 5) was burnt with
sufficient amount of O2. The volume of all reactants was 600 ml, after the explosion the volume of
the products [CO2(g) and H2O(g)] was found to be 700 ml under the similar conditions. The
molecular formula of the compound is
(A) C3H8 (B) C3H6 (C) C3H4 (D) C4H10
Kinetic Theory of Gases
47. A sample of gas is at 0oC. The temperature at which rms speed of the molecule will be doubled is
(A) 103oC (B) 273oC (C) 723oC (D) 819oC
48. The temperature at which H2 has same rms speed (at 1 atm) as that of O2 at NTP is
(A) 37 K (B) 17 K (C) 512 K (D) 27 K
49. In a closed vessel, a gas is heated from 300 K to 600 K the kinetic energy becomes/remain
(A) half (B) double (C) same (D) four times
50. Which of the following gases would have the highest rms speed at 0 oC
(A) O2 (B) CO2 (C) SO3 (D) CO
51. The ratio of rms velocity to average velocity of gas molecules at a particular temperature is
(A) 1.086 : 1 (B) 1 : 1.086 (C) 2 : 1.086 (D) 1.086 : 2
52. On increasing temperature, the fraction of total gas molecule which has acquired most probable
velocity will
(A) Increase (B) decrease
(C) Remains constant (D) cant say without knowing pressure
55. The ratio between the rms velocity of H2 at 50 K and that of O2 at 800 K is
(A) 4 (B) 2 (C) 1 (D) 1/4
56. Let the most probable velocity of hydrogen molecules at a temp tC is Vo. Suppose all the molecules
dissociate into atoms when temp is raised to (2 t + 273)C then the new r.m.s velocity is
(A) 2 / 3 V0 (B) 3(2 273 / t ) V0 (C) 2 3 V0 (D) 6 V0
57. An ideal gas molecule is present at 27C. By how many degree centigrade its temperature should be
raised so that its Vrms , Vmp and Vav all may double.
(A) 900C (B) 108C (C) 927C (D) 81C
58. If most probable speed is represented by mps and fraction of molecules possessing this speed by f,
then with increase in temperature
(A) both mps and f will increase (B) mps will increase but f will decrease
(C) Both will decrease (D) mps will decrease but f will increase
59. Which of the following statements concerning the kinetic theory of gases is (are) correct?
I. Molecules make elastic collisions with each other and with the walls of their container.
II. The average kinetic energy of a large number of molecules of mass, M, is proportional to M1/2 at
a given temperature.
III. The molecules of a gas are in constant random motion.
IV. All the molecules of a gas have the same kinetic energy at a given temperature.
(A) I,II,III,IV (B) I,II,III (C) I,III,IV (D) I,III
60. The root mean square speed of CH4 molecules at 25C is about 0.56 km/s. What is the root mean
square speed of a H2 molecule at 25C ?
(A) 0.070 km/s (B) 0.20 km/s (C) 1.1 km/s (D) 1.6 km/s
61. Assume that the container is filled with the mixture of SO3 and Ne. The molecular weight of SO3 is
80 g/mol and the atomic weight of Ne is 20 g/mol. The average velocity of an SO3 molecules is
(A) One fourth that of a Ne atom (B) One half that of a Ne atom
(C) The same as a Ne atom (D) Two times that of a Ne atom
62. Consider two 1 L flasks, one containing O2, the other containing He, each at STP. Which of the
following statement is NOT true regarding these gases?
(A) Each flask contains the same number of atom or molecule
(B) The gases in each flask have the same average kinetic energy.
(C) The gases in each flask have the same density.
(D) The pressure in each flask is the same.
63. Compare the root mean square speed of an O2 molecule with that of CH4 molecule at the same
temperature and pressure.
(A) The speed are the same, since the weight of O2 and of CH4 are both 16 g/mol
(B) The speed are the same because at the same temperature all gas molecules have the same mean
square speed.
(C) CH4 is 2.00 times faster, because the MW of O2 is times greater than the molecular weight of
CH4.
(D) CH4 is 1.41 times faster, since at equal temperature of all gas molecules have the same kinetic
energy. Square root mean square speed then is inversely proportional to the square root of the
molecular weight.
64. The kinetic molecular theory of gases predicts pressure to rise as the temperature of a gas increases
because
(A) The average kinetic energy of the gas molecules decreases
(B) Gas molecules collide more frequently with the container walls
(C) Gas molecules collide less frequently with the container walls
(D) Gas molecules collide less energetically with the container walls
65. “The higher the temperature of a gas at constant volume, the greater is its pressure.” Which of the
following kinetic molecular explanations of this principle is not correct
(A) Molecule move faster at higher temperatures
(B) The number of molecular impacts per unit area decreases at a higher temperature.
(C) The average kinetic energy of molecules is greater at a higher temperature.
(D) The average momentum and rate of molecular collisions is greater at a higher temperature.
66. A certain gas is at a temperature of 350 K. If the temperature is raised to 700K, the average
translational kinetic energy of the gas will
(A) Remains constant
(B) Increase by a factor of 2
(C) Increase by a factor of square root of 2
(D) Decrease by a factor of square root of 2
68. For two gases, A and B with molecular weights MA and MB, it is observed that a certain temperature,
T, the mean speed of A is equal to the root mean square speed of B. Thus the mean speed of A can
be made equal to the mean speed of B, if:
(A) A is at temperature T and B at T, T > T
8
(B) A is lowered to a temperature T2 T while B is at T
3π
(C) Both A and B are raised to a higher temperature
(D) Both A and B are placed at lower temperature
69. If P is the pressure of gas, then the kinetic energy per unit volume of the gas is
(A) P/2 (B) P (C) 3P/2 (D) 2P
70. If the absolute temperature of a sample of gas in a fixed volume container is quadrupled, then the
root mean square speed in the initial state ui and that in the final stage uf would be related as:
(A) uf = ui/4 (B) uf = ui/2 (C) uf = 2ui (D) uf = 4ui
71. Consider the following statement about Maxwell Boltzmann law of distribution of molecular speeds:
1) The fraction of molecules having speed between c and (c + dc) (regardless of direction) is given
3/2
M 2 Mc 2
by 4π c exp dc
2 RT 2RT
2) The average speed is the arithmetic mean of the different speeds of all the molecules present in a
given sample of the gas.
3) The speed distribution curve becomes sharper and is more peaked at higher temperature as the
average speed increases.
4) The speed distribution function is used to determine average molecular speeds.
of these statements:
(A) 1, 2 and 3 are correct (B) 1, 2 and 4 are correct
(C) 1,3 and 4 are correct (D) 2, 3 and 4 are correct
Compressibility Factor
72. The compressibility factor for an ideal gas is
(A) 1.5 (B) 1 (C) 2 (D)
I
(C) III (D) All the above III
P (atm)
2 CO2
N2
X
75. In a given diagram gas X and Y can be Y
Z 1
(A) Hydrogen and Helium (B) Helium and Hydrogen
(C) Hydrogen and Neon (D) Helium and Neon
0
P
P (atm)
77. For non-zero value of force of attraction between gas molecules gas equation will be
n 2a nRT
(A) PV = nRT – (B) PV = nRT + nbP (C) PV = nRT (D) P =
V Vb
78. Out of the following gases, which one has least value of Vander Waals constant ‘a’
(A) CO2 (B) NH3 (C) CH4 (D) H2
80. Which of the following statement is true for Van der waals gas constant ‘a’ and ‘b’?
(A) ‘a’ depends on size and shape, ‘b’ depends only on size of molecule.
(B) ‘b’ depends on size and shape, ‘a’ depends only on size of molecule.
(C) Both ‘a’ and ‘b’ depends on shape and size of molecule.
(D) Both ‘a’ and ‘b’ depends only on size of molecule.
82. Identify the conditions of pressure and temperature at which a real gas shows maximum deviation
from ideal behavior:
(A)10 atm, 273 K (B) 5 atm, 273 K (C) 10 atm, 373 K (D) 5 atm, 373 K
83. Partial pressure are simply additive for ideal gases. For non–ideal gases (such as ammonia and
oxygen), if we tried to consider them as ideal gases, we would
(A) always overestimate the total pressure
(B) always underestimate the total pressure
(C) underestimate p at low pressure and overestimate p at high pressure
(D) overestimate p at low pressure and underestimate p at high pressure
85. The compressibility factor for gas obeying van der Waals’ equation of state is given by ( where V is
molar volume)
V a a V V b RTV RTV V b
(A) (B) (C) (D)
V b RTV RTV V b V a a V
86. One way of writing the equation of state for one mole of real gas
B C
PV RT A 2 ................
V V
Where A, B and C may be constants or dependent variables.
