Doubt

Q: Find R/S configuration.

6.
 Doubt
Odd exchange rule :

Even exchange rule :

 Doubt

Rotation rule :
 Doubt

Rule III – When 4th priority group is present at solid line then make it at Dash
position by odd exchange method.

We know that in odd exchange the configuration gets reversed. So here if B structure has
R configuration then A structure will have S configuration.
 Ans of HOME WORK on 30-11-20
Q:1 Find R/S configuration.

1. 2. 3.

S S S

4. 5.

S R
Q:2 Find R/S configuration.

1. 2. 3.

R
R SS R
R

4. 5. 6. SS

R
R
R
R SS

7. 8.
R S 9.
R
R
S R
S
SS
 Doubt

8.
 Doubt

9.
Optical Isomerism
 Optical Isomerism

1. Senior most FG should be TOP POSITION in Fischer projection.

2. Now check bottom chiral center. If H & OH or H & NH2 group must
be at horizontal line. If not present then make it at horizontal line
by exchange rule or rotation rule.
3. Now check position of OH/NH2 group…….
position of –OH or –NH2 at right side = D
position of –OH or –NH2 at left side = L

1. 2. 3. 4.
 Optical Isomerism

5. 6.
 Optical Isomerism

7.

8.
9.
Important : 1. Difference between, d,l,D,L.

Here d,l = Direction of optical rotation D,L= Relative configuration

2.we can make L form by taking making FULL mirror image of given D compound.

Q Find L form of following compound ?

Optical Isomerism
 Optical Isomerism

There are two elements of symmetry-

A plane of symmetry is an imaginary plane that bisects a molecule into
halves that are mirror images of each other.
Q: Find POS ?

2.
1.

3. 4.
5.

6.
7. 8.

9. 10.
 Optical Isomerism

It is a point within a molecule from which lines drawn to opposite direction meet
similar points at exactly the same distance and direction.
COS never present in Fischer projection and Odd membered ring.
Q: Find COS ?

COS never present in Fischer projection and Odd membered ring.

 Optical Isomerism

COS never present in Fischer projection and Odd membered ring.

Optical Isomerism
 Optical Isomerism

Nonsuperimposable superimposable
Mirror images Mirror images
HOME WORK on 01-12-20

Chapter: Isomerism
B.Box 4
Ex 1= Q 11,
Ex 2= Q 2,13
Ex 3= Q 3