1. A is temperature dependent, and higher terms B, C………..are temperature independent.
2. A is temperature independent, and higher terms B, C………..are temperature dependent.
3. At Boyle’s temperature, A is unity and B, C….are negligible.
4. At Boyle’s temperature, all terms A, B, C…..are negligible.
Select the correct statements
(A)1, 4 (B) 2, 3 (C) 1, 3 (D) 2, 4
87. The temperature at which a real gas obeys the ideal gas laws at fairly wide range of pressure is
(A) Critical temperature (B) Inversion temperature
(C) Boyle’s temperature (D) Reduced temperature
89. The Van-der-waal’s equation for 1 mol of a real gas may be rearranged to give
RT 2 a ab
Vm3 b Vm Vm 0
P P P
Vm being the molar volume of the gas. Indicate the correct statement amongst the following
(A) At the temperature greater than Tc, there are three value of Vm, one real and two imaginary.
(B)At the temperature Tc, the three real values of Vm are identical.
(C)At the temperature less than Tc, there are three real values Vm are non identical.
(D)All are correct.
Ashwani Tyagi Sir 50 Code: ATJEE / ATNEET
Chemistry Gaseous States
90. Which of the following gases is the least likely to behave ideally?
(A) He (B) N2 (C) HCl (D) H2
91. At moderate pressure, the compressibility factor for a particular gas is given by:
160p
Z = 1 + 0.34p– (p in bar and T in kelvin). What s the Boyle’s temperature of this gas?
T
(A) 298K (B) 340K (C) 470K (D) 680K
1. An iron cylinder contains helium at a pressure of 250 kPa and 270C. The cylinder can withstand a
pressure of 106 Pa. The room in which cylinder is placed catches fire. Predict whether the cylinder
blow up before it melts or not (mp of cylinder = 1800K)
2. a) How large a balloon could you fill with 4.0 g of He gas at 22 oC and 720 mm of Hg?
b) Calculate the density of CO2 at 100 0C and 800 mm Hg pressure.
3. a) A container has 3.2 g of a certain gas at NTP. What would be the mass of the same gas contained
in the same vessel at 200C and 16 atm pressure?
b) A certain quantity of a gas measured 500 mL at a temperature of 15°C and 750 mm Hg. What
pressure is required to compress this quantity of gas into a 400 mL vessel at a temperature of 50°C?
4. An open vessel at 27C is heated until three-fifths of the air in it has been expelled. Assuming the
volume of the vessel remains constant, find the temperature to which the vessel has to be heated.
5. At 60°C the vapour density of N2O4 gas was found to be 30.2. Calculate the percentage of NO2
molecules by moles.
6. 3.6 gm of an ideal gas was injected into a bulb of internal volume of 8L at pressure P atm and
temp T-K. The bulb was then placed in a thermostat maintained at (T+ 15) K.0.6 gm of the gas
was let off to keep the original pressure. Find P and T if molecular weight of gas is 44.
7. A toy balloon originally held 1.0 gm of He gas and had a radius 10 cm. During the night, 0.25 gm of
the gas effused from the balloon. Assuming ideal gas behaivour, under these constant P and T
conditions, what was the radius of the balloon the next morning?
8. One mole of NH4Cl is kept in an open container & then covered with a lid. The container is now
heated to 600 K where all NH4Cl dissociates into NH3 & HCl. If volume of the container is 24.63
litres, calculate what will be the final pressure of gases inside the container. Also find whether the lid
would stay or bounce off if it can with stand a pressure difference of 5.5 atm. Assume that outside
air is at 300 K and 1 atm pressure
9. Three hollow metallic boxes A,B and C are connected through a narrow tube of negligible volume
and filled with He gas. If the internal volumes of these boxes are in the ratio of 1:2:4, (i) Find the
molar ratio of He in these boxes (ii) How the molar ratio of He would change if the boxes A,B and
C are immersed in different temperature baths having temperature 270C,1270C,&3270C,
respectively?
10. A two litre sample of ethane gas at 1.00 atm and 298 K is burned in a 2.00 L oxygen gas at a same
temperature and pressure to form carbon dioxide and liquid water. Ignoring the volume of water,
what is the final volume of the reaction mixture at 1.00 atm and 298 K, if the reaction goes to
completion?
11. At 9450Cand 1.0 atm, 1.7 g of H2S occupy a volume of 5.384 L at equilibrium. Calculate the degree
of dissociation of Hydrogen sulphide, if the reaction proceeds according to the equation :
H2S(g) H2 (g) + S(g)
12. 12 g N2, 4 gm H2 and 9 gm O2 are put into a one liter container at 27°C. What is the total pressure?
13. 1.0×10–2 kg of hydrogen and 6.4×10–2 kg of oxygen are contained in a 10×10–3 m3 flask at 473 K.
Calculate the total pressure of the mixture. If a spark ignites the mixture. What will be the final
pressure?
14. A mixture of He and Ne gas is collected over water at 280C and 745 mm of Hg. If the partial
pressure of He is 368 mm of Hg. What is the partial pressure of Ne? Also calculate the weight
percentage of He and Ne in the original mixture. Vapour pressure of water at 280C is 28.3 mm of
Hg.
16. At 627oC and 1.0 atm, SO3 partially dissociates into SO2 and O2. One liter of the equilibrium mixture
weighs 0.94 g under the above conditions. Determine the partial pressure of the constituent gases in
the mixture.
Graham’s Law
17. At room temp , NH3 gas at one atm & HCl gas at “P” atm are allowed to effuse through identical
pin holes to the opposite ends of a glass tube 1m long & uniform cross-section. A white deposit is
observed at a distance of 60 cm from the HCl end. What is “P”.
18. A gas mixture contains equal number of molecules of N2 and SF6 , some of it is passed through
a gaseous effusion apparatus . Calculate how many molecules of N2 are present in the product
gas for every 100 molecules of SF6
19. Pure O2 diffuses through an aperture in 224 sec, whereas mixture of O2 and another gas containing
80% O2 by moles diffuses from the same in 234 sec. What is molecular weight of the gas?
20. The ratio of rates of effusion of two gases A and B is 1:4. If the ratio of their masses present in the
mixture is 2:3. What is the ratio of their mole fraction in mixture?
21. A gaseous mixture consists of CH4, O2 and SO2 in the weight ratio of 4:2:1. The mixture was then
allowed to effuse through a small hole at a definite temperature. What will be the mole composition
of the mixture leaving the hole initially?
22. 100 cc of iodine vapour at 600C took 125 s to effuse through a pinhole. An equal volume of
oxygen under similar conditions required 50 s. Calculate the degree of dissociation of iodine vapour.
Eudiometry
23. 10 mL of a gaseous hydrocarbon was burnt completely in 80 mL of O2 at NTP. The remaining gas
occupied 70 mL at NTP. This volume became 50 mL on treatment with KOH solution. What is the
formula of the hydrocarbon.
24. 7.5 mL of a gaseous hydrocarbon was exploded with 36 mL of oxygen. The volume of gases on
cooling was found to be 28.5 mL, of which 15ml was absorbed by KOH and the rest was absorbed in
a solution of alkaline pyrogallol. If all volumes are measured under the same conditions, deduce the
formula of the hydrocarbon
25. 10 mL of a gaseous organic compound containing C , H and O only was mixed with 100 mL of
oxygen and exploded under conditions which allowed the water formed to condense. The volume of
the gas after explosion was 90 mL. On treatment with potash solution, a further contraction of 20
mL, in volume was observed. Given that the vapour density of the compound is 23, deduce the
molecular formula. All volume measurements were carried out under the same conditions.
26. 9 volumes of a gaseous mixture consisting of a gaseous organic compound A and just sufficient
amount of oxygen required for complete combusion , yeilded on burning , 4 volumes of CO2 , 6
volumes of water vapour and 2 volumes of N2, all volumes measured at the same temperature and
pressure . If the compound A contained only C , H and N ( i) how many volumes of oxygen are
required for complete combusion , and (ii) what is the molecular formula of the compound A?
27. 50 ml of pure and dry oxygen was subjected to slient electric discharge and on cooling to the original
temperature , the volume of ozonised oxygen was found to be 47 mL. The gas was then brought in
contact with turpentine oil, when after the absorption of ozone, the remaining gas occupied a volume
of 41ml. Find the molecular formula of ozone?
28. 10 mL of a mixture of CO , CH4 and N2 , exploded with excess of oxygen, gave a contraction of 6.5
mL. There was a further contraction of 7 mL when the residual gas treated with KOH. What is the
composition of the original mixture?
29. 5.22 x 10 -4 mole of a gas mixture containing H2, O2 and N2 exerted a pressure of 67.4 mm in a
certain standard volume. The gas was passed over a hot platinum filament which combined H2 and
O2 into H2O which was frozen out. When the gas was returned to the same volume, the pressure was
14.3 mm. Extra oxygen was added to increase the pressure to 44.3 mm. The combusion was repeated
, after which the pressure read 32.9 mm. What was the mole fraction of H2, O2 and N2 in the gas
sample?
31. a) Calculate total energy of one mole of an ideal monatomic gas at 27C?
b) How much thermal energy should be added to 3.45 g Ne in a 10 litre flask to raise the temperature
from 0°C to 100°C. (Atomic weight Ne = 20.18)?
32. At what temperature in °C, the Urms of SO2 is equal to the average velocity of O2 at 27°C.
34. The density of CO at 273 K and 1 atm is 1.2504 kg m–3. Calculate (a) root mean square speed(b) the
average speed and (c) most probable speed.
35. At a certain temperature the speeds of six gaseous molecules in a container are 2.0, 2.2, 2.6, 2.7, 3.3,
and 3.5 ms–1. Calculate the root mean square speed and the average speed of the molecules.
36. A bulb of capacity 1 dm3 contains 1.03 × 1023 H2 molecules & pressure exerted by these molecules
is 101.325 kPa. Calculate the average square molecular speed and the temperature.
37. The critical temperature and pressure of CO2 gas are 304.2K and 72.9 atm respectively. What is the
radius of CO2 molecule assuming it to behave as Vander Waal’s gas?
38. Argon has TC= –122°C PC = 48 atm. What is the radius of the argon atm?
40. Calculate the pressure exerted by 22 g of carbon dioxide in 0.5 dm3 at 298.15 K using:
(a) the ideal gas law and (b) vander waals equation. Given:
6
[a = 363.76 kPa dm mol –2 and b = 42.67 cm3 mol–1]
41. At 273.15 K and under a pressure of 10.1325 MPa, the compressibility factor of O2 is 0.927.
Calculate the mass of O2 necessary to fill a gas cylinder of 100 dm3 capacity under the given
conditions.
42. The vander waals constant for O2 are a = 1.36 atm L2 mol–2 and b = 0.0318 L mol–1. Calculate the
temperature at which O2 gas behaves, ideally for longer range of pressure.
43. The vander Waals constants for gases A, B and C are as follows
Gas a/dm6 kPa mol–2 b/dm3 mol–1
A 405.3 0.027
B 1215.9 0.030
C 607.95 0.032
Which gas has (i) the highest critical temperature, (ii) the largest molecular volume, and (iii) most
ideal behavior around STP?
44. Calculate the pressure of 15 mol neon at 30oC in a 12 lit container using
(i) the ideal gas equation (ii) the vandar waals equation
[a = 0.2107 atm lit2 mol–2, b = 0.0171 lit mol–1]
45. The density of water vapour at 327.6 atm and 776.4 K is 133.2 gm/dm3.
Determine the molar volume, Vm of water and the compression factor.
46. One litre of a gas at 300 atm and 473K is compressed to a pressure of 600 atm and 273 K. The
compressibility factor was found to be 1.072 and 1.375 respectively at the initial and final states.
Calculate the final volume.
7. Helium gas diffuses four times faster than gas X. Molar mass of gas X is
(a) 8 (b)72 (c) 16 (d) 64
8. The average kinetic energy of which of the following gas is highest under same temperature and
pressure?
(a) H2 (b) C2H4 (c) SO2 (d)All are same
9. An LPG cylinder can withstand pressure difference of 15 atm across its boundaries. If at room temp
(270C) it is filled with 2 atm pressure. Determine the temperature at which it will explode?
(a) 2160C (b) 21270C (c) 24000C (d) 270C
10. A balloon having 8 gm Ne gas and radius 20 cm is pricked and 7 gm of Ne gas effused from it. What
will be the radius of balloon under similar conditions :
(a) 5 cm (b) 10 cm (c) 15 cm (d) 20 cm
11. A student put a reaction mixture in a round flask at 270C on the flame. After some time, temperature
of flask was 4770C. What fraction of air would have been expelled out?
(a) 2/5 th (b) 3/5 th (c)1/5 th (d) 4/5 th
12. Temperature and pressure in Delhi is 470C and 800 mmHg whereas in Mumbai is 270C and 750
mmHg. What is ratio of densities of air in Delhi and Mumbai?
(a) 1 : 1.63 (b) 1 : 0.957 (c)1 : 1.12 (d) 1 : 1
13. The density of a gas is 16 at NTP. At what temperature its density will be 14 if pressure remains
constant
(a) 500C (b) 390C (c) 570C (d) 430C
14. A closed flask contains water in all its three states at 00C. In this situation average kinetic energy of
water molecule will be
(a) Same in all the three states (b) the greatest in vapour state
(c) the greatest in liquid state (d) the greatest in solid state
15. Two flasks A and B have capacity 1 L and 2 L and each of them contains 1 mole of a gas. The
temperatures of the flasks are adjusted that average speed of molecules in A is twice as those in B.
The pressure in flask A would be
(a) Same as that in Y (b) half of that in Y
(c) twice of that in Y (d) 8 times of that in Y
16.
Fraction
of
molecules
C1 Velocity
The velocity C1 in the above figure is given by the relation
3RT 2RT 8RT 3RT
(a) C1 (b) C1 (c) C1 (d) C1
M M M M
17. When an ideal gas undergoes unrestricted expansion, no cooling occurs because the molecules
(a) Exert no attractive force on each other (b) Do work equal to loss of kinetic energy
(c) Collide without loss of energy (d) Are above the inversion temperature
20. Vander waal’s constant ‘a’ and ‘b’ are related with
(a) Attractive force and bond energy of molecules respectively
(b) Volume and repulsive forces of molecules respectively
(c) Shape and repulsive forces of molecules respectively
(d) Attractive force and volume of the molecules respectively
21. A gas deviated from ideal behavior at a high pressure because its molecules
(a) have kinetic energy (b) are bound by covalent bonds
(c) have different shape (d) attract one another
22. When do you expect a real gas to behave like an ideal gas?
(a) When both the temperature and pressure are low
(b) When both the temperature and pressure are high
(c) When the temperature is high and pressure is low
(d) When the temperature is low and pressure is high
23. Dominance of strong repulsive forces among the molecules of real gas
(Z = compressibility factor)
(a) Depends on Z and indicated by Z = 1 (b) Depends on Z and indicated by Z < 1
(c) Depends on Z and indicated by Z > 1 (d) Is independent of Z
24. One mole of SO2 gas occupies a volume of 900 ml at 24 atm pressure at 270C. Than
30. At low pressure vander Waal’s equation for 4 moles of a real gas will have its simplified form
PV PV PV PV
(a) = 4 (b) =4 (c) =1 (d) =4
RT Pb 4a RT 4 Pb a
RT RT
V V
to(C) T(K)
3. A quantity of gas is collected in a graduated tube over the mercury. The volume of gas at 18oC is
50.0 mL and the level of mercury in the tube is 100 mm above the outside mercury level. The
barometer reads 750 Torr. Hence, volume at STP is approximately
(A) 22 mL (B) 40 mL (C) 20 mL (D) 44 mL
4. What percent of a sample of nitrogen must be allowed to escape if its temperature, pressure and
volume are to be changed as given?
273oC, 3.00 atm 0oC, 0.75 atm
1.65 L 0.55 L
5. Which of the following relations truly represents macroscopic as well as microscopic model?
1 R M2
(A) KE mu 2 (B) PV = nRT (C) 1 (D) Ptotal = P1 + P2 + P3
2 R2 M1
6. Mole fraction of water vapour in the water saturated air is 0.02. If total pressure is 1.2 atm, partial
pressure of dry air is
(A) 1.18 atm (B) 1.22 atm (C) 1.176 atm (D) 1.224 atm
7. 1 mole of N2O4 (g) at 300 K is kept in closed container under 1 atm. It is heated to 600K when 20%
mass of N2O4(g) decomposes to NO2(g). The resultant pressure is
(A) 1.2 atm (B) 2.4 atm (C) 2 atm (D) 1 atm
8. A closed vessel contains equal volume of N2 & O2 at a pressure of P. If N2 is removed from the
system then the pressure will be
(A) P (B) 2P (C) P/2 (D) P2
9. A spherical air bubble is rising from the depth of a lake where pressure is ‘P’ atm and temperature is
T’ Kelvin. The percentage increase in its radius when it comes to the free surface of lake will be.
(Assume temperature and pressure at the surface be respectively P/4 and 2T Kelvin) :
(A) 100% (B) 50% (C) 40% (D) 200%
10. Excess F2(g) reacts at 150C and 1.0 atm pressure with Br2(g) to give a compound BrFn. If 423 mL
of Br2(g) at the same temperature and pressure produced 4.2 g of BrFn. what is n ? (Br = 80, F = 19)
(A) 3 (B) 1 (C) 5 (D) 7
11. The system shown in the diagram is at equilibrium at 27 o C and volume of the bulb is 150 mL. At
this temperature, the vapour pressure of water is 28 millimetres of mercury. If the bulb contains
0.001 mol of O2(g), volume of the liquid water is approximately
Vacuum
O2(g)
water
161 mm
Hg
(A) 34 mL (B) 10 mL (C) 30 mL (D) 60 mL
Ashwani Tyagi Sir 59 Code: ATJEE / ATNEET
Chemistry Gaseous States
12. In the following figure, when the two stop corks are opened, the total pressure inside the flask will be
CO2
Ar
2.13 atm
1.15 atm
1.5 L H2
2.0 L
1.0 L
0.861atm
13. To determine the molar mass of a liquid, as small sample of the liquid was vaporized in a glass
vessel with a pinhole opening. The volume of the vessel was 115.3mL, and the liquid was
completely vaporized in a boiling water bath at 100C . The atmospheric pressure that day was
743torr. After the vapour was cooled to 25C and had condensed back to a liquid, it was weighed.
The mass of the liquid was 0.4429g. What is the molar mass of the liquid, in units of g/mol?
(A) 120.3 (B) 271.5 (C) 16.03 (D) 96.15
14. Ether was one of the first anesthetics discovered. Assume that several ml of ether are placed in a bulb
with a volume of 293 ml, and the bulb is immersed in water at 36C until the last drop of liquid
disappears, leaving the bulb filled with ether vapour. The bulb is then removed from the water bath,
and the weight of ether that condenses in the bulb is measured. If 0.841 g of ether collects in the
experiment at a pressure of 746 mmHg, what is the molecular weight of ether?
(A) 46 g/mol (B) 60 g/mol (C) 68 g/mol (D) 74 g/mol
3. At 47oC and 16.0 atm, the molar volume of NH3 gas is about 10% less than the molar volume of an
ideal gas. This is due to:
(A) NH3 decomposes to N2 and H2 at 47oC
(B) the force of attraction between NH3 molecules is significant
(C) the volume occupies by NH3 molecules themselves is a significant fraction of the volume of the
container at this temperature and pressure.
(D) at 16 atm, NH3 molecules no longer move randomly
5. The time taken for effusion of 32mL of oxygen will be the same as the time taken for
effusion under identical conditions of
(A) 64mL ofH2 (B) 50mL of N2 (C) 27.3mL of CO2 (D) 22.62mL of SO2
6. The diagram displays the plot of the compression factor Z versus p for a few gases.
Which of the following statement(s) is (are) correct for a van der Waals’ gas?
I IV
III
II
p
(A) The plot I is applicable provided the van der Waals’ constant a is negligible.
(B) The plot II is applicable provided the van der Waals’ constant b is negligible.
(C) The plot III is applicable provided the van der Waals’ constant a and b are negligible.
(D) The plot IV is applicable provided the temperature in the gas is much higher than its
critical temperature.
7. Knowing that average kinetic energy of an ideal gas (X) is directly proportional to absolute
temperature, if T1 = 273K, which statement(s) describe(s) the other curves?
A
Fraction of molecules
at a given velocity
T1(x)
B
Velocity
10. Which of the following statements regarding compression factor is/are correct?
(A) Z for an ideal gas is independent of temperature and pressure.
(B) Z for an ideal gas is greater than one.
(C) Z for a non–ideal gas can be greater than or less than unity depending on T and P.
(D) When Z<1, intermolecular attraction dominates over intermolecular repulsion.
11. The correct statements regarding various types of molecular speeds is/are
(A) Increasing temperature increases the fraction of molecules possessing Umps
(B) Increasing temperature increases Umps.
(C) In a sample of gas, at a given temperature molecules with extremely low and extremely high
speeds are both very less likely.
(D) At the same temperature, lighter gases have narrow distribution of molecular speeds than the
heavier gases.
12. The given graph represents variation of (compressibility factor) versus p, for three real gases A, B
and C. Which of the following statement(s) is/an correct?
A C
Z
p
(A) For the gas A, a = 0 and its dependence on p is linear at all pressures.
(B) For the gas B, b = 0 its dependence on P is linear at all pressures.
(C) For the gas C, which is a typical real gas for which neither ‘a’ nor ’b’ is zero. By knowing the
minima and point of intersection, with Z = 1, ‘a’ and ‘b’ can be determined.
(D) At high pressure, slope is positive for all gases.
13. When gas is expanded at constant temperature
(A) pressure decreases
(B) the average kinetic energy of molecules remain the same
(C) the average kinetic energy decreases
(D) the average kinetic energy increases
14. A mixture of 100 ml CO, CO2 and O2 was sparked. When the resulting gaseous mixture was passed
through KOH solution, contraction in volume was found to be 80 ml, the composition of initial
mixture may be (in the same order)
(A) 30 ml, 60 ml, 10ml (B) 30 ml, 50ml, 20ml
(C) 50 ml, 30 ml, 20ml (D) 30ml, 40ml, 30ml
15. An organic compound is burnt with excess of O2 to produce CO2(g) and H2O(l), which results in
25% volume contraction. Which of the following option(s) satisfy the given conditions.
(A) 10 ml C3H8 + 110 ml O2 (B) 20 ml C2H6 O + 80 ml O2
(C) 10 ml C3H6O2 + 50 ml O2 (D) 40 ml C2H2O4 + 60 mlO2
16. A mixture of C3H8 (g) & O2 having total volume 100 ml in an Eudiometry tube is sparked & it is
observed that a contraction of 45 ml is observed. What can be the composition of reacting mixture?
(A) 15 ml C3H8 & 85 ml O2 (B) 25 ml C3H8 & 75 ml O2
(C) 45 ml C3H8 & 55 ml O2 (D) 55 ml C3H8 & 45 ml O2
COMPREHENSION TYPE
PASSAGE−1
The behaviors of gases has been expressed in terms of various gas laws obtained experimentally i.e.
Boyle’s law, Charles’ law Pressure – temperature law, Dalton’s law of partial pressure, Graham’s
law of diffusion and Avogadro’s hypothesis. Later on Maxwell derived kinetic equation
1
PV mnu 2 , theoretically by assuming the concept of molecules and their motion. The terms u
3
represents root mean square speed of molecule.
P V V
1. For one mole of an ideal gas is equal to:
T V T P P T
R2 R2
(A) 2 (B) 2 (C) + 1 (D) – 1
P P
2. The intercept of plots of log V vs log T curves at constant pressure P for 1 mole gas will
be :
P P R R
(A) log (B) log (C) log (D) log
R R P P
3. If intermolecular forces vanishes among water molecules, then volume occupied by 1.8 g H2O (l) at
STP is :
(A) 2.24 litre (B) 22.4 litre (C) 1.8 mL (D) 2.24 mL
5. The root mean square speed of gas at 300 K is 3 R . The molar mass of gas in kg/mol is
(A) 1 (B) 10 (C) 100 (D) 1,000
PASSAGE−2
On the recently discovered 10th planet it has been found that the gases
follow the relationship PeV 2 nCT , where C is a constant, other notation
are as usual (V in lit., P in atm and T in Kelvin). A curve is plotted
between P and V at 500 K & 2 moles of gas as shown in figure:
2. Find the slope of the curve plotted between P Vs T for closed container of volume 2 lit. having same
moles of gas
(A) e (B) 2000e (C) 500e (D) 2
2000 1000e
3. If a closed container of volume 200 lit. of O2 gas (ideal gas) at 1 atm & 200 K is taken to planet. Find
the pressure of oxygen gas at the planet at 821 K in same container
(A) 10100
atm (B) 2050
atm (C) 1 atm (D) 2 atm
e e
PASSAGE−3
A gas present in a container connected to frictionless, weightless piston acting as a sieve operating
always at one atmosphere pressure such that it permits flow of gas outside (with no adding of gas).
The graph of n (No. of moles) vs T (Kelvin) was plotted & was found to be a straight line with
co-ordinates of extreme points as (300, 2) & (200, 3).
1 atm
(200, 3)
Number
of
moles
(300, 2)
n
T
Temperature(K)
2. The best fit relationship between V & T: (Assuming gas inside is ideal gas)
RT 2 2 3 2
(A) V RT (B) V RT 5 RT (C) V RT 5RT 2 (D) V RT
100 100 200 100
PASSAGE−4
First complete data on pressure - volume -temperature relations
of a substance in both gaseous and liquid state was obtained by
Thomas Andrews on carbon dioxide. He plotted isotherms of
carbon dioxide at various temperatures. Later on it was found 60oC
that real gases behave in the same manner as carbon dioxide. 50oC
Andrews noticed that at high temperatures isotherms look like P
that of an ideal gas and the gas cannot be liquefied even at very 31.1oC
2. The critical temperatures for gases A, B, C and D are 126.0K, 154.3K, 304.15K and 405.5K
respectively. Which gas shows greater negative deviation from ideal behavior with increase in
pressure?
(A) A (B) B (C) C (D) D
PASSAGE−5
The apparatus shown consists of three temperature jacketed 1.000 L bulbs connected by stopcocks.
Bulb A contains a mixture of H2O(g), CO2(g) and N2(g) at 250C and a total pressure of 564 mm
Hg. Bulb B is empty and is held at a temperature of –700C. Bulb C is also empty and is held at a
temperature of
–1900C. The stopcocks are closed, and the volume of the lines connecting the bulb is zero. CO2
sublimes at –780C, and N2 boils at –1960C.
1. The stopcock between A and B is opened and the system is allowed to come to equilibrium. The
pressure in A and B is now 219 mm Hg. Select the correct alternate:
(A) A contains CO2(g) and N2(g) and B contains CO2(g), N2(g) and H2O(s)
(B) A contains CO2(g) and B contains N2(g) and H2O(l)
(C) A contains CO2(g), N2(g) and H2O(s) and B contains CO2(g) and N2(g)
(D) A contains H2O(g) and B contains H2O(g), N2(g) and CO2(g)
2. How many moles of H2O are in the system?
(A) 0.026 mol (B) 0.0013 mol (C) 0.013 mol (D) 0.13 mol
3. Both stopcocks are opened and the system is again allowed to come to equilibrium. The pressure
throughout the system is 33.5 mm Hg. Select the correct alternate.
(A) Each bulb contains N2 (g), H2O(s) and CO2(g)
(B) Each bulb contains N2(g), H2O(g) and CO2(g)
(C) Each bulb contains N2(g), H2O(s) and CO2(s)
(D) A contains N2(g), B contains N2(g), H2O(s); C contains N2(g) and CO2(s)
4. How many moles of N2 are in the system?
(A) 0.022 mol (B) 0.011 mol (C) 0.018 mol (D) 0.036 mol
PASSAGE−6
The constant motion and high velocities of gas particles lead to some important practical
consequences. One such consequence is that gases mix rapidly when they come in contact. Take the
stopper off a bottle of perfume, for instance, and the odour will spread rapidly through the room as
perfume molecules mix with the molecules in the air. This mixing of different gases by random
molecular motion and with frequent collisions is called diffusion. A similar process in which gas
molecules escape without collision through a tiny hole into a vacuum is called effusion.
1. When CO2 under high pressure is released from a fire extinguisher, particles of solid CO2 are
formed despite the low sublimation temperature (-770C) at 1 atm. It is due to:
(A) The gas does work pushing back the atmosphere using kinetic energy of molecules and thus
lowering the temperature.
(B) Volume of the gas is decreased rapidly hence temperature is lowered.
(C) Both of the above (D) None of the above
2. The stopcocks of the bulbs X (containing NH3) and Y (containing HCl) are opened simultaneously;
white fumes of NH4Cl and formed at point B. If AB = 36.5 cm, then BC is approximately:
PASSAGE: 7
A sealed flask 1 contains two different gases A and B and their root mean square speeds are 500 and
400 metre per second respectively. Now this flask is connected to another flask 2, containing only A
with their root mean square speed 400 ms–1, by means of a narrow tube of negligible volume and
gases in the two flask were allowed to mix up.
PASSAGE 8
When air from an air balloon is replaced by gases like H2, He, CH4 etc, gas filled balloon rises from
the surface. If the air is replaced by any of the above mentioned gas maintaining same pressure,
volume and temperature, the maximum weight that the gas filled balloon can lift is known as “
Payload” of balloon and is determined as
Payload = Weight of air – Weight of gas – Weight of balloon
1. What is the most appropriate reason for the rise of gas filled balloon ?
(A) Lighter gas will have higher kinetic energy than the air molecule.
(B) Lighter gas are more likely to behave like an ideal gas
(C) Lower density of gas in gas filled balloon than air in air filled balloon.
(D) Air is mixture of several gases.
2. Which of the following gas when filled in a balloon will rise to the same height as a He–gas filled
under identical condition of P, V and T ?
(A) H2(g) (B) D2(g) (C) Ne(g) (D) CH4(g)
3. If a massless balloon is filled to 100 L with He gas at 300K and one atm, the payload of this balloon
will be (in gram unit)? Assume air to be a mixture of 80% N2(g) and 20% O2(g) by volume and
atmospheric condition is 1.0 atm and 300 K.
(a) 50 (b) 100 (c) 134 (d) 17
PASSAGE – 9
A 10 ml mixture of N2, alkane & O2 undergo combustion in the Eudiometry tube. When the residual
gases were passed through KOH, a contraction of 2ml was observed. To the remaining mixture
(comprising of only one gas) excess H2 was added & after the reaction the gas produced was absorbed
by water, causing a reduction in volume of 8 ml.
MATCHING TYPE
1. Match the gases with the associated conditions in the left column with their corresponding properties
in the right column.
Column I Column II
(A) H2{p = 200 atm, T = 273K} (P) Z 1
(B) H2 [p ~ 0, T = 273] (Q) Attractive force dominating
(C) CO2(g) [p = 1 atm, T = 273] (R) pV = nRT
(D) CO2(g) [p = 200 atm, T = 273] (S) Repulsive force dominating
2. Match the properties in the left column with corresponding functions in the right column.
Column I Column II
(A) Compression factor (Z) of (P) 8a
ideal gas 27 Rb
3. Match the kinetic properties in the left column with their corresponding expression in the right column.
Column I Column II
(A) RMS speed (P) 8RT
M
(B) Average speed (Q) 1 mn(c)2
3 V
(C) Most probable speed (R) 3RT
M
(D) Pressure by kinetic theory (S) 2RT
M
4.
Column – I Column – II (In a closed rigid vessel)
(A) Density of gas (P) Depends on absolute temperature.
(B) Average KE of gas (Q) Depends on molecular mass of gas.
(C) Root mean square speed (R) Depends on total molecules of gas
(D) Effusion rate of gas (S) Independent of molecular mass of gas
3. For an ideal gas, number of moles per litre in terms of its pressure P, gas constant R and
Temperature T is: [AIEEE - 2002]
(A) PT/R (B) PRT (C) P/RT (D) RT/P
4. According to kinetic theory of gases in an ideal gas between two successive collisions a gas
molecule travels: [AIEEE - 2003]
(A) In a straight line path (B) With an accelarated velocity
(C) In a circular path (D) In a wavy path
5. What volume of hydrogen gas, at 273 K and 1 atm pressure will be consumed in obtaining 21.6g
of elemental boron (atomic mass = 10.8) from the reduction of boron trichloride by hydrogen?
[AIEEE - 2003]
(A) 89.6 L (B) 67.2 L (C) 44.8 L (D) 22.4 L
6. As the temperature is raised from 20oC to 40oC, the average kinetic energy of neon atoms
Changes by a factor : [AIEEE - 2004]
313 313 1
(A) 2 (B) (C) (D)
293 293 2
7. In vander Waal’s equation of state of the gas law, the constant ‘b’ is a measure of :[AIEEE - 2004]
(A) Intermolecular collisions per unit volume (B) Intermolecular attractions
(C) Volume occupied by the molecules (D) Intermolecular repulsions
8. Which one of the following statements is not true about the effect of an increase in temperature
on the distribution of molecular speeds in a gas ? [AIEEE - 2005]
(1) The area under the distribution curve remains the same as under the lower temperature
(2) The distribution becomes broader
(3) The fraction of the molecules with the most probable speed increases
(4) The most probable speed increases
10. Equal masses of methane and oxygen are mixed in an empty container at 25°C. The fraction of the
[AIEEE – 2007]
total pressure exerted by oxygen is
(A) 1/2 (B) 2/3 (C) (1/3) X (273/298) (D) 1/3.
11. If 10 –4 dm 3 of water is introduced into a 1.0 dm 3 flask to 300 K, how many moles of water are in
the vapour phase when equilibrium is established ? (Given : Vapour pressure of H2O at 300 K is
3170 Pa ; R = 8.314 J K –1 mol –1 ) [AIEEE – 2010]
–3 –2 –2
(A) 5.56 x 10 mol (B) 1.53 x 10 mol (C) 4.46 x 10 mol (D) 1.27 x 10 –3 mol
1. The ratio of root mean square to average velocity of a gas molecule at a particular temperature is
(JEE 1981)
(a) 1.086 : 1 (b) 1:1.086 (c) 2:1.086 (d) 1.086:2
2. The temperature at which a real gas obeys the ideal gas laws over a wide range of pressure is
(JEE 1981)
(a) Critical temperature (b) Boyle temperature
(c) inversion temperature (d) reduced temperature
3. Equal weights of methane and oxygen are mixed in an empty container at 25°C. The fraction of the
total pressure exerted by oxygen is (JEE 1981)
1 1 2 1 273
(a) (b) (c) (d)
3 2 3 3 298
4. Helium atom is two times heavier than a hydrogen molecule. At 298 K, the average kinetic energy of a
helium atom is (JEE 1982)
(a) two times that of a hydrogen molecule (b) same as that of a hydrogen molecule
(c) four times that of a hydrogen molecule (d) half that of a hydrogen molecule
5. When an ideal gas undergoes unrestrained expansion, no cooling occurs because the molecules
(JEE 1984)
(a) are above the inversion temperature (b) exert no attractive forces on each other
(c) do work equal to loss in kinetic energy (d) collide without loss of energy
6. Equal weight of methane and hydrogen are mixed in an empty container at 25°C. The fraction of the
total pressure exerted by hydrogen is (JEE 1984)
1 8 1 16
(a) (b) (c) (d)
2 9 9 17
7. A liquid is in equilibrium with its vapour at its boiling point. On the average, the molecules in the two
phases have equal (JEE 1984)
(a) inter – molecular force (b) potential energy
(c) kinetic energy (d) total energy
9. The average velocity of an ideal gas molecular at 27° C is 0.3 m/s. The average velocity at 927° C will
be (JEE 1986)
(a) 0.6m/s (b) 0.3m/s (c) 0.9m/s (d) 3.0m/s
10. In van der Waals equation of state for a non-ideal gas, the term that accounts for intermolecular forces is
(JEE 1988)
a
(a) (V-b) (b) RT (c) p 2 (d) (RT)-1
V
11. A bottle of dry ammonia and a bottle of dry hydrogen chloride connected through a long tube are
opened simultaneously at both ends the white ammonium chloride ring first formed will be
(JEE 1988)
(a) at the centre of the tube (b) near the hydrogen chloride bottle
(c) near the ammonia bottle (d) throughout the length of the tube
12. The value of van der Waals’ constant ‘a’ for the gases O2, N2 , NH3 and CH4 are 1.360 , 1.390, 4.170
and 2.253 L2 atm mol-2 respectively. The gas which can most easily be liquefies is
(JEE 1989)
(a) O2 (b) N2 (c) NH3 (d) CH4
14. The rate of diffusion of methane at a given temperature is twice that of a gas X. The molecular weight
of X is (JEE 1990)
(a) 64.0 (b) 32.0 (c) 4.0 (d) 8.0
15. According to kinetic theory of gases, for a diatomic molecule (JEE 1991)
(a) the pressure exerted by the gas is proportional to mean velocity of the molecule
(b) The pressure exerted by the gas is proportional to the root mean velocity of the molecule
(c) The root mean square velocity of the molecule is inversely proportional to the temperature
(d) the mean translational kinetic energy of the molecule is proportional to the absolute temperature
16. At constant volume, for a fixed number of moles of a gas the pressure of the gas increases with rise of
temperature due to (JEE 1992)
(a) increases in average molecular speed
(b) increases rate of collisions amongst molecules
(c) increase in molecular attraction
(d) decrease in mean free path
17. Equal weights of ethane and hydrogen are mixed in an empty container at 25°C the fraction of the total
pressure exerted by hydrogen is (JEE 1993)
(a) 1:2 (b) 1:1 (c) 1:16 (d) 15:16
18. The ratio between the root mean square speed of H2 at 50 K and that of O2at 800 K is (JEE 1996)
1
(a) 4 (b) 2 (c) 1 (d)
4
20. The critical temperature of water is higher than that of O2 because the H2O molecule has
(JEE 1997)
(a) fewer electrons thanO2 (b)two covalent bonds
(c) V-shape (d) dipole moment
r
21. According to Graham’s law, at a given temperature the ratio of the rates of diffusion A of gases A and
rB
B is given by (where, p and M are pressures and molecular weights of gases A and B respectively)
(JEE 1998)
1 1 1 1
p M 2 M p 2 p M 2 M p 2
(a) A A (b) A A (c) A B (d) A B
pB M B M B pB pB M A M B pA
23. The rms velocity of hydrogen is 7 times the rms velocity of nitrogen. If T is the temperature of the
gas (JEE 2000)
(a) T (H2) = T(N2) (b) T(H2) > T(N2) (c) T(H2) <T(N2) (d) T(H2) = 7 T(N2)
24. The compressibility of a gas is less than unity at STP. Therefore, (JEE 2000)
(a) Vm> 22.4L (b) Vm< 22.4 L (c) Vm = 22.4L (d) Vm = 44.8L
25. At 100°C and 1 atm if the density of the liquid water is 1.0g cm-3 and that of water vapour is 0.0006 g
cm-3 , then the volume occupied by water molecules in 1 L of steam at this temperature is
(JEE 2000)
3 3 3 3
(a) 6cm (b) 60cm (c) 0.6cm (d) 0.06cm
26. The root mean square velocity of an ideal gas at constant pressure varies with density (d) as
(JEE 2001)
2
(a) d (b) d (c) d (d) 1/ d
27. Which of the following volume (V) temperature (T) plots represents the behaviour of one mole of an
ideal gas at the atmospheric pressure? (JEE 2002)
V(L) (38.8 L, V(L) (28.6 L,
373K) 373K)
(22.4L, (20.4L,
273K) 273K)
T(K) T(K)
(a) (b)
V(L) (30.6 L, V(L)
373K)
(22.4L, (22.4L,
273K) (14.2 L,
273K) 373K)
T(K) T(K)
(c) (d)
28. Positive deviation from ideal behaviour takes place because of (JEE 2003)
(a) molecular interaction between atom and pV/nRT>1
(b) molecular interaction between atom and pV/nRT < 1
(c) finite size of atoms and pV/nRT > 1
(d) finite size of atom and pV/nRT < 1.
29. For a monatomic gas kinetic energy = E. The relation with rms velocity is (JEE 2004)
1/2 1/2 1/2 1/2
2E 3E E E
(a) u (b) u (c) u (d) u
m 2m 2m 3m
30. If helium and methane are allowed to diffuse out of the container under the similar conditions of
temperature and pressure, then the ratio of rate of diffusion of helium to methane is (JEE 2009)
(a) 2.0 (b) 1.0 (c) 0.5 (d) 4.0
31. The term that corrects for the attractive forces present in a real gas in the van der Waals’ equation is
(JEE 2009)
(a) nb (b) n2 a/V2 (c) –(n2a/V2) (d) -nb
C
A
A
1 Idealgas
B
Z C
B
O P atm
Identify the only incorrect statement
(a) For the gas A, a=0 and its dependence on p is linear at all pressure.
(b) For the gas B, b = 0 and its dependence on p is linear at all pressure.
(c) For the gas C, which is typical real gas for which neither a nor b = 0. By Knowing the minima and
the point of interaction, with Z = 1, a and b can be calculated.
(d) At high pressure, the slope is positive for all real gases.
(a) Statement I is true ; Statement II is true; Statement II is the correct explanation of Statement I.
(b) Statement I is true; Statement II is true; Statement II is not the correct explanation of Statement I.
(c) Statement I is true; Statement II is false.
(d) Statement I is false; Statement II is true.
1. Statement I : The value of Van der Waal’s constant ‘a’ is larger for ammonia than for nitrogen.
Statement II: Hydrogen bonding is present in ammonia. (JEE 1998)
2. Statement I: The pressure of a fixed amount of an ideal gas is proportional to its temperature.
Statement II : Frequency of collisions and their impact both increase in proportion to the square root of
temperature. (JEE 2000)
True/ False
1. Kinetic energy of a molecule is zero at 0°C. (JEE 1985)
2. A gas in a closed container will exert much higher pressure due to gravity at the bottom than at the top.
(JEE 1985)
n 2a
3. In the van der Waals’ equation, p 2 (V nb) nRT
V
The constant ‘a’ reflects the actual volume of the gas molecules. (JEE 1993)
4. A mixture of ideal gases is cooled up to liquid helium temperature (4.22K) to form an ideal solution.
(JEE 1996)
Integer type Questions
1. To an evacuated vessel with movable piston under external pressure of 1 atm 0.1 mole of He and 1.0
mole of an unknown compound (vapour pressure 0.68 atm at 0° C) are introduced. Considering the
ideal gas behaviour, the total volume (in litre) of the gases at 0° C is close to
(JEE 2011)
Subjective Questions:
1. Calculate the density of NH3 at 30° C and 5 atm pressure. (JEE 1978)
2. 4.215 g of metallic carbonate was heated in a hard glass tube, the CO2 evolved was found to measure
1336 mL at 27°C 700 mm of Hg pressure. What is the equivalent weight of the metal?
(JEE 1979)
3. 3.7g of a gas at 25°C occupied the same volume as 0.184 g of hydrogen at 17°C and at the same
pressure. What is the molecular weight of the gas? (JEE 1979)
4. A hydrocarbon contains 10.5g of carbon per gram of hydrogen. 1L of the vapour of the hydrocarbon at
127°C and 1 atm pressure weighs 2.8 g. Find the molecular formula of the hydrocarbon.
(JEE 1980)
5. The pressure in a bulb dropped from 2000 to 1500 mm of mercury in 47 min when the contained
oxygen leaked through a small hole. The bulb was then evacuated. A mixture of oxygen and another
gas of molecular weight 79 in the molar ratio of 1:1 at a total pressure of 4000 mm of mercury was
introduced. Find the molar ratio of the two gases remaining in the bulb after a period of 74 min.
(JEE 1981)
6. Calculate the average kinetic energy, in joule per molecule in 8.0g of methane at 27°C.
(JEE 1982)
7. At room temperature, ammonia gas at 1 atm pressure and hydrogen chloride gas at p atm pressure are
allowed to effuse through identical pin holes from opposite ends of a glass tube of one metre length and
of uniform cross-section. Ammonium chloride is first formed at a distance 60cm from the end through
which HCl gas is sent in. What is the value of p? (JEE 1982)
8. When 2g of a gas A is introduced into an evacuated flask kept at 25°C, the pressure is found to be one
atmosphere. If 3g of another gas B is then added to the same flask,the total pressure becomes 1.5 atm.
Assuming ideal gas behaviour, calculate the ratio of the molecular weight MA : MB.
(JEE 1983)
9. Oxygen is present in one litre flask at a pressure of 7.6 × 10-10 mm Hg. Calculate the number of Oxygen
molecules in the flask at 0°C. (JEE 1983)
11. Calculate the root mean square velocity of Ozone kept in a closed vessel at 20°C and 82 cm mercury
pressure. (JEE 1985)
Ashwani Tyagi Sir 75 Code: ATJEE / ATNEET
Chemistry Gaseous States
12. A spherical balloon of 21 cm diameter is to be filled up with hydrogen at NTP from a cylinder
containing the gas at 20 atmospheres at 27°C. If the cylinder can hold 2.82 L of water, calculate the
number of balloons that can be filled up. (JEE 1987)
13. The average velocity at T1 K and the most probable at T2 K of CO2 gas is 9.0 ×104 cms-1. Calculate the
values of T1 and T2. (JEE 1990)
14. Calculate the volume occupied by 5.0 g of acetylene gas at 50°C and 740 mm pressure.
(JEE 1991)
15. At 27° C, hydrogen is leaked through a tiny hole into a vessel for 20 min. Another unknown gas at the
same temperature and pressure as that of hydrogen is leaked through same hole for 20min. After the
effusion of the gases the mixture exerts a pressure of 6 atm. The hydrogen content of the mixture is 0.7
mole. If the volume of the container is 3 L. What is the molecular weight of the unknown gas?
(JEE 1992)
17. A gas bulb of 1 L capacity contains 2.0 ×1021 molecules of nitrogen exerting a pressure of 7.57 × 103
Nm-2. Calculate the root mean square speed and the temperature of the gas molecules. If the ratio of the
most probable speed to root mean square speed is 0.82, calculate the most probable speed for these
molecules at this temperature. (JEE 1993)
18. A 4 : 1 molar mixture of He and CH4 is contained in a vessel at 20 bar pressure. Due to a hole in the
vessel, the gas mixture leaks out. What is the composition of the mixture effusing out initially?
(JEE 1994)
19. An LPG (liquefied petroleum gas) cylinder weighs 14.8 kg when empty. When full it weighs 29.0 kg
and shows a pressure of 2.5 atm. In the course of use at 27°C, the weight of the full cylinder reduces to
23.2 kg. Find out the volume of the gas in cubic meters used up at the normal usage conditions, and the
final pressure inside the cylinder. Assume LPG to the n-butane with normal boiling point of 0°C.
(JEE 1994)
20. A mixture of C2H6 and C2H4 occupies 40L at 1.00 atm and at 400K. The mixture reacts completely
with 130g of O2 to produce CO2 and H2O. Assuming ideal gas behaviour, calculate the mole fractions of
C2H4 and C2H6 in the mixture. (JEE 1995)
21. The composition of the equilibrium mixture (Cl2⇌ 2Cl) which is attained at 1200°C, is determined by
measuring the rate of effusion through a pin-hole. It is observed that at 1.80mm Hg pressure, the
mixture effuses 1.16 times as fast as krypton effuses under the same conditions. Calculate the fraction of
chlorine molecules dissociated into atoms (atomic weight of Kr = 84)
(JEE 1995)
22. A mixture of ideal gases is cooled up to liquid helium temperature (4.22 K) to form an ideal solution. Is
this statement true or false? Justify your answer in not more than two lines.
(JEE 1996)
23. An evacuated glass vessel weight 50.0 g when empty 148.0 g when filled with a liquid of density 0.98 g
ml-1 and 50.5 g when filled with an ideal gas at 760 mm Hg at 300 K. Determine the molar mass of the
gas. (JEE 1998)
24. Using vander Waals equation calculate the constant ‘a’ when two moles of a gas confined in a four litre
Flask exert a pressure of 11.0 atm at a temperature of 300 K. The value of ‘b’ is 0.05 L mol-1.
(JEE 1998)
25. (a) One mole of nitrogen gas at 0.8 atm takes 38 s to diffuse through a pin-hole. Whereas one mole of
an unknown compound of xenon with fluorine at 1.6 atm takes 57 s to diffuse through the same hole.
Calculate the molecular formula of the compound.( Given M (Xe) = 131 g/mole)
(b) The pressure exerted by 12g of an ideal gas at temperature t° C in a vessel of volume V litre is one
atm. When the temperature is increased by 10° C at the same volume, the pressure increases by
10%. Calculate the temperature ‘t’ and volume V. (Molecular weight of the gas = 120)
(JEE 1999)
26. Calculate the pressure exerted by one mole of CO2 gas at 273 K if the van der Waals’ constant a = 3.592
dm6 atm mol-2. Assume that the volume occupied by CO2 molecules is negligible.
(JEE 2000)
27. The compression factor (compressibility factor) for one mole of a van der Waals gas at 0° C and 100
atm pressure is found to be 0.5. Assuming that the volume of a gas molecule is negligible, calculate the
van der Waals’ constant ‘a’. (JEE 2001)
28. The density of the vapour of a substance at 1 atm pressure and 500K is 0.36 kg m-3. The vapour effuses
through a small hole at a rate of 1.33 times faster than oxygen under the same condition.
(a) Determine, (i) molecular weight (ii) molar volume (iii) compression factor (z) for the vapour and
(iv) which forces among the gas molecules are dominating, the attractive or the repulsive?
(b) If the vapour behaves ideally at 1000 K, determine the average translational kinetic energy of a
molecule. (JEE 2002)
29. The average velocity of gas molecules is 400 ms-1, find the rms velocity of the gas. (JEE 2003)
30. At 400 K, the root mean square (rms) speed of a gas A (molecular weight = 40) is equal to the most
probable speed of gas Y at 60 K. The molecular weight of the gas Y is ? (JEE 2009)
9. EXPERTISE ATTAINERS
1. A vessel contains 10 g of I2(s) and N2 at a pressure of 10 atm at 25°C. The volume of the vessel is
one litre. If this vessel is connected to a 40 litre empty vessel and the temperature of the first vessel is
increased to 250°C and of the second to 200°C. Calculate the final pressure in vessels.
3. In a space shuttle the CO2 output per astronaut has been estimated as 44g/hr. An experimental
catalytic converter reduces CO2 at a rate of 600 ml STP per minute into H2O. What fraction of time
would such a converter have to operate in order to keep up the CO2 output of one astronaut?
4. A compound exists in the gaseous state both as a monomer (A) and dimer (A2). The molecular weight
of the monomer is 48. In an experiment, 96 g of the compound was confined in a vessel of volume
33.6 litres and heated to 273°C. Calculate the pressure developed, if the compound exists as a dimer to
the extent of 50 per cent by weight, under these conditions (R = 0.082)
5. A mixture of H2O vapour, CO2 and N2 was trapped in a glass apparatus with a volume of 0.731 ml.
The pressure of total mixture was 1.74 mm of Hg at 23°C. The sample was transferred to a bulb in
contact with dry ice (–75°C) so that (H2O)v are frozen out. When the sample returned to normal
value of temperature, pressure was 1.32 mm of Hg. The sample was then transferred to a bulb in
contact with liquid N2 (–95°C) to freeze out CO2. The measured, pressure was 0.53 mm of Hg at
normal temperature. How many moles of each constituent are in mixture?
6. A 50 litre vessel is equally divided into three parts with the help of two stationary semi permeable
membrane (SPM). The vessel contains 60 g H2 gas in the left chamber, 160 g O2 in the middle & 140
g N2 in the right one. The left SPM allows transfer of only H2 gas while the right one allows the
transfer of both H2 & N2. Calculate the final ratio of pressure in the three chambers
7. A closed vertical cylinder is divided into two parts by a frictionless piston, each part contains 1 mole
of air . At 27 ºC the volume of the upper part is 4 times than that of the lower part. Calculate the
temperature when volume of the upper part will be three times than that of the lower part.
8. One mole of an ideal gas is subjected to a process in which P =1 8.21 V where P is in atm & V in litre.
If the process is operating from 1 atm to finally 10 atm (no higher pressure achieved during the
process) then what would be the maximum temperature obtained & at what instant will it occur in the
process.
9. A barometer does not read correctly because of the presence of a small amount of air trapped above
the mercury column. At a pressure of 755 mm of Hg, the barometer reads 748 mm of Hg, and at 740
mm of Hg, it reads 736 mm of Hg. What is the actual pressure if the barometer reads 750 mm of Hg
at a constant temperature
10. A 100 feet long classroom maintains seating rows after every 10 feet and has doors on both front and
back sides. A N2O (laughing gas) gas cylinder and a methane (tear gas) cylinder were opened
simultaneously at the front and the back door, respectively.
(a) Student of which row, from front, will first get rid off tear ?
(b) Student of which row, from front, will first shed tear while laughing? Assume, both the gases
were present at the same temperature and pressure and have similar valve dimensions.
11. A one litre flask was evacuated, 5.0 g of liquid ammonia were added to the flask, and the flask was
sealed with a stop cork of radius 1.00 cm. When the ammonia gas in the flask warms up to 21C ,
will the cork be blown out of the mouth of the flask ? Assume that the cork is holding the mouth of
the flask with a force of 200N.
12. What pressure difference must be generated across the length of a 15 cm vertical drinking straw in
order to drink a water like liquid of density 1.0 g/cc?
13. A stockroom supervisor measured the content of a partially filled100 L acetone drum on a day when
the temperature was 18C and the atmospheric pressure was 750 mm of Hg and found that 60 L
solvent remained. After tightly sealing the drum, an assistant dropped the drum while carrying it
upstairs to the organic laboratory. The drum was dented and its internal volume was decreased to 80
L. What is the total pressure inside the drum after the accident? The vapour pressure of acetone at
18C is 400 mm of Hg.
14. A mixture of C5H8 and H2 gas was placed in a container at a constant temperature. Initial volume of
mixture was 10 ml. Sparking the mixture caused hydrogenation reaction
C5 H 8 g 2 H 2 g C5 H12 g
Due to above reaction ( on cooling) volume decreases by 6 ml. Excess of O2 was then added and on
sparking the volume further decreased by 15 ml. Calculate
(i) Volume of each gas in original mixture. (ii) Mole fraction of C5H8 in original mixture.
15. The respiration of the suspension of yeast cells was measured by observing the decrease in pressure of
gas above the cell suspension. The apparatus show that the gas was confined to a constant volume, 16
ml and the entire pressure change was caused by uptake of O2 by the cells. The pressure was
measured in a manometer, the fluid of which had a density of 1.034 gm/ml. The entire apparatus was
immersed in a thermostat at 37°C. In a 30 min. observation period the fluid in open side of
manometer dropped 37 mm. neglecting the solubility of O2 in yeast suspension, compute rate of O2
consumed by the cells in lt of O2 (S.T.P.) per hour.
16. Find the critical constant (Pc, Vc and Tc) in terms of A and B, also find compressibility factor (z) for
A 2B
the following equation of state. PV = RT –
V V2
where A and B are constant, P = pressure and V = molar volume.
17. A thin tube of uniform cross section is sealed at both ends. It lies horizontally. The middle 5 cm
containing Hg and the two equal ends containing air at the same pressure P0. When the tube is held at
an angle 60° with the vertical, the length of air column above and below the mercury are 46 and 44.5
cm respectively. Calculate the pressure P0 in cm of Hg (the temperature of the system is kept at
30°C).
18. Inside the spherical glass flask A of radius 1 m containing 300g of H2 there was a rubber balloon B
containing some N2. Inside the balloon B was another rubber balloon C containing some O2. At 27°C
it was found that the balloon B had a radius of 60 cm and balloon C had a radius of 30 cm. Calculate
total weight of gases inside the flask. If another 50 gm of H2 was not introduced in flask A, what
would be the volume of B & C. If the flask is now dipped in a bath containing acetone and dry ice (–
78°C) for sufficient time the temperature of the entire contents would reacts the bath temperature.
Assuming that at this temperature rubber cracks up and both the balloons burst what would be
pressure inside flask.
19. A mixture of CH4 & O2 is used as an optimal fuel if O2 is present in thrice the amount required
theoretically for combustion of CH4. Calculate number of effusions steps required to convert a
mixture containing 1 part of CH4 in 193 parts mixture (parts by volume). If calorific value (heat
evolved when 1 mole is burnt) of CH4 is 100 cal/mole & if after each effusion 90% of CH4 is
collected, find out what initial mole of each gas in initial mixture required for producing 1000 cal of
energy after processing. [Given (0.9)5 = 0.6]
20. Find out the percentage of molecule in a gas at 1 atm and 27°C whose kinetic energy lies in the
3
range of E and E + 0.01E. [Where E = kT]
2
21. If volume occupied by CO2 molecules is negligible, then calculate the pressure exerted by one mole
of CO2 gas at 273 K. a = 3.592 atm litre2 mole−2.
1
1 3
20
24
21 32 : 4 2 :1
22 27%
23 C2H4
24 C2H4
25 C2H6O
26 C2H6N2, 7ml
27 O3
28 Vol. of CO = 5 ml, Vol. of CH4 = 2 ml , Vol. of N2 = 3 ml
29 0.638 , 0.262 , 0.1
30 a)1.16 107 cm/sec b)1.632
31 a)900 cals b)51.29 cal
32 236°C
33 1.83 x 10 3 m/sec
34 URMS = 493 m/s ,Ump = 403m/s Uav=454.4 m/s
35 RMS = 2.77 m/s,
average speed = 2.716 m/s
36 942 m /s ; 71.2 K
37 1.62Å
38 1.47 10–8 cm
39 58.997 cm3
40 (a) 2.479 × 103 kPa, (b) 2225.55 kPa
41 15.40 kg
42 521 K
43 (i) B, (ii) C, (iii) A
44 (i) 31.1 atm, (ii) 31.4 atm
45 Molar vol = 0.1353 L/mol, Z = 0.6957
46 370 cc
Get Equipped for IIT-JEE (MAIN)
COMPREHENSION TYPE
PASSAGE−1 1. A 2. C 3. A 4. A 5. C
PASSAGE−2 1.B 2. D 3. A
PASSAGE−3 1.C 2. B 3. B 4. D
PASSAGE−4 1.B 2. D 3. B
PASSAGE−5 1.A 2. B 3. D 4. B 5. C
PASSAGE−6 1. A 2. B
PASSAGE – 7 1.D 2. B 3.C
PASSAGE – 8 1.C 2. B 3. B
PASSAGE – 9 1.D 2.B 3.C 4.A
MATCHING TYPE
1. A – p,s ; B – r, C – p,q; D – p,s
2. A–r; B – s, C – q; D–p
3. A–r; B – p, C – s; D–q
4. A p, q; B p, s; C p, q; D p, q, r
Objective questions II
1. (a,b) 2. (b) 3. (a,c) 4. (a,c,d)
True/False
1. F 2. F 3. F 4. F
Expertise Attainers
1. 0.4254 atm 2.3 cm 3.0.622 4. 2 atm
–8 –8 –8
5. 2.1 10 , 3.1 10 , 1.7 10 6. 4 : 7 : 5 7. 421.9 K
8. 10,000 K 9. 758 mm of Hg
th rd
10. (a) 4 row (b) 3 row
11. Yes, since the force exerted by gas on cork is 226 N which is more than 200 N
12. 1.5 kPa 13. 1100 mm of Hg 14. (i) 4 ml C5H8, 6 ml H2 (ii) 0.4
-4
15. 064 × 10 ltr/hr
6B A2 A3 P V 1
16. VC = ,TC = , PC = 2
, compressibility factor = C C =
A 6RB 108B RTC 3
17. 75.4 cm 18. 0.768 atm